Entanglements, an intrinsic feature of long chains, are critical to the rheological and mechanical properties of polymers. Adding low molecular weight solvents or oligomers into entangled polymers can reduce the entanglements, but the entanglement cannot recover without removing the solvents. Reversible control of the entanglement degree is still a big challenge. In this work, we introduce the azobenzene polymer (Pazo) with reversible photoswitchable side-chain conformation as dynamic diluent into entangled poly(butyl methacrylate) (PBMA) to form a partially miscible blend system. The reduction of entanglement of PBMA by trans-Pazo is similar to a typical solvent, while an unexpectedly stronger tube dilation effect was found for cis-Pazo. Cis-Pazo/PBMA blends exhibit a stronger dependence of plateau modulus on PBMA content, GN(φ)∼φ4.5, which is significantly different from the well-established relation GN(φ)∼φ2 for polymer solutions and blends. The cis-Pazo can disentangle PBMA at a much lower concentration (∼55 %) than the trans-Pazo (>70 %). Pazo content of 55 %–70 % can induce a completely unentangled state of PBMA in Pazo/PBMA blends when Pazo is in the cis state after UV light irradiation, and the entanglement can recover when it is transformed to the trans state. Adding azobenzene polymer does not alter the activation energy of the re-entanglement process.