Unconventional Strain Research Articles

Expanded Stability of Layered SnSe-PbSe Alloys and Evidence of Displacive Phase Transformation from Rocksalt in Heteroepitaxial Thin Films.

Bulk PbSnSe has a two-phase region, or miscibility gap, as the crystal changes from a van der Waals-bonded orthorhombic 2D layered structure in SnSe-rich compositions to the related 3D-bonded rocksalt structure in PbSe-rich compositions. This structural transition drives a large contrast in the electrical, optical, and thermal properties. We realize low temperature direct growth of epitaxial PbSnSe thin films on GaAs via molecular beam epitaxy using an in situ PbSe surface treatment and show a significantly reduced two-phase region by stabilizing the Pnma layered structure out to Pb0.45Sn0.55Se, beyond the bulk limit around Pb0.25Sn0.75Se at low temperatures. Pushing further, we directly access metastable two-phase films of layered and rocksalt grains that are nearly identical in composition around Pb0.50Sn0.50Se and entirely circumvent the miscibility gap. We present microstructural and compositional evidence for an incomplete displacive transformation from a rocksalt to layered structure in these films, which we speculate occurs during the sample cooling to room temperature after synthesis. In situ temperature-cycling experiments on a Pb0.58Sn0.42Se rocksalt film reproduce characteristic attributes of a displacive transition and show a modulation in electronic properties. We find well-defined orientation relationships between the phases formed and reveal unconventional strain relief mechanisms involved in the crystal structure transformation using transmission electron microscopy. Overall, our work adds a scalable thin film integration route to harness the dramatic contrast in material properties in PbSnSe across a potentially ultrafast crystalline-crystalline structural transition.

An overview of Parafrankia (Nod+/Fix+) and Pseudofrankia (Nod+/Fix-) interactions through genome mining and experimental modeling in co-culture and co-inoculation of Elaeagnus angustifolia.

While Pseudofrankia strains typically lack the common traits of ability to nodulate the host plant (Nod-) and/or fix nitrogen (Fix-), they are still recovered from actinorhizal nodules. The enigmatic question of how and why these unconventional strains establish themselves within nodule tissue, thriving either alongside symbiotic strains (Nod+/Fix+) or independently, while considering potential metabolic costs to the host plant, remains a perplexing puzzle. This study endeavors to unravel the competitive dynamics between Pseudofrankia inefficax strain EuI1c (Nod+/Fix-) and Parafrankia strain EU1Nf (Nod+/Fix+) through a comprehensive exploration of genomic data and empirical modeling, conducted both in controlled laboratory settings and within the host plant environment.

Construction of an infectious clone for enterovirus A89 and mutagenesis analysis of viral infection and cell binding.

Enterovirus A89 (EV-A89) is an unconventional strain belonging to the Enterovirus A species. Limited research has been conducted on EV-A89, leaving its biological and pathogenic properties unclear. Developing reverse genetic tools for EV-A89 would help to unravel its infection mechanisms and aid in the development of vaccines and anti-viral drugs. In this study, an infectious clone for EV-A89 was successfully constructed and recombinant enterovirus A89 (rEV-A89) was generated. The rEV-A89 exhibited similar characteristics such as growth curve, plaque morphology, and dsRNA expression with parental strain. Four amino acid substitutions were identified in the EV-A89 capsid, which were found to enhance viral infection. Mechanistic studies revealed that these substitutions increased the virus's cell-binding ability. Establishing reverse genetic tools for EV-A89 will significantly contribute to understanding viral infection and developing anti-viral strategies.IMPORTANCEEnterovirus A species contain many human pathogens and have been classified into conventional cluster and unconventional cluster. Most of the research focuses on various conventional members, while understanding of the life cycle and infection characteristics of unconventional viruses is still very limited. In our study, we constructed the infectious cDNA clone and single-round infectious particles for the unconventional EV-A89, allowing us to investigate the biological properties of recombinant viruses. Moreover, we identified key amino acids residues that facilitate EV-A89 infection and elucidate their roles in enhancing viral binding to host cells. The establishment of the reverse genetics system will greatly facilitate future study on the life cycle of EV-A89 and contribute to the development of prophylactic vaccines and anti-viral drugs.

Mechanical performance of additively manufactured cobalt-chromium-molybdenum auxetic meta-biomaterial bone scaffolds

Auxetic meta-biomaterials offer unconventional strain behaviour owing to their negative Poisson's ratio (−υ) leading to deformation modes and mechanical properties different to traditional cellular biomaterials. This can lead to favourable outcomes for load-bearing tissue engineering constructs such as bone scaffolds. Emerging early-stage studies have shown the potential of auxetic architecture in increasing cell proliferation and tissue reintegration owing to their −υ. However, research on the development of CoCrMo auxetic meta-biomaterials including bone scaffolds or implants is yet to be reported. In this regard, this paper proposes a potential framework for the development of auxetic meta-biomaterials that can be printed on demand while featuring porosity requirements suitable for load-bearing bone scaffolds. Overall, the performance of five CoCrMo auxetic meta-biomaterial scaffolds characterised under two scenarios for their potential to offer near-zero and high negative Poisson's ratio is demonstrated. Ashby's criterion followed by prototype testing was employed to evaluate the mechanical performance and failure modes of the auxetic meta-biomaterial scaffolds under uniaxial compression. The best performing scaffold architectures are identified through a multi-criteria decision-making procedure combining ‘analytic hierarchy process’ (AHP) and ‘technique for order of preference by similarity to ideal solution’ (TOPSIS). The results found the Poisson's ratio for the meta-biomaterial architectures to be in the range of −0.1 to −0.24 at a porosity range of 73–82%. It was found that the meta-biomaterial scaffold (AX1) that offered the highest auxeticity also showed the highest elastic modulus, yield, and ultimate strength of 1.66 GPa, 56 MPa and 158 MPa, respectively. The study demonstrates that the elastic modulus, yield stress, and Poisson's ratio of auxetic meta-biomaterials are primarily influenced by the underlying meta-cellular architecture followed by relative density offering a secondary influence.

Implications of slip transition on the work hardening and texture evolution of nickel‑tungsten‑iron ternary alloy

The present study investigates the microstructure, texture, and work hardening behavior of the hot rolled and homogenized Ni-24W-22Fe alloy. This alloy has a single f.c.c. phase microstructure with some annealing twins. Upon tensile test, the alloy showed unconventional strain hardening behavior which was determined to occur due to transition from single slip to multiple slips. The bulk texture measurement also confirmed the evidence of planar slip during the early stage of deformation. To further ensure the transition in slip modes, i.e., single slip to multiple slips, in-situ electron backscatter diffraction was performed, and evidence of the occurrence of slip transition was shown by grains having rotation path toward <112> direction. Grains of similar orientation were picked and found to rotate in different directions. Some grains rotate toward <112>, while others rotate toward <111> direction. • Work-hardening behavior of concentrated Ni-24W-22Fe alloy was studied. • Kocks-Mecking plot shows the hump formation due to slip transition. • Bulk texture evolution shows the deterioration of [100] fiber and evolution of [111] fiber. • Similar oriented grains takes different rotation paths, some grains rotate toward <112> and others rotate toward <111>.

Nanowires Bending over Backward from Strain Partitioning in Asymmetric Core-Shell Heterostructures.

The flexibility and quasi-one-dimensional nature of nanowires offer wide-ranging possibilities for novel heterostructure design and strain engineering. In this work, we realize arrays of extremely and controllably bent nanowires comprising lattice-mismatched and highly asymmetric core-shell heterostructures. Strain sharing across the nanowire heterostructures is sufficient to bend vertical nanowires over backward to contact either neighboring nanowires or the substrate itself, presenting new possibilities for designing nanowire networks and interconnects. Photoluminescence spectroscopy on bent-nanowire heterostructures reveals that spatially varying strain fields induce charge carrier drift toward the tensile-strained outside of the nanowires, and that the polarization response of absorbed and emitted light is controlled by the bending direction. This unconventional strain field is employed for light emission by placing an active region of quantum dots at the outer side of a bent nanowire to exploit the carrier drift and tensile strain. These results demonstrate how bending in nanoheterostructures opens up new degrees of freedom for strain and device engineering.

Structural evolution and enhanced piezoresponse in cobalt-substituted BiFeO3 thin films

The role of cobalt substitution in the crystal structure and piezo/ferroelectric properties of BiFeO3 (BFO) thin films was studied. With the aid of epitaxial strain, (1 − x)BiFeO3–xBiCoO3 (BFCO) (0 ≤ x ≤ 0.12) films were stabilized on SrTiO3 substrates, and an enhancement in their piezoresponses was observed. In the x = 0.15 BFCO film, an unconventional strain relaxation behavior, resulting in V-shaped domains of a “giant-c/a” phase of approximately 1.25, was observed. This observation demonstrates that the crystal structure and piezo/ferroelectric properties of BFO can be finely tuned by a combination of cobalt substitution and epitaxial strain.

Strain-Induced Spin States in Atomically Ordered Cobaltites

Epitaxial strain imposed in complex oxide thin films by heteroepitaxy is recognized as a powerful tool for identifying new properties and exploring the vast potential of materials performance. A particular example is LaCoO(3), a zero spin, nonmagnetic material in the bulk, whose strong ferromagnetism in a thin film remains enigmatic despite a decade of intense research. Here, we use scanning transmission electron microscopy complemented by X-ray and optical spectroscopy to study LaCoO(3) epitaxial thin films under different strain states. We observed an unconventional strain relaxation behavior resulting in stripe-like, lattice modulated patterns, which did not involve uncontrolled misfit dislocations or other defects. The modulation entails the formation of ferromagnetically ordered sheets comprising intermediate or high spin Co(3+), thus offering an unambiguous description for the exotic magnetism found in epitaxially strained LaCoO(3) films. This observation provides a novel route to tailoring the electronic and magnetic properties of functional oxide heterostructures.

Abnormal Phenomena Recorded by Several Earthquake Precursor Observation Instruments Before the Ms 8.0 Wenchuan, Sichuan Earthquake

Abstract:The paper introduces the anomalies observed by digital tiltmeter, cross‐fault deformation meter, 4‐component borehole strainmeter and geothermometer before May 12, 2008, Ms8.0 Wenchuan earthquake, Sichuan. The digital tiltmeter installed in the epicentral region in Shifang County recorded the tilt anomalies 15 days before the earthquake with variation amplitude of 3.7 times larger than the annual deviation of 2007. The cross‐fault deformation meter installed at Zimakua station on the Xianshuihe‐Anninghe fault zone detected displacement anomaly occurring since 2006 with the variation amplitude exceeding the cumulative value of the last ten years. Five borehole strainmeter stations in the Chongqing section of Three Gorges Reservoir area observed unconventional strain changes occurring in the period from May 1 through 12, 2008. Among them, the strainmeter at Wanzhou station recorded the great compression strain rate on the EW component at 14:00 o'clock of May 10, and the anomaly amplitude was so large that the instrument output exceeded its dynamic range, corresponding to a level of ∼104 nanostrains. The geothermometers installed in Xi'an, Chongqing and Xichang recorded the sudden temperature changes from November 2007 to January 2008 with the variation amplitudes several times larger than the ordinary deviation. The above phenomena and the criteria for distinguishing the anomalies from background fluctuations are discussed in this paper.

Identification of Unconventional Intestinal Pathogenic Escherichia coli Isolates Expressing Intermediate Virulence Factor Profiles by Using a Novel Single-Step Multiplex PCR

Intestinal pathogenic Escherichia coli represents a global health problem for mammals, including humans. At present, diarrheagenic E. coli bacteria are grouped into seven major pathotypes that differ in their virulence factor profiles, severity of clinical manifestations, and prognosis. In this study, we developed and evaluated a one-step multiplex PCR (MPCR) for the straightforward differential identification of intestinal pathotypes of E. coli. The specificity of this novel MPCR was validated by using a subset of reference strains and further confirmed by PCR-independent pheno- and genotypic characterization. Moreover, we tested 246 clinical E. coli isolates derived from diarrhea patients from several distinct geographic regions. Interestingly, besides strains belonging to the defined and well-described pathotypes, we identified five unconventional strains expressing intermediate virulence factor profiles. These strains have been further characterized and appear to represent intermediate strains carrying genes and expressing factors associated with enteropathogenic E. coli, Shiga toxin-producing E. coli, enterotoxigenic E. coli, and enteroaggregative E. coli alike. These strains represent further examples of the extraordinary plasticity of the E. coli genome. Moreover, this implies that the important identification of specific pathotypes has to be based on a broad matrix of indicator genes. In addition, the presence of intermediate strains needs to be accounted for.

Band-Structure Engineering in Novel Optoelectronic Devices

AbstractIn this paper we show that unconventionally strained semiconductor heterostructures with unusual band structure exhibit novel and desirable electronic and optical properties not seen in the conventional strained materials. In addition to improving the performance of existing components, unconventional strain may be used to achieve greater functionality in novel optoelectronic devices. We give as examples three such devices that we have conceived and demonstrated, in the two areas of strain, lattice mismatch induced and thermal expansion coefficient mismatch induced. The higher performance and functionality in these devices demonstrate that strain engineered heterostructures are a very promising area for device research and development.