Ultramafic Clasts Research Articles

Fluid‐Mantle Interaction Along the Mariana Convergent Margin

AbstractActive serpentinite mud volcanoes in the forearc region of the Izu‐Bonin‐Mariana system represent an excellent natural laboratory for studying the geochemical processes along convergent plate margins and the associated forearc. During IODP Expedition 366, serpentinite mud with lithic clasts from the underlying forearc crust and mantle as well as from the subducting Pacific Plate was recovered. Ultramafic clasts from Fantangisña Seamount reveal very high degrees of serpentinization with mesh and bastite textures as well as development of late lizardite and chrysotile veins, which suggests serpentinization temperatures below 200°C. On the other hand, recovered harzburgites and, on occasion, dunites from Asùt Tesoru Seamount show a well‐preserved primary assemblage with low degrees of serpentinization and forearc peridotite characteristics. Fine‐grained antigorite associating with lizardite has been identified throughout the serpentine mud matrix, suggesting an alteration temperature of c. 340°C. Furthermore, alteration conditions during rodingitization point to temperatures of at least 228°C, estimated via chlorite geothermometry. Additionally, a rare ophicarbonate clast containing andraditic as well as Cr‐rich hydrogarnets from Asút Tesoru Seamount indicates crystallization temperatures of at least 230°C. Hence, a trend of lower temperature of serpentinization and higher degree of alteration closer to the trench. The detailed characterization of the fluid‐rock alteration conditions as well as fluids composition and transport permits a better constraining of the fluid–rock interactions and related mass transfers within subduction zones and during ascent of serpentinite fault gouge within mud volcano conduits and in mudflows after their emplacement on the flanks of the edifices.

Petrology and mineralogy of mesosiderite Northwest Africa 12949: Implications for geological history on its parent body

AbstractMesosiderites are breccias composed of roughly equal parts of metal phases and silicate clasts. However, the parent body and formation process of mesosiderites remain enigmatic. Northwest Africa (NWA) 12949 is a newly found mesosiderite belonging to type 2A. One type of ultramafic clasts and four types of mafic clasts (gabbroic, poikilitic, subophitic, and cataclastic), compositionally consistent with diogenites and eucrites, have been identified in NWA 12949. However, these clasts have undergone different thermal histories, with cooling rates varying from ~0.0044 °C year−1 to a few °C h−1, and equilibrium temperatures varying from ~880 to 910 °C to ~1000 to 1100 °C. All the lithic clasts have undergone redox reactions during extensive metamorphism, forming excess troilite, chromite, merrillite, tridymite, and pyroxene with lower Fe/Mg and Fe/Mn. The petrology and mineralogy of NWA 12949 support a formation scenario involving two major impact events, and a candidate parent body of 4 Vesta.

Geochemical and C‐O Isotopic Study of Ophiolite‐Derived Carbonates of the Barzaman Formation, Oman: Evidence of Natural CO2 Sequestration Via Carbonation of Ultramafic Clasts

AbstractCarbonate precipitation through atmospheric CO2 uptake by alkaline‐hyperalkaline waters offers a potential approach to mitigating anthropogenic CO2 emissions. The Oman Ophiolite produces high‐pH water characterized by continuous sequestration of CO2 at the air‐water interface. The geochemical and isotopic data of carbonates from the Barzaman Formation is used to assess the amount of atmospheric CO2 stored in the dolomite‐calcite assemblage. Post Archean Australian Shale ‐normalized rare earth elements patterns, with the exception of La and Ce anomalies, are similar to those of the bulk oceanic and lower crusts, with increasing LREE and flat HREE trends, and a positive Eu anomaly. The δ13CVPDB and δ18OVSMOW isotope values of the analyzed samples show two distinct end‐members, in which dolomite (−7.77‰ and +27.3‰) is isotopically heavier than calcite (−9.93‰ and +21.5‰). The estimated carbonate growth temperatures (18°C–56°C) are indistinguishable from the previously reported range (18°C–66°C). The C‐O isotope model for calcite, groundwater, and atmospheric CO2 shows that an ophiolite‐derived calcite sample absorbed an unequivocal amount of atmospheric CO2 (78% ± 11%) during precipitation. At the same time, dissolved inorganic carbon (DIC) in water accounts for the remaining carbon contribution (22% ± 9%). DIC is closely associated with different carbonate lithofacies and ophiolite‐derived soil, exhibiting large variations in C‐O isotopic compositions caused by isotopic disequilibrium. Taken together, geochemical and isotopic properties confirm that the carbonates were formed under oxic conditions triggered by the water‐rock interaction. For a reliable estimate of CO2 sequestered by carbonates of the Barzaman Formation, a systematic groundwater analysis is recommended to determine the contribution of CO2 in DIC.

Systematic changes in serpentine Si isotope signatures across the Mariana forearc – a new proxy for slab dehydration processes

The Mariana forearc is a unique location for exploring the role serpentinization plays in the marine Si cycle by means of Si stable isotope variations. Here, active mud volcanism transports deep, serpentinized mantle wedge material to the surface and thus offers a natural window to slab dehydration processes in dependence of changing temperature and pressure with depth. Si isotopes were measured in situ by femtosecond laser ablation MC-ICPMS in serpentine within ultramafic clasts from three mud volcanoes (Yinazao, Fantangisña, and Asùt Tesoru) sampled during International Ocean Discovery Program Expedition 366. To corroborate the results, serpentinization of olivine was studied in batch experiments. The Si isotope ratios show large variations between the mud volcanoes and between individual serpentine generations within a given mud volcano. Serpentine that formed early under low water/rock ratios exhibits δ30Si of −0.41 ± 0.04‰ (1SD) similar to unaltered olivine which agrees well with experimental findings predicting no significant isotope fractionation during early serpentinization. In contrast, late serpentine veins formed under higher water/rock ratios span a wide range of Si isotope ratios that differ significantly between the individual mud volcanoes. With increasing distance to the trench, δ30Si of late veins are −0.10 ± 0.07‰, −1.94 ± 0.13‰, and −0.80 ± 0.22‰ and −0.93 ± 0.21‰. These δ30Si values are interpreted to record the isotopic composition of the fluid source, namely subducted biogenic silica and pore fluids, clays, and altered oceanic crust that dehydrate as consequence of rising pressure and temperature with depth. We show that Si isotopes of mantle wedge serpentinites can be used as a reliable new proxy for slab dehydration processes. They may be used in paleo-forearc systems to unravel oceanic sediment and silica biomineralization evolution through geological time.

Temporal and spatial mineralogical changes in clasts from Mariana serpentinite mud volcanoes: Cooling of the hot forearc-mantle at subduction initiation

Mafic and ultramafic clasts (mostly ~1–5 cm in size) were recovered from three different serpentinite mud volcanos in the Mariana forearc during Integrated Ocean Drilling Program (IODP) Expedition 366. Mafic clasts from drill sites distant from the trench bear lawsonite, Al-rich riebeckite, jadeitic pyroxene (~80 mol% jadeite), and aragonite as metamorphic minerals. In contrast, mafic clasts from drill sites closer to the trench are characterized by prehnite–pumpellyite-facies mineral associations and/or the presence of analcime and natrolite. An occurrence of antigorite-bearing ultramafic clasts becomes progressively more frequent with distance from the trench. One amphibolite clast from a mud volcano near the trench also has prehnite filling veins, and it also occurs as pseudomorphs after plagioclase. Amphibolite clasts at other mud volcanoes distant from the trench are partially overprinted by blueschist-facies minerals. The apparent metamorphic grades increase with distance from the trench; these metamorphic conditions represent the increasing depth from zeolite- to lawsonite–blueschist-facies conditions in a subduction zone. Considering the consistency of the low-temperature metamorphic grade of mafic and ultramafic clast mineralogy in each mud volcano, they likely reflect the thermal structure of the slab-mantle interface before the ascent. As a result, these clasts were brought up to the seafloor en masse by the serpentinite mudflow. The polymetamorphosed amphibolite clasts suggest cooling of the hot forearc-mantle at the initiation of Mariana subduction in the Eocene. The ultramafic clasts in the mud volcanoes distant from the trench frequently contain Ca amphibole and talc, which indicates hot mantle hydration by metasomatic fluids released from the slab at subduction initiation.

Clasts in Archean conglomerates and implications for uplift: Evidence from the 2.7 Ga Agnew Greenstone Belt (Western Australia)

Archean greenstone belts commonly consist of a stratigraphy that records subaqueous deposition capped by subaerial sedimentation, yet it remains unclear if the controls on this change were driven by horizontal or vertical processes. Clasts in conglomerates can provide important constraints on this question because they inform on the changing nature of sources. The 2.7 Ga Agnew Greenstone Belt, Yilgarn Craton, Australia, provides the ideal opportunity for such a study because it contains abundant and diverse conglomerate facies and its basal stratigraphy is well understood. This study focusses on the texture and composition of lithic clasts derived from three stratigraphic conglomerate units and their host successions. The lowermost conglomerate-bearing unit, hosted in the Vivien Formation, unconformably overlies the mafic-ultramafic lavas and intrusions of the Kalgoorlie Group (ca. 2720–2690 Ma) and is dominated by aphyric to porphyritic mafic and felsic volcanic clasts. The conformably overlying Maria Mine Formation conglomerates contain a higher proportion of felsic clasts with medium- and plutonic groundmass textures. The Vivien and Maria Mine Formations (ca. 2690–2670 Ma) are dominated by cherts, turbidites and conglomerates, and represent subaqueous sediments formed in the ring-plain surrounding an emergent volcanic island. The unconformably overlying Scotty Creek Formation (ca. 2665–2655 Ma) contains conglomerates with many plutonic felsic clasts, and is dominated by bedded and cross-bedded sandstones formed in a subaerial environment. Whole-rock geochemistry of mafic and ultramafic clasts matches the local Kalgoorlie Group rocks and indicates progressive erosion of the underlying supracrustal sequence. Undeformed conglomerates lack clasts with metamorphic foliations, indicating uplift by horizontal compression could not have been significant before ca. 2655 Ma, which is considered as the time of the first major compressional event in many published structural frameworks for the region. The systematic erosion of a felsic stratovolcano, its associated plumbing system, and any resultant upwarping of underlying sequences through vertically-driven diapirism, better explains the progressive changes observed in clast texture and composition, as opposed to horizontally-driven uplift, such as compression associated with subduction.

Variant across-forearc compositions of slab-fluids recorded by serpentinites: Implications on the mobilization of FMEs from an active subduction zone (Mariana forearc)

Serpentinite mud volcanism in the Mariana forearc provides a window into the shallow portions of an active subduction zone. Fluid–rock interactions and related mass transfers into the mantle wedge can be assessed by studying the trace element compositions of slab-derived fluids and serpentinized mantle wedge materials brought to the seafloor by the serpentinite mud volcanoes. We investigated variably serpentinized ultramafic clasts from the Yinazao, Fantangisña, and Asùt Tesoru mud volcanoes recovered on International Ocean Discovery Program Expedition 366 to examine the transfer of fluid-mobile elements (FMEs) from the slab to the wedge. These mud volcanoes sample the slab–wedge interface at depths of ~13–18 km and estimated temperatures of 80–250 °C. Our samples represent the serpentinized forearc and exhibit a multi-phase serpentinization history, as apparent from microfabrics, mineralogy, and in situ major and trace elemental analyses of distinct generations of serpentine. Initial hydration of the forearc mantle occurred under reducing conditions by Si-rich fluids. Early serpentine is characterized by generally high concentrations of Li, Sr, Rb, Cs, and Ba. Subsequent fluid–rock interactions were driven by Si-rich and FME-poor fluids and at later stages by Si- and FME-poor fluids in the mud volcano conduits, the latter of which resulted in the abundant formation of Fe-rich brucite. Iowaite and hematite indicate that less reducing conditions prevailed during the alteration of clasts after their emplacement at the seafloor. Concentrations of B are generally high but our dataset does not allow distinguishing slab- from seawater-derived B.Serpentine from the shallow-sourced Yinazao exhibits high Rb/Cs ratios of ≤37, highest concentrations of Li, but lowest Rb, Sr, Ba, and Cs contents. The serpentinizing fluids were derived from expulsion of sedimentary pore waters and by the breakdown of opal in the subducted sediments. Serpentine at the intermediate-sourced Fantangisña has Rb/Cs ratios of <10, similar Li, Sr, and Ba concentrations as Yinazao, but higher Rb and Cs contents. These patterns likely reflect dewatering and FME-release from clays in the subducted sediments. Fluids at the deeply sourced Asùt Tesoru as well originate from clay-breakdown, but increased concentrations of Rb, Sr, Cs, and Ba are further indicative of beginning dehydration of altered oceanic crust.Including data from the South Chamorro serpentinite mud volcano (18 km slab depth; Kahl et al., 2015, Lithos), we provide a detailed record of slab dehydration reactions at shallow forearc depths and the related mobilization of FMEs as well as their transport into the mantle wedge. Our study demonstrates that slab-derived fluids undergo extensive alteration during the interaction with mantle wedge peridotite. Pore waters from the serpentinite mud volcanoes hence provide incomplete insight into the processes at depth; fluid signatures at the slab–wedge interface as well as their across-forearc changes are best recorded in early hydration products such as serpentine.

Petrogenesis of ultramafic-mafic clasts in the Dos Hermanos Mélange, Ilocos Norte: Insights to the evolution of western Luzon, Philippines

The clasts of ophiolitic mélanges formed in orogenic margins reflect the tectonomagmatic history of a region and record the petrological signatures of oceanic lithospheres that interacted in the past. Exposed at the northwestern edge of Luzon, Philippines, the highly deformed Dos Hermanos Mélange (DHM) provides new insights on the complex history of western Luzon island. The DHM is a tectonic mélange composed predominantly of ultramafic-mafic clasts set in a sheared serpentinite matrix. The ultramafic clasts are mostly harzburgites with rare occurrences of lherzolite, dunite and chromitite. Petrographic (e.g. protogranular to equigranular texture) and geochemical characteristics (e.g. spinel Cr# = 0.17–0.60, olivine Fo content = 87–91) of the peridotites typify residual mantle peridotites which underwent low to moderately high degrees of partial melting. Mineral chemistry of some dunite and harzburgite samples (e.g. high spinel TiO2 = 0.01–0.64 wt%) further record subsequent modification of the depleted mantle material by arc-related processes (e.g. metasomatism). Most of the mafic clasts classify as gabbros and are composed of highly anorthitic plagioclase (An88–99) and Ti-poor pyroxenes which suggest derivation from arc-related melts. One troctolite clast, however, records the distinct petrographic (e.g. ophitic texture) and geochemical (e.g. low An content of plagioclase = 73–80) signatures of primitive MOR-related magma. These contrasting petrologic signatures in the ultramafic-mafic clasts of the DHM are similar to those observed in the crustal and mantle sections of the Eocene Zambales Ophiolite Complex (ZOC). This suggests that the DHM, like the ZOC, records the complex history of the convergence and emplacement of an ancient oceanic crust onto the Philippine Mobile Belt. Later tectonic processes in the region, which occurred after the emplacement of the ZOC, resulted to the extensive dissection and translation of ophiolitic blocks northwards transforming them into the DHM.

Shallow forearc mantle dynamics and geochemistry: New insights from IODP Expedition 366

The Mariana forearc is a unique setting on Earth where serpentinite mud volcanoes exhume clasts originating from depths of 15 km and more from the forearc mantle. These peridotite clasts are variably serpentinized by interaction with slab derived fluid, and provide a record of forearc mantle dynamics and changes in geochemistry with depth. During International Oceanic Discovery Program (IODP) Expedition 366, we recovered serpentinized ultramafic clasts contained within serpentinite muds of three different mud volcanoes located at increasing distance from the Mariana trench and at increasing depth to the slab/mantle interface: Yinazao (distance to the trench: 55 km / depth to the slab/mantle interface: 13 km), Fantangisña (62 km / 14 km) and Asùt Tesoru (72 km / 18 km). Four different types of ultramafic clasts were recovered: blue serpentinites, lizardite-serpentinites, antigorite/lizardite- and antigorite-serpentinites. Lizardite-serpentinites are primarily composed of orange serpentine, forming mesh and bastite textures. Raman and microprobe analyses revealed that these textures contain a mixture of Fe-rich brucite (XMg ~ 0.84) and lizardite/chrysotile. Antigorite/lizardite- and antigorite-serpentinites record the progressive recrystallization of mesh and bastite textures to antigorite, magnetite and pure Fe-poor brucite (XMg ~ 0.92). Oxygen isotope compositions of clasts and pore fluids showed that the transition from lizardite to antigorite is due to the increase in temperature from 200 °C to about 400 °C within the forearc area above the slab/mantle interface. Lizardite-, antigorite/lizardite- and antigorite-serpentinites displayed U-shaped chondrite normalized Rare Earth Element (REE) patterns and are characterized by high fluid mobile element concentrations (Cs, Li, Sr, As, Sb, B, Li) relative to abyssal peridotites and/or primitive mantle. The recrystallization of lizardite to antigorite is accompanied by a decrease in Cs, Li and Sr, and an increase in As and Sb concentrations in the bulk clasts, whereas B concentrations are relatively constant. Some clasts are overprinted by blue serpentine, often in association with sulfides. Most of these blue serpentinites were recovered at Yinazao and the uppermost units of Fantangisña and Asùt Tesoru suggesting alteration in the shallower portions of the forearc, possibly during exhumation of the clasts. This episode of alteration resulted in a flattening of REE spectra and an increase of Zn concentrations in serpentinites. Otherwise, no systematic changes of ultramafic clasts chemistry or mineralogy were observed with increasing depth to the slab. The samples document previously undescribed prograde metamorphic events in the shallow portions of the Mariana subduction zone, consistent with a continuous burial of the serpentinized forearc mantle during subduction. Similar processes, induced by the interaction with fluids released from the downgoing slab, likely occur in subduction zones worldwide. At greater depth, breakdown of brucite and antigorite will result in the massive transfer of fluids and fluid mobile elements, such as As, Sb and B, to the source of arc magmas.

Pervasive silicification and hanging wall overplating along the 13°20′N oceanic detachment fault (Mid‐Atlantic Ridge)

AbstractThe corrugated detachment fault zone of the active 13°20′N oceanic core complex (Mid‐Atlantic Ridge) was investigated with a deep‐sea vehicle to assess the links between deformation, alteration, and magmatism at detachment fault zones. We present a study of 18 in situ fault rock samples from striated fault outcrops on the flanks of microbathymetric corrugations. All the samples are mafic breccias that are mostly derived from a diabase protolith, with two of them also showing mixing with ultramafic clasts. Breccias are cataclastic and display variable deformation textures, recording numerous slip events, and showing pervasive silicification throughout the fault zone. Deformation‐silicification relationships are also complex, showing both static and syntectonic quartz precipitation; undeformed quartz overprints the fault breccia textures, and reflective and striated fault surfaces cross‐cut silicified rocks. In situ detachment fault rocks are mainly fault breccias with almost exclusively basaltic clasts, with rare ultramafic ones, a lithology and texture never observed previously at other oceanic detachment fault zones. We propose the lower dyke complex in the hanging wall crust at the volcanic rift valley floor is the most plausible diabase source. Mechanical mixing of predominantly mafic and rare ultramafic clasts suggests an underlying ultramafic footwall and that mafic accretion operates in the shallowest crust (1–2 km), at the base of the dyke complex at temperatures &gt;400°C. Silicification is produced by silica‐rich fluids syntectonically channeled along the fault zone, and likely derived from hydrothermal alteration of basaltic rocks, likely mixed with serpentinization‐derived fluids.

The Munali Ni sulfide deposit, southern Zambia: A multi-stage, mafic-ultramafic, magmatic sulfide-magnetite-apatite-carbonate megabreccia

The Munali Intrusive Complex (MIC) is a flattened tube-shaped, mafic-ultramafic intrusion located close to the southern Congo Craton margin in the Zambezi belt of southern Zambia. It is made up of a Central Gabbro Unit (CGU) core, surrounded by a Marginal Ultramafic-mafic Breccia Unit (MUBU), which contains magmatic Ni sulfide mineralisation. The MIC was emplaced into a sequence of metamorphosed Neoproterozoic rift sediments and is entirely hosted within a unit of marble. Munali has many of the characteristics of craton-margin, conduit-style, dyke-sill complex-hosted magmatic sulfide deposits. Three-dimensional modelling of the MUBU on the southern side of the MIC, where the Munali Nickel Mine is located, reveals a laterally discontinuous body located at the boundary between footwall CGU and hangingwall metasediments. Mapping of underground faces demonstrates the MUBU to have intruded after the CGU and be a highly complex, multi stage megabreccia made up of atypical ultramafic rocks (olivinites, olivine-magnetite rocks, and phoscorites), poikilitic gabbro and olivine basalt/dolerite dykes, brecciated on a millimetre to metre scale by magmatic sulfide. The breccia matrix is largely made up of a sulfide assemblage of pyrrhotite-pentlandite-chalcopyrite-pyrite with varying amounts of magnetite, apatite and carbonate. The sulfides become more massive towards the footwall contact. Late stage, high temperature sulfide-carbonate-magnetite veins cut the rest of the MUBU. The strong carbonate signature is likely due, in part, to contamination from the surrounding marbles, but may also be linked to a carbonatite melt related to the phoscorites. Ductile deformation and shear fabrics are displayed by talc-carbonate altered ultramafic clasts that may represent gas streaming textures by CO2-rich fluids. High precision U-Pb geochronology on zircons give ages of 862.39±0.84Ma for the poikilitic gabbro and 857.9±1.9Ma for the ultramafics, highlighting the multi-stage emplacement but placing both mafic and later ultramafic magma emplacement within the Neoproterozoic rifting of the Zambezi Ocean, most likely as sills or sheet-like bodies. Sulfide mineralisation is associated with brecciation of the ultramafics and so is constrained to a maximum age of 858Ma. The Ni- and Fe-rich nature of the sulfides reflect either early stage sulfide saturation by contamination, or the presence of a fractionated sulfide body with Cu-rich sulfide elsewhere in the system. Munali is an example of a complex conduit-style Ni sulfide deposit affected by multiple stages and sources of magmatism during rifting at a craton margin, subsequent deformation; and where mafic and carbonatitic melts have interacted along deep seated crustal fault systems to produce a mineralogically unusual deposit.

Record of Jurassic mass transport processes through the orogenic cycle: Understanding chaotic rock units in the high-pressure Zermatt-Saas ophiolite (Western Alps)

The eclogite facies Zermatt-Saas ophiolite in the Western Alps includes a composite chaotic unit exposed in the Lake Miserin area, in the southern Aosta Valley region. The chaotic unit is characterized by a block-in-matrix texture consisting of ultramafic clasts and blocks embedded within a carbonate matrix. This unit overlies massive serpentinite and ophicarbonate rocks and is unconformably overlain by layered calcschist. Despite the effects of subduction and collision-related deformation and metamorphism, the internal stratigraphy and architecture of the chaotic unit are recognizable and are attributed to different types of mass transport processes in the Jurassic Ligurian-Piedmont Ocean. This finding represents an exceptional record of the preorogenic history of the Alpine ophiolites, marked by different pulses of extensional tectonics responsible for the rough seafloor topography characterized by structural highs exposed to submarine erosion. The Jurassic tectonostratigraphic setting envisioned is comparable to that observed in present-day magma-poor slow- and ultraslow-spreading ridges, characterized by mantle exposure along fault scarps that trigger mass transport deposits and turbiditic sedimentation. Our preorogenic reconstruction is significant in an eclogitized collisional orogenic belt in which chaotic rock units may be confused with the exclusive product of subduction-related tectonics, thus obscuring the record of an important preorogenic history.

Ultramafic clasts from the South Chamorro serpentine mud volcano reveal a polyphase serpentinization history of the Mariana forearc mantle

Serpentine seamounts located on the outer half of the pervasively fractured Mariana forearc provide an excellent window into the forearc devolatilization processes, which can strongly influence the cycling of volatiles and trace elements in subduction zones. Serpentinized ultramafic clasts recovered from an active mud volcano in the Mariana forearc reveal microstructures, mineral assemblages and compositions that are indicative of a complex polyphase alteration history. Petrologic phase relations and oxygen isotopes suggest that ultramafic clasts were serpentinized at temperatures below 200°C. Several successive serpentinization events represented by different vein generations with distinct trace element contents can be recognized. Measured in situ Rb/Cs ratios are fairly uniform ranging between 1 and 10, which is consistent with Cs mobilization from sediments at lower temperatures and lends further credence to the low-temperature conditions proposed in models of the thermal structure in forearc settings. Late veins show lower fluid mobile element (FME) concentrations than early veins, suggesting a decreasing influence of fluid discharge from the subducting slab on the composition of the serpentinizing fluids. The continuous microfabric and mineral chemical evolution observed in the ultramafic clasts may have implications as to the origin and nature of the serpentinizing fluids. We hypothesize that opal and smectite dehydration produce quartz-saturated fluids with high FME contents and Rb/Cs between 1 and 4 that cause the early pervasive serpentinization. The partially serpentinized material may then be eroded from the basal plane of the suprasubduction mantle wedge. Serpentinization continued but the interacting fluids did not carry a pronounced sedimentary signature, either because FMEs were no longer released from the slab, or due to an en route loss of FMEs. Late chrysotile veins that document the increased access of fluids in a now fluid-dominated regime are characterized by reduced trace element contents with a slightly increased Rb/Cs ratio near 10. This lack of sediment-dominated geochemical signatures consistently displayed in all late serpentinization stages may indicate that the sediment-derived fluids have been completely reset (i.e. the FME excesses were removed) by continued water–rock reaction within the subduction channel. The final stage of buoyant rise of matrix and clasts in the conduits is characterized by brucite-dominated alteration of the clasts from the clast rim inward (independent of the intra-clast fabric relations), which corresponds to re-equilibration with alkaline, low-silica activity fluids in the rising mud.

Exhumation of subcontinental mantle rocks: evidence from ultramafic-bearing clastic deposits nearby the Lherz peridotite body, French Pyrenees

Abstract In the eastern Pyrenees, the lherzolites always outcrop as restricted bodies scattered across Mesozoic sedimentary units along the North Pyrenean fault. In this article, we focus on the sedimentary processes associated with the tectonic exhumation of the mantle rocks during the Lower Cretaceous and we provide a new detailed analysis of the ultramafic-bearing sedimentary sequences associated with the Lherz body. The Lherz body, 1.5 km long only, belongs to a series of ultramafic bodies of restricted size (a few m to some hundred of m), occurring within sedimentary formations composed mostly of carbonate breccias originating from the reworking of Mesozoic platform limestones and dolomites. The carbonate clasts include marbles displaying different evolutions in relation with the Cretaceous thermal metamorphic event. The clastic formations also include numerous layers of polymictic breccias reworking ultramafic clasts. These layers are found far from any peridotitic body, implying that ultramafic clasts have been transported far away from their sources by sedimentary processes after their disaggregation on the seafloor. In addition, clasts of ultramafic-rich breccias and sandstones are also observed which indicates rapid sedimentation and diagenesis within a tectonically active environment. We discuss the significance of these deposits and their bearing on our understanding of the tectono-sedimentary processes associated with mantle exhumation in a context of development of narrow intracontinental basins suffering extreme crustal thinning.

Tectonics of an Early Carboniferous forearc inferred from a high‐P/T schist‐bearing conglomerate in the Nedamo Terrane, Northeast Japan

AbstractThe Nedamo Terrane, an Early Carboniferous accretionary complex, is the oldest biostratigraphically dated accretionary complex in Japan. The purpose of this study is to describe and interpret a conglomerate from the Nedamo Terrane that contains clasts of high‐pressure/low‐temperature (high‐P/T) schist (mainly garnet‐bearing phengite schist) and ultramafic rock, and to infer the tectonics of an Early Carboniferous arc–trench system at the eastern margin of the paleo‐Asian continent. Clasts of high‐P/T schist and ultramafic rock within the conglomerate make up 8.4 and 6.7% of the total clasts, respectively, based on modal counts. These clasts are subangular to subrounded, whereas volcanic clasts are well rounded. The source of the schist clasts, which yield a radiometric age of 347–317 Ma, is considered to be the Renge Metamorphic Rocks of Southwest Japan or equivalent rocks. Based on the chemical composition of chromian spinel, the source of ultramafic clasts is inferred to be the island‐arc‐type Ordovician Miyamori and Hayachine ultramafic complexes in the Kitakami Massif. The conglomerate records multiple provenance regions, including an island arc (South Kitakami Terrane) and a forearc ridge; the high P/T schist and ultramafic rocks were exhumed in the forearc region. The duration of the interval from the early stages of exhumation of the schist to its deposition in the trench as clasts is estimated to have been less than 30 my.

SIMS U–Pb study of zircon from Apollo 14 and 17 breccias: Implications for the evolution of lunar KREEP

We report the results of a SIMS U–Pb study of 112 zircons from breccia samples from the Apollo 14 and 17 landing sites. Zircon occurs in the breccia matrices as rounded, irregular shaped, broken and rarely euhedral grains and as constituent minerals in a variety of lithic clasts ranging in composition from ultra-mafic and mafic rocks to highly evolved granophyres. Crystallisation of zircon in magmatic rocks is governed by the zirconium saturation in the melt. As a consequence, the presence of zircon in mafic rocks on the Moon implies enrichment of their parent melts in the KREEP component. Our SIMS results show that the ages of zircons from mafic to ultramafic clasts range from ca. 4.35 Ga to ca. 4.00Ga demonstrating multiple generations of KREEPy mafic and ultramafic magmas over this time period. Individual zircon clasts in breccia matrices have a similar age range to zircons in igneous clasts and all represent zircons that have been incorporated into the breccia from older parents. The age distributions of zircons from breccias from both the Apollo 14 and Apollo 17 landing sites are essentially identical in the range 4.35–4.20Ga. However, whereas Apollo 14 zircons additionally show ages from 4.20 to 3.90Ga, no zircons from Apollo 17 samples have primary ages less than ca. 4.20Ga. Also, in contrast to previous suggestions that the magmatism in the lunar crust is continuous our results show that the zircon age distribution is uneven, with distinct peaks of magmatic activity at ca. 4.35Ga, ca. 4.20Ga in Apollo 14 and 17 and a possible third peak in zircons from Apollo 14 at ca. 4.00 Ga. To explain the differences in the zircon age distributions between the Apollo 14 and 17 landing sites we propose that episodes of KREEP magmatism were generated from a primary reservoir, and that this reservoir contracted over time towards the centre of Procellarum KREEP terrane. We attribute the peaks in KREEP magmatism to impact induced emplacement of KREEP magma from a primary mantle source or to a progressive thermal build-up in the mantle source until the temperature exceeds the threshold for generation of KREEP magma, which is transported into the crust by an unspecified possibly plume-like process.

Integrated analyses constraining the provenance of sandstones, mudstones, and conglomerates, a case study: the Laojunshan conglomerate, Qilian orogen, northwest China

The Qilian orogenic belt in the northern Tibetan plateau connects the Altaids to the north with the Tethyan orogenic system to the south and occupies a key tectonic position in the evolution and assembly of Asia. The belt contains a wide range of subduction–accretion-related petrotectonic units. The Early–Middle Devonian Laojunshan conglomerate, deposited unconformably upon Cambrian–Silurian strata along the northern margin of the North Qilian terrane, contains a record of the late Paleozoic tectonism of the Qilian orogen. Its provenance and tectonic setting are critical in understanding not only the tectonic evolution of Tibetan plateau, but Paleozoic global reconstructions as well. The composition of clastic conglomerates and heavy mineral assemblages of sandstones suggests that coeval mafic, felsic, metamorphic, and sedimentary rocks were the main sources. The geochemistry of volcanic clasts and paleocurrent and paleogeographic data suggest derivation from subduction–accretion complexes in the North Qilian terrane. The geochemistry of siltstones and mudstones indicates that the Laojunshan conglomerate was derived from an arc and accumulated in an active continental margin. Geochemical data of granitoid clasts suggest that they were derived from Ordovician–Silurian subduction-related magmatic rocks. Mafic and ultramafic clasts, chromite, and magnetite decrease upwards in the stratigraphy whereas metamorphic, sedimentary and granitoid clasts, and garnet increase. These data imply that mafic rocks were the predominant source during initial deposition. Regional studies suggest that the North China plate subducted southwards and produced subduction-related arc magmatism along the southern margin of the North Qilian terrane during the Early–Middle Devonian. Therefore, we interpret the Laojunshan conglomerate as a fore-arc basin fill.

Arc and mantle detritus in the post-collisional, Lower Silurian Kabadah Formation, Lachlan Orogen, New South Wales

The Kabadah Formation outcrops in central New South Wales as a thrust package 66 km long, interleaved with Lower Silurian Canowindra Volcanics and situated between the Junee – Narromine and Molong Volcanic Belts of the Ordovician Macquarie Arc. The Kabadah Formation contains Early Silurian corals and Llandovery graptolites. Its provenance is complex, with detrital fragments of mafic – intermediate volcanic rocks, free crystals of pyroxene, chromite and ultramafic clasts, detrital volcanic quartz, garnet, and clasts of welded S-type rhyolitic volcanic rocks; and rare clasts from uplifted fold-belt rocks (granite and metamorphosed and deformed sediments). The variety of these clasts suggests that the Kabadah Formation records the Benambran collision of the Macquarie Arc with Ordovician quartz-rich sedimentary rocks, with detritus also derived from coeval Early Silurian mafic and felsic magmatism. The major source of detritus was from the short-lived emergent Fifield arc that formed from the subduction of an older backarc basin. The Kabadah Formation accumulated in an upward-shallowing Early Silurian marine basin between phases of the Benambran Orogeny.

Serpentine and brucite of ultramafic clasts from the South Chamorro Seamount (Ocean Drilling Program Leg 195, Site 1200): inferences for the serpentinization of the Mariana forearc mantle

AbstractSerpentine minerals and brucite in ultramafic rocks from the South Chamorro Seamount were characterized chemically to investigate the serpentinization of the Mariana forearc mantle. Relict primary minerals of the serpentinites are olivine, enstatite and minor Cr-spinel and diopside. The secondary minerals are mostly serpentine and brucite with minor magnetite. The serpentine minerals, mostly lizardite and chrysotile, display large compositional variations. Al2O3 and Cr2O3 contents depend generally upon the nature of the primary mineral from which the serpentine was derived. Both serpentine minerals and brucite exhibit wide Mg, Fe and Mn substitution: the Mg# ranges are 95.1–77.2 and 88.9–60.8, respectively. These mineralogical and chemical features allowed us to estimate an upper temperature limit for serpentinization of ∼200–300°C, in agreement with recent thermal models which suggest that the serpentinized mantle wedge of the Izu-Bonin-Mariana subduction zone is cold. The high degree of serpentinization (40–100%, average &gt;75%), and the serpentine + brucite paragenesis of these ultramafics imply that the Mariana forearc mantle has a significantly reduced density and strength down to ∼30 km, which provides a driving mechanism for serpentinite diapirism. Pervasive serpentinization of the forearc by fluids released from the décollement zone also explains the low seismicity of the Izu-Bonin-Mariana subduction zone.

Phonolitic Diatremes within the Dunedin Volcano, South Island, New Zealand

The Port Chalmers Breccia is a vent-filling, clastic volcanic unit exposed within the Miocene Dunedin Volcano of South Island, New Zealand. Clasts (up to in excess of 1 m but generally <20 cm) are supported in ash and fine lapilli of phonolitic (ne-benmoreite or tephro-phonolite) composition and the dominant clast type (55 to almost 100%) is also phonolitic. Less abundant lithologies include ne-normative basalt (basanite), hawaiite, mugearite and trachyandesite, syenites and microsyenites, coarse-grained mafic (gabbros) and ultramafic rocks (pyroxenites, hornblendites), schists and sediments. The breccias were emplaced as diatremes associated with localized, but highly explosive, eruptive events in which mantle-derived CO2 was an important component. The syenitic and ultramafic clasts could represent intrusive suites produced by crystal fractionation acting on parental ne-benmoreite magmas that may themselves have been derived by crystal fractionation from basanitic precursors. An alternative variation on this model is that the parental ne-benmoreites were generated through partial melting of an alkalic igneous underplate. Sr, Nd and Pb isotopic compositions are strikingly similar to those of intraplate igneous rocks, ranging in age from 100 to less than 10 Ma, from elsewhere in the South Island, and New Zealand's sub-Antarctic islands, the south Tasman Sea and the Ross Sea region. This regional, HIMU-influenced, isotopic signature is believed to be derived from within the lithospheric mantle.