Controlled stress is critical to both fabrication and operation of solid-state batteries to ensure pristine, low-impedance interfaces. The effects of externally applied stresses on overall cell performance and degradation due to altered thermodynamics, interfacial kinetics, and bulk transport of the active species have been studied in several prior works. In addition to the applied stack pressure which can vary up to 100s MPa, internal and localized stresses up to a few ~1 GPa can be generated from volume changes during charge and discharge. Electrode volume changes can result in cracking and delamination, causing loss of conductive pathways and active electrode-electrolyte area, and electrolyte fracture in the case of dendrite growth. The extent of these stress-electrochemistry couplings depends on the material and geometry of interfaces that affects the local stress distribution. To decouple some of these stress-potential, stress-kinetics, and stress-transport coupling phenomena, we use a nanoindenter platform to apply controlled uniaxial compressive forces to a thin-film electrochemical devices and batteries1. Interfaces in a thin-film sample can be uniform and planar over large areas, helping us study the effect of stress on the interfacial electrochemistry more directly and with greater quantitative accuracy. In this work we present our observations and analysis on the direct electrochemical-mechanical coupling in thin-film TiO2 and V2O5 metal oxide thin films as the working electrode with the single-ion Li+ conductor solid electrolyte LiPON. Preliminary results show that external uniaxial compressive load affects the electrochemistry observed through cyclic voltammetry and electrochemical impedance spectroscopy (EIS) measurements on thin-film batteries with TiO2 and V2O5 electrodes.