The development of the biomass economy contributes to economic growth and social development. The study of biomass energy economy from the perspective of industrial structure type has the significance of promoting the optimization and upgrading of industrial structure, promoting the development of green industry and other aspects. It helps to promote the sustainable development of the economy and society. And industrial structure is a major component of the socio-economic system. Therefore, it is necessary to study the impact of material energy supply and demand from the perspective of regional industrial structure type. The objective of this study is to explore the relationship between the type of industrial structure and the development of biomass energy from the perspective of the economic direction, so as to fill the gap in this research perspective. Based on the three major industries generally regarded to constitute GDP - agriculture, industry, and service - the regression results of STATA software were used to calculate biomass potential according to crop distribution status. Using the ArcGIS analysis tool, the biomass break-even model related to resource supply-demand has been used to obtain the break-even status of the research area under six industrial structures in the past 20 years. According to research results, the break-even degree of biomass energy supply is between 0.109 and 1.236 when the industrial structure types of counties and cities are service-agriculture-industry and industry-agriculture-service. This is suitable for biomass energy development. When the industrial structure type of counties and cities is service-industry-agriculture, the break-even degree of biomass energy supply is between -0.428 and 0.277, which is not suitable for biomass energy development.