Abstract Of all the British claimants to the invention of photography, Henry Brougham is the one whose experiments have been given least attention in existing histories of photography. In his posthumously published three-volume autobiography of 1871, The Life and Times of Henry, Lord Brougham, written by himself, Brougham claimed to have engaged in some ‘experiments upon light and colours’ during the years 1794-–5 (when he was 16 years of age). He had, he tells us, included a discussion of his experiments in a paper offered to the Royal Society in 1795. Most of this paper, his first in the field of natural philosophy, was published in the Society's Philosophical Transactions (No. 86) of 1796 under the title ‘Experiments and observations on the inflection, reflection, and colours of light’. The paper, as published, was an attempt to discover analogous relationships between the bending of light within bodies (refraction or, using the 18th-century term, ‘refrangibility’) and the bending of light outside of bodies (reflection and diffraction or, in Brougham's terminology, flexion). As he wrote in the opening lines of his paper: It has always appeared wonderful to me, since nature seems to delight in those close analogies which enable her to preserve simplicity and even uniformity in variety, that there should be no dispositions in the parts of light, with respect to inflection and reflection, analogous or similar to their different refrangibility. In order to ascertain the existence of such properties, I began a course of experiments and observations, a short account of which forms the substance of this paper.1