Unmanaged Environments Research Articles

Mono-material product design with bio-based, circular, and biodegradable polymers

Mono-material product design with bio-based, circular, and biodegradable polymers

Recent Advances in Bioplastics: Application and Biodegradation.

The success of oil-based plastics and the continued growth of production and utilisation can be attributed to their cost, durability, strength to weight ratio, and eight contributions to the ease of everyday life. However, their mainly single use, durability and recalcitrant nature have led to a substantial increase of plastics as a fraction of municipal solid waste. The need to substitute single use products that are not easy to collect has inspired a lot of research towards finding sustainable replacements for oil-based plastics. In addition, specific physicochemical, biological, and degradation properties of biodegradable polymers have made them attractive materials for biomedical applications. This review summarises the advances in drug delivery systems, specifically design of nanoparticles based on the biodegradable polymers. We also discuss the research performed in the area of biophotonics and challenges and opportunities brought by the design and application of biodegradable polymers in tissue engineering. We then discuss state-of-the-art research in the design and application of biodegradable polymers in packaging and emphasise the advances in smart packaging development. Finally, we provide an overview of the biodegradation of these polymers and composites in managed and unmanaged environments.

Biodegradable Plastic Blends Create New Possibilities for End-of-Life Management of Plastics but They Are Not a Panacea for Plastic Pollution.

Plastic waste pollution is a global environmental problem which could be addressed by biodegradable plastics. The latter are blended together to achieve commercially functional properties, but the environmental fate of these blends is unknown. We have tested neat polymers, polylactic acid (PLA), polyhydroxybutyrate, polyhydroxyoctanoate, poly(butylene succinate), thermoplastic starch, polycaprolactone (PCL), and blends thereof for biodegradation across seven managed and unmanaged environments. PLA is one of the world's best-selling biodegradable plastics, but it is not home compostable. We show here that PLA when blended with PCL becomes home compostable. We also demonstrate that the majority of the tested bioplastics and their blends degrade by thermophilic anaerobic digestion with high biogas output, but degradation times are 3-6 times longer than the retention times in commercial plants. While some polymers and their blends showed good biodegradation in soil and water, the majority of polymers and their blends tested in this study failed to achieve ISO and ASTM biodegradation standards, and some failed to show any biodegradation. Thus, biodegradable plastic blends need careful postconsumer management, and further design to allow more rapid biodegradation in multiple environments is needed as their release into the environment can cause plastic pollution.

Temporally Bounding TSO for Fence-Free Asymmetric Synchronization

This paper introduces a temporally bounded total store ordering (TBTSO) memory model, and shows that it enables nonblocking fence-free solutions to asymmetric synchronization problems, such as those arising in memory reclamation and biased locking. TBTSO strengthens the TSO memory model by bounding the time it takes a store to drain from the store buffer into memory. This bound enables devising fence-free algorithms for asymmetric problems, which require a performance-critical fast path to synchronize with an infrequently executed slow path . We demonstrate this by constructing (1) a fence-free version of the hazard pointers memory reclamation scheme, and (2) a fence-free biased lock algorithm which is compatible with unmanaged environments as it does not rely on safe points or similar mechanisms. We further argue that TBTSO can be implemented in hardware with modest modifications to existing TSO architectures. However, our design makes assumptions about proprietary implementation details of commercial hardware; it thus best serves as a starting point for a discussion on the feasibility of hardware TBTSO implementation. We also show how minimal OS support enables the adaptation of TBTSO algorithms to x86 systems.

Temporally Bounding TSO for Fence-Free Asymmetric Synchronization

This paper introduces a temporally bounded total store ordering (TBTSO) memory model, and shows that it enables nonblocking fence-free solutions to asymmetric synchronization problems, such as those arising in memory reclamation and biased locking. TBTSO strengthens the TSO memory model by bounding the time it takes a store to drain from the store buffer into memory. This bound enables devising fence-free algorithms for asymmetric problems, which require a performance-critical fast path to synchronize with an infrequently executed slow path . We demonstrate this by constructing (1) a fence-free version of the hazard pointers memory reclamation scheme, and (2) a fence-free biased lock algorithm which is compatible with unmanaged environments as it does not rely on safe points or similar mechanisms. We further argue that TBTSO can be implemented in hardware with modest modifications to existing TSO architectures. However, our design makes assumptions about proprietary implementation details of commercial hardware; it thus best serves as a starting point for a discussion on the feasibility of hardware TBTSO implementation. We also show how minimal OS support enables the adaptation of TBTSO algorithms to x86 systems.

Germination differentiation patterns of wild and domesticated columnar cacti in a gradient of artificial selection intensity

Germination of wild and managed populations of columnar cacti was compared to analyze differences associated to management intensity. The species studied: Polaskia chende, Escontria chiotilla, Myrtillocactus schenckii, Polaskia chichipe, and Stenocereus pruinosus are in a gradient from lower to higher management intensity, respectively. Within each species wild, silvicultural, and cultivated populations also represent a gradient from lower to higher management intensity. We hypothesized that seeds of plants under higher management intensity would require more water to germinate than others since managed environments are relatively wetter than unmanaged environments. Such pattern could be visualized within and among species according to management intensity. We tested germination of seeds from different populations of the different species to the water potentials: 0.0, −0.2, −0.4, −0.6, −0.8, and −1.0 MPa. In all species studied seeds of managed populations had significantly more mass than seeds from wild populations. Each species had different susceptibility to water availability decrease, which could be related to particular adaptations to drought resistance. Stenocereus pruinosus and Polaskia chende were the most and least susceptible species, respectively. In control treatments of all species, seeds of managed populations had higher germination rate than seeds from wild populations, but when water availability decreased the pattern was the contrary. Our results suggest that artificial selection for larger fruits and heavier seeds in plants established in wetter environments have affected germination patterns. Although species have particular critical points of water availability for germination, differences in germination patterns are more pronounced according to management and artificial selection intensity.

Transgenes and national boundaries – The need for international regulation

What happens when one nation cultivates a transgenic crop variety but neighboring nations do not? Using alfalfa as a case study, we argue that the potential for international transgene flow is substantial, and therefore, the need for international cooperation in regulatory decisions concerning transgenic crops is imperative. Alfalfa (Medicago sativa, L.) is the major forage crop in North America. Recently, genetically modified (GM) alfalfa received a moratorium on further cultivation in the US on the grounds that the approvals were based on inadequate environmental impact assessments. With their deep root system, symbiotic nitrogen fixation, prolific seed production and prolonged dormancy, alfalfa plants are capable of establishing self-perpetuating (feral) populations in unmanaged environments. Given what is known about alfalfa pollen dispersal, such feral populations could facilitate gene flow between GM and non-GM fields. The border between the US and Canada, particularly in farming areas, is very narrow (< 10 m wide). We surveyed along the US-Canada border and found both alfalfa fields and potentially feral alfalfa plants in the ditches along the border. Our survey results provide evidence of the possibility of cross-border transgene flow, suggesting a need for international co-operative risk assessment initiatives between the US and Canada. Such situations could occur for other crops, in other international border regions as well.

The ecological significance of increasing atmospheric carbon dioxide

This article discusses the impact on the plant-soil-water ecosystem of the doubling of atmospheric carbon dioxide (CO 2) postulated for the next few decades. In controlled environments, like greenhouses and managed soils, increasing CO 2 levels will significantly increase crop yields. In relatively unmanaged environments, such as forests and moorlands, increases in CO 2 may cause long-term problems still needing investigation. Nutrient deficiencies in soils and the acidification of soils and freshwaters may occur, as well as the better known climatic change effects.

EVALUATING THE OPTIONS FOR WATER QUALITY MANAGEMENT1

ABSTRACT: The agricultural revolution occurred because the un‐managed environment was not providing food in either the quantity or quality that society desired. The “environmental revolution” is developing because the unmanaged environment is clearly not capable of assimilating societal wastes without being seriously degraded. Effective environmental management will require regional and site‐specific modification of general principles and practices that can be used at a national or international level. An environmental management system can be operated in the same manner as any industrial quality control system with three basic components: (a) sensors at appropriate locations, (b) rapid generation and feedback of information, and (c) a quality control group capable of taking immediate effective action when system performance is outside predetermined boundary conditions. This discussion focuses primarily on three areas: (a) management options available to regulate intrusion of societal wastes into natural systems, (b) types of methods available for predicting and validating effects on natural systems, and (c) modifications of present legislation that would permit the most flexibility in selecting from the various management options. Also considered are multispecies toxicity tests using species with cosmopolitan distribution in test systems with a high degree of environmental realism. Among the many values of such tests is the ability to exchange information from all parts of the world effectively because the test organisms are not restricted to a particular geographic region.