Typical Products Research Articles

Combining Cold Atmospheric Plasma and Environmental Nanoparticle Removal Device Reduces Neurodegenerative Markers

Ageing leads to a gradual deterioration of the organs, with the brain being particularly susceptible, often leading to neurodegeneration. This process includes well-known changes such as tau hyperphosphorylation and beta-amyloid deposition, which are commonly associated with neurodegenerative diseases but are also present in ageing. These structures are triggered by earlier cellular changes such as energy depletion and impaired protein synthesis, both of which are essential for cell function. These changes may in part be induced by environmental pollution, which has been shown to accelerate these processes. Cold Atmospheric Plasma (CAP) or atmospheric pressure gas discharge plasmas have shown promise in activating the immune system and improving cellular function in vitro, although their effects at the organ level remain poorly understood. Our aim in this work is to investigate the effect of a device that combines CAP treatment with the effective removal of environmental nanoparticles, typical products of pollution, on the activity of aged mouse brains. The results showed an increase in energy capacity, a reduction in reticulum stress and an activation of cellular autophagic clearance, minimising aggresomes in the brain. This leads to a reduction in key markers of neurodegeneration such as tau hyperphosphorylation and beta-amyloid deposition, demonstrating the efficacy of the tested product at the brain level.

Carbon sequestration behavior of magnesium oxychloride cement based on salt lakes magnesium residue and industrial solid waste

With the extensive utilization of lithium-ion battery in the electric vehicle and energy storage field, the consumption of lithium has been sharply increasing. Lithium resource occurrence area were facing increasing environmental pressure, particularly the magnesium residue (MR) produced in the lithium extraction process, and a sustainable exploitation pathway have not been established. In the framework of "net-zero", MRs were onverted to Salt lake magnesium oxide (SL-MgO) which was characterized by various elemental and surface analysis methods. Magnesium oxychloride cement (MOC) was prepared form SL-MgO and two industrial solid wastes [fly ash (FA) and phosphogypsum (PG)], and its carbon sequestration capacity was analyzed and evaluated. If all the MRs produced from the lithium extraction process were used to manufacture MOC materials for CO2 sequestration. When the PG content was 20 %, the CO2 sequestration capacity of the MOC was 0.29 kg/m2, the compressive strength was 85.30 MPa, and the MOC neutralized 220.10 % of the CO2 emissions from the lithium extraction process. In this procedure, evidence was found of the typical metastable carbonate products identifiable. Overall, utilizing MRs and industrial solid waste to manufacture new low-carbon MOCs may become the most direct and effective countermeasures to alleviate environmental pressure in these regions.

Review on herbal drug used in various dental problems

Polyherbal tooth paste is gaining recognition as an organic a substitute for conventional oral care utilizing the advantages of various herb constituents for elevated oral hygiene this review looks at the contents evaluation and antibacterial properties of polyherbal toothpaste with a focus on key components of medicinal value such clove tulsi neem and aloe vera we discuss formulation techniques and their effects on stability and effectiveness as well as assessment instruments to measure physical and microbiological characteristics in vitro tests show that polyherbal toothpaste is effective against a common oral infections in comparison to typical products clinical assessments offer further context for user experiences and safety profiles all things considered polyherbal toothpaste satisfies consumers growing need for natural goods while offering an economical solution to dental hygiene

Development of Bontang City Typical White Bread Food Products with the Use of Mackerel Tuna Fish (Euthynnus affinis) Broth on White Bread Quality

Development of Bontang City Typical White Bread Food Products with the Use of Mackerel Tuna Fish (Euthynnus affinis) Broth on White Bread Quality

Influence of Candle Emissions on Monoterpene Oxidation Chemistry and Secondary Organic Aerosol.

Candle burning is a considerable contributor to indoor pollutants, while secondary organic aerosols (SOA) from monoterpene ozonolysis represent another type. However, knowledge of the interactions of different indoor pollutants is limited. We investigated physicochemical properties of SOA generated from typical indoor chemistry of the O3/α-pinene reaction with and without the presence of particles and gases from a burning candle. Ozonolysis of α-pinene in the presence of candle gaseous emissions yielded a considerably lower particle number, larger particle sizes, and lower particle oxygen-to-carbon ratio compared with experiments without candle emissions. More nitrogen-containing organic compounds were observed in the aerosol phase with candle emissions. Furthermore, concentrations of some typical particle-phase products from the O3/α-pinene reaction (i.e., terebic acid, cis-pinic acid, and 3-methyl-1,2,3-butanetricarboxylic acid) were less abundant in the presence of candle emissions. The predicted volatility of particulate organic compounds was higher in experiments with candle emissions. The study demonstrates that candle burning can affect the chemical and physical properties of particles formed from other sources (e.g., α-pinene ozonolysis) by affecting gas-phase chemistry and gas-particle partitioning.

Powder casting of polyetheretherketone and polyphenylene sulfone: Sintering

Systematic studies of the influence of the basic powder characteristics and its sintering conditions on the physical and mechanical properties of samples intended for the implementation of the technology of powder injection molding of products from typical heat-resistant high performance engineering polymers - crystallizing polyetheretherketone (PEEK) and amorphous polyphenylene sulfone (PPSu) - were carried out. Polymers with different MW were synthesized as initial materials and powders with different sizes and bulk density were obtained. The influence of these parameters on the nature of powder sinterability and, as a consequence, on their elastic modulus and tensile strength was shown. Optimum characteristics for bulk density and sintering temperature were established, which provide maximum values of mechanical characteristics of the molded samples. The results of the fundamental research conducted allowed us to produce two typical products for biomedicine - an intervertebral cage (an implant replacing a removed vertebra) and a blood dialyzer part.

Advancements in the Engineering Modification of Sucrose Phosphorylase

Sucrose phosphorylase (SPase) is a member of the glycoside hydrolase family 13, catalyzing the reversible phosphorolysis of sucrose to produce α–glucose–1–phosphate and exhibiting transglycosylation activity toward multiple substrates. Its wide substrate specificity enables the synthesis of various glycosides, which are broadly applied in food, cosmetics, and pharmaceuticals. However, the industrial application of SPase is constrained by its poor thermostability and limited transglycosylation activity. Therefore, current research focuses on enhancing the thermostability and transglycosylation activity of SPase through efficient engineering strategies based on its crystal structure and catalytic mechanism. This paper systematically reviews the crystal structure and catalytic mechanism of SPase, outlines the application of protein engineering and immobilization strategies in improving the thermostability of SPase, and analyzes how modifications at key amino acid sites affect the synthesis of typical glycosylation products. It also summarizes the limitations of SPase engineering modification strategies and explores the potential of diversified approaches for SPase modification, highlighting its broad application prospects in industrial production and laying a solid foundation for further advancements in SPase engineering modification and its industrial application.

Multi-principal element alloys for fast reactor cladding applications

Given the extensive list of multi-principal element alloys (MPEAs) within literature and the overwhelming number of alloys that can be made from only a handful of elements, this article proposes a methodology for prioritizing alloys for use as cladding within advanced reactors. This paper applies neutronic, mechanical, and chemical assessments to a collection of MPEAs available within literature for use as advanced reactor cladding. The results are compared to a reference design of HT9, a ferritic/martensitic steel, for employed in sodium-cooled fast reactor. Mechanical assessments determined pressure limits for a thin-walled tube pressure boundary, thus relating the material's mechanical properties to a minimum acceptable wall thickness. Neutronic analyses reveal a maximum allowable wall thickness that a given material must meet to provide a level of neutronic economy that is equivalent to than that of HT9. Lastly, each alloying element is compared to typical fission products found in a fast reactor fuels to mitigate deleterious phenomena such as fuel-cladding chemical interactions (FCCI). These analyses indicate that Mo-Nb-Ti-V-based alloys are likely to be advantageous and that the inclusion of elements with a high neutronic penalty (e.g., Hf) could be considered with minimal consequences.

Competition & UV254 projection in odorants vs natural organic matter adsorption onto activated carbon surfaces: Is the chemistry right?

Powdered activated carbon (PAC) adsorption remains an indispensable method for addressing odor problems in drinking water. While natural organic matter (NOM) is ubiquitous and competes strongly in deteriorating odorant adsorption capacity, it can also serve as a promising indicator for predicting odorant adsorption through online measurement. However, the impact of PAC surface chemistry on NOM competition and feasibility of prediction across various adsorbents are not well understood. Here, we examined the role of PAC properties (pore structure and surface chemistry) in the competitive adsorption between odorants and NOM components, aligned with the applicability assessment of using NOM optical properties for odorant adsorption projection across various PAC samples. Chemical oxidation and thermal treatment achieved considerable changes in surface functional group composition, alongside minimal changes in pore structure, of two typical PAC products with microporous/mesoporous pore characteristics. The effect of NOM interference on the reduction of odorant adsorption exhibited a similar level regardless of the PACs with different pore structure (average pore size of 1.7 nm vs. 4.2 nm). Surface modification increased the equilibrium adsorption capacity (qe50) of odorants by 15.1% to 146.4% (thermal treatment) or decreased by -81.3% to -34.1% (chemical oxidation), respectively, but minimal changes in odorant-NOM selectivity. For various odorants, hydrophobicity (log D) influenced the adsorption capacity while the structural flexibility (reflected by the rotatable bonds) affected the vulnerability of odorant adsorption to NOM competition. It was found for the first time that four-parameter Richards model (RMSE = 2.6%) is superior to the linear model (RMSE = 12.5%) or logarithmic model (RMSE = 77.6%) to describe the S-shape UV254 projection curves associated with odorant adsorption on PAC. Moreover, the feasibility was confirmed to use UV254 projection curves of pristine PAC fitted with the Richard model to predict the odorant adsorption on surface-modified PAC in two different surface waters (RMSE 9.2% and 7.4%, respectively). This study provides insight into the role of PAC surface chemistry and pore characteristics in odorant adsorption in NOM-containing waters and enhances the feasibility of the NOM surrogate model for odorant monitor and control during PAC adsorption.

INNOVATION DEVELOPMENT STRATEGY FOR KARANGPATIHAN CIPRAT BATIK AS AN EFFORT TO IMPROVE THE LOCAL ECONOMY

The batik industry is an industry that is relied upon in the local market as well as the export market in the textile sector. Likewise, Karangpatihan ciprat batik (splashed motif in batik) is deliberately empowered as a form of local government concern for disabled residents who have limitations. This research aims to analyze the strategy for developing Ponorogo's typical Karangpatihan ciprat batik in order to increase industrial competitiveness batik industry in Ponorogo Regency. The method used in this research is a qualitative approach using the SWOT analysis method and a survey conducted on the Karangpatihan village head and the chairman of Rumah Harapan Mulya as the Karangpatihan Social Welfare Institution. The results of the research analysis conclude that the strategies that can be used are determining market opportunities based on geographic location, demographics and consumer behavior, identifying the target market to be addressed both within and outside the city of Ponorogo by understanding consumer preferences and needs regarding batik, increasing human resource development in order to achieve this. more innovative quality batik products that can increase consumer appeal. Determining sales channels by considering the place and method to be used. Then determine competitive prices by adjusting product quality and competition in the market, protection of rights to regional typical batik products with Intellectual Property Rights, promotional program innovations aimed at introducing batik on the national and international stage to encourage sales and establishing good relationships with consumers and distributors so that it can expand the marketing of batik products.

Oxidation of 4-hydroxybenzoic acid in strongly alkaline and high-salt solutions via ultrasonic-assisted ozone: Helping radioactive waste disposal and environmental safety

4-Hydroxybenzoic acid (4-HBA), as a gibbsite dissolution inhibitor and typical personal care products (PPCPs), seriously troubles radioactive waste disposal and environmental safety. This work studies the degradation mechanism of 4-HBA in ultrasonic-assisted ozonation in strongly alkaline and high-salt solutions, and comprehensively evaluates its environmental lifetime. Ultrasonic can significantly increase the effect of ozone by 1.52 times, making the degradation rate of 4-HBA reach 63.49 % within 60 min. The better electrochemical performance indicates that the redox reaction between US/O3 system and 4-HBA is more prominent. Experimental analysis and density functional theory (DFT) calculations show that the effects of OH, 1O2, O2−, and others on the degradation of 4-HBA are 56.6 %, 17.8 %, 22.1 %, and 3.5 % respectively, and HO3 is the most important precursor for OH evolution. Mechanistic exploration and DFT calculations show that degradation behavior of 4-HBA in strongly alkaline and high-salt solutions, i.e., decarboxylation reaction, ring opening, hydroxylation, aldol condensation, and hydrogenation, is significantly different from acidic or neutral solutions. Based on the environmental lifetime assessment of the intermediate product, US/O3 technology can help reduce the toxicity of 4-HBA. The US/O3 process is used to remove 4-HBA from strongly alkaline and high-salt solutions, which has huge potential economic benefits in the fields of nuclear waste chemistry and environment.

Lower Limb Rehabilitation Exoskeleton Robots, A review

Using a lower limb exoskeleton for rehabilitation (LLE) Lower limb exoskeleton rehabilitation robots (LER) are designed to assist patients with daily duties and help them regain their ability to walk. Even though a substantial portion of them is capable of doing both, they have not yet succeeded in conducting agile and intelligent joint movement between humans and machines, which is their ultimate goal. The typical LLE products, rapid prototyping, and cutting-edge techniques are covered in this review. Restoring a patient's athletic prowess to its pr-accident level is the aim of rehabilitation treatment. The core of research on lower limb exoskeleton rehabilitation robots is the understanding of human gait. The performance of common prototypes might be used to match wearable robot shapes to human limbs. To imitate a normal stride, robot-assisted treatment needs to be able to control the movement of the robot at each joint and move the patient's limb.

Investigation on mechanism of mechanical activation and chemical reactions in CMP of diamond assisted by hydroxyl free radicals

Chemical mechanical polishing (CMP) is a crucial manufacturing process for diamond substrate applications. However, due to the extremely high hardness and chemical stability of diamond, its CMP efficiency is extremely low. This study aims to achieve microscopic simulation of atomic oxidation removal at the three-phase interface between diamond abrasive particle, diamond substrate, and hydroxyl free radicals (∙OH) aqueous solution. The mechanical activation behavior, microscopic mechanism, and feasibility of elementary reactions in the ∙OH aqueous solution environment was studied using various perspectives of radial distribution function, central atomic coordination state, atomic bonding and removal forms, energy, electron orbitals, and density functional theory (DFT). The simulation results indicate that during the process of diamond atomic oxidation removal, the atomic density at the first adjacent position centered on one atom decreases, and the stable covalent bond structure is disrupted, resulting in an amorphous phase transition. The chemical adsorption reaction generates C-O and C–H bonds. The C atoms mainly separate from the diamond substrate by the forming products such as carbon monoxide (CO), carbon dioxide (CO2), and carbon chains. The mechanical activation behavior indirectly reduces the activation energy of chemical reactions, while increasing the absolute value of adsorption energy and improving the ability of chemical adsorption solution atoms H and O, as well as ∙OH groups. Based on DFT, it has been verified that the intrusion process of ∙OH groups in the elementary reactions involving the typical product C*O2 is an exothermic reaction that can occur spontaneously, and the energy barrier needs to be overcome by the mechanical action of abrasive particles. At the same time, the energetics of the oxidation of diamond C atoms to generate C*O2 have successfully confirmed that the combined action of ∙OH and diamond abrasive particles is expected to achieve efficient oxidation removal and finishing polishing of diamond atoms.

Inhibition effect of non-contact biocontrol bacteria and plant essential oil mixture on the generation of N-nitrosamines in deli meat during storage

To reduce the risk of N-nitrosamines in deli meat products, this study formulated a novel non-contact N-nitrosamines inhibiting preservative IV (NIP-IV) consisting of biocontrol bacteria and plant essential oils (EOs) (Stenotrophomonas rhizophila SR-1 + Paenibacillus provencensis PP-2 + Bacillus subtilis CF-3+ cinnamon EO + grapefruit EO). Luncheon pork, spiced beef, and red sausage were taken as representatives of typical deli meat products and used to validate the effectiveness of NIP-IV in inhibiting N-nitroso dimethylamine (NDMA) production. The results showed that NIP-IV restrain protein degradation and lipid oxidation in deli meat products and effectively control microbial activity. Biogenic amines, such as phenethylamine, spermidine, cadaverine, and tyramine, were reduced. The conversion of nitrite to NDMA in deli meats was effectively inhibited by NIP-IV. Volatile organic compounds were the key to excellent NIP-IV non-contact preservation. Butyric acid, 3-methylbutanoic acid, benzaldehyde, d-limonene, and (E)-cinnamaldehyde were significantly negatively correlated with NDMA in deli meat products.

Comparative Life Cycle Assessment and Carbon Footprint of Typical Hydrogen Energy Products

To compare the environmental impact and carbon footprint of gray hydrogen, blue hydrogen, and green hydrogen, inventories were obtained through literature research. Some inventories that were not available in China were obtained through foreign inventories combined with localized power conversion. The localized end-point destructive life cycle impact assessment method was used to calculate the environmental impact potential of the raw material acquisition, transportation, and hydrogen production stages of five hydrogen products. The carbon footprint was calculated, and the sensitivity analysis and uncertainty analysis were carried out and compared with the ReCiPe method. The results showed that： ① The environmental impact from large to small was： gray hydrogen （coal） （1 203 mPt·kg-1） > blue hydrogen （coal） （876 mPt·kg-1） > gray hydrogen （gas） （492 mPt·kg-1） > green hydrogen （323 mPt·kg-1） > blue hydrogen （gas） （252 mPt·kg-1）. The environmental impacts of gray hydrogen and blue hydrogen were mainly concentrated in climate change, fine particulate matter formation, and fossil fuels. The environmental impacts of green hydrogen were mainly concentrated in climate change, fine particulate matter formation, fossil fuels, and mineral resources. ② The carbon footprint from large to small was： gray hydrogen （coal） （23.79 kg·kg-1, measured by CO2eq, the same below） > blue hydrogen （coal） （11.07 kg·kg-1） > gray hydrogen （gas） （10.97 kg·kg-1） > blue hydrogen （gas） （3.47 kg·kg-1） > green hydrogen （1.97 kg·kg-1）. Direct carbon emissions in the production process of gray hydrogen and blue hydrogen accounted for the largest proportion, whereas that of green hydrogen accounted for a large proportion of power input. ③ Measures to reduce environmental impact and carbon emissions include reducing direct emissions of pollutants and greenhouse gases, reducing power consumption, and strengthening raw material substitution and reduction.

Nano-magnetite enhances dissimilated iron reduction to vivianite from sewage by structuring an enormous and compact electron transfer network

Acting as both terminal and conductor of extracellular electron transfer (EET), little studies were focused on how nano-magnetite participated in the dissimilated iron reduction (DIR), especially the synthesis of vivianite, which was the typical DIR products from sewage. In this study, nano-magnetite was confirmed to enhance DIR of ferrihydrite and akaganeite for vivianite recovery from sewage. Nano-magnetite incorporation enriched Comamonas and Geobacter in sewage, and microbial protein content was increased by 123 % and 57 % in ferrihydrite and akaganeite batches, respectively. In Geobacter sulfurreducens PCA pure culture, vivianite yield was promoted by 21 % and 37 % in ferrihydrite and akaganeite batches in the presence of nano-magnetite, respectively. Due to its nanoscale size and superior electrical conductivity, nano-magnetite embedded in the gaps formed by the microorganisms and electron acceptor, and architected coherent conductive pathways to promote EET. Simultaneously, the addition of nano-magnetite stimulated the secretion of proteins, polysaccharides, and humic acids in the extracellular polymeric substances. Nano-magnetite addition structured an enormous and compact electron transfer network, thus enhanced DIR and vivianite formation. Our study proposed a new strategy to promote iron-reduction-coupled phosphorus recovery with natural DIR products, and provided theoretical support for clarifying the interaction between minerals and microorganisms.

Wastewater treatment in the pulp and paper industry: A review

The pulp and paper industry plays a large role in global manufacturing, which creates significant water consumption and generation of wastewater that is filled with organic compounds and other chemicals. This paper will explore many different aspects of the pulp and paper industry such as raw material sourcing, manufacturing processes, environmental concerns, technological advancements, and the various wastewater treatment approaches. While there are many different methods to approach this wastewater issue, in this paper we will focus on anaerobic digestion, the application of biological aerated filters, and the use of constructed wetlands. The main material utilized in this industry is wood pulp, which undergoes multiple different procedures and processes to create the typical paper products we use every day. These processes, such as pulping and bleaching, create a large number of environmental concerns despite efforts to encourage better manufacturing practices and paper recycling.

Copper Single-Atom Nanozyme Mimicking Galactose Oxidase with Superior Catalytic Activity and Selectivity.

Due to the low stability and high cost of some natural enzymes, nanozymes have been developed as enzyme-imitating nanomaterials. Single-atom nanozymes are a class of nanozymes with metal centers that mimic the structure of metal-based natural enzymes. Herein, Cu-N-C single-atom nanozyme (SAN) is synthesized with excellent peroxidase- and enhanced oxidase-like activities to mimic the action of natural galactose oxidase. Cu-SAN demonstrates stereospecific activity akin to that of natural galactose oxidase by oxidizing D-galactose and primary alcohol but not L-Galactose or other carbohydrates. The SAN can catalyze the oxidation of galactose in the presence of oxygen, producing hydrogen peroxide as a sub-product. The produced hydrogen peroxide then oxidizes 3,3',5,5'-tetramethylbenzidine catalyzed by the SAN, yielding the typical blue product. The relationship between absorbance and galactose concentration is linear in the 1-60µm range with a detection limit as low as 0.23µm. This strategy can be utilized in the diagnosis of galactosemia disorder and detection of galactose in some dairy and other commercial products. DFT calculations clarify the high activity of the Cu sites in the POD-like reaction and explain the selectivity of the Cu-SAN oxidase-like reaction toward D-galactose.

Collaborative Governance dalam Pemberdayaan UMKM Melalui Pemanfaatan Potensi Alam Menuju Sustainable Tourism di Desa Wisata Taro Kabupaten Gianyar

Taro Village is located in Tegallalang District, Gianyar Regency, which has quite a lot of natural potential that is in demand by tourists and has developed rapidly since it was designated as a Tourism Village in 2017. Taro Tourism Village can be said to be a tourism village that has implemented sustainable tourism. This can be seen from its implementation which tends to emphasize the sustainability aspect. However, the management of the natural potential of Taro Village leaves various gaps of opportunity that have not been utilized by the community, reflected in the absence of typical products of Taro Tourism Village. In carrying out community service activities, namely empowerment targeting the Taro Village Women Farmers Group and MSMEs through the utilization of the natural potential of Taro Village. Collaborative governance practices are carried out by involving three actors, namely the government, the community and the private sector. First, collaboration involving the government through the Village-Owned Enterprise (BUMDes) Sarwada Amertha. Second, the role of the community as a group that is empowered so that they can produce a valuable product and can support sustainable tourism in Taro Tourism Village. We involve the private sector by visiting industries engaged in tourism, such as lodging and resorts that have the potential for us to collaborate with.

Synthesis of Polycyclic Chromeno[4,3,2‐ij]Isoquinoline‐3‐Carbonitriles in the Presence of Ammonium acetate as a Dual Rule Reagent‐Catalyst

AbstractIn this paper, a two‐step process is described for the chemoselective synthesis of highly fluorescent polycyclic chromeno[4,3,2‐ij]isoquinoline‐3‐carbonitriles using a sequential nucleophilic addition reaction involving 4‐chloro‐3‐vinyl coumarins, α,α‐dicyanoolefins and ammonium acetate as a source of nitrogen. In this process, it is believed that ammonium acetate is converted into ammonia and acetic acid during the reaction. Ammonia is the source of nitrogen, and the acid produced can catalyze the progress of the reaction. Single‐crystal X‐ray analysis was performed to confirm the structure of one of the typical products. In addition, the photophysical characteristics of the product 3 a were investigated through absorption and emission spectroscopy. This analysis reveals that the new heterocyclic system has impressive fluorescence characteristics. Several advantages of the presented synthetic strategy can be found in its simplicity, readily available starting materials, high‐efficiency products, highly chemoselective route, metal‐free catalyst, and ability to purify products by washing them with EtOH (96 %), a technique called GAP (Group‐Assisted‐Purification) chemistry.