Addressing energy poverty is integral to the United Nations Millennium Development Goals, and clean energy technology serves as an essential tool in mitigating this issue. Existing studies pay less attention to the correlation between the two. In this study, we quantify the spread of clean energy technology using patent citation information and analyze balanced panel data from 30 provinces in China spanning the years 2004 to 2019. The findings reveal that the diffusion of clean energy technology not only directly reduces energy poverty but also indirectly alleviates it by enhancing energy efficiency and fostering employment. However, the positive impact of technology on poverty is affected by human capital. Specifically, when the number of college students per 10,000 people in a province surpasses 179, technology diffusion becomes effective in alleviating energy poverty. Furthermore, the efficacy of this mitigation varies significantly based on different regions. Technologies originating from developed economies such as the United States, Japan, and the European Union exhibit a more substantial impact than domestic alternatives. Additionally, the effect of alleviating energy poverty is more significant in the eastern region. Therefore, we make policy recommendations for alleviating energy poverty through the use of incentive policies, exploring differentiated models of clean energy technology development, and strengthening international cooperation.