Transmission electron microscopy (TEM) revealed a commensurate modulated structure in a Na-rich alkali feldspar (Ab660r29Ans) from a basalt from Anhui Province, China. High-resolution TEM images with wavelike (001) lattice fringes directly reveal one-dimensional modulation waves in the crystal. The average modulation period along the b axis is l4dolO (;;;; 180 A), although both larger and smaller spacings have been observed. The modulated structure can be described as periodic stacking of (010) layer domains following the albite twin law. The relationship between the extended cell (supercell) of the modulated structure and the normal alkali feldspar unit cell (subcell) is as follows: a,up ;;;; a,ub, b,up ;;;; l4boub,c,uP ;;;; C,ub,{3,up ;;;; {3,ub (subscripts sup and sub indicate the supercell and subcell, respectively). A possible space group for the modulated structure is Pm. In situ heating and cooling experiments suggestthat the phase transition in this feldspar thin foil might be a weakly first-order and displacive transformation. The transition temperature is close to 500 DCfor the crystal examined. The modulated structure formed during the phase transition of the feldspar from C2/m symmetry to Cl at a rapid cooling rate. A heuristic nonlinear dynamics model for the arrangement of triclinic domains in the feldspar at the phase transition from monoclinic to triclinic symmetry was developed on the basis of a Landau potential, a damping term accounting for the structural differences among neighboring units, and a periodic force in the crystal along the b axis. Numerical solutions indicate that periodic modulation arises during the monoclinic to triclinic transition only under special conditions relatively far from equilibrium, and a nonperiodic arrangement of triclinic domains along the b axis is the more general case. Therefore, according to this model, the modulated structure is a metastable and intermediate structure between monoclinic (C2/m) and triclinic (Cl) phases. This type of modulated structure in Na-rich alkali feldspars may indicate high-temperature growth as a monoclinic crystal, followed by very rapid cooling into the triclinic stability field.