From 2008 to 2021, this study analyzed the spatial correlation characteristics between provincial transportation carbon emission intensity and explored ways to reduce transportation carbon emissions. This study used the modified gravity model, social network analysis (SNA) method, and temporal exponential random graph model (TERGM) to analyze the spatial correlation network evolution characteristics and driving mechanism of China’s transportation carbon emission intensity. This study found that China’s transportation carbon emission intensity and spatial correlation network have unbalanced characteristics. The spatial correlation network of transportation carbon emission intensity revealed that Shanghai, Beijing, Tianjin, Guangdong, Fujian, and other provinces were at the center of the network, with significant intermediary effects. The spatial correlation of transportation carbon emission intensity was divided into four functional plates: “two-way spillover”, “net benefit”, “broker”, and “net spillover”. The “net benefit” plate was mainly located in developed regions, and the “net spillover” plate was primarily located in underdeveloped regions. Endogenous structural and exogenous mechanism variables were the main factors affecting the evolution of the spatial correlation network of provincial transportation carbon emission intensity.