Unbiased Spectral Line Survey Research Articles

The physical and chemical structure of Sagittarius B2. VIII. Dust and ionized gas contributions to the full molecular line survey of 47 hot cores

The physical and chemical structure of Sagittarius B2. VIII. Dust and ionized gas contributions to the full molecular line survey of 47 hot cores

Molecules in the Cep E-mm jet: evidence for shock-driven photochemistry?

ABSTRACT The chemical composition of protostellar jets and its origin are still badly understood. More observational constraints are needed to make progress. With that objective, we have carried out a systematic search for molecular species in the jet of Cep E-mm, a template for intermediate-mass Class 0 protostars, associated with a luminous, high-velocity outflow. We made use of an unbiased spectral line survey in the range 72–350 GHz obtained with the IRAM 30-m telescope, complementary observations of the CO J = 3–2 transition with the JCMT, and observations at 1 arcsec angular resolution of the CO J = 2–1 transition with the IRAM Plateau de Bure Interferometer. In addition to CO, we have detected rotational transitions from SiO, SO, H2CO, CS, HCO+, and HCN. A strong chemical differentiation is observed in the southern and northern lobes of the jet. Radiative transfer analysis in the large velocity gradient approximation yields typical molecular abundances of the order of 10−8 for all molecular species other than CO. Overall, the jets exhibit an unusual chemical composition, as CS, SO, and H2CO are found to be the most abundant species, with a typical abundance of (3–4)× 10−8. The transverse size of the CO jet emission estimated from interferometric observations is about 1000 au, suggesting that we are detecting emission from a turbulent layer of gas entrained by the jet in its propagation and not the jet itself. We propose that some molecular species could be the signatures of the specific photochemistry driven by the UV radiation field generated in the turbulent envelope.

An unbiased spectral line survey observation toward the low-mass star-forming region L1527

Abstract An unbiased spectral line survey toward a solar-type Class 0/I protostar, IRAS 04368+2557, in L1527 has been carried out in the 3 mm band with the Nobeyama 45 m telescope. L1527 is known as a warm carbon-chain chemistry (WCCC) source, which harbors abundant unsaturated organic species such as CnH (n = 3, 4, 5, …) in a warm and dense region near the protostar. The observation covers the frequency range from 80 to 116 GHz. A supplementary observation has also been conducted in the 70 GHz band to observe fundamental transitions of deuterated species. In total, 69 molecular species are identified, among which 27 species are carbon-chain species and their isomers, including their minor isotopologues. This spectral line survey provides us with a good template of the chemical composition of the WCCC source.

Complex organic molecules in the Galactic Centre: the N-bearing family

We present an unbiased spectral line survey toward the Galactic Centre (GC) quiescent giant molecular cloud (QGMC), G+0.693 using the GBT and IRAM 30$\,$ telescopes. Our study highlights an extremely rich organic inventory of abundant amounts of nitrogen (N)-bearing species in a source without signatures of star formation. We report the detection of 17 N-bearing species in this source, of which 8 are complex organic molecules (COMs). A comparison of the derived abundances relative to H$_2$ is made across various galactic and extragalactic environments. We conclude that the unique chemistry in this source is likely to be dominated by low-velocity shocks with X-rays/cosmic rays also playing an important role in the chemistry. Like previous findings obtained for O-bearing molecules, our results for N-bearing species suggest a more efficient hydrogenation of these species on dust grains in G+0.693 than in hot cores in the Galactic disk, as a consequence of the low dust temperatures coupled with energetic processing by X-ray/cosmic ray radiation in the GC.

Herschel/HIFI spectral line survey of the Orion Bar

Photon Dominated Regions (PDRs) are interfaces between the mainly ionized and mainly molecular material around young massive stars. Analysis of the physical and chemical structure of such regions traces the impact of far-ultraviolet radiation of young massive stars on their environment. We present results on the physical and chemical structure of the prototypical high UV-illumination edge-on Orion Bar PDR from an unbiased spectral line survey with a wide spectral coverage. A spectral scan from 480-1250 GHz and 1410-1910 GHz at 1.1 MHz resolution was obtained by the HIFI instrument onboard the Herschel Space Observatory. For molecules with multiple transitions we used rotational diagrams to obtain excitation temperatures and column densities. For species with a single detected transition we used an optically thin LTE approximation. In case of species with available collisional rates, we also performed a non-LTE analysis to obtain kinetic temperatures, H2 volume densities, and column densities. About 120 lines corresponding to 29 molecules (including isotopologues) have been detected in the Herschel/HIFI line survey, including 11 transitions of CO, 7 transitions of 13CO, 6 transitions of C18O, 10 transitions of H2CO, and 6 transitions of H2O. Most species trace kinetic temperatures in the range between 100 and 150 K and H2 volume densities in the range between 10^5 and 10^6 cm^-3. The species with temperatures and / or densities outside of this range include the H2CO transitions tracing a very high temperature (315 K) and density (1.4x10^6 cm^-3) component and SO corresponding to the lowest temperature (56 K) measured as a part of this line survey. The observed lines/species reveal a range of physical conditions (gas density /temperature) involving structures at high density / high pressure, obsoleting the traditional 'clump / interclump' picture of the Orion Bar.

ATLASGAL-selected massive clumps in the inner Galaxy

The processes leading to the birth of high-mass stars are poorly understood. We characterise here a sample of 430 massive clumps from the ATLASGAL survey, which are representative of different evolutionary stages. To establish a census of molecular tracers of their evolution we performed an unbiased spectral line survey covering the 3-mm atmospheric window between 84-117 GHz with the IRAM 30m. A smaller sample of 128 clumps has been observed in the SiO (5-4) transition with the APEX telescope to complement the SiO (2-1) line and probe the excitation conditions of the emitting gas, which is the main focus of the current study. We report a high detection rate of >75% of the SiO (2-1) line and a >90% detection rate from the dedicated follow-ups in the (5-4) transition. The SiO (2-1) line with broad line profiles and high detection rates, is a powerful probe of star formation activity, while the ubiquitous detection of SiO in all evolutionary stages suggests a continuous star formation process in massive clumps. We find a large fraction of infrared-quiet clumps to exhibit SiO emission, the majority of them only showing a low-velocity component (FWHM~5-6 km/s) centred at the rest velocity of the clump. In the current picture, where this is attributed to low-velocity shocks from cloud-cloud collisions, this can be used to pinpoint the youngest, thus, likely prestellar massive structures. Based on the line ratio of the (5-4) to the (2-1) line, our study reveals a trend of changing excitation conditions that lead to brighter emission in the (5-4) line towards more evolved sources. Our analysis delivers a more robust estimate of SiO column density and abundance than previous studies and questions the decrease of jet activity in massive clumps as a function of age.

Chemical complexity in the Horsehead photodissociation region

The interstellar medium is known to be chemically complex. Organic molecules with up to 11 atoms have been detected in the interstellar medium, and are believed to be formed on the ices around dust grains. The ices can be released into the gas-phase either through thermal desorption, when a newly formed star heats the medium around it and completely evaporates the ices; or through non-thermal desorption mechanisms, such as photodesorption, when a single far-UV photon releases only a few molecules from the ices. The first mechanism dominates in hot cores, hot corinos and strongly UV-illuminated PDRs, while the second dominates in colder regions, such as low UV-field PDRs. This is the case of the Horsehead were dust temperatures are ≃20–30 K, and therefore offers a clean environment to investigate the role of photodesorption. We have carried out an unbiased spectral line survey at 3, 2 and 1mm with the IRAM-30m telescope in the Horsehead nebula, with an unprecedented combination of bandwidth, high spectral resolution and sensitivity. Two positions were observed: the warm PDR and a cold condensation shielded from the UV field (dense core), located just behind the PDR edge. We summarize our recently published results from this survey and present the first detection of the complex organic molecules HCOOH, CH2CO, CH3CHO and CH3CCH in a PDR. These species together with CH3CN present enhanced abundances in the PDR compared to the dense core. This suggests that photodesorption is an efficient mechanism to release complex molecules into the gas-phase in far-UV illuminated regions.

The Submillimeter Array 1.3 mm line survey of Arp 220

We present the first aperture synthesis unbiased spectral line survey toward an extragalactic object. The survey covered the 40 GHz frequency range between 202 and 242 GHz of the 1.3 mm atmospheric window. We find that 80% of the observed band shows molecular emission, with 73 features identified from 15 molecular species and 6 isotopologues. The 13C isotopic substitutions of HC3N and transitions from H2(18)O, 29SiO, and CH2CO are detected for the first time outside the Galaxy. Within the broad observed band, we estimate that 28% of the total measured flux is due to the molecular line contribution, with CO only contributing 9% to the overall flux. We present maps of the CO emission at a resolution of 2.9"x1.9" which, though not enough to resolve the two nuclei, recover all the single-dish flux. The 40 GHz spectral scan has been modelled assuming LTE conditions and abundances are derived for all identified species. The chemical composition of Arp 220 shows no clear evidence of an AGN impact on the molecular emission but seems indicative of a purely starburst-heated ISM. The overabundance of H2S and the low isotopic ratios observed suggest a chemically enriched environment by consecutive bursts of star formation, with an ongoing burst at an early evolutionary stage. The large abundance of water (~10^-5), derived from the isotopologue H2(18)O, as well as the vibrationally excited emission from HC3N and CH3CN are claimed to be evidence of massive star forming regions within Arp 220. Moreover, the observations put strong constraints on the compactness of the starburst event in Arp 220. We estimate that such emission would require ~2-8x10^6 hot cores, similar to those found in the Sgr B2 region in the Galactic center, concentrated within the central 700 pc of Arp 220.

A Molecular Line Survey of Orion KL in the 350 Micron Band

With the Caltech Submillimeter Observatory, we have carried out an unbiased spectral line survey of Orion KL throughout the 350 μm band (from 795 to 903 GHz). This is the first systematic study of molecular radiation in this frequency range. A total of 541 features, resulting from 929 transitions from a total of 26 species, have been detected. High-excitation transitions from CH3OH, CH3CN, H2CO, HNCO, and C2H5CN indicate the presence of a very hot (~250 K) component at the systemic velocity characteristic of the Hot Core. Physical parameters (column density and rotational temperature) relative to a number of species have been estimated by fitting, in the LTE approximation, the whole 100 GHz spectrum at once, thus taking line blending and optical depth effects properly into account. We also report the tentative detection, for the first time outside the Galactic center region, of the radical NH2, one of the building blocks of the chemistry of ammonia.