Ultrathin Carbon Foils Research Articles

Improving the beam quality of the low-energy muon beamline at Paul Scherrer Institute: Characterization of ultrathin carbon foils

The low-energy muon (LEM) beamline at the Paul Scherrer Institute currently stands as the world’s only facility providing a continuous beam of low-energy muons with keV energies for conducting muon spin rotation experiments on a nanometer depth scale in heterostructures and near a sample’s surface. As such, optimizing the beam quality to reach its full potential is of paramount importance. One of the ongoing efforts is dedicated to improving the already applied technique of single muon tagging through the detection of secondary electrons emerging from an ultrathin carbon foil. In this work, we present the results from installing a thinner foil with a nominal thickness of 0.5 μg cm−2 and compare its performance to that of the previously installed foil with a nominal thickness of 2.0 μg cm−2. Our findings indicate improved beam quality, characterized by smaller beam spots, reduced energy loss and straggling of the muons, and enhanced tagging efficiency. Additionally, we introduce a method utilizing blue laser irradiation for cleaning the carbon foil, further improving and maintaining its characteristics. Published by the American Physical Society 2024

A low-energy particle experiment for both ion and electron measurements using a single microchannel plate-based detector

We have developed a low-energy particle experiment that alternately measures ions and electrons in space. The ability to switch between ion and electron measurements is achieved by simply adding ultra-thin carbon foils and positive and negative outputs to a conventional top-hat electrostatic analyzer and a high-voltage power supply, respectively. The advantage of this experiment is that it can perform both ion and electron measurements using only one MCP-based detector for electrons, since it detects secondary electrons emitted from the carbon foils. For the SS520-3 sounding rocket program, we prepared two identical energy analyzers, one for ions and the other for electrons to demonstrate this technique. Laboratory tests confirmed that the performance of the two analyzers was comparable to that of conventional analyzers for ion and electrons. The SS520-3 rocket experiment in the high latitude auroral region yielded observations that captured typical features of ions and electrons, which were similar to previous observations.Graphical

Imaging Neutral Particle Analyzer Engineering Design and Installation for the ASDEX Upgrade Tokamak

An imaging neutral particle analyzer (INPA) has been installed in the ASDEX Upgrade (AUG) tokamak to provide simultaneous measurements of the radial profile and the energy of the confined fast-ion (FI) population. The INPA diagnostic leverages the advantages of neutral particle analyzers (NPAs) and FI loss detectors (FILDs) by measuring charge exchange (CX) neutrals ionized by an ultrathin carbon foil is deflected into a scintillator by the local magnetic field. The design of this diagnostic has been developed under a series of constraints, such as the lack of space and hazardous environment (high level of neutron and gamma radiation), the need of high precision in the alignment of the nonsequential optical system (with six optical axes), and the optimization of the scintillator plate (signal emitter). To this end, a modular and adjustable design has been pursued with several degrees of freedom to ensure precise positioning during the installation and optical calibration. The induced electromagnetic and thermal stresses have been assessed and compared against the material limits of the detector, showing that no significant stress is expected for the system. The thermal analysis shows that the diagnostic scintillator can work efficiently during normal operation conditions. The CAD design, a comparison between the synthetic and real optical signals and the mechanical assessment [based on finite element analysis (FEA)], is presented in this contribution.

In situ STEM analysis of electron beam induced chemical etching of an ultra-thin amorphous carbon foil by oxygen during high resolution scanning

Support foils for (scanning) transmission electron microscopy ((S)TEM) samples are commonly amorphous carbon foils. State of the art (S)TEM high resolution imaging methods use ultra-thin carbon foils of only a few nm thickness, especially for imaging beam sensitive materials with low acceleration voltages and electron fluxes. In this study we analyze in situ the effect of chemical etching on a 2 nm amorphous carbon foil due to residual oxygen and by leaking in oxygen into the microscope column. We vary the vacuum level on a Nion UltraStem 100 between ultra high vacuum and that typical in TEM. This enables us to carry out a systematic investigation of chemical etching as function of both, oxygen pressure and electron flux. In addition the results of chemical etching are compared with those of sputtering from knock-on damage leading to the conclusion that chemical etching is the important cause for carbon removal from an amorphous foil at low oxygen pressures and low electron fluxes. We observe that the electron flux dependency using high resolution scanning conditions differs from the case of a resting electron beam. To interpret the results of chemical etching a scanning etching model is proposed that takes care of the specific conditions of STEM.

Selective Ion Acceleration by Intense Radiation Pressure.

We report on the selective acceleration of carbon ions during the interaction of ultrashort, circularly polarized and contrast-enhanced laser pulses, at a peak intensity of 5.5×10^{20} W/cm^{2}, with ultrathin carbon foils. Under optimized conditions, energies per nucleon of the bulk carbon ions reached significantly higher values than the energies of contaminant protons (33 MeV/nucleon vs 18MeV), unlike what is typically observed in laser-foil acceleration experiments. Experimental data, and supporting simulations, emphasize different dominant acceleration mechanisms for the two ion species and highlight an (intensity dependent) optimum thickness for radiation pressure acceleration; it is suggested that the preceding laser energy reaching the target before the main pulse arrives plays a key role in a preferential acceleration of the heavier ion species.

Dosimetry of laser-accelerated carbon ions for cell irradiation at ultra-high dose rate

Charged particle radiotherapy is currently used in an increasing number of centres worldwide. While protons are the most widely used ion species, carbon ions have shown many advantages for the treatment of radioresistant tumours, thanks to their higher Linear Energy Transfer (LET) and Relative Biological Effectiveness (RBE). The complexity and the high cost of conventional carbon therapy facilities has stimulated the investigation of alternative acceleration approaches such as the processes based on high-power laser interaction with solid targets. Recent developments in ion acceleration have allowed to investigate for the first time the biological effects of carbon ions at ultra-high dose-rate (109-1010 Gy/s) using the GEMINI laser system at Rutherford Appleton Laboratory (RAL). Carbon ions were accelerated from ultrathin (10-20 nm) carbon foils and energy selected by a magnet allowing to irradiate the cells with an average carbon energy of 10 MeV/u ± 8%. A dosimetry approach specifically designed for these low-energy ions was employed, which was based on the use of unlaminated EBT3 Radiochromic films. The details of the dosimetry arrangement as well as the Geant4 simulation performed to predict the energy and the dose distribution at the cell plane will be reported.

Angular scattering of protons through ultrathin graphene foils: Application for time-of-flight instrumentation.

Space plasma instruments often rely on ultrathin carbon foils for incident ion detection, time-of-flight (TOF) mass spectrometry, and ionization of energetic neutral atoms. Angular scattering and energy loss of ions or neutral atoms in the foil can degrade instrument performance, including sensitivity and mass resolution; thus, there is an ongoing effort to manufacture thinner foils. Using new 3-layer graphene foils manufactured at the Los Alamos National Laboratory, we demonstrate that these are the thinnest foils reported to date and discuss future testing required for application in space instrumentation. We characterize the angular scattering distribution for 3-30 keV protons through the foils, which is used as a proxy for the foil thickness. We show that these foils are ∼2.5-4.5 times thinner than the state-of-the-art carbon foils and ∼1.6 times thinner than other graphene foils described in the literature. We find that the inverse relationship between angular scattering and energy no longer holds, reaffirming that this may indicate a new domain of beam-foil interactions for ultrathin (few-layer) graphene foils.

Mars Ion and Neutral Particle Analyzer (MINPA) for Chinese Mars Exploration Mission (Tianwen-1): Design and ground calibration

The main objective of the Mars Ion and Neutral Particle Analyzer (MINPA) aboard the Chinese Mars Exploration Mission (Tianwen-1) is to study the solar wind–Mars interaction by measuring the ions and energetic neutral atoms (ENAs) near Mars. The MINPA integrates ion and ENA measurements into one sensor head, sharing the same electronics box. The MINPA utilizes a standard toroidal top-hat electrostatic analyzer (ESA) followed by a time of flight (TOF) unit to provide measurement of ions with energies from 2.8 eV to 25.9 keV and ENAs from 50 eV to 3 keV with a base time resolution of 4 seconds. Highly polished silicon single crystal substrates with an Al2O3 film coating are used to ionize the ENAs into positive ions. These ions can then be analyzed by the ESA and TOF, to determine the energy and masses of the ENAs. The MINPA provides a 360°×90° field of view (FOV) with 22.5°×5.4° angular resolution for ion measurement, and a 360°×9.7° FOV with 22.5°×9.7° angular resolution for ENA measurement. The TOF unit combines a –15 kV acceleration high voltage with ultra-thin carbon foils to resolve H+, He2+, He+, O+, O2+ and CO2+ for ion measurement and to resolve H and O (≥ 16 amu group) for ENA measurement. Here we present the design principle and describe our ground calibration of the MINPA.

Characterization of a double Time-Of-Flight detector system for accurate velocity measurement in a storage ring using laser beams

The Isochronous Mass Spectrometry (IMS) is a powerful tool for mass measurements of exotic nuclei with half-lives as short as several tens of micro-seconds in storage rings. In order to improve the mass resolving power while preserving the acceptance of the storage ring, the IMS with two Time-Of-Flight (TOF) detectors has been implemented at the storage ring CSRe in Lanzhou, China. Additional velocity information beside the revolution time in the ring can be obtained for each of the stored ions by using the double TOF detector system. In this paper, we introduced a new method of using a 658 nm laser range finder and a short-pulsed ultra-violet laser to directly measure the distance and time delay difference between the two TOF detectors which were installed inside the $10^{-11}$ mbar vacuum chambers. The results showed that the distance between the two ultra-thin carbon foils of the two TOF detectors was ranging from 18032.5 mm to 18035.0 mm over a measurable area of 20$\times$20 mm$^2$. Given the measured distance, the time delay difference which comes with signal cable length difference between the two TOF detectors was measured to be $\Delta t_{delay1-2}=99$(26) ps. The new method has enabled us to use the speed of light in vacuum to calibrate the velocity of stored ions in the ring. The velocity resolution of the current double TOF detector system at CSRe was deduced to be $\sigma(v)/v=4.4\times 10^{-4}$ for laser light, mainly limited by the time resolution of the TOF detectors.

Polarization Dependence of Bulk Ion Acceleration from Ultrathin Foils Irradiated by High-Intensity Ultrashort Laser Pulses.

The acceleration of ions from ultrathin (10-100nm) carbon foils has been investigated using intense (∼6×10^{20} W cm^{-2}) ultrashort (45fs) laser pulses, highlighting a strong dependence of the ion beam parameters on the laser polarization, with circularly polarized (CP) pulses producing the highest energies for both protons and carbons (25-30 MeV/nucleon); in particular, carbon ion energies obtained employing CP pulses were significantly higher (∼2.5 times) than for irradiations employing linearly polarized pulses. Particle-in-cell simulations indicate that radiation pressure acceleration becomes the dominant mechanism for the thinnest targets and CP pulses.

Accelerating and guiding of C6+ by an intense laser irradiating on a foil target with a tapered channel

A novel scheme with a tapered channel attached to an ultra-thin carbon foil is proposed to accelerate and guide carbon ions via breakout afterburner mechanism. Also, the problems involved are investigated by using two-dimensional particle-in-cell simulations. It is demonstrated that the tapered channel can efficiently accelerate and guide carbon ions and result in a much better quality beam with an order of magnitude higher in density and 22% larger in cut-off energy than that without the tapered channel. The enhanced reasons are analyzed in detail, which are mainly attributed to the guidance of the longitudinal electric field and the focus of the transverse electric field, as well as the convergence effect of the tapered channel. All of them are certified to guide greatly carbon ions to move along the longitudinal direction. Besides, during the simulation time, the ion beam with a tapered channel can remain eight times smaller in divergence angle than that without the tapered channel. Such a target may be beneficial to many applications such as ion fast ignition in inertial fusion, high-energy physics, and proton therapy.

The Low-Energy Neutral Imager (LENI).

To achieve breakthroughs in the areas of heliospheric and magnetospheric energetic neutral atom (ENA) imaging, a new class of instruments is required. We present a high angular resolution ENA imager concept aimed at the suprathermal plasma populations with energies between 0.5 and 20 keV. This instrument is intended for understanding the spatial and temporal structure of the heliospheric boundary recently revealed by Interstellar Boundary Explorer instrumentation and the Cassini Ion and Neutral Camera. The instrument is also well suited to characterize magnetospheric ENA emissions from low‐altitude ENA emissions produced by precipitation of magnetospheric ions into the terrestrial upper atmosphere, or from the magnetosheath where solar wind protons are neutralized by charge exchange, or from portions of the ring current region. We present a new technique utilizing ultrathin carbon foils, 2‐D collimation, and a novel electron optical design to produce high angular resolution (≤2°) and high‐sensitivity (≥10−3 cm2 sr/pixel) ENA imaging in the 0.5–20 keV energy range.

Investigation of the influence of surface composition on the charge state distribution of ∼keV hydrogen exiting thin carbon foils for space plasma instrumentation

Energetic neutral atom (ENA) imaging techniques have become a powerful tool for remotely probing plasma environments in space. ENA imagers cover energies from 0.01keV up to a few MeV, and they use different techniques to cover such a broad energy range. Most of them convert the ENA into a charged particle to remove the converted ENA from the initial neutral direction. In the >∼0.2keV/nuc to 10’s of keV/nuc range, the conversion subsystem is usually an ultra-thin carbon foil. The sensitivity of ENA imagers based on charge conversion by carbon foils is driven by the ability of these foils to convert a neutral atom into an ion. The charge state distribution after the carbon foils is a strong function of the chemical and physical properties of the exit surface.In this study, we analyze the composition and structure of the surface using X-ray photoelectron spectroscopy. The surface is roughly 88% carbon and 12% oxygen, forming strong CO bonds. Annealing the foil lowers the oxygen content to about 9%. We coat the surface of the foils with Au, Al2O3, or MgO. We compare the exit charge state distributions of hydrogen prior to and post coatings. While no significant difference is observed in the exit charge state for the Au and Al2O3 coatings, there is a slight decrease of the positive fraction after MgO. The annealing of the foil has the benefit of reducing the angular scattering of hydrogen by a factor of ∼1.2. This is a significant improvement that has the potential to increase sensitivity of ENA imagers.

MAVEN SupraThermal and Thermal Ion Compostion (STATIC) Instrument

The MAVEN SupraThermal And Thermal Ion Compostion (STATIC) instrument is designed to measure the ion composition and distribution function of the cold Martian ionosphere, the heated suprathermal tail of this plasma in the upper ionosphere, and the pickup ions accelerated by solar wind electric fields. STATIC operates over an energy range of 0.1 eV up to 30 keV, with a base time resolution of 4 seconds. The instrument consists of a toroidal “top hat” electrostatic analyzer with a $360^{\circ} \times 90^{\circ}$ field-of-view, combined with a time-of-flight (TOF) velocity analyzer with $22.5^{\circ}$ resolution in the detection plane. The TOF combines a $-15~\mbox{kV}$ acceleration voltage with ultra-thin carbon foils to resolve $\mathrm{H}^{+}$ , $\mathrm{He}^{++}$ , $\mathrm{He}^{+}$ , $\mathrm{O}^{+}$ , $\mathrm{O}_{2}^{+}$ , and $\mathrm{CO}_{2}^{+}$ ions. Secondary electrons from carbon foils are detected by microchannel plate detectors and binned into a variety of data products with varying energy, mass, angle, and time resolution. To prevent detector saturation when measuring cold ram ions at periapsis ( $\sim10^{1 1}~\mbox{eV/cm}^{2}\,\mbox{s}\,\mbox{sr}\,\mbox{eV}$ ), while maintaining adequate sensitivity to resolve tenuous pickup ions at apoapsis ( $\sim10^{3}~\mbox{eV/cm}^{2}\,\mbox{s}\,\mbox{sr}\,\mbox{eV}$ ), the sensor includes both mechanical and electrostatic attenuators that increase the dynamic range by a factor of $10^{3}$ . This paper describes the instrument hardware, including several innovative improvements over previous TOF sensors, the ground calibrations of the sensor, the data products generated by the experiment, and some early measurements during cruise phase to Mars.

Avalanche photodiode based time-of-flight mass spectrometry.

This study reports on the performance of Avalanche Photodiodes (APDs) as a timing detector for ion Time-of-Flight (TOF) mass spectroscopy. We found that the fast signal carrier speed in a reach-through type APD enables an extremely short timescale response with a mass or energy independent <2 ns rise time for <200 keV ions (1-40 AMU) under proper bias voltage operations. When combined with a microchannel plate to detect start electron signals from an ultra-thin carbon foil, the APD comprises a novel TOF system that successfully operates with a <0.8 ns intrinsic timing resolution even using commercial off-the-shelf constant-fraction discriminators. By replacing conventional total-energy detectors in the TOF-Energy system, APDs offer significant power and mass savings or an anti-coincidence background rejection capability in future space instrumentation.

A Satellite-borne Miniature Ion Mass Spectrometer for Space Plasma

The miniature design technology is an important trend in space exploration. Mass spectrometer is used extensively in the space environment detection. The miniature ion mass spectrometer utilizes a 127° cylindrical electrostatic analyzer accompanied with a Time of Flight (TOF) unit based on ultrathin carbon foil to measure the energy spectra and composition of space plasma. The Time of Flight technique has been used broadly in space plasma measurement. A new type of miniature method for the ion mass spectrometer is introduced. The total mass of the instrument is 1.8 kg and the total power consumption is 2.0W. The calibration results show that the energy measurement range is 8.71～43550eV, the energy resolution is 1.86% and the ion mass from 1 amu (1 amu = 1.67 × 10^-27 kg) to 58 amu can be resolved by the miniature mass spectrometer. The miniature ion mass spectrometer also has a potential to be increased in the field of view by an electrostatic deflecting system to extend its application in space plasma detection. The miniature ion mass spectrometer has been selected for pre-study of Chinese Strategic Priority Research Program on Space Science.

Thin carbon foil resistance to differential pressure

Thin carbon foils are used in different environments for various purposes. For example, they are used in vacuum technology to create a barrier between two volumes, in space plasma instrumentation to detect the crossing of a particle passing through them, or as a stripper of electrons for high energy particles. In the case of a change of pressure on either side of the foil, the pressure differential creates mechanical stresses to the foil that can lead to irreversible damage. Few experiments have characterized the survivability of carbon foils as a function of pressure. In this study, we show measurements of the resistance to pressure of carbon foils (CF) up to partial rupture. The focus is on ultra-thin carbon foils (e.g., 0.5–1.0 μg/cm2) that are typically used in space plasma instrumentation. However, our results can be used in other areas of experimental physics. Our results show that the finer the pitch of the supporting grid, the more pressure resistant the foil is, indicating that the CF support grid is perhaps more important in the design trade than the foil thickness. For example, we find that nominal 1.0 μg/cm2 foils mounted on 13.1 lpmm (333 lines per inch) nickel grids can hold a remarkable static pressure of ∼9 kPa (∼1.3 psi) with almost no damage.

Charge state of ∼1 to 50 keV ions after passing through graphene and ultrathin carbon foils

Carbon foils have been used reliably for many decades in space plasma instrumentation to detect ions and energetic neutral atoms (ENA). When these particles pass through a foil, secondary electrons are emitted on both sides. Those electrons are used for coincidence detection and/or timing signals. Ultrathin carbon foils are also used to convert an ENA into an ion for further analysis. The interaction of particles with carbon foils also includes unwanted effects such as energy straggling and angular scattering, both of which scale with foil thickness. Therefore, it has always been a goal to use foils as thin as practically possible. The foils used in space are usually made of amorphous carbon of roughly a hundred atomic layers. Graphene can be made much thinner, even down to a single atomic layer, and is therefore a natural candidate for this kind of application. We evaluate one aspect of the interaction of particles with foils: charge exchange. We show the first measurements of exit charge state distributions of ∼1 to 50 keV ions passing through self-supported graphene foils. We compare the charge state fraction of exiting particles with state-of-the-art amorphous carbon foils.

Preparation of self-supporting diamond-like carbon nanofoils with thickness less than 5 nm for laser-driven ion acceleration

Ultrathin (<5nm) self-supporting diamond-like carbon (DLC) foils are prepared by filtered cathodic vacuum arc (FCVA) deposition method as targets for laser-driven ion acceleration. The thickness and the morphology of these foils are characterized by atomic force microscope (AFM) and scanning electron microscope (SEM).

A Composition Analysis Tool for the Solar Wind Around Pluto (SWAP) Instrument on New Horizons

We describe the response of the Solar Wind Around Pluto (SWAP) instrument (McComas et al. in Space Sci. Rev. 140:261, 2008) to 1–40 amu ions in order to assess whether it can be used to determine plasma composition. Our goal is to enhance the scientific return on the SWAP plasma measurements obtained during the New Horizons traversal down Jupiter’s magnetotail in 2007. We present calibration data for the SWAP flight instrument and another largely flight-like SWAP sensor, dubbed “SWAP-II”. SWAP’s mass-dependent response was characterized by analyzing the count ratios from its two channel electron multipliers (CEMs). We observe significant differences in the instrument response between light (mass ≤ He) and heavy (mass > He) ions, especially for energies below ∼4 keV. We attribute these differences to the mass-dependent electron emission yield from SWAP’s ultra-thin (∼1 μg/cm2) carbon foil. Using these results, we develop a plasma composition analysis technique to statistically distinguish between light and heavy plasma ions measured by the instrument.