UG2 Chromitite Research Articles

Determination of strength of UG2 chromitite pillars at Impala Platinum from laboratory tests and FLAC3D

The results of FLAC3D modelling on chromitite Upper Group 2 Reef pillars from the Bushveld Complex of South Africa are described. The model input parameters were determined from laboratory triaxial tests with post-failure measurements. These geomechanical tests were performed on rock materials within the pillars and the immediate pillar foundations. In the models, post-failure behaviour was simulated using the concept of cohesion softening. Models were built to determine the strength and behaviour of pillars with a width-to-height ratio of approximately two. The original research aimed to find a suitable depth below the surface where Impala Platinum Ltd could safely introduce crush pillars; however, the paper only describes the model results: the ideal depth of the crush pillar introduction is not discussed. The results of the modelling are compared with the PlatMine formula for peak pillar strength and with an underground instrumented pillar located elsewhere on the same reef. Some insight into the effects of grid size on strength is also provided. Further underground measurements are recommended to verify the model results.

The effects of iron-rich ultramafic pegmatite on the composition and mineralogy of the UG2 chromitite: a case study in the western Bushveld Complex, South Africa

Discordant iron-rich ultramafic pegmatites (IRUPs) intersect the UG2 chromitite at many places in the Bushveld Complex. The effects of IRUP interactions on the UG2 ore mineralogy and PGE grade are assessed at the Thaba mine, north-west Bushveld, based on a borehole profile through the UG2 layer and detailed analysis of mineral textures and compositional variations across the UG2-IRUP contacts using micro-XRF element mapping. The UG2-IRUP interaction operated at different scales and probably by different mechanisms. At the local scale (< 10 cm), a thin layer of Fe–Ti–Cr spinel and ilmenite formed on the IRUP side of the contact with UG2, whereas the UG2 chromitite developed grain coarsening, loss of interstitial silicates, and chemical gradients in Cr, Al, Fe, and Ti that extend a few centimeters from the contact into the seam. These local effects are attributed to the intrusion of IRUP melt into the solidified UG2 layer, followed by re-equilibration of the oxide minerals across the contact during cooling. On a larger scale, changes in the ore and gangue mineral assemblages in UG2 took place throughout the entire meter-thick main seam. Compared with regional UG2 compositions, chromite has higher TiO2 and lower Mg#, and there is an anomalously low abundance of interstitial plagioclase. The IRUP-affected UG2 shows relatively abundant secondary hydrous silicates, replacement of PGE sulfides by PGE alloys and PGE-As–Sb–Bi–Te–Pb phases, and formation of secondary Ni–Cu–Fe sulfides after pentlandite and chalcopyrite. These large-scale effects are attributed to hydrothermal fluids derived from IRUP melts. The IRUP bodies at the Thaba mine caused redistribution of PGE within the UG2 layer but did not significantly reduce the overall grade. However, significant changes in the ore mineral assemblage and an increased abundance of secondary silicates can reduce the efficiency of PGE recovery.

The Formation of Chromite Chains and Clusters in Igneous Rocks

Abstract Crystal clusters are common in both extrusive and plutonic rocks, but the mechanisms by which they form are not well-constrained. Following a consideration of the physics of nucleation, we outline the expected microstructural characteristics of clusters formed by heterogeneous nucleation and those formed by synneusis, together with the ways they might evolve during subsequent grain growth and textural equilibration. By combining analysis of the microstructures in experimental chromite-basalt charges with a detailed microstructural analysis of the UG2 chromitite of the Bushveld layered intrusion using EBSD, we argue that the UG2 chromitite formed by settling and accumulation of single grains and clusters comprising randomly oriented grains produced by the aggregation of previously isolated chromite crystals. Although there is no evidence of epitaxy, at least some of the lowermost chromite grains of the main UG2 chromitite may have nucleated heterogeneously on the silicate grains forming the floor, with subsequent accumulation and sintering of individual grains or clusters. The reduced thickness of chromitites on the steep and overhanging parts of the floor is thus due to the relative difficulty of sticking more grains to the existing layer in these orientations. The absence of any fining-upwards of grains in either the main UG2 chromitite or the associated stringer can be accounted for if both layers were formed by the settling and accumulation of clusters as well as single grains. Comparison with examples of clustered chromite grains in extrusive rocks suggests that aggregation by synneusis is a widespread magmatic process. The ‘chicken-wire’ texture formed by clustered chromite grains commonly found in olivine-rich cumulates is argued to also be formed by gravitational settling, with the possible exception of clusters of chromite grains in relatively thin seams argued to be the result of metasomatism, which may instead have formed by impingement during in situ growth.

The use of Laser Induced Breakdown Spectroscopy for the mineral chemistry of chromite, orthopyroxene and plagioclase from Merensky Reef and UG-2 chromitite, Bushveld Complex, South Africa

A new approach using scanning Laser Induced Breakdown Spectroscopy (LIBS) was developed to unravel cryptic variations in the mineral chemistry of chromite, orthopyroxene, and plagioclase in drill core from Merensky Reef and UG-2. The LIBS method provides continuous spatially resolved chemical data, elucidating variations in mineral chemistry and in element partitioning, taking into account textural features of the rock itself, of individual minerals, and of immediate neighbourhoods. Since the method is relatively fast and easy to apply to numerous core sections, it is of special interest when comparing the lateral variability of diagnostic horizons such as Merensky Reef and UG-2. This approach for measuring Mg/Fe, Cr/Al and Ca/Na ratios is based on the strength of LIBS in detecting chemical variations using intensity ratios within a single matrix, which in this application is one single particular type of mineral phase. Supervised classification followed by k-means clustering was applied to identify those spectra that consist of pure chromite, orthopyroxene, and plagioclase. Measurements and data processing strategies were focused on minimizing the standard deviation in the LIBS-based ratios to be able to detect relatively small variations in mineral chemistry. The LIBS-based Cr/Al and Mg/Fe ratios were successfully validated with respect to electron probe microanalysis on multiple polished sections. Distinct trends could indeed be extracted from a continuous LIBS measurement of 6 m drill core through the Merensky Reef. The data correlate with whole-rock geochemistry and hydrous phases such as phlogopite. The LIBS-based approach opens up unique insights into chemical and mineralogical expressions of large- and local-scale processes. This allows unique and detailed interpretations relevant for the genesis of mineralizations and metal distributions, based on a comprehensive dataset.

Sulfide mineral chemistry and platinum-group minerals of the UG-2 chromitite in the northern limb of the Bushveld Igneous Complex, South Africa

ABSTRACT The UG-2 chromitite layer, with its elevated platinum-group element content, is a key marker horizon in the eastern and western limbs of the Bushveld Igneous Complex and the largest platinum-group element chromite-hosted resource of its kind in the world. In contrast, much less is known about its stratigraphic equivalent in the northern limb, the “UG-2 equivalent” (UG-2E) chromitite. Recent studies on chromite mineral chemistry show similarities between the UG-2 and sections of the UG-2E, but also that the UG-2E was partially contaminated by assimilation of local metasedimentary rocks. Here, we provide a detailed characterization of sulfide minerals and platinum-group minerals in a suite of samples from the UG-2E and compare the results with data obtained from a reference suite of samples from the UG-2. Results from petrographic observations, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, quantitative evaluation of materials by scanning electron microscopy, and δ34S isotopes show that: (1) sulfide minerals in the UG-2E and UG-2 consist mainly of pentlandite-chalcopyrite-pyrrhotite, but pyrrhotite is significantly more abundant in the UG-2E and almost absent in the UG-2; (2) iron contents in pentlandite from the UG-2E are significantly higher than in the UG-2; (3) platinum-group element contents within sulfide minerals are different between the two chromitites; (4) UG-2E platinum-group minerals are dominated by arsenides and bismuthotellurides, and by alloys and platinum-group element-sulfide minerals in the UG-2; (5) sulfide mineral chemistry and δ34S values indicate some crustal contamination of the UG-2E; and (6) sulfide mineral and secondary silicate mineral textures in both the UG-2E and UG-2 are indicative of minor, millimeter- to centimeter-scale, hydrothermal alteration. From our observations and results, we consider the UG-2E chromitite in the northern limb to be the equivalent to the UG-2 in the eastern and western limbs that has been contaminated by assimilation of Transvaal Supergroup footwall rocks during emplacement. The contamination resulted in UG-2E sulfide mineral elemental contents and platinum-group mineral types and abundances that are distinct from those of the UG-2 in the rest of the Bushveld.

Contamination of the Bushveld Complex (South Africa) magmas by basinal brines: Stable isotopes in phlogopite from the UG2 chromitite

Abstract There is abundant evidence for significant H2O in evolved melts from the platinum-rich UG2 chromitite and the Merensky Reef of the Bushveld Complex (South Africa), but there is no consensus about the source of H2O. We report triple-oxygen and hydrogen isotope ratios of interstitial, late-magmatic phlogopite from three localities of the UG2 layer. The phlogopite yielded δD values of −43 to −23, which is &amp;gt;30 higher than previously known from Bushveld rocks and far above the mantle values of ~−75. The phlogopite triple-oxygen isotope ratios are the first to be reported for Bushveld rocks, with values of Δ′17O0.5305 (17O excess relative to the reference line 0.5305) from –0.069 to –0.044 (δ18O 5.2–6.2). The oxygen data support existing models of as much as 30%–40% contamination of mantle-derived magmas in the lower to middle crust. However, the high δD values require a second step of contamination, which we attribute to brines from the marine sediments in the Transvaal Basin at the emplacement level.

A Turbulent Magmatic Density Current and the Origin of the Anastomosing UG-1 Chromitites at Dwars River in the Bushveld Complex

AbstractThe origin of the enigmatic UG-1 chromitites at Dwars River in the eastern limb of the Bushveld Complex has been vigorously debated. The UG-1 chromitites form an anastomosing network of multiple layers that are hosted in poikilitic anorthosites and their formation has previously been explained by depositional, erosional, and intrusive processes. We propose that the UG-1 chromitites formed in response to the emplacement of a turbulent magmatic density current into the developing chamber. We use theoretical constraints in fluid mechanics to describe the evolution of the current and in this context, we provide an explanation for the enigmatic igneous features that are preserved at Dwars River. The current was emplaced as an instantaneous single pulse (fixed volume) of dense plagioclase-charged magma (i.e. a plagioclase slurry) that turbulently propagated along the chamber floor. Settling of the initial cargo of entrained plagioclase laths resulted in the formation of a thick sequence of feldspathic mush. The remaining melt turbulently outruns on the chamber floor ahead of the feldspathic mush. This led to the density current becoming stratified into two layers: (1) a basal granular layer, and (2) an upper melt-rich layer. Both layers evolved in a viscous-dominated regime from a Newtonian to a non-Newtonian behaviour (i.e. a power law fluid). In the current’s propagation stage, the resident magma in the chamber was entrained and efficiently admixed into the melt-dominated upper layer, producing a superheated chromite-saturated hybrid melt. Chromite precipitation from this hybrid melt led to the formation of a series of chromite-laden slurries that flowed in the turbulent current and were split (‘bifurcated’) as they passed around rising buoyant plagioclase diapirs that were developing in the back of the current. This led to the anastomosing and bifurcating nature of the UG-1 chromitites. The chromite slurries merged in the tail of the current and eventually back-injected into the deposited plagioclase cumulates on the chamber floor—forming the main ∼2-m thick UG-1 chromitite layer. The cooling and crystallization of the propagating upper layer of the current led to an increase in its viscosity that slowed its velocity until it eventually stagnated on the chamber floor. The mechanical sorting of crystals in plume structures became dominant at the stagnation stage. We argue that spatial variations in crystal packing controlled the heterogeneous distribution of brittle and ductile deformation features that are observed at Dwars River. In situ crystallization of trapped pore melts led to the nucleation of large orthopyroxene and plagioclase oikocrysts that cemented the anorthosite and the chromitite layers, respectively. The emplacement of magmatic density currents and intra-chamber magma mixing may be pertinent to the development of stratiform chromitites in incrementally constructed magma chambers.

Spatial association between platinum minerals and magmatic sulfides imaged with the Maia Mapper and implications for the origin of the chromite-sulfide-PGE association

ABSTRACT The spatial association between Pt minerals, magmatic sulfides, and chromite has been investigated using microbeam X-ray fluorescence (XRF) element mapping and the Maia Mapper. This lab-based instrument combines the Maia parallel energy dispersive (ESD) detector array technology with a focused X-ray beam generated from a liquid metal source. It proves to be a powerful technique for imaging Pt distribution at low-ppm levels on minimally prepared cut rock surfaces over areas of tens to hundreds of square centimeters, an ideal scale for investigating these relationships. Images of a selection of samples from the Bushveld Complex and from the Norilsk-Talnakh ore deposits (Siberia) show strikingly close association of Pt hotspots, equated with the presence of Pt-rich mineral grains, with magmatic sulfide blebs in all cases, except for a taxitic low-S ore sample from Norilsk. In all of the Bushveld samples, at least 75% of Pt hotspots (by number) occur at or within a few hundred microns of the outer edges of sulfide blebs. In samples from the leader seams of the UG2 chromitite, sulfides and platinum hotspots are also very closely associated with the chromite seams and are almost completely absent from the intervening pyroxenite. In the Merensky Reef, the area ratio of Pt hotspots to sulfides is markedly higher in the chromite stringers than in the silicate-dominated lithologies over a few centimeters either side. We take these observations as confirmation that sulfide liquid is indeed the prime collector for Pt and, by inference, for the other platinum group elements (PGEs) in all these settings. We further propose a mechanism for the sulfide-PGE-chromite association in terms of in situ heterogeneous nucleation of all these phases coupled with transient sulfide saturation during chromite growth and subsequent sulfide loss by partial re-dissolution. In the case of the amygdular Norilsk taxite, the textural relationship and high PGE/S ratio is explained by extensive loss of S to an escaping aqueous vapor phase.

Rapid cooling of the Rustenburg Layered Suite of the Bushveld Complex (South Africa): Insights from biotite 40Ar/39Ar geochronology

Abstract Despite their importance to understanding magma chamber processes and the formation of economically viable precious metal deposits, the cooling histories of layered mafic intrusions remain enigmatic due to limited geochronologic constraints. We provide a comprehensive 40Ar/39Ar study of biotite throughout the Rustenburg Layered Suite (RLS) of the Bushveld Complex, South Africa. Analyses of individual biotite grains from 10 samples, encompassing ∼5.5 km of RLS stratigraphy, yielded weighted mean plateau ages that all overlap at 2σ (α-95% confidence level) and range from 2056.3 ± 3.2 Ma to 2052.0 ± 7.6 Ma (2σ). A weighted mean of all biotite plateau ages yielded an age of 2054.47 ± 0.84 Ma (2σ, n = 30, mean square of weighted deviates = 0.23, P = 1.00; ±21 Ma fully propagated). The overlap between our 40Ar/39Ar biotite and published U-Pb zircon ages suggests that the RLS cooled rapidly to the closure temperature of biotite, with cooling rates on the order of 1000 °C m.y.–1 throughout the stratigraphy. Thermal modeling requires enhanced heat loss, due to the hydrothermal system associated with the emplacement of the RLS, to produce the inferred rapid cooling rates. Previously reported young 40Ar/39Ar biotite ages from the UG-2 and MG-1 chromitite seams and the Merensky Reef are likely a product of localized late-stage circulation of hydrothermal fluids. The lack of similarly young 40Ar/39Ar biotite ages from the remainder of the stratigraphy suggests that late-stage hydrothermal events were potentially localized to chromitites and the Merensky Reef.

Chromite chemistry of a massive chromitite seam in the northern limb of the Bushveld Igneous Complex, South Africa: correlation with the UG-2 in the eastern and western limbs and evidence of variable assimilation of footwall rocks

The Bushveld Igneous Complex (BIC) is known for its laterally extensive platinum group element–bearing layers, the most famous being the Merensky Reef and the UG-2 chromitite in the eastern and western limbs of the complex. In the northern limb, the Platreef mineralization and a thick chromitite seam below it (referred to as the “UG-2 equivalent” or UG-2E) have been proposed to be the stratigraphic equivalents of the Merensky Reef and the UG-2, respectively. In this study, we compare a suite of UG-2E samples from the Turfspruit project with a UG-2 reference suite from the western limb using petrography, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, and Mössbauer spectroscopy. The results show that (a) in Mg# vs. Cr# diagrams, UG-2E chromites have a distinct compositional field; however, when samples of similar chromite modal abundance (≥ 80%) are used, the UG-2E chromites overlap the field that characterizes UG-2 chromites; (b) the UG-2E is more variable in chromite modal abundance than the UG-2; and (c) variations in Mg# and Fe3+/ΣFe in the UG-2E indicate contamination of the magma by metasedimentary rocks of the Duitschland Formation (Transvaal Supergroup) during emplacement, followed by partial re-equilibration of chromite grains with a trapped melt. Thus, we conclude that for chromite modes higher than 80%, the chromite composition retains enough information to allow correlation and that the UG-2E in the northern limb is very likely the UG-2 chromitite.

The Upper Critical Zone of the Rustenburg Layered Suite in the Swartklip Sector, north-western Bushveld Complex, on the farm Wilgerspruit 2JQ: I. Stratigraphy and PGE mineralization patterns

AbstractThe Upper Critical Zone of the Rustenburg Layered Suite (RLS) in the Swartklip Sector, north-western Bushveld Complex, is considerably attenuated relative to other parts of the Complex. The interval between the UG2 chromitite and the Merensky Reef amounts to as little as 25 m in places. Within this interval, the aggregate thickness of orthopyroxenite-dominated ultramafic layers hosting the UG1 and UG2 chromitites and the Merensky and Bastard reefs does not differ significantly from the area around Rustenburg, to the south. The total thickness of ultramafic lithologies is, in fact, increased by the presence of the 3 to 5 m thick olivine-rich Pseudo Reef Unit, which is developed between the UG2 and Merensky Reef units in the Swartklip Sector, but does not occur in any significant form elsewhere in the Bushveld intrusion. The substantial thinning of the succession is due almost entirely to the fact that plagioclase-rich rocks (norite and anorthosite) between the ultramafic layers are radically thinned in the Swartklip Sector relative to virtually all other parts of the Bushveld Complex. The ultramafic layers, although dominated by orthopyroxenite, are characterized by higher proportions of olivine than in other parts of the Bushveld Complex. In our logging of the substantial number of exploration drill cores that form the basis of this study, we have found it expedient to define stratigraphic units that are either exclusively plagioclase-rich (norite and anorthosite) or plagioclase-poor (consisting of varying proportions of orthopyroxenite, harzburgite and chromitite). This effectively binary system of lithological classification has no overt genetic connotations.Our nomenclature has, in fact, enabled us to rigorously document the nature of contacts between ultramafic and plagioclase-rich units, and thus to identify unconformities between the ultramafic units (orthopyroxenite and harzburgite) and intervening noritic and anorthositic units, which have in the past been ascribed to localized thermo-chemical erosion of pre-existing plagioclase-rich cumulates. Apart from the well-documented evidence of erosional unconformities at the basal contacts of ultramafic units, we also provide evidence for unconformities at the tops of these units.

A non-horizontal floor during accumulation of the Bushveld Complex – Evidence and implications

Many models of igneous layered complexes assume that the instantaneous boundary between accumulated grains and overlying magma was horizontal. In the case of the Bushveld Complex, several km of hot, dense magma intruded into low-density sandstones and shales. This unstable density profile and the effect of heating of the floor rocks produced diapirism, features that have been well-documented around the intrusion. As a consequence, the grain - magma interface was probably not horizontal. The Al2O3 content of orthopyroxene is very sensitive to pressure (0.2% increase per km depth). It is shown here that the orthopyroxene compositions in the Upper Group 2 chromitite unit from nine detailed profiles change from 1.5 to 1.1% Al2O3 (at the same Mg/Mg + Fe value) along a strike length of 160 km in the western Bushveld. Such changes indicate that there was topographic relief possibly >1.5 km to the grain - magma interface. Such low Al2O3 concentrations and the lateral variations challenge models that envisage injections of pyroxene slurries either from depth or from a laterally displaced source. Basal, dense additions of magma at such intervals as the UG2 chromitite and Merensky units would need to have been >1.5 km in vertical extent in order to flood over such topographic variations. The proposed model to explain such pyroxene compositions involves two-phase convection with initiation of crystallization close to the top of the magma chamber and continuing grain growth and new grains nucleating as the package of grains plus magma descended to the uneven floor.

Chemical and Textural Re-equilibration in the UG2 Chromitite Layer of the Bushveld Complex, South Africa

Chemical and Textural Re-equilibration in the UG2 Chromitite Layer of the Bushveld Complex, South Africa

Litho- and chemostratigraphy of the Flatreef PGE deposit, northern Bushveld Complex

The Flatreef is a world-class platinum-group element (PGE) deposit recently discovered down-dip from existing mining and exploration operations on the northern limb of the Bushveld Complex. Current indicated resources stand at 42 Moz PGE (346 Mt with 3.8 g/t Pt+Pd+Rh+Au, 0.32% Ni and 0.16% Cu) which, in the case of Pt, is equivalent to ~ 10 years global annual production, making it one of the largest PGE deposits on earth. The grade and thickness of the Flatreef mineralised interval is highly unusual, with some drill core intersections containing up to 4.5 g/t Pt+Pd+Rh+Au over 90 m in drill core. Here, we document the down-dip and along-strike litho- and chemostratigraphy of the Flatreef and its footwall and hanging wall rocks, based on a diamond drill core database totalling > 720 km. At the base of the sequence intersected in the drill cores are up to 700-m-thick sills of ultramafic rocks (dunite, harzburgite, pyroxenite) emplaced into pelitic, dolomitic, and locally quartzitic and evaporitic rocks belonging to the Duitschland Formation of the Transvaal Supergroup. Next is an approximately 100–200-m sequence of low-grade-sulphide-mineralised, layered mafic-ultramafic rocks containing abundant sedimentary xenoliths and, in places, several chromite seams or stringers. This is overlain by a ~ 100-m-thick sequence of well-mineralised mafic-ultramafic rocks (the Flatreef sensu strictu), overlain by a laterally persistent mottled anorthosite layer at the base of > 1 km of homogenous Main Zone gabbronorite. Based on stratigraphic, lithological and compositional analogies to the layered rocks in the eastern and western Bushveld Complex, we correlate the Flatreef and its chromite bearing footwall rocks with the Upper Critical Zone, notably the interval between the UG2 chromitite and the Bastard Reef as found elsewhere in the Bushveld Complex. This includes recognition of a Merensky Reef correlative. The ultramafic rocks below the main chromitite seam (UG2 correlative) in the Flatreef footwall are correlated with the Lower Critical and Lower zones. However, compared to the western and eastern Bushveld limbs, the studied sequence is strongly enriched in sulphide and PGE, many of the rocks show elevated CaO, K2O, Rb and Zr contents, and lateral continuity of layers between drill cores is less pronounced than elsewhere in the Bushveld, whereas ultramafic units are locally considerably thickened. These compositional and lithological traits are interpreted to result from a range of processes which include contamination with calcsilicate and hornfels, intrusion of granitic magmas, and the influence of multiple structural events such as pre- to syn-emplacement regional-scale open folding and growth faults. Evidence for the existence of potholes also exists. In the shallow, up-dip portions of the project area, the entire magmatic sequence below the Main Zone becomes increasingly contaminated to the extent that individual units are somewhat more difficult to correlate between drill cores. This package represents the Platreef as exposed in outcrop and shallow bore holes across much of the northern limb of the Bushveld Complex. The new data presented here thus indicate that the Platreef is a relatively more contaminated up-dip extension of parts of the Critical and Lower zones.

Magma Mixing as a Trigger for Sulphide Saturation in the UG2 Chromitite (Bushveld): Evidence from the Silicate and Sulphide Melt Inclusions in Chromite

AbstractIt is of great importance to understand the origin of UG2 chromitite reefs and reasons why some chromitite reefs contain relatively high contents of platinum group elements (PGEs: Os, Ir, Ru, Rh, Pt, Pd) or highly siderophile elements (HSEs: Au, Re, PGE). This paper documents sulphide‐silicate assemblages enclosed in chromite grains from the UG2 chromitite. These are formed as a result of crystallisation of sulphide and silicate melts that are trapped during chromite crystallisation. The inclusions display negative crystal shapes ranging from several micrometres to 100 μm in size. Interstitial sulphide assemblages lack pyrrhotite and consist of chalcopyrite, pentlandite and some pyrite. The electron microprobe data of these sulphides show that the pentlandite grains present in some of the sulphide inclusions have a significantly higher iron (Fe) and lower nickel (Ni) content than the pentlandite in the rock matrix. Pyrite and chalcopyrite show no difference. The contrast in composition between inter‐cumulus plagioclase (An68) and plagioclase enclosed in chromite (An13), as well as the presence of quartz, is consistent with the existence of a felsic melt at the time of chromite saturation. Detailed studies of HSE distribution in the sulphides and chromite were conducted by LA‐ICP‐MS (laser ablation‐inductively coupled plasma‐mass spectrometry), which showed the following. (I) Chromite contained no detectable HSE in solid solution. (II) HSE distribution in sulphide assemblages interstitial to chromite was variable. In general, Pd, Rh, Ru and Ir occurred dominantly in pentlandite, whereas Os, Pt and Au were detected only in matrix sulphide grains and were clearly associated with Bi and Te. (III) In the sulphide inclusions, (a) pyrrhotite did not contain any significant amount of HSE, (b) chalcopyrite contained only some Rh compared to the other sulphides, (c) pentlandite was the main host for Pd, (d) pyrite contained most of the Ru, Os, Ir and Re, (e) Pt and Rh were closely associated with Bi forming a continuous rim between pyrite and pentlandite and (f) no Au was detected. These results show that the use of ArF excimer laser to produce high‐resolution trace element maps provides information that cannot be obtained by conventional (spot) LA‐ICP‐MS analysis or trace element maps that use relatively large beam diameters.

An intrusive origin of some UG-1 chromitite layers in the Bushveld Igneous Complex, South Africa: Insights from field relationships

The UG-1 chromitite in the Bushveld Complex is a 1m thick massive layer overlain by orthopyroxenite (4–9m thick) and underlain by anorthosite (1.5–2.0m thick), which is strongly interleaved with numerous thin layers of UG-1 chromitite (mm to 10s of cm thick). The chromitite-bearing anorthosite is further underlain by mottled anorthosite, which is devoid of chromitites. Sometimes, the massive UG-1 chromitite may be hosted entirely within orthopyroxenite; in this study, however, the orthopyroxenite occurs intermediate to the massive UG-1 layer and the footwall interleaved anorthosite unit, which has a 10cm thick chromitite layer at the contact. Though the UG-1 chromitites display complex features in the field outcrops (e.g., presence of numerous anorthosite autoliths, bifurcations, and dimpled contacts with anorthosite), the ones discussed in this study are distinctive and diagnostic of the emplacement mechanism for this chromitite layer. In this study of the UG-1 chromitite at the Impala Platinum mine, the chromitite is seen to form a small pothole (≈1.5m deep; 3.6m wide) that cuts down into the underlying orthopyroxenite (exposed only on the right side of the pothole) and anorthosite layers. A 15cm thick UG-1 chromitite layer (85 modal% chromites) is observed to protrude or branch out of the pothole margin and laterally extend into the anorthosite, with which it shows several crosscutting features. Examples include truncation of layering defined by interstitial pyroxene mottles within the footwall anorthosite against the protruding UG-1 layer, and truncation of several thinner UG-1 layers in the hanging wall anorthosite against erosive outlines of this chromitite layer. These observations strongly attest to the emplacement of the protruding UG-1 chromitite layer as a sill into the anorthosite. The presence of thin anorthosite lenses with high aspect ratios within this UG-1 layer, along with lateral variations in thickness of the layer, its irregular contact with the host anorthosite, and disturbances observed for the UG-1 layers in the footwall anorthosite adjacent to the erosive contact, implies that the superheated melt, parental to the chromitite, chemically dissolved the anorthosite and made space for it to flow as a sill within the latter. The probable mode of emplacement of the laterally protruding UG-1 layer would be through the opening of fractures related to the event of pothole formation where there is ponding of hot, thick and dense melt above the anorthosite. The melt subsequently filled the fractures and flowed laterally into the anorthosite thereby eroding it. An open magmatic system ensured continuous addition of melts in the pothole and their supply into the sill. This study thus emphasizes that some of the UG-1 chromitite layers within anorthosite can be emplaced as sills, and not all need to form from discrete cyclical pulses of chromite-saturated and plagioclase-saturated melts being brought into the chamber.

The significance of magmatic erosion for bifurcation of UG1 chromitite layers in the Bushveld Complex

One of the most puzzling features of the UG1 chromitite layers in the famous exposures at Dwars River, Eastern Bushveld Complex, is the bifurcation, i.e. convergence and divergence of layers along strike that isolate lenses of anorthosite. The bifurcations have been variously interpreted as resulting from: (1) the intermittent accumulation of plagioclase on the chamber floor as lenses, terminated by crystallization of continuous chromitite layers (the depositional model); (2) late-stage injections of chromite mush or chromite-saturated melt along anastomosing fractures that dismembered semi-consolidated plagioclase cumulates (the intrusive model); (3) post-depositional deformation of alternating plagioclase and chromite cumulates, resulting in local amalgamation of chromitite layers and anorthosite lenses that wedge out laterally (the deformational model). None of these hypotheses account satisfactorily for the following field observations: (a) wavy and scalloped contacts between anorthosite and chromitite layers; (b) abrupt lateral terminations of thin anorthosite layers within chromitite; (c) in situ anorthosite inclusions with highly irregular contacts and delicate wispy tails within chromitite; many of these inclusions are contiguous with footwall and hanging wall cumulates; (d) transported anorthosite fragments enclosed by chromitite; (e) disrupted anorthosite and chromitite layers overlain by planar chromitite; (f) protrusions of chromitite into underlying anorthosite; (g) merging of chromitite layers around anorthosite domes. We propose a novel hypothesis that envisages basal flows of new dense and superheated magma that resulted in intense thermo-chemical erosion of the temporary floor of the chamber. The melting and dissolution of anorthosite was patchy and commonly inhibited by chromitite layers, resulting in lens-like remnants of anorthosite resting on continuous layers of chromitite. On cooling, the magma crystallized chromite on the irregular chamber floor, draping the remnants of anorthosite and merging with pre-existing chromitite layers excavated by erosion. With further cooling, the magma crystallized chromite-bearing anorthosite. Emplacement of multiple pulses of magma led to repetition of this sequence of events, resulting in a complex package of anorthosite lenses and bifurcating chromitite layers. This hypothesis is the most satisfactory explanation for most of the features of this enigmatic igneous layering in the Bushveld Complex.

Platinum-group elements and minerals in the lower and middle group chromitites of the western Bushveld Complex, South Africa

The chromitites of the Bushveld Complex in South Africa contain vast resources of platinum-group elements (PGE). However, knowledge of the distribution and the mineralogical siting of the PGE in the lower group (LG) and middle group (MG) chromitite seams of the Bushveld Complex is limited. We studied concentrates from the LG-6 and MG-2 chromitites of the western Bushveld Complex by a variety of microanalytical techniques. The dominant PGM are sulfides, namely laurite, cooperite-braggite, and malanite-cuprorhodsite, followed by PGE-sulfarsenides, sperrylite, and Pt-Fe alloys. Laurite is the most abundant PGM (vol%). The matching sets of PGM present in the LG and MG chromitites of both the western and the eastern Bushveld Complex, and in the UG-2 chromitite, show strong similarities which support the assumption of a characteristic and general chromitite-related PGM assemblage. Palladium and Rh contents in pentlandite are low and erratic although maximum contents of 7730 ppm Pd and 6020 ppm Rh were detected. Rare thiospinels of the polydymite-linnaeite-greigite series have PGE contents of 1430 ppm Pt, 5370 ppm Rh, and 1460 ppm Pd. The various PGE occur in different deportment: Platinum is generally present in the form of discrete PGM (sulfides, arsenides, alloys). Palladium is present as a large variety of discrete PGM and also incorporated in pentlandite. Rhodium forms discrete PGM and is occasionally present in pentlandite. The IPGE (Os, Ir, and Ru) are dominantly incorporated in laurite (often as inclusions in chromite) and also occur as sulfarsenides.

Formation of transgressive anorthosite seams in the Bushveld Complex via tectonically induced mobilisation of plagioclase-rich crystal mushes

The formation of anorthosites in layered intrusions has remained one of petrology's most enduring enigmas. We have studied a sequence of layered chromitite, pyroxenite, norite and anorthosite overlying the UG2 chromitite in the Upper Critical Zone of the eastern Bushveld Complex at the Smokey Hills platinum mine. Layers show very strong medium to large scale lateral continuity, but abundant small scale irregularities and transgressive relationships. Particularly notable are irregular masses and seams of anorthosite that have intrusive relationships to their host rocks. An anorthosite layer locally transgresses several 10 s of metres into its footwall, forming what is referred to as a “pothole” in the Bushveld Complex. It is proposed that the anorthosites formed from plagioclase-rich crystal mushes that originally accumulated at or near the top of the cumulate pile. The slurries were mobilised during tectonism induced by chamber subsidence, a model that bears some similarity to that generally proposed for oceanic mass flows. The anorthosite slurries locally collapsed into pull-apart structures and injected their host rocks. The final step was down-dip drainage of Fe-rich intercumulus liquid, leaving behind anorthosite adcumulates.

Cryptic mineral variation and PGE distribution in the Merensky Reef and its discontinuous mela-gabbronoritic hanging wall (“Brown Sugar Norite” - BSN) at Two Rivers Platinum Mine, Eastern Bushveld Complex, South Africa

Two Rivers Platinum Mine, situated on the southern sector of the eastern limb of the Bushveld Complex, extracts Platinum Group Elements (PGE) from the UG-2 chromitite layer. A trial operation of the Merensky Reef (MR) exposed unusual occurrences of mela-gabbronoritic lenses, ‘brown sugar norite’ (BSN in mine terminology), within the pyroxenite of the hanging wall. The BSN is a fine-grained mela-gabbronorite, which appears to only occur where the upper chromitite stringer of the Merensky Reef unit is present, and forms laterally inconsistent, flat lenses. Textural features, mineral chemistry of the various rock types, Sr analyses of plagioclase separates and whole rock geochemistry indicate multiple magma injections, fractionation and disequilibrium crystallization of the magma within the Merensky interval. Whole rock MgO and enstatite content of orthopyroxene are higher in BSN compared with the surrounding Merensky Reef pyroxenite, thus supporting the notion of the BSN having formed from a more primitive magma. Both the pyroxenite and BSN plagioclase have 87Sr/86Sr ratios representative of Critical Zone magma; that of the BSN has a lower initial 87Sr/86Sr isotope ratio relative to that of the pyroxenite, suggesting a more primitive magma source. It is suggested that the unusual, discontinuous BSN lenses within pyroxenite may have formed by magmatic erosion of a new magma injection, which affected the crystal mush of the earlier deposited BSN layer. This resulted in isolated lenses of relict, but more primitive orthopyroxene of the BSN in a residual plagioclase-rich melt from an earlier pyroxenitic MR magma. In both rock types (MR pyroxenite and BSN), the PGE occur as discrete platinum-group minerals (PGM), and in solid solution in sulphides. At Two Rivers Platinum Mine, the presence of PGE in sulphides has been identified by EMPA and LA-ICP-MS. The PGE occur mineralogically either in solid solution or as PGM inclusions of different size. Pentlandite, chalcopyrite, pyrrhotite and rare pyrite occur disseminated as individual grains with associated PGM throughout the Merensky pyroxenite interval, but more enriched near the bottom and top chromitite stringers. PGM encountered are moncheite, platarsite and irarsite, relatively enriched in Pt, but poor in Pd and Rh. Our results show that most of the Pd and Rh are incorporated in pentlandite, whereas pyrrhotite, chalcopyrite, and pyrite are almost devoid of PGE. Textural features of the encountered PGM grains suggest their redistribution through late stage magmatic (probably hydrothermal) processes. The BSN contains relatively little if any base metal sulphides and PGM, indicating its formation from magma depleted in PGE.