Undergraduate General Chemistry Research Articles

Social and Emotional Learning as Experienced by Students in Undergraduate General Chemistry Labs

Students can meticulously perform laboratory techniques and be proficient in writing lab reports yet report negative affective experiences within the chemistry teaching labs. This study addresses this contradiction by studying students’ experiences using a Social and Emotional Learning (SEL) framework to qualitatively and deductively analyze semi-structured student interviews (N=15). The interviews followed the students’ completion of introductory chemistry and focused on their experiences with the laboratories. What emerged from this analysis were the SEL competencies intertwining with all aspects of the teaching labs as students worked with their lab partners, peers, and teaching assistants. The labs provide a unique environment for students to apply their SEL skills, including effective relationship and self-management skills. Despite students using and relying on their SEL skills, they are not always supported in lab design, and this presents a barrier to student success and a positive learning experience associated with the teaching labs. Given this, there is a need to change chemistry laboratory teaching practices and curricula to emphasize support and learning outcomes related to SEL. These findings were used to implement changes to the first-year labs to support SEL competencies, such as designing and implementing a TA manual, providing students with tips for dividing lab procedures, and offering more resources including rubrics.

Implementing an interactive online platform in a large undergraduate general chemistry course and its impact on student learning and perceptions

The rise of technology and online approaches has challenged the traditional learning and teaching model for first year chemistry of formal face-to-face lectures and in-person laboratory sessions. The COVID-19 pandemic since 2020 has created a rapidly changing environment in assessment and learning experiences for students and led to rapid adoption of online technology within chemistry courses. This study, during 2019–2021, examined the implementation of an active learning platform in a large undergraduate chemistry course. This study was informed by constructivist theories of learning and of relevance was the 5E framework, with learning phases of engage, explore, explain, elaborate, and evaluate. A combination of post-survey data and coursework data were analysed. Post-survey results indicated that students positively perceived that the interactive online platform helped them to learn. User statistics data for learning and self-assessment activities affirmed that students gave priority to the self-paced interactive online approach, in preference to conventional social learning activities. Modernization of delivery of the curriculum to replace unstructured independent private study with structured learning and revision activities was of greatest benefit to student learning for lower performing students that were typically mature age students, with significant differences observed for online quiz and final exam results for this cohort of students. Overall, student learning was supported with the introduction of digital technologies in the course. The findings revealed that the self-paced learning activities for chemistry, delivered with an interactive online platform, combined with conventional learning activities can be effective in creating a culture of learning in students and maintaining academic outcomes.

Role of concept map format and student interest on introductory electrochemistry learning

AbstractElectrochemistry, a key topic in introductory chemistry, is a topic that many students struggle with conceptually. Visual learning tools like concept maps allow the externalization of key concepts and the relationships between these concepts may aid in students' acquisition and retention of newly learned electrochemistry concepts. Partnering with a general chemistry instructor, this study explored the effectiveness of two concept map formats—fill‐in‐the‐concepts and student‐corrected maps, on electrochemistry outcomes with undergraduate general chemistry students. To examine students' engagement with these maps, we also explored the role of students' interest. Results indicated that prior knowledge and map condition were significant predictors of students' electrochemistry performance. Specifically, the fill‐in‐the‐concepts condition resulted in better learning outcomes than the map correction condition. Furthermore, students with a higher interest in electrochemistry were more likely to perform well on their respective concept mapping activities, thus, scoring higher on the posttest. These findings suggested that concept maps can effectively represent key concepts of a challenging topic, and are beneficial for students' learning and retention of information. Importantly, instructors may further support learning by providing scaffolds in the form of fill‐in‐the‐concept maps to help students better organize their mental structures and identify misconceptions.

“Design a Sensor”: Implementation of Entrepreneurial-Minded Learning in Undergraduate General Chemistry

This article describes the design and implementation of a sensors-based entrepreneurial-minded learning (EML) module in a large (>150 students) first-year General Chemistry II course. Students worked in groups create a novel sensor that solves an existing scientific problem or improves upon an existing sensor. Students proposed and explained the chemical background of their sensors as well as presented their final products to the class in the style of a brief elevator pitch. This module necessitates that students think innovatively, integrate knowledge from varied sources, and collaborate with their peers. The aim of implementing this EML module is to spur creative thinking, innovation, and entrepreneurial learning among first-year undergraduate chemistry students. We conducted course surveys to gauge students’ reception of this module and found that the majority of students enjoyed this activity and learned valuable skills from their experience. Moving forward, we advocate that these and similar learning modules are implemented in large, introductory course settings due to the many benefits that they offer to students.

Using social influence models to characterize student interest in a general chemistry peer-led team learning setting

Motivation helps drive students to success in general chemistry, and active learning environments with social interactions has consistently shown to improve motivation. However, analyzing student outcomes in an interactive environment is best done by considering students not as isolated units but as working together and influencing each other. Therefore, we used social network analysis with self-determination theory as a framework for understanding motivation and social comparison theory as a framework for understanding how students influence each other. When analyzing an undergraduate general chemistry course that has incorporated peer-led team learning using data from the Learning Climate Questionnaire and Intrinsic Motivation Inventory, a series of progressively sophisticated statistical models with data gathered from 270 students shows that perceived competence and relatedness predict student interest in the activities with their peer-led sessions. However, we also found evidence that students tend to become polarized in their interest toward peer-led team learning activities, which is one possible outcome of social comparisons with their peers. In addition to these findings, this project demonstrates how social network analysis can expand how chemistry education researchers consider relational data and the effects of non-independent data on statistical analysis.

Direct Current (DC) Electric Field-Enabled Beating Heart of Ga-Based Liquid Metal

Mercury beating heart (MBH) is a well-known demonstration of redox processes. However, the development and application of the MBH system are significantly restricted due to its safety issues. Here, a direct current electric field-enabled gallium-based liquid metal heartbeat in a salt solution or alkaline solution is introduced as a demonstration appropriate for undergraduate general chemistry. The former oscillation occurs on the cathode, the latter on the anode. The objective is to achieve a visually appealing effect in the classroom and motivate students to understand the underlying concepts. Students are encouraged to assemble the instrument and perform the demonstration under supervision. Apart from the gallium-based liquid metal and a helping-hand stand, the demonstration utilizes common laboratory apparatus, and the materials for the solutions can be obtained in an undergraduate general chemistry laboratory.

Service-Learning in Undergraduate General Chemistry: A Review

Background: Service-learning is gaining recognition as a valuable pedagogy for students to gain both academic and psychosocial benefits. This high-impact practice allows students to achieve course learning objectives while contributing to their community's needs. A review from 2007 revealed a lack of research focused on the topic in the prior decade, despite the interest that was shown by the American Chemical Society in 2000. Purpose: This review of recent case studies on the topic provides future researchers and practitioners with an understanding of the current state of service-learning in undergraduate chemistry courses. Methodology/Approach: To create a representative sample of recent literature for a non-exhaustive scoping review, only peer-reviewed articles addressing service-learning in undergraduate chemistry, published in reliable journals in the last two decades were included. These studies were analyzed in terms of course design, research design, and research quality. Findings/Conclusions: While the scoping review identified papers with notable contributions to establishing service-learning in undergraduate general chemistry, the review also identified several key gaps in the literature, including small sample size, reliance on subjective and indirect measures, and qualitative measures that exclude correlation analysis. Implications: Recommendations for future work for both practitioners and researchers are provided.

Qualifying domains of student struggle in undergraduate general chemistry laboratory

Learning and learning goals in undergraduate chemistry laboratory have been a popular research topic for the past three decades due to calls for curriculum reform, cost justification, and overall efficacy of necessary skill development. While much work has been done to assess curricular interventions on students’ learning and attitudes towards lab, few have discussed the increased difficulties of these non-traditional laboratory activities or the obstacles students must overcome in the laboratory setting. The work presented here focuses on student struggles in undergraduate general chemistry laboratory activities, the source of these struggles, and the actions students take to overcome them. Using an activity theoretical lens and multiple domains (cognitive, epistemological, socioemotional, and psychomotor), we developed a domains-of-struggle framework which encompasses how struggles emerge through contradictions within the laboratory activity system. This framework was extended and refined through iterative analysis of two consecutive semesters of undergraduate general chemistry laboratory (GC1 and GC2) video (n = 51), survey (n = 327), and interview (n = 44) data. In this paper, we model the activity system of the general chemistry laboratory, define the domains of struggle observed, and present actions the students took to move past these obstacles, while illustrating the interconnected complexity of the activity system. We then discuss how this framework may be used in future curriculum design or teacher training, as well as potential for future research on the learning outcomes associated with moments of struggle.

Assessing the Use of Kahoot! in an Undergraduate General Chemistry Classroom

Assessing the Use of <i>Kahoot!</i> in an Undergraduate General Chemistry Classroom

A Choose-Your-Own-Adventure-Style Virtual Lab Activity

Especially in the wake of the recent COVID-19 pandemic, which has caused universities across the globe to suspend in-person classes, online alternatives for laboratory activities are needed. Here, we report a choose-your-own-adventure (CYOA)-style activity, in which undergraduate general chemistry students influence the observed outcome of a prerecorded electrochemistry lab experiment. During the activity, students decide how to build an electrochemical cell by varying experimental parameters including electrode charge, power source voltage, and salt addition. We show evidence that students’ understanding of electrochemistry concepts improved after completing the CYOA-style activity. We propose that CYOA-style activities strike a good balance between the demand for instructor time and student opportunity to develop laboratory decision-making skills. We suggest the use of CYOA-style activities as a better alternative to simply having students watch prerecorded videos of laboratory experiments when a traditional in-laboratory activity is impossible.

The Briggs–Rauscher Reaction: A Demonstration of Sequential Spatiotemporal Patterns

The Briggs–Rauscher reaction is a popular demonstration to illustrate chemical oscillations in laboratories, classrooms, and public seminars because of its simplicity and visual appeal. Here, we adapt the Briggs–Rauscher reaction to present reaction–diffusion–convection patterns in the undergraduate general or physical chemistry laboratory. By maintaining the ratio between malonic acid and potassium iodate concentrations as 0.2 in an uncovered Petri dish, sequential patterns (transient dendritic patterns and rotating dendritic patterns) can be observed, which are induced by the interaction of reaction, diffusion, and convection. This beautiful demonstration captures students’ attention and inspires reflection and discussion about similar phenomena in nature as well as the wealth of behaviors in systems far from equilibrium.

Efficacy of an Asynchronous Online Preparatory Chemistry Course: An Observational Study

In an ongoing effort to increase student retention and success in the undergraduate general chemistry course sequence, a fully online preparatory chemistry course was developed and implemented at a large public research university. To gain insight about the efficacy of the online course, an observational study was carried out in which student performance on final exams and performance in the subsequent general chemistry course were compared between the online cohort and a previous student cohort which completed the preparatory chemistry course in a traditional lecture format. Multiple linear regression analyses were used to compare final exam scores and general chemistry course grades between the online and in-person student cohorts, while statistically controlling for incoming student academic achievement. Results from these analyses suggest the fully online course resulted in statistically significant increases in both the preparatory chemistry final exam scores and course grades in the subsequent general chemistry course. Because the retention of less academically prepared students in STEM majors is a historical problem at the institution in which the online preparatory chemistry course was implemented, the analyses also aimed to determine if this at-risk group demonstrated similar achievement relative to the population at large. Notably, it was determined that students with the lowest incoming Math SAT scores appeared to perform better in the online course relative to the analogous group of students in the in-person course. Though the observational nature of this study does not allow for the determination of causality, these results suggest a fully online course can result in improved performance for large populations of students, without resulting in a negative achievement gap for less academically prepared students. The structure and implementation of the online course and the results from the statistical analyses will be described herein.

Reducing achievement gaps in undergraduate general chemistry could lift underrepresented students into a "hyperpersistent zone".

Students from underrepresented groups start college with the same level of interest in STEM majors as their peers, but leave STEM at higher rates. We tested the hypothesis that low grades in general chemistry contribute to this "weeding," using records from 25,768 students. In the first course of a general chemistry series, grade gaps based on binary gender, race/ethnicity, socioeconomic status, and family education background ranged from 0.12 to 0.54 on a four-point scale. Gaps persisted when the analysis controlled for academic preparation, indicating that students from underrepresented groups underperformed relative to their capability. Underrepresented students were less likely than well-represented peers to persist in chemistry if they performed below a C-, but more likely to persist if they got a C or better. This "hyperpersistent zone" suggests that reducing achievement gaps could have a disproportionately large impact on efforts to achieve equity in STEM majors and professions.

Students’ interpretation and use of graphical representations: insights afforded by modeling the varied population schema as a coordination class

Explanations of phenomena in chemistry are grounded in discussions of particulate-level behavior, but there are limitations to focusing on single particles, or as an extension, viewing a group of particles as displaying uniform behavior. More sophisticated models of physical processes evoke considerations related to the dynamic nature of bulk solutions, in which an ensemble of molecules exists with a distribution of values that vary with respect to different parameters (e.g., speed, kinetic energy, etc.). Viewing phenomena as a varied population instead of a homogenous solution has been identified as a foundational idea that is critical for reasoning in chemistry, but little work has investigated how students reason about these ideas and how instructors can support students in viewing phenomena as a distribution of states. In this qualitative study, during semi-structured interivews twelve undergraduate general chemistry students were provided with frequency distribution graphs (number of molecules vs. speed, number of molecules vs. kinetic energy) and were asked to provide explanations and make predictions. The design and analysis of this study was informed by coordination class theory, a model within the knowledge-in-pieces perspective of cognition that defines a concept as a combination of approaches for obtaining information (read-out strategies) and a cluster of knowledge elements used to draw conclusions (causal net). Framing the varied population schema as a coordination class, this work focuses on the interaction between features students attended to in distribution graphs and the ideas they discussed. Analysis indicates students have productive resources for reasoning about a varied population in general terms, but these ideas are not necessarily activated when interpreting graphs, as reflected in the students’ readout strategies. Moreover, we posit that one of the barriers toward interpreting distribution graphs was the inappropriate application of covariational reasoning. As a practical consideration, we encourage interested instructors to review the Appendix, which provides a short summary of the main findings and suggestions for practitioners.

Measuring student engagement in the undergraduate general chemistry laboratory

In this study a survey was developed to investigate students’ engagement during general chemistry laboratory sessions. Aspects of engagement surveyed included cognitive, behavioral, and emotional engagement, and the survey items were focused on activities during the pre-laboratory introduction, laboratory procedures, and data collection. Exploratory factor analysis of the results was conducted to determine the various underlying factors in the survey, and the scores of the general chemistry laboratory students along these underlying factors were compared. The findings supported the various dimensions of engagement reported in the literature.

Exploring Chemical Equilibrium for Alcohol-Based Cobalt Complexation through Visualization of Color Change and UV–vis Spectroscopy

Introducing chemical equilibrium concepts in undergraduate general chemistry promotes improved understanding of chemical reactions. We have developed an engaging laboratory experiment exploring the...

Undergraduate Chemistry Students’ Epistemic Criteria for Scientific Models

To engage meaningfully with scientific models, undergraduate students must come to understand what counts as a scientific model and why. To gain a sense of the characteristics that undergraduate chemistry students ascribe to scientific models, we analyzed survey data that address students’ ideas about both model criteria in general and criteria related to specific models of chemical phenomena. The findings suggest that undergraduate general chemistry students possess some productive and some intuitive ideas about the characteristics of scientific models but may not have systematic or coherent conceptions about models across contexts.

Phosphorus – a “political” element for transdisciplinary chemistry education

AbstractThe paper describes a curriculum innovation project for integrating the sustainability-oriented socio-scientific issue of phosphate recovery into undergraduate chemistry education. Justification for the topic is derived from the importance of responsible use of phosphates as fertilizers for achieving some of the sustainable development goals issued by the United Nations in 2015, but also by the consideration of the phosphorus biochemical flow into the environment in the concept of the world’s planetary boundaries. Integration of the topic into undergraduate general chemistry was operated by a digital learning environment providing the base for a transdisciplinary approach towards the topic. Findings are reported from an implementation case in a research university in the USA.

Hands-On Experiment To Verify Consistency from Bulk Density to Atomic and Ionic Radii with Lumps of Metals and Ionic Compounds

A hands-on experiment to obtain atomic and ionic radii with lumps of metal and ionic compounds is reported here. The experiment is performed with industrial-grade typical metals (iron, copper, aluminum, and lead) and single-crystal lumps of ionic compounds (sodium chloride, potassium chloride, and potassium bromide). Students measure the dimension of the given lumps with Vernier calipers and weigh them with a precision balance. After measuring the dimension and mass of the given lumps, students can calculate the atomic and ionic radius of each corresponding atom and ion with the obtained density values and information about the lattice structures. The obtained values of the metal atomic radii and the ionic radii of the ionic compounds are very close to the values in the literature. After this activity, the students came to appreciate that atomic radii, as typical submicroscopic and symbolic representations, are actually existing features and not an abstract concept. The experiment reported here is suitable for a first-year undergraduate general chemistry class as well as an introductory class at the high school level.

Adapting a Core-Idea Centered Undergraduate General Chemistry Curriculum for Use in High School

Connecting the behavior of invisible (to the naked eye) particles governed by the principles of quantum mechanics to the world we can see and touch requires a host of inferences, almost none of which can be extrapolated from experience. Molecular-level sensemaking thus relies upon intellectual resources that must be developed in large part by formal learning environments. Over a decade of research at the college-level indicates that centering instruction around scaffolded progressions of core ideas can help students cultivate, organize, and use their disciplinary knowledge to explain and model a range of phenomena. Informed by this literature, we have adapted a core-idea centered, evidence-based undergraduate general chemistry curriculum for use in high school. Our adaptation process, which was a collaborative effort between researchers and classroom teachers, is described in detail with emphasis on alignment between the Next Generation Science Standards and our materials. Efforts reported here represent a first-in-class model for high school curriculum development wherein conceptual progressions developed and validated at the college level form the basis for high school coursework.