Ultrahigh-pressure Rocks Research Articles

Structural Characteristics of E–W-Trending Shear Belts in the Northeastern Dabie Orogen, China: Evidence for Exhumation of High–Ultrahigh-Pressure Rocks

The Dabie–Sulu Orogen hosts the largest area of ultrahigh-pressure (UHP) rocks in the world. There is still significant divergence regarding the exhumation process and mechanism of UHP rocks in the Dabie Orogen, which mainly resulted from the erosion of large volumes of rocks in the Orogen during the post-collisional stage. Based on detailed field investigations, this study discovered the occurrence of E–W-trending sinistral shear belts that developed on the northeastern Dabie Orogen. These shear belts formed under greenschist facies conditions and are characterized by steep foliation and gentle mineral lineation. E–W-trending shear belts developed in HP rocks with metamorphic ages ranging from 227 to 219 Ma and were cut by the older phase of ductile shear belts of the Tan-Lu Fault Zone, indicating that they were formed around 219–197 Ma. Based on a comprehensive analysis of existing data, it can be concluded that E–W-trending shear belts were formed during the exhumation process of HP–UHP rocks. When HP rocks returned to the shallow crust and the lower UHP rocks continued to move, stress concentration occurred in the HP rocks and further resulted in the formation of E–W-trending shear belts. The development of E–W-trending shear belts indicates that HP–UHP rocks had essentially returned to the shallow crust by the Late Triassic, marking the near completion of the exhumation process.

Pressure–Temperature–Time Evolution of a Polymetamorphic Paragneiss With Pseudomorphs After Jadeite From the HP–UHP Gneiss‐Eclogite Unit of the Variscan Erzgebirge Crystalline Complex, Germany

ABSTRACTA quartz‐rich paragneiss from the Variscan Erzgebirge Crystalline Complex (ECC) was studied in detail because of abundant millimetre‐sized and clearly oriented pseudomorphs after a sodic mineral interpreted to have been jadeite. This mineral, or pseudomorphs after it, is rarely found in extensive high‐pressure (HP)–ultrahigh‐pressure (UHP) terranes worldwide despite reported pressure–temperature (P–T) conditions suitable for the formation of jadeite in common paragneisses and orthogneisses. In the studied rock, which contains abundant large and oriented potassic white mica flakes and minor millimetre‐sized garnet grains, the pseudomorphs consist of clusters of small albite grains with thin phengitic muscovite flakes in between. X‐ray maps for Ca and Mg in garnet demonstrate that an early generation of this mineral (Gt1) was corroded and subsequently overgrown by a Ca‐richer generation (Gt2). White mica is phengite with maximum Si contents of 3.42 atoms per formula unit. P–T conditions of 0.85 GPa and 650°C and 1.7 GPa and 660°C were derived for the formation of Gt1 and Gt2 rim + Si‐rich phengite, respectively, using pseudosection modelling. The latter conditions representing the pressure peak experienced by the paragneiss are compatible with the original presence of jadeite and possibly paragonite as well. This metamorphic peak occurred at 338.4 ± 2.3 (2σ) Ma based on in situ dating of monazite grains with the electron microprobe. A single monazite age of 386.4 ± 10.5 (2σ) Ma is related to the formation of Gt1. Thus, a Late Devonian metamorphism is suggested here for the first time to have occurred in ECC gneisses before the major HP event in the Early Carboniferous. Furthermore, the study demonstrates that the eclogite‐facies gneisses of the Gneiss‐Eclogite Unit of the ECC experienced peak pressures of not more than 2 GPa in contrast to recent proposals of an extensive UHP area in this unit. In addition, it is suggested that the localized occurrence of UHP rocks surrounded by other lithologies otherwise lacking evidence for UHP conditions should be interpreted with caution with respect to their regional extent and significance.

Tourmaline composition probes serpentinite-derived fluid mobility in subduction zones

Serpentinite dehydration in subduction zones plays a pivotal role in geochemical cycling on Earth. A number of geochemical studies on arc magmas have elucidated the contributions of serpentinite-derived fluids to mantle sources. However, due to complex geological overprints during subduction zone processes, discerning serpentinite signatures in exposed metamorphic rocks within fossil subduction zones remains challenging. In this study we address these difficulties through in-situ investigations of tourmaline, the geochemistry of which reflects the host environment as well as potential fluid-induced processes. The presence of zonations in tourmaline makes it an excellent recorder of consecutive geological events. Integrated major and trace elements along with in-situ boron isotopes of tourmaline from the high-pressure Sopron area (Hungary) in the Eastern Alps were used to unravel fluid action sourced from serpentinite. Despite the presence of color zoning, tourmaline in the orthogneiss (Tur-G) has low XMg [Mg/(Mg + Fe)] of ca. 0.3–0.6 and δ11B values of around −11 ‰, along with variable trace element compositions. Petrological observations and geochemical analyses suggest that the inner domains of Tur-G are of igneous origin, while the outer rims are likely affected by subsequent metamorphic events. Tourmaline in metasomatized kyanite-quartzite (Tur-K) veins exhibits distinct geochemical zoning, and preserves metamorphic cores and fluid-induced rims. The inner domains of Tur-K display low XMg (<0.6), relatively high trace element concentrations and δ11B values of less than −10 ‰, whereas the overgrowths exhibit extremely high XMg values (>0.99), low trace element concentrations and high δ11B values reaching up to +21 ‰, clearly indicating the incorporation of serpentinite-derived Mg-11B-rich fluids. Through comparison with other metamorphic and metasomatic tourmalines in (ultra)high-pressure rocks globally, we establish that tourmaline with high XMg > 0.85 and δ11B values >0 ‰ may serve as an effective proxy for detecting serpentinite-derived fluids in subduction zones.

Coesite-bearing garnet xenocrysts from diatexite in the Nordøyane domain, Western Gneiss Region, Norway: implications for eclogite-melt interaction at ultra-high pressure

Ultra-high-pressure (UHP) metamorphic rocks in the Western Gneiss Region (WGR) of Norway formed in subducted Baltican crust during the Scandian phase of the Caledonian orogeny. In the Nordøyane UHP domain, eclogites locally preserve coesite and microdiamond. Along the north coasts of Haramsøya and Flemsøya, in situ eclogite bodies are surrounded by dioritic “diatexite selvages” containing abundant eclogitic enclaves and xenocrysts. In one location eclogite and diatexite are associated with a quartz diorite dyke that is highly contaminated with eclogitic material. The diatexite matrix and dyke have similar plagioclase + quartz + biotite assemblages with abundant embayed and fragmented garnet and clinopyroxene xenocrysts. Coesite is present in some garnet xenocrysts but has not been found in the adjacent eclogite bodies. Pressure–temperature ( P– T) estimates from in situ eclogites range from 2.2–3.2 GPa and 810–840 °C, spanning the quartz–coesite transition, with P– T estimates from xenocrysts spanning a wider range. Diorites and retrogressed eclogites record amphibolite-facies conditions, ca. 1.0–1.5 GPa and 700–800 °C. The wide range and large uncertainties in P– T estimates reflect high-temperature re-equilibration and a relative lack of P-sensitive assemblages. Differences in texture, composition, and included assemblages indicate that the xenocrysts were not derived from the nearby eclogite bodies. By implication, their dioritic hosts were not locally derived but must have originated from a different, probably deeper, source. The results are integrated with a numerical model for WGR tectonic evolution to assess the sources of the melts and their possible effects on the exhumation of UHP rocks in western Norway.

Exhumation of ultra-high pressure (UHP) rocks modulated by rifted margin-subduction feedback: Implications for their preservation in old collisional orogens

In continental subduction, rifted margins can be carried to mantle depths (> 90 km) where ultra-high pressure (UHP) metamorphism above coesite stability is attained. Although different exhumation mechanisms for UHP rocks have been discussed, none of them integrate the recent understanding of rifted continental margins. Here, we perform high-resolution thermomechanical numerical experiments to demonstrate that segments of magma-poor rifted margins that reach UHP conditions can efficiently exhume back to shallower levels, while segments of magma-rich rifted margins cannot. This is because the thick layer of rocks with a basaltic composition in magma-rich margins becomes negatively buoyant during metamorphism, preventing their exhumation. This new concept might be pivotal for explaining why exhumed UHP rocks, a key feature of modern-style continental orogens, only appeared and became common late in Earth's history. We suggest that higher mantle potential temperatures and fertility in Earth's early history favored magma-rich rifted margins, making exhumation of UHP crust inefficient. Conditions for magma-poor rifted margins may have arisen during Earth's middle age (1.5–0.8 Ga) due to a colder, more refractory mantle that limited melting and magmatism. We argue that at the end of Neoproterozoic, these colder and positively buoyant magma-poor rifted margins were then subducted and efficiently exhumed to form the large collisional orogens of Gondwana where Earth's oldest coesite-bearing UHP rocks have been unequivocally found. Since then, UHP rocks have become a key and ubiquitous feature of continental orogens.

Experimental constraints on the nature of multiphase solid inclusions and their bearing on mantle wedge metasomatism, Bohemian Massif

This study tests experimentally the hypothesis that calculated bulk compositions of multiphase solid inclusions present in minerals of ultrahigh pressure rocks, can be equated to the composition of the former trapped fluids. We investigated samples from the ultrahigh pressure garnet peridotites of the Bohemian Massif, spatially associated with ultrahigh pressure crustal rocks and representing a former subduction interface environment. Inclusions present in garnets, composed of amphibole + Ba-mica kinoshitalite + carbonates (dolomite + magnesite + norsethite), were taken to their entrapment conditions of c. 4.5 GPa and 1075 ºC. They (re)crystallized into a garnet fringe at the boundary between inclusion and host garnet, kinoshitalite ± olivine, carbonatite melt, and a hydrous fluid. Although the latter may have exsolved from the carbonatite melt upon quenching, microstructures suggest it was present at trapped conditions, and mass balance indicates that it corresponds to a Na-K-Cl-F-rich saline aqueous fluid (brine). Experiments demonstrate the stability of kinoshitalite at 4.5 GPa and 1075 ºC, and suggest that Ba-rich mica + carbonatite melt + brine coexisted at near-peak conditions. Barium is compatible in the carbonatite melt and mica with respect to the brine, with a partition coefficient between carbonatite melt and mica of ≈ 2.5–3. The garnet fringe formed from incongruent reaction of the former inclusion assemblage due to reversing the fluid(s)-host garnet reaction that occurred upon natural cooling/decompression. Loss of H2 or H2O from the inclusions due to volume diffusion through garnet and/or decrepitation, during geological timeframes upon decompression/cooling, may have prevented rehomogenization to a single homogeneous fluid. Our study shows that great care is needed in the interpretation of multiphase solid inclusions present in ultrahigh pressure rocks.

Monazite and zircon U–(Th–)Pb dating reveals multiple episodes of HT metamorphism in the Cima Lunga unit (Central Alps): implications for the exhumation of high‐pressure rocks

High- to ultrahigh-pressure (HP–UHP) rocks recording high-temperature (HT) > 700 °C are well exposed in the Central Alps, making it an ideal region to study the timing of metamorphic stages and the mechanisms of deep-seated rocks exhumation. Here, we report an integrated dataset of petrological and U–(Th–)Pb dating of metapelites surrounding ultramafic lenses from the Cima Lunga unit. At the interface with ultramafics preserving (U)HP–HT assemblages (1.5–3.1 GPa, 650–850 °C), metapelites record higher P‒T values (1.3–2.7 GPa, 700–850 °C) and traces of partial melting, whereas the rest of the unit is dominated by amphibolite-facies conditions. U–Th–Pb dating on zircon and monazite from migmatites indicates that partial melting was episodic involving at least two stages at ~38 to 35 Ma and 33–30 Ma, respectively. While the 38–35 Ma stage matches the HP conditions (> 1.5 GPa) and it is recorded around only one lens with scarce volumes of melt, partial melting at 33–30 Ma is witnessed at lower pressure (~1 GPa) and more widely distributed around the lenses, as within the major shear zones. Far from the ultramafics, zircon from the amphibolite-facies metasedimentary rocks record inherited pre-Variscan ages, while monazite ages at ~22 Ma document mineral growth during the Barrovian cooling. Field and petro-chronological evidence highlight that multiple episodes of partial melting locally developed at the rheological interface promoted by the interplay of fluids extracted from the ultramafic lenses associated with shear heating. New evidence suggests that local variation of P‒T equilibria play a significant role during the exhumation history.Graphical

Subduction polarity reversal facilitated by plate coupling during arc-continent collision: Evidence from the Western Kunlun orogenic belt, northwest Tibetan Plateau

Abstract Subduction polarity reversal usually involves the break off or tearing of the downgoing plate (DP) along the continent-ocean transition zone, in order to initiate subduction of the overriding plate (OP) with opposite polarity. We propose that subduction polarity reversal can also be caused by DP-OP coupling and can account for the early Paleozoic geological relationships in the Western Kunlun orogenic belt in the northwestern Tibetan Plateau. Our synthesis of elemental and isotopic data reveals transient (~2 m.y.) changes in the sources of early Paleozoic arc magmatism in the southern Kunlun terrane. The early-stage (ca. 530–487 Ma) magmatic rocks display relatively high εNd(t) (+0.3 to +8.7), εHf(t) (−3.6 to +16.0), and intra-oceanic arc-like features. In contrast, the late-stage (485–430 Ma) magmatic rocks have predominantly negative εNd(t) (−4.5 to +0.3), εHf(t) (−8.8 to +0.9), and higher incompatible trace elements (e.g., Th), similar to the sub-continental lithospheric mantle beneath the Tarim craton. This abrupt temporal-spatial variation of arc magmatism, together with the detrital zircon evidence, indicate that subduction polarity reversal of the Proto-Tethys Ocean occurred in a period of ~10 m.y., consistent with the time interval reflected by ophiolite age. This rapid polarity reversal corresponds with the absence of ultrahigh-pressure (UHP) metamorphic and post-collisional magmatic rocks, features normally characteristic of slab break-off or tearing. Numerical modeling shows that this polarity reversal was caused by plate coupling during arc-continent collision. This coupling modified the normal succession of arc-continent collision events, preventing slab break-off or tearing-induced buoyant rock rebound and asthenosphere upwelling. Our model successfully explains early Paleozoic orogenesis in the Western Kunlun orogenic belt and may be applied elsewhere where post-collisional magmatic and UHP rocks are absent.

Cold deep subduction of Indian continental crust and release of ultrahigh‐pressure fluid during initial exhumation: Insights from coesite‐bearing eclogite‐vein systems in Kaghan Valley, Pakistan

AbstractThe ultrahigh‐pressure (UHP) eclogites from the Kaghan Valley in Pakistan, which formed by the deep subduction of the Indian plate beneath the Asian plate in the Eocene, contain complex metamorphic vein systems (including both isolated veins and vein networks), with mineral assemblages of epidote + quartz + kyanite + phengite ± omphacite ± garnet. The investigations on the Kaghan UHP eclogite‐vein systems provide important insights into the mechanism and timing of metamorphic dehydration, fluid flow, and fluid–rock interaction in the deeply subducted Indian continental slab as well as the chemical characteristics of slab‐derived, aqueous fluids. Abundant lawsonite pseudomorphs, characterized by prismatic aggregates of epidote, kyanite, and quartz porphyroblasts, are first recognized in the Kaghan eclogites. This observation, in combination with the occurrence of coesite pseudomorphs in epidote porphyroblasts as well as the coexistence of epidote and coesite in the eclogite zircon, indicates the previous existence of UHP lawsonite in these eclogites. Petrological studies and phase equilibrium modelling reveal clockwise P–T trajectories for the Kaghan eclogites that are featured by prograde vectors in lawsonite‐stability regions with peak conditions of 3.0–3.4 GPa/650–690°C, followed by isothermal decompression and lawsonite breakdown under UHP conditions during the initial exhumation stage. The results of metamorphic evolution, together with in situ epidote and bulk Sr isotopic analyses, indicate that the fluids responsible for vein systems are most likely derived from the breakdown of UHP lawsonite in the eclogites. SIMS U–Pb dating of metamorphic zircons from the eclogites, integrated with the Raman analysis of inclusions in zircons, indicates that the UHP dehydration of eclogites occurred at 46.4 ± 1.2 and 46.8 ± 0.9 Ma. Analyses of hydrothermal zircons from the veins yielded slightly younger ages of 44.7 ± 1.0 and 44.9 ± 1.4 Ma, which represent the timing of fluid flow and/or vein crystallization during exhumation of the UHP rocks. Mass‐balance calculation results, in combination with the vein compositions, show that the fluid flow and fluid‐eclogite interaction led to the transfer of Si, Al, Ca, K, and incompatible trace elements from the eclogites into the fluids, from which the vein systems crystallized. This study indicates cold deep subduction of Indian continental crust along low geothermal gradients (6–7°C/km). The UHP fluid liberation and channelized fluid flow occurred during the initial exhumation of the cold Indian slab and are expected to induce the transfer of H2O and incompatible trace elements from the Indian slab to the Asian lithosphere, which potentially contributes to the formation of post‐collisional magmas. Moreover, we suggest that metamorphic vein systems in UHP lawsonite eclogites offer important constraints on the occurrence and timing of fast slab exhumation in continental subduction‐collision zones.

Nitrogen behavior during fluid-rock interaction in a continental subduction zone: Results from the UHP Dora-Maira Massif whiteschists and Eastern Alps leucophyllites

Deep-Earth cycling of nitrogen (N) along the subduction pathway, remains relatively poorly understood, particularly that related to deep subduction of continental crust. The ultrahigh-pressure (UHP) Dora-Maira Massif whiteschists in the Western Alps and their lower-P-T equivalent leucophyllites in the Eastern Alps show a decrease in N concentration and an increase in δ15N relative to their presumed country rock protoliths. On average, the whiteschists contain 20.7 ± 10.5 ppm N (mean ± 1σ) with δ15Nair = +2.7 ± 2.5‰ (mean ± 1σ) and the leucophyllites contain 59.8 ± 12.3 ppm N with δ15Nair = +4.3 ± 2.0‰, whereas the metagranitic country rocks from Dora-Maira contain 41.3 ± 12.5 ppm N with δ15Nair = −1.9 ± 3.2‰ and the country rocks from the Eastern Alps contain 91.1 ± 42.5 ppm N with δ15Nair = +1.7 ± 2.1‰. The loss of N and isotope shift in the whiteschists and leucophyllites from these two localities was accompanied by loss of LILE (Rb, Ba), Sr, CaO, Na2O, and FeOtotal. The other stable isotope systems applied to study both suites (Mg, Fe, O, Li and Ba) show no obvious correlation with variations in δ15N. Infiltration by and interaction with a serpentinite-derived fluid depleted in N and LILE could have led to leaching of N from the country rock protoliths and production of the +4.6‰ (Dora-Maira Massif) and +2.6‰ (Eastern Alps) isotope shifts adequately explained using a Rayleigh distillation model. The N exchange and leaching process is best explained as involving N2-NH4 or NH3-NH4 at about 550–600 °C, the latter the approximate temperatures at which the fluid infiltration is thought to have occurred. These results provide new insights regarding N behavior and isotopic fractionation during fluid-rock interactions occurring in UHP rocks and point to the importance of H2O-rich fluids from serpentinite dehydration as agents of metasomatism along deep subduction interfaces. Furthermore, the data for the metagranites indicate the potential of this lithology to retain significant amounts of N to at least 100 km and beyond sub-arc depths.

Garnet microstructures suggest ultra-fast decompression of ultrahigh-pressure rocks

Plate tectonics is a key driver of many natural phenomena occurring on Earth, such as mountain building, climate evolution and natural disasters. How plate tectonics has evolved through time is still one of the fundamental questions in Earth sciences. Natural microstructures observed in exhumed ultrahigh-pressure rocks formed during continental collision provide crucial insights into tectonic processes in the Earth’s interior. Here, we show that radial cracks around SiO2 inclusions in ultrahigh-pressure garnets are caused by ultrafast decompression. Decompression rates of at least 8 GPa/Myr are inferred independently of current petrochronological estimates by using thermo-mechanical numerical modeling. Our results question the traditional interpretation of fast and significant vertical displacement of ultrahigh-pressure tectonic units during exhumation. Instead, we propose that such substantial decompression rates are related to abrupt changes in the stress state of the lithosphere independently of the spatial displacement.

From divergent to convergent plate boundary: A ca. 200 Ma Wilson cycle recorded by ultrahigh-pressure eclogites in the Dora-Maira Massif, Western Alps

Sparse eclogite exposure in accretionary-to-collisional orogens cannot only reveal the sites of ancient subduction zones and plate boundaries, but also elucidate the multi-stage tectonic evolution in the Wilson cycle. The southern part of the Dora-Maira Massif in the Western Alps is well known for its ultrahigh-pressure (UHP) rocks and contains small occurrences of petrographically distinct types of eclogite. Due to the lack of detailed geochronological and geochemical data on these rocks, the nature of their protolith and related geodynamic setting has remained unknown. In the current study, 33 samples from 13 localities were studied by whole-rock major- and trace-element analysis, and a selection of the samples were studied using Sr-Nd-Hf isotopes, as well as high-resolution elemental mapping and U-Pb geochronology of zircon. According to macroscopic appearance, petrography, chemical composition, and principal-component analysis of multi-elements, two major types are distinguished. Light-colored eclogite is phengite-rich, commonly foliated, bears kyanite and quartz/coesite, shows relatively high MgO, K2O, SiO2, εNd(t) (−2.2 to +1.4), and εHf(t) (+3.5 to +7), with a protolith geochemically similar to an enriched-type mid-oceanic-ridge basalt (E-MORB). Dark eclogite generally is massive, rutile-rich, shows higher values of Ti, Fe, P, Nb, and Zr, εNd(t) values between −2.8 and −0.8, εHf(t) values between −6.1 and −3.2, with an oceanic island basalt (OIB)-type protolith composition. Magmatic zircon cores, which are characterized by steep heavy rare earth element (HREE) patterns and negative Eu anomalies, yield consistent protolith ages of ca. 253−252 Ma in both eclogite types. Metamorphic zircon domains with flat HREE patterns and insignificant Eu anomalies yield a younger mean age of ca. 34 Ma, which is the age commonly assigned to eclogite-facies UHP metamorphism. Considering the various geochemical signatures of E-MORB- to OIB-like eclogites and the regional tectonic evolution, their protolith is best explained as rocks, which crystallized from rift-related basaltic magma, associated with the break-up of the Pangea Supercontinent that eventually resulted in the birth of the Piemonte-Liguria Ocean (Alpine Tethys Ocean) between the future Eurasia and Adria plates. Therefore, the UHP eclogites in the Dora-Maira Massif likely fingerprint a multi-stage tectonic evolution from divergent (continental extension, rifting) to convergent (subduction zone) plate boundary, corresponding to the beginning and end of a Wilson cycle. Incidentally, they reveal that mafic rocks in the Alpine basement units may not be polymetamorphic, but may actually consist of post-Variscan products that underwent only Alpine metamorphism.

UHP metamorphism, decompression anatexis and retrogression of garnet-bearing metagranite and granitic gneiss from the Dabie orogen during continental collision

Metamorphosed granitic rocks are commonly volumetrically dominant in continental collisional terranes, which are crucial targets for resolving the metamorphic evolution of deeply subducted continental crust. However, their metamorphic processes in ultrahigh pressure (UHP) belts are often poorly understood, because they are commonly intensely retrogressed and presently dominated by amphibolite-facies minerals with very rare petrological evidences of UHP metamorphism. It is known that, in these lithologies, zircon can potentially preserve evidence of the UHP history; therefore, the P-T-t path of metafelsic rocks may be estimated using a multidisciplinary approach which combines zircon microanalysis with phase equilibria modelling. In the central Dabie UHP metamorphic zone (CDZ) (China), two types of metamorphosed garnet-bearing granitic rocks, i.e. metagranite and granitic gneiss, whose massive vs. gneissic structure reflects a different degree of deformation, are closely associated with eclogites. Opposite to the eclogites, their detailed metamorphic evolution is poorly understood. In this study, a three-stage metamorphic evolution is reconstructed for these lithologies, based on field observation, bulk-rock elemental geochemistry, sensitive high-resolution ion microprobe zircon UPb dating, Raman micro-spectroscopy analysis of zircon inclusion, mineral chemistry, conventional thermobarometry and phase equilibria modelling. The first UHP stage is represented by the assemblage coesite-rutile-garnet-phengite preserved in the metamorphic domains of zircon and by garnet core in the matrix, revealing minimum peak pressures of 44 kbar and 30 kbar for granitic gneiss and metagranite, respectively, at 231 ± 4 Ma. The second stage is represented by anatexis at 18–20 kbar, 725–870 °C and 222 ± 3 Ma, evidenced by leucosomes at the outcrop scale and by quartzofeldspathic films with low dihedral angles, melt inclusions preserved in peritectic garnet and quartz/K-feldspar/plagioclase- garnet intergrowth at the micro-scale. The third stage is represented by amphibolite-facies overprint at 590–700 °C, 9–14 kbar, at 214–219 Ma, recorded by biotite-plagioclase-quartz symplectites developed at the expenses of phengite, re-equilibration of the peritectic garnet rim, and amphibole-quartz (biotite-titanite) inclusions in zircon overgrowth rims. The resulting P-T-t path overlaps with previous results estimated from other CDZ UHP rocks. Besides, the protoliths of both metagranite and granitic gneiss were emplaced during the mid-Neoproterozoic (683–786 Ma) period, as already documented throughout the Dabie orogen. Compared with previously published data for meta-granitic rocks in the CDZ, the weakly deformed metagranite does not appear to represent low-grade metamorphic rocks. Instead, this study (i) suggests that the two groups of lithologies experienced a coeval metamorphic evolution; (ii) reconstructs a multistage P-T-t history based on zircon microanalysis and pseudosections; (iii) reveals that anatexis, retrogression and deformation facilitate the elimination of (U)HP mineralogical records of metagranitoids. Overall, these results provide new constraints on the metamorphic evolution and exhumation processes of deeply subducted granitic rocks during continental collision.

Detrital garnet petrology challenges Paleoproterozoic ultrahigh-pressure metamorphism in western Greenland

Abstract. Modern-style plate tectonics is characterised by the global operation of cold and deep subduction involving blueschist facies and ultrahigh-pressure metamorphism. This has been a common process since the Neoproterozoic, but a couple of studies indicate similar processes were active in the Paleoproterozoic, at least on the local scale. Particularly conspicuous are extreme ultrahigh-pressure conditions of ∼ 7 GPa at thermal gradients &lt; 150 ∘C GPa−1 proposed for metamorphic rocks of the Nordre Strømfjord shear zone in the western part of the Paleoproterozoic Nagssugtoqidian Orogen of Greenland. By acquiring a large dataset of heavy minerals (n = 52 130) and garnet major-element composition integrated with mineral inclusion analysis (n=2669) from modern sands representing fresh and naturally mixed erosional material from the metamorphic rocks, we here intensely screened the area for potential occurrences of ultrahigh-pressure rocks and put constraints on the metamorphic evolution. Apart from the absence of any indications pointing to ultrahigh-pressure and low-temperature–high-pressure metamorphism, the results are well in accordance with a common Paleoproterozoic subduction–collision metamorphic evolution along a Barrovian-type intermediate temperature and pressure gradient with a pressure peak at the amphibolite–granulite–eclogite-facies transition and a temperature peak at medium- to high-pressure granulite-facies conditions. In addition, we discuss that all “evidence” for ultrahigh-pressure metamorphism proposed in the literature for rocks of this area is equivocal. Accordingly, the Nordre Strømfjord shear zone is not an example of modern-style plate tectonics in the Paleoproterozoic or of very low thermal gradients and extreme pressure conditions in general.

In Situ High-Pressure Raman Spectroscopic, Single-Crystal X-ray Diffraction, and FTIR Investigations of Rutile and TiO2II

In ultrahigh-pressure (UHP) metamorphic rocks, rutile is an important accessory mineral. Its high-pressure polymorph TiO2II can be a significant indicator of pressure in the diamond stability field. In the present study, in situ high-pressure Raman spectroscopic measurements of natural rutile in UHP eclogite from the main hole of the Chinese Continental Scientific Drilling Project (CCSD) have been conducted up to ~16 GPa. Rutile and recovered TiO2II have also been analyzed via single-crystal X-ray diffraction and FTIR spectroscopy. The results indicate that (1) the phase transition from rutile to baddeleyite-type TiO2 terminates at about 16 GPa under compression at ambient temperature; (2) the metastable TiO2II in the exhumated UHP rocks formed during deep continental subduction can be characterized by a highly distorted octahedral site in the crystal structure. X-ray powder diffraction analyses (with Cu Kα radiation) at ambient conditions are sufficient for identifying the lamellae of TiO2II within natural rutile based on the angles (2θ) of two strong peaks at 25.5° and 31.5°; (3) rutile and recovered TiO2II in the continental slabs can contain certain amounts of water during deep subduction and exhumation. The estimated water contents of rutile in the present study range from 1590 to 1780 ppm of H2O by weight. In the crystal structure of TiO2II, hydrogen can be incorporated close to the long O-O edges (&gt;2.5143 Å) of the TiO6 octahedra. Further studies on the pressure–temperature stability of hydroxyls in rutile and TiO2II may help to understand the transportation and release of water in subducted continental slabs.

Fast exhumation of Earth’s earliest ultrahigh-pressure rocks in the West Gondwana orogen, Mali

Abstract Did exhumation of ultrahigh-pressure (UHP) rocks proceed at comparable rates in the Neoproterozoic and in modern collisional orogens? We address this question with a multimineral geochronological study of UHP rocks from the Gourma fold-and-thrust belt in Mali. Integrated petrology and zircon U-Pb geochronology reveal peak metamorphic conditions of 820–740 °C and 3.3–3.4 GPa at 611.7 ± 3.6 Ma, providing evidence for subduction of the passive margin of the West African craton to ~125 km depth in the West Gondwana orogen. Rutile U-Pb cooling ages indicate further exhumation of the Gourma UHP unit to mid-crustal levels (~35 km) at 601.7 ± 3.2 Ma. These two ages provide a time lag between peak conditions and exhumation to 35 km of 10 ± 3.1 m.y., constraining an average vertical exhumation rate of 0.9 ± 0.3 cm/yr. Our data indicate a fast exhumation rate for the oldest known UHP rocks, comparable to that reported for modern collisional orogens. We argue that exhumation of the deeply subducted UHP rocks along the West Gondwana orogen contributed to significant changes in the Neoproterozoic atmosphere and biosphere.

Assembly of the Variscan Orogenic Wedge in the Bohemian Massif: Monazite U‐Pb Geochronology of the Tectonic Events Recorded in Saxothuringian Metasediments

AbstractThe geochronology of metasediments incorporated to orogenic wedges provides an important key in understanding the early evolution of collisional systems. This study reveals the timing of Variscan processes in the Saxothuringian orogenic wedge, reflecting transition from oceanic to continental subduction and collision. In situ monazite U‐Pb geochronology and Rare Earth Elements (REE) geochemistry were performed in the Erzgebirge Crystalline Complex on phyllites and micaschists surrounding the ultra‐high‐pressure (UHP) core of the Erzgebirge dome. The resulting ages and REE patterns were linked to the individual tectonometamorphic events and revealed that the hanging‐wall phyllites experienced prograde metamorphism around ∼350 Ma, followed by exhumation at ∼345–340 Ma. The oldest age (∼339 Ma) recorded in garnet cores in the foot‐wall micaschists is considered as an upper age limit for their prograde metamorphism, while matrix monazite ages of ∼330 Ma reflect a significant resetting of the monazite age system. Spatial distribution of metamorphic isograds and ages indicates a phase of accretion of continental material resulting in an inverted metamorphic field gradient in the wedge between ∼360 and ∼340 Ma. This phase was followed by exhumation of a significant portion of buoyant subducted continental material leading to massive ductile thinning of the wedge around ∼335 Ma. Finally, a late Variscan intracontinental deformation was responsible for heterogeneous reactivation and final exhumation of the wedge at ∼330 Ma. It is newly shown that the Saxothuringian wedge can be divided into a younger inner part, formed by micaschists and UHP rocks, and an older outer part, formed by phyllites.

Tracking the multi-stage metamorphism and exhumation history of felsic gneisses in the South Altyn ultra-high pressure metamorphic belt, Western China

Felsic gneisses are usually the dominant rock types in most high-pressure (HP) and ultrahigh-pressure (UHP) terranes, although their peak metamorphic conditions and complete P–T paths are rarely known. This lack of knowledge is attributed to the high variance of mineral assemblages at HP/UHP conditions of the felsic gneisses, or to the effects of retrograde-related overprinting. Thus, it is difficult to distinguish whether felsic gneisses underwent HP/UHP metamorphism. In this paper, we focus on the felsic gneiss that has been previously documented as having formed under HP granulite-facies metamorphism with peak P–T of > 1.15 GPa and > 860 °C from the Danshuiquan locality in the South Altyn HP–UHP belt. The Danshuiquan felsic gneiss is strongly deformed and is spatially associated with weakly deformed garnet-rich felsic gneiss. On the basis of detailed microstructure observations on mineral assemblages and phase equilibria modelling, three stages of metamorphic evolution for the weakly deformed garnet-rich felsic gneiss are identified. The first stage is represented by garnet cores, revealing a prograde P–T path from 1.5 GPa/750 °C to 2.1 GPa/900 °C. The second stage is characterized by garnet mantles with multiphase inclusions, defining HP eclogite-facies metamorphic conditions of 2.2–2.6 GPa/950–1100 °C. The third stage is represented by the composition of garnet rims, biotite, and plagioclase, suggesting an HP granulite to amphibolite facies decompression cooling process to 1.1–1.3 GPa/710–770 °C. In contrast, the strongly deformed felsic gneiss just records a deformation-related decompression process from 1.1 to 1.2 GPa/750–760 °C to 0.87–0.98 GPa/760–770 °C, and finally to 0.83 GPa/740 °C. Zircon U–Pb dating yields c. 920 Ma protolith ages, c. 500 Ma eclogite-facies ages, and c. 480 Ma granulite to amphibolite facies retrograde ages for the Danshuiquan felsic gneisses. Our results show that the Danshuiquan felsic gneisses underwent a similar metamorphic evolution process to that of Yinggelisayi HP–UHP rocks in the eastern segment of the South Altyn Tagh. Most HP mineralogical records tend to be eliminated by the strong deformation at crustal depths (∼30 km), meaning that the peak metamorphic conditions of the studied felsic rocks in UHP metamorphic terranes are previously underestimated.

On the enigmatic mid-Proterozoic: Single-lid versus plate tectonics

The mid-Proterozoic (ca. 1850–850 Ma) is a peculiar period of Earth history in many respects: ophiolites and passive margins of this age are rare, whereas anorthosite and A-type granite suites are abundant; metamorphic rocks typically record high thermobaric (temperature/pressure) ratios, whereas ultrahigh pressure (UHP) rocks are rare; and the abundance of economic mineral deposits features rare porphyry Cu-Au and abundant Ni-Cu and Fe-oxide Cu-Ag (IOCG) deposit types. These collective observations have been used to propose that a stagnant-lid, or single-lid, tectonic regime operated at this time, between periods of plate tectonics in the Paleoproterozoic and Neoproterozoic. In our reappraisal of the mid-Proterozoic geological record, we not only assess the viability of the single-lid hypothesis for each line of evidence, but also that of the plate tectonic alternative. We find that evidence for the single-lid hypothesis is equivocal in all cases, whereas for plate tectonics the evidence is equivocal or supporting. We therefore find no reason to abandon a plate tectonic model for the mid-Proterozoic time period. Instead, we propose that the peculiarities of this enigmatic interval can be reconciled through the combination of two processes working in tandem: secular mantle cooling and the exceptionally long tenure and incomplete breakup of Earth's first supercontinent, where both of these phenomena had a dramatic effect on lithospheric behaviour and its resulting imprint in the geological record.

Pre-plate tectonics and origin of continents

<p indent="0mm">Established in the mid-1960s and regarded as a revolution in Earth sciences, the plate tectonics theory can reasonably interpret nearly all geological phenomena, processes, and events that happened during post-Archean time (from 2.5 billion years ago to the present), and has also been applied to explain the formation and evolution of continents. According to the plate tectonics theory, the mafic lower crust and the felsic upper crust of continents can develop from an island arc that formed by subduction of one oceanic crust beneath another, where the mafic lower crust of continents can be extracted from the mantle through the partial melting of the mantle wedge in the subduction zone, whereas the felsic upper crust of continents can form by the partial melting of the already-formed mafic lower crust. However, such an island arc model under a plate tectonic regime cannot well explain the magmatic, metamorphic and structural features of Archean (&gt;2.5 billion years) continents. For example, island arc models fail to explain the presence of ~1600°C komatiites, absence of andesites that is dominant in post-Archean arcs, nearly coeval and craton-scale emplacement of tonalite-trondhjemite-granodiorite (TTG) rocks, dominancy of dome-and-keel structures, and lack of ultrahigh-pressure rocks, paired metamorphic belts and ophiolites, etc. All of these imply that Archean continents may not have been formed under plate tectonic regimes, but were originated from some pre-plate tectonics (non-plate tectonics). So far, researchers have proposed a number of pre-plate tectonics models, of which the most representative ones are mantle plumes, sagduction, heat-pipes and stagnant lids. Although each of these pre-plate tectonics models can satisfactorily interpret some features of Archean cratons, none of them is successful in explaining all lithological, structural and metamorphic features of Archean cratons. For example, although the mantle plume-derived oceanic plateau models can well explain many features of Archean cratons, oceanic plateaus formed by mantle plumes may not provide enough water (H₂O) for aqueous partial melting of basaltic rocks to create TTG magmas. It is the same case with heat-pipe models. As the sagduction models assume the existence of an old felsic continental crust, they are not suitable for discussing the origin of Archean continents. As for stagnant lids, they just describe the state of a single lithosphere plate which itself cannot provide any geodynamic mechanisms for making a mafic crust be partially melt to form TTG magmas. Therefore, none of available pre-plate tectonics models proposed so far has been successfully applied to interpret the origins of Archean continents. Thus, a number of research groups in the world are conducting extensive and comprehensive investigations on this important scientific conundrum. Although Chinese geologists missed a chance to have made contributions to establishing plate tectonic theory in the 1960s, they have a great potential for breakthroughs in establishing a pre-plate tectonics theory since they have done tremendous work on the early geodynamic mechanisms for the formation and evolution of Archean continents and produced large amounts of new data and competing interpretations in the past four decades.