The development of lean-burn concepts for internal combustion engines, utilizing a homogeneous air/fuel charge, aims to improve multiple aspects simultaneously, including thermal efficiency, fuel consumption, nitric oxide, and carbon monoxide emissions. However, the adoption of this technology may result in a notable increase in the emission of unburned hydrocarbons (uHC) compared to stoichiometric engines. The sources of uHC are diverse and their relative significance depends on fuel characteristics, engine operating conditions, and geometric features of the combustion chamber. This concern becomes more pronounced when considering engines fueled with natural gas, as methane has a high global warming potential compared to other pollutant emissions. This research proposes an enhancement to an existing simulation model that describes the primary mechanisms involved in uHC formation, which are filling/emptying of the piston top-land crevice volume and the flame wall quenching, with subsequent uHC post-oxidation. The improvements include the calculation of flame penetration into crevice volumes, the description of uHC production from non-piston crevices, and the introduction of a novel scavenging model. The uHC model is integrated into commercial software (GT-Power) as a “user routine”. Validation of the model is conducted with reference to three large bore engines (W31DF, W31SG, and W46SG) with bore sizes of 31 cm and 46 cm, fueled with natural gas, and operated under lean mixtures (λ > 2), employing different ignition methods (dual fuel mode or pre-chamber device). The uHC model is validated against engine-out measurements, exhibiting an average error of 10.0 % for W31DF, 19.4 % for W31SG, and 14.0 % for W46SG engines, respectively. The reliability of the uHC model is demonstrated by the absence of case-specific adjustments to its tuning constants, even when there are significant variations in engine load and geometric design of the crevice volumes.
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