Types Of Nylon Research Articles

The Presence of Microplastics in the Gills and Gastrointestinal Tract of Mackerel (Rastrelliger Kanagurta Cuvier, 1816) from Jakarta Bay, Indonesia.

This study examined the characteristics of microplastics (MPs) in the gills and gastrointestinal tract (GIT) of mackerel (Rastrelliger kanagurta) captured in Jakarta Bay, Indonesia. All 120 fish contained MPs, with fragment > fiber > film being the most prevalent types, in that order. The total abundances of fragments, fibers, and films in the gills were as follows: 4.8 ± 1.6, 1.0 ± 0.7, and 0.3 ± 0.3, respectively. The total abundances of fragments, fibers, and films in the GIT were 5.9 ± 2.3, 1.3 ± 0.8, and 0.4 ± 0.4, respectively. Statistical analysis showed that the abundance of fragments, fibers and films in both the gills and GIT of mackerel did not differ significantly between sampling locations. In the gills and GIT, MPs with sizes less than 0.1mm and MPs that were black in color were most prevalent. Fourier transform infrared (FTIR) spectroscopy tests on MPs from the tissues of mackerel showed that there were 8 different types of MP polymers, namely, latex, nylon, polymethyl methacrylate (PMMA), cellulose acetate (CA), polyurethane (PU), polycarbonate (PC), polystyrene (PS), and polytetrafluoroethylene (PTFE). Latex and polycarbonate were detected in fish samples from Jakarta Bay.

Science and Business Developments

Science and Business Developments

Effect of different types of mulch on bulb yield of shallot

The possibility of using different types of mulch to improve the bulb yield of shallot (Allium cepa var aggregatum) is observed in this paper. The field experiment compared five different types of mulches, including silver, black, straw, screen nylon, and clear plastic mulches, with a non-mulch as a control treatment. Straw mulch and screen nylon mulch reduced shallot biomass but did not significantly affect bulb yield than the control treatment. At the same time, clear plastic mulch increased fresh bulb yield significantly by 30% from 10.26 t ha-1 to 13.29 t ha-1.

Microplastic Exposure by Razor Clam Recreational Harvester-Consumers Along a Sparsely Populated Coastline

Microplastics (MPs) are anthropogenic contaminants found in coastal and marine environments worldwide. Pacific razor clams (Siliqua patula), important for local indigenous culture, economy, gastronomy and food security along the United States West Coast, are subjected to myriad environmental stressors including predation, storm events, disease, toxins, and MPs. This study aimed to determine MP burdens in Olympic Coast, Washington Pacific razor clams and estimate annual MP exposure of recreational razor clam harvester-consumers from eating this species. We quantified suspected MP burdens in Pacific razor clams collected from eight tribal, recreational, and commercial harvest areas on the Olympic Coast in April 2018. We administered questionnaires to 107 recreational razor clam harvesters during the same timeframe to determine consumption patterns, preparation styles, knowledge and concerns about MPs, and demographics. Razor clams containing suspected MPs, primarily microfibers, were found at all eight sites. Average suspected MP burden differed by sample type (whole = 6.75 ± 0.60, gut-tissue = 7.88 ± 0.71, non-gut tissue = 4.96 ± 0.56, and cleaned samples = 3.44 ± 0.25). FTIR analyses of a random subset of microfiber-type MPs in whole and cleaned clams indicated material types of polyethylene terephthalate, cellulose acetate, cellophane, polyester, nylon, and cellulose. The average number of razor clams consumed per meal by Olympic Coast recreational razor clam harvesters was 4.27 ± 0.27, which varied by gender and ethnicity, but not income or age. Harvesters ate 0–209 meals/year of razor clams (16.2% harvested but did not eat razor clams), and most respondents (88.3%) fully cleaned razor clams before consuming them. Annual suspected MP exposure for razor clam harvester-consumers was 60–3,070 for cleaned and 120–6,020 for whole clams. Our findings suggest Olympic Coast recreational razor clam harvester-consumers are exposed to low levels of MPs from eating razor clams. MP exposure can be reduced by roughly 50% if clams are cleaned before consumption. Our work serves as an important reference in the growing portfolio of Pacific Northwest microplastic research, to inform future MP attenuation recommendations and development of human health standards for this type of pollution.

Study of the annealing influence on the mechanical performance of PA12 and PA12 fibre reinforced FFF printed specimens

PurposeThe purpose of this study is to evaluate and compare the mechanical performance of FFF parts when subjected to post processing thermal treatment. Therefore, a study of the annealing treatment influence on the mechanical properties was performed. For this, two different types of Nylon (PA12) were used, FX256 and CF15, being the second a short fibre reinforcement version of the first one.Design/methodology/approachIn this study, tensile and flexural properties of specimens produced via FFF were determined after being annealed at temperatures of 135°C, 150°C or 165°C during 3, 6, 12 or 18 h and compared with the non-treated conditions. Differential scanning calorimetry (DSC) was performed to determine the degree of crystallinity. To evaluate the annealing parameters’ influence on the mechanical properties, a full factorial design of experiments was developed, followed by an analysis of variance, as well as post hoc comparisons, to determine the most significative intervening factors and their effect on the results.FindingsThe results indicate that CF15 increased its tensile modulus, strength, flexural modulus and flexural strength around 11%, while FX256 presented similar values for tensile properties, doubling for flexural results. Flexural strain presented an improvement, indicating an increased interlayer behaviour. Concerning to the DSC analysis, an increase in the degree of crystallinity for all the annealed parts.Originality/valueOverall, the annealing treatment process cause a significant improvement in the mechanical performance of the material, with the exception of 165°C annealed specimens, in which a decrease of the mechanical properties was observed, resultant of material degradation.

Effect of the characteristics of nylon microparticles on Mode-I interlaminar fracture toughness of carbon-fibre/epoxy composites

Interleaving a laminated composite with thermoplastic particles is known as an effective method to improve the interlaminar fracture toughness. In this work, to provide useful insight into what particle characteristics are the most critical to the toughening effect, the interlaminar fracture behaviours of carbon fibre/epoxy composites interleaved with different types of nylon 6 and 12 particles were investigated in the same range of particle areal weights.The results showed the particle size affects the toughness only when the particle–matrix interfacial bonding is well established, which is related to the curing temperature relative to the melting temperature of the particle. High interfacial bonding strength allowed the particles to be plastically deformed while bridging the crack, and smaller particles were more effective due to the increased density of particle bridging. It was also found that both the particle size and shape affect thickening of the interlayer, which can cause a knockdown of in-plane laminate properties due to the reduced fibre volume fraction.

Experimental characterisation of fused filament fabrication printed parts under tension, shear, and combined shear–tension loads via Arcan test

The mechanical performance of fused filament fabrication printed parts is considered the weak point of the technology due to its high anisotropic structure and irregular behaviour. This research focuses on the application of the Arcan-based method to fused filament fabrication printed parts, to better understand their mechanical behaviour. In order to characterise and quantify the anisotropic behaviour, a butterfly type specimen was developed, taking into account the flaws presented by the process (e.g. need for support material for tilted surfaces, low resolution, etc.). Together with the Arcan type grip, a combination of vertical–transversal (VT), vertical-longitudinal (VL) and horizontal (H) printed samples were tested under three distinct loading conditions, 90° – tensile, 45° – combined loading and 0° – pure shear. For each set of samples, digital image correlation was used to analyse the deformation fields imposed by the distinct building orientations and loading conditions. Regarding the material, two different types of Nylon® (PA 12) were used, namely FX256 and CF15, being the second a short carbon fibre reinforced version of the first, allowing a comparison of the mechanical behaviour. The results show that the building orientation prevails, originating distinct fracture types and overall behaviour difference. It was shown that fibre presence does not create a stronger material, yet an increase in stiffness is observed for all building orientations, except VT, where both materials presented similar values, indicating that the fibre orientation is critical when taking into account the loading conditions. It was also observed that of all sample types, FX256 H specimens showed the closest to isotropic behaviour.

AFM investigation of the influence of ethanol absorption on the surface structure and elasticity of polyamides

We study the variations of surface structure and elasticity of different types of Nylon during absorption of ethanol using AFM surface topography and AFM micro-mechanics. We observe that ethanol absorption induces significant changes in the surface structure, in particular an increase of roughness as well as the presence of local damage. All investigated Nylons soften by a factor 1.5–2.5 as a consequence of ethanol absorption. The Young modulus of the samples as a function of immersion time shows a complex, non-monotonic behavior with a minimum at intermediate immersion times. This behavior results from an interplay between the reduction of the glass transition temperature $$T_g$$ , typically observed in bulk, and surface-specific effects such as the onset of surface crystallisation and degradation.

Influence of the geometry fidelity of resonant sound-absorbing liner samples on their acoustic characteristics

Samples of sound-absorbing Helmholtz resonator-type liners of circular shape were manufactured from two types of ABS plastic and nylon on the basis of 3D modeling and 3D printing technology. Check samples were made of metal on a numerically controlled machine. Deviations of geometric parameters of the manufactured samples from the design values were determined by visual and dimensional inspection using high-precision equipment. The minimum deviations were obtained for check samples made of metal. The acoustic characteristics of the samples were experimentally determined using an interferometer with normal wave incidence at high sound pressure levels. Numerical simulation of the acoustic processes in the interferometer for the given samples was carried out on the basis of solving full Navier-Stokes equations with account for compressibility. The obtained values of the resonant frequency, impedance and sound absorption coefficient were compared with the experimental ones. It was noted that the impedance values are most sensitive to the deviations of the geometric parameters of the samples from the design values, while the deviations in the sound absorption coefficient and resonance frequency are not so sensitive to them.

Impact of substrate material on algal biofilm biomass growth.

Algae are being grown for wastewater purification and biofuels production. Their growth on a substrate facilitates these uses by allowing facile separation of algae from the water. Here, we compare different materials to determine which would best serve this purpose. A mixed culture of Anabaena and Chlorella was grown on various synthetic and natural fiber fabric substrates in a trough system with recirculating simulated wastewater. Filter materials studied as substrates for algal growth were muslin, olefin, pellon (acrylic), two types of polyester, and two types of nylon. Biomass accumulation on the various filter substrates was recorded at 7, 14, and 28days. Filters were weighed before and after the growth periods and changes in dry biomass were recorded. Biomass accumulation was significantly affected by the fabric type. Olefin fostered the greatest increase in biomass while nylon and polyester also supported competitive increases in biomass. Pellon showed the smallest biomass increase and muslin decreased in mass due to material disintegration. Other concerns such as abrasion resistance and UV susceptibility are discussed.

Mechanical properties and microstructure of recycled mortar reinforced with hybrid fiber

This study investigated the hybrid effects of two types of microfiber, namely, polypropylene and nylon, on the mechanical properties of high-strength mortar, which produced fine recycled aggregate (FRA). The amount of microfibers was maintained at a volumetric fraction of 0.6%. The microstructure and mechanical strength properties (compressive strength and flexural strength) of recycled mortar reinforced with hybrid-size microfibers were evaluated at various curing ages. Experimental results show that the inclusion of hybrid fibers significantly influenced the mechanical performance of the recycled mortar. The hybridization fiber at volume fraction 0.3% polypropylene + 0.3% nylon yielded the most promising mechanical performance. Enhancements of 8% on compressive and 11% flexural strength were achieved at 28 days. Scanning electron microscopy observations revealed that reinforcement at the microscale prohibited the initiation and growth of cracks at the micro level. High loads were required to form macrocracks within composites, thereby improving the mechanical strength of the mortar matrix.

Efficacy of Silver Dihydrogen Citrate and Steam Vapor against a Human Norovirus Surrogate, Feline Calicivirus, in Suspension, on Glass, and on Carpet.

Carpets and other soft surfaces have been associated with prolonged and reoccurring human norovirus (HuNoV) outbreaks. Environmental hygiene programs are important to prevent and control HuNoV outbreaks. Despite our knowledge of HuNoV transmission via soft surfaces, no commercially available disinfectants have been evaluated on carpets. Our aim was to adapt a current standardized method for virucidal testing by assessing two disinfection technologies, silver dihydrogen citrate (SDC) and steam vapor, against one HuNoV surrogate, feline calicivirus (FCV), on wool and nylon carpets. First, we evaluated the effect of both technologies on the appearance of carpet. Next, we evaluated the efficacy of SDC in suspension and the efficacy of SDC and steam vapor against FCV on a glass surface, each with and without serum. Lastly, we tested both technologies on two types of carpet, wool and nylon. Both carpets exhibited no obvious color changes; however, SDC treatments left a residue while steam vapor left minor abrasions to fibers. SDC in suspension and on glass reduced FCV by 4.65 log10 and >4.66 log10 PFU, respectively, but demonstrated reduced efficacy in the presence of serum. However, SDC was only efficacious against FCV on nylon (3.62-log10 PFU reduction) and not wool (1.82-log10 PFU reduction). Steam vapor reduced FCV by >4.93 log10 PFU on glass in 10 s and >3.68 log10 PFU on wool and nylon carpet carriers in 90 s. There was a limited reduction of FCV RNA under both treatments compared to that of infectivity assays, but RNA reductions were higher in samples that contained serum.IMPORTANCE Human noroviruses (HuNoV) account for ca. 20% of all diarrheal cases worldwide. Disease symptoms may include diarrhea and vomit, with both known to contribute to transmission. The prevention and control of HuNoV are difficult because they are environmentally resilient and resistant to many disinfectants. Several field studies have linked both hard and soft surfaces to HuNoV outbreaks. However, many disinfectants efficacious against HuNoV surrogates are recommended for hard surfaces, but no commercially available products have demonstrated efficacy against these surrogates on soft surfaces. Our research objectives were to evaluate liquid and steam-based technologies in suspension and on hard surface carriers in addition to adapting and testing a protocol for assessing the virucidal effects of disinfection technologies on carpet carriers. These results will inform both the government and industry regarding a standard method for evaluating the virucidal effects of disinfectants on carpet while demonstrating their efficacy relative to suspension and hard-surface tests.

Günther Wilke (1925-2016).

Günther Wilke (1925-2016).

Evaluation of Diffuse Reflection Infrared Spectrometry for End-of-Shift Measurement of α-quartz in Coal Dust Samples

The inhalation of toxic substances is a major threat to the health of miners, and dust containing respirable crystalline silica (α-quartz) is of particular concern, due to the recent rise in cases of coal workers’ pneumoconiosis and silicosis in some U.S. mining regions. Currently, there is no field-portable instrument that can measure airborne α-quartz and give miners timely feedback on their exposure. The U.S. National Institute for Occupational Safety and Health (NIOSH) is therefore conducting studies to investigate technologies capable of end-of-shift or real-time measurement of airborne quartz. The present study focuses on the potential application of Fourier transform infrared (FT-IR) spectrometry conducted in the diffuse reflection (DR) mode as a technique for measuring α-quartz in respirable mine dust. A DR accessory was used to analyze lab-generated respirable samples of Min-U-Sil 5 (which contains more than 90% α-quartz) and coal dust, at mass loadings in the ranges of 100–600 μg and 600–5300 μg, respectively. The dust samples were deposited onto three different types of filters, borosilicate fiberglass, nylon, and polyvinyl chloride (PVC). The reflectance, R, was calculated by the ratio of a blank filter and a filter with deposited mine dust. Results suggest that for coal and pure quartz dusts deposited on 37 mm PVC filters, measurements of -log R correlate linearly with known amounts of quartz on filters, with R2 values of approximately 0.99 and 0.94, respectively, for samples loaded up to ∼4000 μg. Additional tests were conducted to measure quartz in coal dusts deposited onto the borosilicate fiberglass and nylon filter media used in the NIOSH-developed Personal Dust Monitor (PDM). The nylon filter was shown to be amenable to DR analysis, but quantification of quartz is more accurate when the filter is “free,” as opposed to being mounted in the PDM filter holder. The borosilicate fiberglass filters were shown to produce excessive interference, making quartz quantification impossible. It was concluded that, while the DR/FT-IR method is potentially useful for on-filter measurement of quartz in dust samples, the use of PVC filters produced the most accurate results.

Comparison of fiber reinforcement placed at different locations of pontic in interim fixed partial denture to prevent fracture: An in vitro study.

Background:The interim restoration is an important phase in fixed prosthodontic therapy. It should provide sufficient durability to withstand the forces of mastication. A fractured interim restoration is damaging to the prosthodontic care and may lead to an unscheduled appointment for repair. Several attempts have been made to reinforce interim fixed partial dentures (FPDs). These have included the use of metal wire, a lingual cast metal reinforcement, a processed acrylic resin interim restoration, and different types of fibers, e.g., carbon, polyethylene, nylon and glass. These fibers can be placed in the occlusal, middle or cervical thirds in the FPD. There is no scientific data to evaluate the effect of fiber placement methods on the fracture resistance of clinical interim FPDs.Purpose of the Study:Hence this study was designed to evaluate fracture load values of interim FPDs with different locations of fiber reinforcement.Materials and Methods:30 interim FPD samples with polymethyl methacrylate (PMMA) reinforced with fibers at three different locations mainly occlusal, cervical and middle (10 samples each) were fabricated using a metal FPD on a master die. They were tested for fracture resistance in universal testing machine.Results:The fracture resistance was recorded and is tabulated and analyzed statistically. The results showed that the placement of the reinforcement in the occlusal third of the pontic resulted in higher fracture resistance which was significantly higher (P < 0.05) than all other locations.Conclusion:The occlusal third of the pontic region from mesial to the distal end of the connector is the best site of placement of the fiber for reinforcing the PMMA interim restorative resin.

Study on friction and wear behavior of SAE 1045 steel, reinforced nylon 6.6 and NBR rubber used in clutch disks

The friction and wear properties of AISI 1045 steel, nylon 6.6 composites with different types and percentages of reinforcement and a nitrile rubber, Alpha 66, were submitted to sliding wear tests. The five types of nylon 6.6 composites tested generated matching, low values for the coefficient of friction. This may be due to the greater influence of the nylon 6.6 matrix on the coefficient of friction. However, the wear in nylon composites showed wide variation, determined by the type of reinforcement added to the composite. The other two materials tested, nitrile rubber and 1045 steel, showed behavior different from that of the composites. The NBR (signifying a norm established by the Brazilian Association of Technical Norms) rubber showed a superior coefficient of friction and greater wear. On the other hand, the steel showed a high coefficient of friction and low wear, suggesting that the coefficient of friction has no direct connection to the wear resistance of the materials studied here.

Research on Compatibility between Ethyl Fluoride with/without Lubricant Oils, and Plastics and Elastomers

According to the method of alternative materials compatibility study accepted by an international institute, an experimental device to study the compatibility between refrigerant and materials was designed and constructed. The compatibility between ethyl fluoride (HFC-161, C2H5F, CAS No. 353-36-6) with/without the presence of lubricant oils (polyolester (POE) and polyalkylene glycol (PAG)) and five types of plastics (acrylonitrile butadiene styrene (ABS) plastic, polytetrafluoroethylene (PTFE), polypropylene (PP), polyvinyl chloride (PVC), and nylon) and three types of elastomers (natural rubber, silicone rubber, and neoprene) was evaluated in the high-pressure glass tank at 60 °C, respectively. The experimental results indicated that PTFE, PP, PVC, and nylon, as well as silicone rubber and natural rubber, could be used in the refrigeration systems of HFC-161, while ABS and neoprene were not recommended. The absorption of POE oil by the three types of elastomers was stronger than that of PAG oil. Furthermore, results showed that the presence of the lubricant oils could reduce the corrosive effect of HFC-161 to ABS to some extent.

ATY 노즐 직경에 따른 방호의류용 아라미드와 아라미드/나일론 하이브리드 ATY사의 물성변화

This paper investigates the physical properties of aramid and aramid/nylon hybrid air jet textured filaments for protective garments relative to ATY nozzle diameters. Three types of para-aramids(840d, 1,000d, 1,500d) and nylon(420d) filaments were prepared; in addition, 840d aramid/420d nylon and three kinds of aramid filaments were texturized with a variation of air jet nozzle diameters(0.6, 0.75, 1 and 1.2 mm) on the AIKI air jet texturing machine. The measured physical properties of 16 specimens are as follows. The linear densities of aramid and aramid/nylon hybrid ATY increased with a larger nozzle diameter. The tenacity and initial modulus of aramid and hybrid ATY linearly decreased with a larger nozzle diameter; in addition, the breaking strain increased with the nozzle diameter. The dry and wet thermal shrinkage of hybrid ATY increased with a larger nozzle diameter from 0.6 mm to 1 mm and then decreased at a nozzle diameter of 1.2 mm (which seems to be a critical diameter). The wet and dry thermal shrinkage of aramid/nylon hybrid ATY are influenced by the nylon part of the hybrid yarns because the wet and dry thermal shrinkages of aramid ATY are less than 0.2%. The instabilities of aramid and aramid/nylon hybrid ATY were not influenced by the air jet nozzle diameter; however, they increased with the linear density of ATY.

Extrusion‐based differences in two types of nylon 6 capillary‐channeled polymer (C‐CP) fiber stationary phases as applied to the separation of proteins via ion exchange chromatography

AbstractNylon 6 capillary‐channeled polymer (C‐CP) fibers used as the stationary phase in high‐performance liquid chromatography protein separations have been investigated. A difference in chromatographic behavior between two (presumably identical) nylon 6 C‐CP fibers, designated simply as nylon 6A and nylon 6B, reveals unknown differences in their chemical and physical nature as proteins are less retained on the latter. The possible differences are evaluated through several test methods, including Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), mechanical testing, MALDI‐TOF mass spectrometry, an organic reaction with ninhydrin, and dilute solution viscometry. Nylon 6B is shown to be a larger perimeter, stronger fiber, yet in a 200 mm, 0.8 mm i.d. column having an interstitial fraction of ∼0.6, it has an available surface area of ∼189 cm2, while nylon 6A is almost double that at ∼374 cm2. It is revealed that when in amorphous form, the base polymers have very comparable FTIR and DSC characteristics. When in their solid, extruded fiber form there are significant differences found in crystallinity, tensile strength, molecular weight distribution, and end group density. Nylon 6A is a lower molecular weight fiber, which results in ∼1.3× more amine end groups than nylon 6B. It is the end group density that ultimately determines the separation qualities. These results imply that both a difference in base nylon 6 molecular weight and also the fiber extrusion process have a significant influence on the performance of nylon 6 C‐CP fiber separation of proteins via ion exchange chromatography. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

An Experimental Study on Fluidization of Binary Mixture in Particulate Flows

In this article, we studied experimentally the fluidization of binary mixture in particulate flows. A laboratory fluidized bed is built with water being used as carrying fluid. Three types of solid particles, nylon, glass, and aluminum of the same size and different densities, were used in the experiments. We investigated the wall effect to the fluidization of a single particle, the fluidization of binary mixture of nylon and aluminum with a density ratio of 0.42, and the fluidization of binary mixture of glass and aluminum with a density ratio of 0.91. Our results show that the presence of narrow walls reduces the minimum fluidization velocity for a single particle up to 40%. We also found that in the case of binary mixture of glass and aluminum particles, uniform mixing can be easily achieved with no segregation observed; on the other hand, in the case of binary mixture of nylon and aluminum particles, significant segregation and separation are observed. Based on experimental results, correlation relationships between fluidization velocity and bed height are also reported.