Two-level Quantum System Research Articles

Fluorescence by incoherently pumped polar quantum dot placed in a low-frequency monochromatic field

Abstract We studied spectral properties of high-frequency fluorescent radiation from a two-level quantum system with broken inversion spatial symmetry, which can be implemented as a model of a one-electron two-level asymmetric polar semiconductor quantum dot whose electric dipole moment operator has permanent unequal diagonal matrix elements. The case of the excitation of this system by incoherent pumping of some sort supplemented with an additional driving monochromatic field, which frequency is much lower than the optical transition frequency of the quantum dot, was considered. An analytical expression for the fluorescence spectrum as a function of the amplitude and frequency of the monochromatic driving field, as well as of the pumping intensity, was derived. We also discussed feasible practical applications of the effects under study in the field of quantum optics and optoelectronics for the generation of high-frequency radiation, possessing stationary equidistant spectrum, and for the control of the radiative properties of such nanodevices as spasers (dipole nanolasers).

Exact quantum dynamics for two-level systems with time-dependent driving

Abstract It is well known that the time-dependent Schrrödinger equation can only be solved exactly in very rare cases, even for two-level quantum systems. Thus, finding the exact quantum dynamics under a time-dependent Hamiltonian is not only fundamentally important in quantum physics but also facilitates active quantum manipulations for quantum information processing. In this work, we present a method for generating nearly infinite analytically assisted solutions to the Schrrödinger equation for a qubit under time-dependent driving. These analytically assisted solutions feature free parameters with only boundary restrictions, making them applicable in a variety of precise quantum manipulations. Due to the general form of the time-dependent Hamiltonian in our approach, it can be readily implemented in various experimental setups involving qubits. Consequently, our scheme offers new solutions to the Schrrödinger equation, providing an alternative analytical framework for precise control over qubits.

Random Lasing under Dissipative Tunneling Conditions in a Network Quantum Material

A new mechanism of the generation of a random laser based on a random photonic network with dissipative tunneling of photons between microcavities that are placed at the nodes of such network and contain identical two-level quantum systems has been revealed. It has been shown that an additional source of photon losses in tunneling promotes the separation of individual modes of the random laser and the achievement of the lasing threshold even at a vanishingly small population inversion. In this case, the enhancement of laser modes has an interference nature and is due to the energy redistribution between the nodes of the photonic network that correspond to different signs of the frequency detuning of stationary modes of the random laser from the transition frequency of two-level systems. It has been shown that the traditional lasing mechanism, which demonstrates features of the spectrum of single microcavities, i.e., is almost independent of the topological properties of the network and the tunneling parameter, is present in the region of zero detuning.

Hamiltonian Identification via Quantum Ensemble Classification.

Identifying the Hamiltonian of an unknown quantum system is a critical task in the area of quantum information. In this article, we propose a systematic Hamiltonian identification approach via quantum ensemble multiclass classification (HI-QEMC). This approach is implemented by a three-step iterative refining process, i.e., parameter interval guess, verification, and judgment. In the parameter interval guess step, the parameter interval is divided into several sub-intervals and the true Hamiltonian parameter is guessed in one of them. In the parameter interval verification step, cross verification is applied to verify the accuracy of the guess. In the parameter interval judgment step, an adaptive interval judgment (AIJ) algorithm is designed to determine the sub-interval containing the true Hamiltonian parameter. Numerical results on two typical quantum systems, i.e., two-level quantum systems and three-level quantum systems, demonstrate the effectiveness and superior performance of the proposed approach for quantum Hamiltonian identification.

Reverse engineering control of the relative phase and populations of two-level quantum systems

Reverse engineering control of the relative phase and populations of two-level quantum systems

Simulating Chemistry on Bosonic Quantum Devices.

Bosonic quantum devices offer a novel approach to realize quantum computations, where the quantum two-level system (qubit) is replaced with the quantum (an)harmonic oscillator (qumode) as the fundamental building block of the quantum simulator. The simulation of chemical structure and dynamics can then be achieved by representing or mapping the system Hamiltonians in terms of bosonic operators. In this Perspective, we review recent progress and future potential of using bosonic quantum devices for addressing a wide range of challenging chemical problems, including the calculation of molecular vibronic spectra, the simulation of gas-phase and solution-phase adiabatic and nonadiabatic chemical dynamics, the efficient solution of molecular graph theory problems, and the calculations of electronic structure.

Quantum decoherence dynamics in stochastically fluctuating environments.

We theoretically study the decoherence of a two-level quantum system coupled to noisy environments exhibiting linear and quadratic fluctuations within the framework of a stochastic Liouville equation. It is shown that the intrinsic energy levels of the quantum system renormalize under either the linear or quadratic influence of the environmental noise. In the case of quadratic dependence, the renormalization of the energy levels of the system emerges even if the environmental noise exhibits stationary statistical properties. This is in contrast to the case under linear influence, where the intrinsic energy levels of the system renormalize only if the environmental noise displays nonstationary statistics. We derive the analytical expressions of the decoherence function in the cases where the fluctuation of the frequency difference depends linearly and quadratically on the nonstationary Ornstein-Uhlenbeck noise (OUN) and random telegraph noise (RTN) processes, respectively. In the case of the linear dependence of the OUN, the environmental nonstationary statistical property can enhance the dynamical decoherence. However, the nonstationary statistics of the environmental noise can suppress the quantum decoherence in this case under the quadratic influence of the OUN. In the presence of the RTN, the quadratic influence of the environmental noise does not give rise to decoherence but only causes a determinate frequency renormalization in dynamical evolution. The environmental nonstationary statistical property can suppress the quantum decoherence of the case under the linear influence of the RTN.

Local coherence by thermalized intra-system coupling

Quantum superposition of energy eigenstates can appear autonomously in a single quantum two-level system coupled to a low-temperature thermal bath, if such coupling has a proper composite nature. We propose here a principally different and more feasible approach employing engineered interactions between two-level systems being thermalized into a global Gibbs state by weakly coupled thermal bath at temperature T. Therefore, in such case quantum coherence appears by a different mechanism, whereas the system-bath coupling does not have to be engineered. We demonstrate such autonomous coherence generation reaching maximum values of coherence. Moreover, it can be alternatively built up by using weaker but collective interaction with several two-level systems. This approach surpasses the coherence generated by the engineered system-bath coupling for comparable interaction strengths and directly reduces phase estimation error in quantum sensing. This represents a necessary step towards the autonomous quantum sensing.

Super dense coding out of thermal equilibrium

We have examined the potentiality of superdense coding for a quantum system placed out of thermal equilibrium. To this aim, the dynamics of two two-level quantum systems are analyzed and explicit expressions for transition rates are evaluated. The dependence of superdense coding capacity on initial states is observed and examined for different ratios of anti-symmetric to symmetric transition rates. The effect of sub-radiant and super-radiant terms is interpreted. The validity of dense coding is also analyzed for different probability amplitudes and it is perceived that maximally entangled states show the highest degree of coding capacity. Moreover, the optimal time of coding capacity is greatest for initially entangled state. This strategy can be relevant to analyze further applications out of thermal equilibrium.

Heat Bath in a Quantum Circuit.

We discuss the concept and realization of a heat bath in solid state quantum systems. We demonstrate that, unlike a true resistor, a finite one-dimensional Josephson junction array or analogously a transmission line with non-vanishing frequency spacing, commonly considered as a reservoir of a quantum circuit, does not strictly qualify as a Caldeira-Leggett type dissipative environment. We then consider a set of quantum two-level systems as a bath, which can be realized as a collection of qubits. We show that only a dense and wide distribution of energies of the two-level systems can secure long Poincare recurrence times characteristic of a proper heat bath. An alternative for this bath is a collection of harmonic oscillators, for instance, in the form of superconducting resonators.

Qubit dephasing by spectrally diffusing quantum two-level systems

Qubit dephasing by spectrally diffusing quantum two-level systems

Parameter estimation from quantum-jump data using neural networks

We present an inference method utilizing artificial neural networks for parameter estimation of a quantum probe monitored through a single continuous measurement. Unlike existing approaches focusing on the diffusive signals generated by continuous weak measurements, our method harnesses quantum correlations in discrete photon-counting data characterized by quantum jumps. We benchmark the precision of this method against Bayesian inference, which is optimal in the sense of information retrieval. By using numerical experiments on a two-level quantum system, we demonstrate that our approach can achieve a similar optimal performance as Bayesian inference, while drastically reducing computational costs. Additionally, the method exhibits robustness against the presence of imperfections in both measurement and training data. This approach offers a promising and computationally efficient tool for quantum parameter estimation with photon-counting data, relevant for applications such as quantum sensing or quantum imaging, as well as robust calibration tasks in laboratory-based settings.

Towards Establishing a Connection Between Two-Level Quantum Systems and Physical Spaces

Towards Establishing a Connection Between Two-Level Quantum Systems and Physical Spaces

Engineering Clock Transitions in Molecular Lanthanide Complexes.

Molecular lanthanide (Ln) complexes are promising candidates for the development of next-generation quantum technologies. High-symmetry structures incorporating integer spin Ln ions can give rise to well-isolated crystal field quasi-doublet ground states, i.e., quantum two-level systems that may serve as the basis for magnetic qubits. Recent work has shown that symmetry lowering of the coordination environment around the Ln ion can produce an avoided crossing or clock transition within the ground doublet, leading to significantly enhanced coherence. Here, we employ single-crystal high-frequency electron paramagnetic resonance spectroscopy and high-level ab initio calculations to carry out a detailed investigation of the nine-coordinate complexes, [HoIIIL1L2], where L1 = 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraaza-cyclododecane and L2 = F- (1) or [MeCN]0 (2). The pseudo-4-fold symmetry imposed by the neutral organic ligand scaffold (L1) and the apical anionic fluoride ion generates a strong axial anisotropy with an mJ = ±8 ground-state quasi-doublet in 1, where mJ denotes the projection of the J = 8 spin-orbital moment onto the ∼C4 axis. Meanwhile, off-diagonal crystal field interactions give rise to a giant 116.4 ± 1.0 GHz clock transition within this doublet. We then demonstrate targeted crystal field engineering of the clock transition by replacing F- with neutral MeCN (2), resulting in an increase in the clock transition frequency by a factor of 2.2. The experimental results are in broad agreement with quantum chemical calculations. This tunability is highly desirable because decoherence caused by second-order sensitivity to magnetic noise scales inversely with the clock transition frequency.

Landau–Zener–Stückelberg–Majorana-like dynamics induced by tunneling of spin qubit states in a multiband two-state magnetic quantum wire

We investigate the transfer between spin quantum bit (qubit) states and study the Landau–Zener–Stückelberg–Majorana (LZSM)-like dynamics of tunneling spin qubits in a multiband two-state magnetic quantum wire. Indeed, within the framework of an optical parabolic potential in a three-dimensional (3D) heterostructure quantum wire and under the influence of an external time-varying magnetic field, a model for a multiband two-state magnetic quantum wire is developed. Here, the external magnetic field is used to coherently manipulate and control spin qubit states. By driving the system through an avoided crossing, we consider the associated effective quantum two-level system (TLS) related to the spin qubit states in each band, driving by an external coherent magnetic field in which the related Hamiltonian is Hermitian, and which generally paves a way to LZSM interferometry. Thus, we establish the analytical expressions of the energy eigenvalues in each band and derive the analytical solution of the dynamical evolution of the tunneling probabilities of the associated TLS. Accordingly, nonadiabatic and adiabatic tunneling probabilities (survival and transition) are calculated for each band of the multiband TLS. In this respect, the nonadiabatic and adiabatic dynamical evolutions of the tunneling probabilities of spin qubit populations in the first four bands, with band quantum numbers n = 0, 1, 2 and 3 are analyzed. As a result, depending on the amplitude strength of the driven magnetic field and the magnitude of the driving frequency, we report two striking nonadiabatic and adiabatic scenarios in each band for both the diabatic and adiabatic states. In this context, driving the two states of each band of the multiband TLS related to the spin qubit states through an avoided level crossing can result in nontrivial and incoherent dynamics at certain phases, resulting to apparent inaccurate probabilities, especially in the case of strong driven magnetic field and high driving frequency.

Controlling the charge-transfer dynamics of two-level systems around avoided crossings.

Two-level quantum systems are fundamental physical models that continue to attract growing interest due to their crucial role as a building block of quantum technologies. The exact analytical solution of the dynamics of these systems is central to control theory and its applications, such as that to quantum computing. In this study, we reconsider the two-state charge transfer problem by extending and using a methodology developed to study (pseudo)spin systems in quantum electrodynamics contexts. This approach allows us to build a time evolution operator for the charge transfer system and to show new opportunities for the coherent control of the system dynamics, with a particular emphasis on the critical dynamic region around the transition state coordinate, where the avoided crossing of the energy levels occurs. We identify and propose possible experimental implementations of a class of rotations of the charge donor (or acceptor) that endow the electronic coupling matrix element with a time-dependent phase that can be employed to realize controllable coherent dynamics of the system across the avoided level crossing. The analogy of these rotations to reference frame rotations in generalized semiclassical Rabi models is discussed. We also show that the physical rotations in the charge-transfer systems can be performed so as to implement quantum gates relevant to quantum computing. From an exquisitely physical-mathematical viewpoint, our approach brings to light situations in which the time-dependent state of the system can be obtained without resorting to the special functions appearing in the Landau-Zener approach.

Engineering Artificial Atomic Systems of Giant Electric Dipole Moment.

The electric dipole moment (EDM) plays a crucial role in determining the interaction strength of an atom with electric fields, making it paramount to quantum technologies based on coherent atomic control. We propose a scheme for engineering the potential in a Paul trap to realize a two-level quantum system with a giant EDM formed by the motional states of a trapped electron. We show that, under realistic experimental conditions, our system exhibits enhanced EDMs compared to those attainable with Rydberg atoms, serving as a complementary counterpart in the megahertz (MHz) resonance-frequency range. Furthermore, we show that such artificial atomic dipoles can be efficiently initialized, read out, and coherently controlled, thereby providing a potential platform for quantum technologies such as ultrahigh-sensitivity electric-field sensing.

Simulating two-level quantum systems via classical orbit motion: Adiabatic cyclic evolution and Berry phase

Simulating two-level quantum systems via classical orbit motion: Adiabatic cyclic evolution and Berry phase

Signatures of Dynamically Dressed States.

The interaction of a resonant light field with a quantum two-level system is of key interest both for fundamental quantum optics and quantum technological applications employing resonant excitation. While emission under resonant continuous-wave excitation has been well studied, the more complex emission spectrum of dynamically dressed states-a quantum two-level system driven by resonant pulsed excitation-has so far been investigated in detail only theoretically. Here, we present the first experimental observation of the complete resonance fluorescence emission spectrum of a single quantum two-level system, in the form of an excitonic transition in a semiconductor quantum dot, driven by finite Gaussian pulses. We observe multiple emerging sidebands as predicted by theory, with an increase of their number and spectral detuning with excitation pulse intensity and a dependence of their spectral shape and intensity on the pulse length. Detuning-dependent measurements provide additional insights into the emission features. The experimental results are in excellent agreement with theoretical calculations of the emission spectra, corroborating our findings.

Bandwidth of quantized surface plasmons: competition between radiative and nonradiative damping effects.

We investigate the damping effects of coherent electron oscillations on the bandwidth of a quantized nanoparticle plasmon resonance. The nanoparticle (NP) is treated as a two-level quantum system, and the total relaxation time involves both the population relaxation time associated with radiative processes and the collisional relaxation time associated with nonradiative processes that result in dephasing/decoherence of electron oscillations. We describe the optical response of NPs to an external electromagnetic field by the optical Bloch equations employing the density matrix formalism to capture the quantum description nature of dipolar plasmon resonance and suggest a generalized criterion for the validity of dipole approximation. Then we explore the competition between the radiative and nonradiative damping in determining the plasmon bandwidth of two typical NP models; metallic nanospheres and dielectric core-metal shell NPs (nanoshells). We show that the frequency of plasmon resonance, in addition to the NP size, plays an important role in the competition between the damping mechanisms. Consequently, the damping processes are significantly influenced by the factors that determine the resonance frequency, such as the core size, the dielectric constant of the medium, and the shell thickness (for nanoshells). For both models of NPs, we identify the optimum parameters that achieve a narrower plasmon bandwidth (minimal damping), which is a prerequisite for advanced sensing and medical applications. We demonstrate excellent agreement of the simulated spectral features of the plasmon resonance with previously reported experimental results for a single NP where the inhomogeneous broadening of the plasmon line is excluded. For NP ensembles where inhomogeneous broadenings and interface chemical effects are significant, our theoretical approach successfully predicts the overall trend of size-dependent damping rates.