Wavelength Tuning Research Articles

Deep ultraviolet AlGaN-multiple quantum wells with photoluminescence enhanced by topological corner state

The AlGaN-based deep ultraviolet light-emitting diode (DUV LED) has advantages of environmentally friendly materials, tunable emission wavelength, and easy miniaturization. However, an increase in Al composition leads to a decline in the lattice quality, thereby reducing the internal quantum efficiency (IQE). In addition, the light extraction efficiency (LEE) is limited due to the strong transverse magnetization polarization emission from the multiple quantum wells. Here, we designed the topological corner structure in AlGaN-MQWs, and the high electric field intensity in a tiny space at the corner results in an extremely high local density of optical states (LDOS), which could shorten the luminescence decay time of the emitter and increase the radiative rate by 26 times. Meanwhile, because the excited topological corner state resonance mode is a transverse-electric mode, enhancing only the transverse-electric luminescence without any gain for transverse-magnetic luminescence, thereby significantly improving the light extraction efficiency. Finally, according to theoretical calculations, the IQE could reach 68.75% at room temperature.

Color-Tunable Perovskite Nanomaterials with Intense Circularly Polarized Luminescence and Tailorable Compositions.

The ability to design halide perovskite nanocrystals (PNCs) with circularly polarized luminescence (CPL) offers exceptional potential in photonic technologies. Despite recent inspiring advances, the creation of PNCs with full-color tailorablity, outstanding CPL, and long-term stability remains a substantial challenge. Herein, a robust strategy to craft CPL-active PNCs is reported, exhibiting appealing full-color tunable wavelengths, enhanced CPL, and prolonged stability. In contrast to conventional methodologies, this strategy utilizes chiral nematic mesoporous silica (CNMS) as host to render in situ confined growth of diverse achiral PNCs. By strategically engineering photonic bandgap, adjusting loading amount of PNCs, and manipulating cations/anion compositions of PNCs, robust CPL responses with tunable wavelength and intensity are successfully obtained. The resulting PNCs-CNMS achieves stable CPL emissions with full-color tunability and impressive luminescent dissymmetric factors up to -0.17. Remarkably, silica-based hosts as a protective barrier confer exceptional resistance to humidity, photodegradation, and thermal stability, even up to 95 °C. Furthermore, the ability to achieve reversible CPL switching within PNCs-CNMS is attainable by leveraging the responsiveness of CNMS matrix or dynamic behavior of impregnated PNCs. Additionally, circularly polarized light-emitting diode devices based on PNCs-CNMS can be conveniently fabricated. This research affords a powerful platform for designing functional chiroptical materials.

Deeply subwavelength mid-infrared phase retardation with α-MoO3 flakes

Phase retardation is a cornerstone of modern optics, yet, at mid-infrared (mid-IR) frequencies, it remains a major challenge due to the scarcity of simultaneously transparent and birefringent crystals. Most materials resonantly absorb due to lattice vibrations occurring at mid-IR frequencies, and natural birefringence is weak, calling for hundreds of microns to millimeters-thick phase retarders for sufficient polarization rotation. Here, we demonstrate mid-IR phase retardation with flakes of α-MoO3 that are more than ten times thinner than the operational wavelength, achieving 90 degrees polarization rotation within one micrometer of material. We report conversion ratios above 50% in reflection or transmission mode, and wavelength tunability by several micrometers. Our results showcase that exfoliated flakes of low-dimensional crystals can serve as a platform for mid-IR miniaturized integrated low-loss polarization control.

Wavelength-tunable spatiotemporal mode-locking in a large-mode-area Er:ZBLAN fiber laser at 2.8 µm.

We report a tunable spatiotemporally mode-locked large-mode-area Er:ZBLAN fiber laser based on the nonlinear polarization rotation technique. A diffraction grating is introduced to select the operating wavelength. Under the spectral and spatial filtering effects provided by the grating and spatial coupling respectively, stable ps-level spatiotemporally mode-locked pulses around 2.8 µm with a repetition rate of 43.4 MHz are generated. Through a careful adjustment of the grating, a broad wavelength tuning range from 2747 to 2797 nm is realized. To the best of our knowledge, this is the first wavelength-tunable spatiotemporally mode-locked fiber laser in the mid-infrared region.

Enhancing detectivity of organic photodetectors through the biomass carbon quantum dots from sugarcane bagasse

In recent years, organic photodetectors (OPDs) have received sustained attention due to their tunable wavelength detection, low-cost manufacturing and compatibility with flexible devices. However, as the preparation process proceeds, organic materials inevitably produce some toxic by-products, which triggers an urgent need for green non-toxic optical materials. This paper reports a carbon quantum dot (CQDs) extracted from the green precursor sugarcane bagasse as the sole carbon source, and successfully applied in the OPDs with a structure of FTO/ZnO:CQDs/P3HT/MoO3/Ag for the first time. After CQDs incorporation, the surface of the ZnO thin films exhibits an increased density of oxygen vacancies and adsorbed oxygen. The resulting OPDs exhibit a high detectivity of 2.46 × 1011 Jones and a low noise equivalent power of 1.15 × 10−12 W @ 525 nm. The facile preparation method of CQDs offers a promising opportunity for the green and sustainable synthesis of advanced functional nanomaterials, and the successful demonstration paves new way for the advancement of high-performance OPDs.

Highly luminescent CsPbX3/PMMA (X=Br, I) composites with improved stability for full-color Micro-LED displays

Inorganic metal halide perovskite quantum dots (PQDs) have recently emerged as promising candidates for color conversion materials in Micro-LED displays, due to their outstanding color purity, high absorption coefficient, tunable emission wavelength. However the inferior stability and undesirable photoluminescence quantum yield (PLQY) restrict their particle applications. Herein, CsPbX3/PMMA (X = Br, I) composites with improved stability and optical performance were successfully prepared by a general and mild in-situ polymerization strategy. The ester carbonyl (CO) group in MMA formed complexes with Pb2+, leading to the in-situ thermal polymerization of polymethyl methacrylate (PMMA) under the action of the initiator. The multifunctional PMMA can efficiently passivate halogen vacancies while acting as a barrier against the degradation caused by heat, water, and oxygen. As a result, the PLQYs and stability of PMMA-coated CsPbX3 PQDs have been significantly improved. When implementing CsPbX3/PMMA/PDMS composites as color conversion layers in Micro-LEDs, they achieve an impressive color gamut of 127.23% with excellent stability. We believe our work will stimulate the exploration of perovskite/polymer composites for industrial Micro-LED applications.

Highly Efficient Inverted Light-Emitting Diodes Based on Vertically Aligned CdSe/CdS Nanorod Layers Fabricated by Electrophoretic Deposition.

Inverted colloidal-nanocrystal-based LEDs (NC-LEDs) are highly interesting and invaluable for large-scale display technology and flexible electronics. Semiconductor nanorods (NRs), in addition to the tunable wavelengths of the emitted light (achieved, for example, by the variation of the NR diameter or the diameter of core in a core-shell configuration), also exhibit linearly polarized emission, a larger Stokes shift, faster radiative decay, and slower bleaching kinetics than quantum dots (QDs). Despite these advantages, it is difficult to achieve void-free active NR layers using simple spin-coating techniques. Herein, we employ electrophoretic deposition (EPD) to make closely packed, vertically aligned CdSe/CdS core/shell nanorods (NRs) as the emissive layer. Following an inverted architecture, the device fabricated yields an external quantum efficiency (EQE) of 6.3% and a maximum luminance of 4320 cd/m2 at 11 V. This good performance can be attributed to the vertically aligned NR layer, enhancing the charge transport by reducing the resistance of carrier passage, which is supported by our finite element simulations. To the best of our knowledge, this is the first time vertically aligned NR layers made by EPD have been reported for the fabrication of NC-LEDs and the device performance is one of the best for inverted red NR-LEDs. The findings presented in this work bring forth a simple and effective technique for making vertically aligned NRs, and the mechanism behind the NR-LED device with enhanced performance using these NRs is illustrated. This technique may prove useful to the development of a vast class of nanocrystal-based optoelectronics, including solar cells and laser devices.

Few-Mode Fiber-Based Long-Period Fiber Gratings: A Review

Long-period fiber gratings (LPFGs) are efficient ways to achieve high-order core mode conversion and vortex mode conversion in few-mode fibers (FMFs), which have the benefits of flexible structure, high integration, low insertion loss, and strong wavelength selectivity. With the rapid development of mode division multiplexing (MDM) optical communications, the FMF-LPFGs could have promising applications in the field of MDM optical communications and optical sensors. In this paper, we briefly introduce the principle of optical coupling, theoretical analysis, fabrication techniques, and applications of the FMF-LPFGs in optical communications and optical sensors. The CO2-laser writing technique and arc discharge technique are widely used for the fabrication of FMF-LPFGs and FMF helical long-period gratings (HLPGs). The hydrogen-oxygen flame technique has the advantage on the fabrication of FMF-HLPGs. The mechanical micro-bending and acoustic induction techniques are flexible and effective methods in fundamental researches. The femtosecond laser technique has the advantages for the fabrication of parallel FMF-LPFGs and micro-structure FMF-LPFGs. The mode converters based on the FMF-LPFGs have been demonstrated using different inscription techniques. The FMF-LPFG converters have the advantages such as temperature insensitivity and wavelength tunability. The broadband converters have been demonstrated based on the phase-shift FMF-LPFG, cascaded FMF-LPFGs, and FMF-LPFG operating at dispersion turning point. The FMF-LPFGs and FMF-HLPGs are an excellent option to generate all-fiber orbital angular momentum (OAM) modes in different specialty FMFs, especially the FMF-HLPGs can excite different-order OAM modes directly. As the novel fiber component, the sensing application of FMF-LPFGs and FMF-HLPGs is also briefly introduced.

Wavelength-tunable quasi-unidirectional spatiotemporal mode-locked solitons in an isolator-free Er-doped fiber laser

In this letter, we have demonstrated the realization of the wavelength-tunable spatiotemporal mode-locked (STML) operation in an Er-doped partial multimode fiber laser without the intracavity isolator. The laser adopts an all-fiber structure and the saturable absorption effect is attributed to nonlinear multimode interference (NL-MMI) from the single mode fiber-graded index multimode fiber-single mode fiber (SMF-GIMF-SMF) design. The STML laser can operate in the quasi-unidirectional regime with an emission strength difference of larger than 30 dB for the two counter-propagating lasers. And the switching between the dominating operating directions in the clockwise (CW) or counter-clockwise (CCW) directions can be easily achieved by adjusting the MM polarization controller (PC). Both STML conventional solitons (CSs) and the STML soliton molecules are obtained with a similar tunable wavelength from ∼1.56 μm to ∼1.58 μm for the opposite operating directions. Furthermore, the spatial dynamics of the STML soliton are also investigated in detail. The experimental results are of great help for us to explore nonlinear spatiotemporal dynamics and provide potential applications in fields of all-optical signal processing, fiber sensing and information coding.

Vortex random lasing with tunable wavelength and orbital angular momentum

Random lasing with special structured light field has broad application prospects in various fields. However, the complex spatial modes of random lasing increase the difficulty of light field regulation and limit its practical application. Here, a vortex random lasing with dynamically tunable wavelength and orbital angular momentum is proposed based on the microfluidic channel. Different color random lasers are integrated into the same microfluidic channel for coarse control of the emission wavelengths from 462 to 685 nm by dynamically controlling the liquid flow. A special-shape cavity with a variable size of a gain region is further constructed to finely manipulate the emission wavelengths. Moreover, the vortex random lasing with tunable orbital angular momentum mode from −50 to 50 is realized. The results provide an outstanding strategy for generating the partially coherent vortex beams and may promote the practical applications of random lasers in the fields of sensing, imaging, and communication.

Synergistic-potential engineering enables high-efficiency graphene photodetectors for near- to mid-infrared light

High quantum efficiency and wide-band detection capability are the major thrusts of infrared sensing technology. However, bulk materials with high efficiency have consistently encountered challenges in integration and operational complexity. Meanwhile, two-dimensional (2D) semimetal materials with unique zero-bandgap structures are constrained by the bottleneck of intrinsic quantum efficiency. Here, we report a near-mid infrared ultra-miniaturized graphene photodetector with configurable 2D potential well. The 2D potential well constructed by dielectric structures can spatially (laterally and vertically) produce a strong trapping force on the photogenerated carriers in graphene and inhibit their recombination, thereby improving the external quantum efficiency (EQE) and photogain of the device with wavelength-immunity, which enable a high responsivity of 0.2 A/W–38 A/W across a broad infrared detection band from 1.55 to 11 µm. Thereafter, a room-temperature detectivity approaching 1 × 109 cm Hz1/2 W−1 is obtained under blackbody radiation. Furthermore, a synergistic effect of electric and light field in the 2D potential well enables high-efficiency polarization-sensitive detection at tunable wavelengths. Our strategy opens up alternative possibilities for easy fabrication, high-performance and multifunctional infrared photodetectors.

Strategic Construction of meso-Aryl-Substituted N,N-Carbonyl-Bridged Dipyrrinones as Small, Bright, and Tunable Fluorophores.

A series of novel N,N-carbonyl-bridged dipyrrinone fluorophores have been directly constructed from α-halogenated dipyrrinones, which are conveniently obtained from the acid-catalyzed hydrolysis of readily available α,α'-dihalodipyrrins. This novel methodology affords efficient modulation of the functional groups at both the meso- and α-positions of this fluorophore. These resultant dyes show tunable absorption and emission wavelengths, good molar absorption coefficients, relatively large Stokes shifts, and excellent fluorescence quantum yields up to 0.99, and have been successfully applied in both one- and two-photon fluorescence microscopy imaging in living cells.

Fast-reconfigurable frequency comb generation based on AlGaAsOI waveguide with electro-optic time lens

Tunable optical frequency combs offer a flexible solution for specific applications such as dual-comb spectroscopy, optical communications and microwave photonics, delivering improved precision, compatibility, and performance. However, previously, there has been a trade-off between reconfigurability and system simplicity in comb generation. Here, we present a fast-switched repetition rate frequency comb system that utilizes an electro-optic modulation time-lens technique with a high third-order nonlinear AlGaAsOI waveguide. Only one stage of modulator is used in the time-lens system which significantly reduces the complexity of the overall system. Our system allows for tuning of the center wavelength from 1542 nm to 1556 nm, as well as independent adjustment of the repetition rates from 18 GHz to 26.5 GHz, enabling fast-switching capabilities. Additionally, our system exhibits a high pump-to-comb conversion efficiency of up to 67.9%. It also demonstrates robustness to temperature changes and environmental instability. All the involved devices can be integrated onto a single chip, making this comb suitable for various applications.

Wavelength-tunable Tm:Y2O3 ceramic vortex laser with a changeable orbital angular momentum state.

Wavelength-tunable orbital angular momentum (OAM) lasers with controllable topological charges have the potential for serving as light sources for large-capacity optical communication by combining conventional wavelength division multiplexing (WDM) with OAM mode-division multiplexing (OAM-MDM). In this study, we demonstrate a wavelength-tunable Tm-bulk laser that can control OAM states in the 2-µm spectral range. The excitation conditions for different Laguerre-Gaussian (L G 0,l ) modes in a bulk laser cavity are theoretically determined by measuring the spatial propagation dynamics of the annular pump beam. As a proof-of-principle study, we experimentally generate OAM states of |ℏ| and |2ℏ| from a T m:Y 2 O 3 ceramic laser with a tunable emission wavelength using a Lyot filter (LF). The spatial properties of the scalar optical vortices are well conserved during wavelength tuning, indicating the feasibility of our approach for producing wavelength-tunable structured light. These OAM laser sources, which are characterized by their robustness and compactness, have potential applications in various areas such as optical communications, quantum optics, super-resolution microscopes, and more.

Spectroscopic and 1.5–1.6 μm laser properties of Er:Yb:GdSr3(PO4)3 crystal

An Er:Yb:GdSr3(PO4)3 crystal was grown by the Czochralski method, and its spectroscopic properties were investigated at room temperature. The peak absorption cross section is 1.12 × 10−20 cm2 at 975 nm and the full width at half maximum of the absorption band is 5.8 nm. The peak emission cross section is 0.74 × 10−20 cm2 at 1535 nm and the full width at half maximum of the fluorescence band is 41 nm. Fluorescence lifetime of the 4I13/2 multiplet of Er3+ and Yb3+→Er3+ energy transfer efficiency in the crystal are 7.97 ms and 91.8 %, respectively. End-pumped by a 975 nm diode laser, a 1563 nm continuous-wave laser with a maximum output power of 60 mW and a slope efficiency of 16.1 % was realized in an Er:Yb:GdSr3(PO4)3 crystal at an absorbed pump power of 413 mW. Using a SiO2 birefringent filter as a wavelength tuning element, a continuously tunable 1.5–1.6 μm laser with a range of 45 nm and a maximum output power of 30 mW at 1541 nm was obtained at the same pump power.

Hybrid integrated tunable external cavity laser with sub-10 Hz intrinsic linewidth

In this work, a hybrid integrated tunable external cavity laser (ECL) with a sub-10 Hz intrinsic linewidth is demonstrated. In this hybrid ECL, two Si3N4-based subwavelength hole defect assisted microring resonators, acting as high-Q laser reflectors, are butt-coupled with a chip-scale semiconductor optical amplifier at the two edges, respectively. The experimental results show that the hybrid ECL achieves a sub-10 Hz intrinsic linewidth across a wavelength tuning range from 1525 to 1565 nm, featuring a record lowest value of 6.06 Hz. The demonstrated hybrid ECL opens up opportunities toward the applications of high-speed optical communications and high-resolution light detection and ranging.

All-fiber high-resolution incoherent broadband spectrometer.

Portable optical spectrometers are crucial devices for bio-chemical sensing and spectroscopic applications whereby robust, compact and cost-effective set-ups are desirable. However, existing miniaturized instruments typically struggle to achieve broad wavelength operation and high spectral resolution at the same time. Here, an all-fiber optical spectrometer based on two cascaded Bragg gratings is devised and demonstrated, showing a record resolution and a wavelength span-to-resolution ratio larger than that of most miniature broadband spectrometers reported to date. Thanks to a synchronous control of the grating lengths and to a unique combination of their reflection features, spectral analysis of incoherent light within 1 pm is achieved. On the other hand, fast and reproducible wavelength tuning over several nanometers on a millisecond-timescale is ensured by mechanical stretching of the internal fiber, limited only by the actuator's dynamic range. A striking evidence of the spectrometer capabilities is provided with Doppler-limited spectroscopy of gas absorption bands performed with a near-infrared LED source. The observed spectra exhibit lineshapes comparable with those obtained by laser-based set-ups and the retrieved gas-line parameters are in agreement with existing spectroscopic databases. The spectrometer lends itself to applications in high-resolution interrogation of multiple fiber-optic sensors as well as broadband imaging with supercontinuum light.

Frequency tripled semiconductor disk laser with over 0.5 W ultraviolet output power.

Semiconductor disk lasers can produce high output power and good beam quality simultaneously. The high intracavity circulating power of about hundreds of watts, along with the flexibility of tailorable emitting wavelengths, make it an attractive light source for obtaining ultraviolet (UV) radiation from near-infrared lasers through nonlinear frequency conversion. This work reports a frequency tripled 327 nm semiconductor disk laser with record output power and wavelength tuning range by using a type-I phase-matched LiB3O5 (LBO) crystal and a type-I phase-matched β-BaB2O4 (BBO) crystal as the frequency-doubling and -tripling crystals respectively. Thanks to the obviously larger nonlinear coefficient of the type-I phase-matched BBO compared to the commonly used type-II phase-matched LBO, as well as the small spot size specifically designed at the crystal location, the maximum output power of UV lasers reaches 538 mW, corresponding to an optical-to-optical conversion efficiency from pump to UV laser of about 1.14%. A wavelength tuning range of about 8.6 nm and good power stability with a standard deviation of about 0.94 are also achieved.

Design of 2-Pyridone Fluorophores for Brighter Emissions at Longer Wavelengths.

The recent discovery of blue fluorophores with high quantum yields based on pyridone structures inspired the development of new low-molecular-weight fluorophores with bright emissions at tunable wavelengths, which are highly attractive for various applications. In this study, we propose a rational design strategy for 2-pyridone-based fluorophores with bright emissions at long wavelengths. With a detailed understanding of the positional substitution effects on each carbon atom of the 2-pyridone core, we developed a bright blue fluorophore (λabs =377 nm; λem =433 nm; ϵ=13,200 M-1 cm-1 ; ϕF =88 %) through C3 -aryl and C4 -ester substitutions followed by cyclization. Furthermore, by applying the intramolecular charge transfer (ICT) principle, we invented a bright green fluorophore through C3 - and C4 -diester and C6 -aryl substitutions. The ICT fluorophore based on the pyridone structure shows large molar absorptivity (ϵ=20,100 M-1 cm-1 ), longer emission wavelength (λem =539 nm), high emission quantum yield (ϕF =74 %), and large Stokes shift (Δv=5720 cm-1 ), which are comparable to those of practical fluorescent probes.

Scalable Photonic Digital-to-Analog Converters

This work introduces a novel architecture for implementing a parallel coherent photonic digital-to-analog converter (PDAC), designed to transform parallel digital electrical signals into corresponding analog optical output, convertible to analog electrical signals using photodiodes. The proposed architecture incorporates microring resonator-based modulators (MRMs), phase shifters, and symmetric multimode interference couplers. Efficient modulation is achieved by MRMs utilizing carrier depletion-induced refractive index changes, while metal heaters facilitate tuning of the ring resonator resonance wavelength. The proposed architecture is scalable to higher bit resolutions and exhibits a dynamic range limited by MRM’s sensitivity to applied bias and noise levels. Experimental results of the fabricated chip in the silicon-on-insulator (SOI) platform showcase the successful realization of a 4 GSample/sec conversion rate in a 2-bit resolution operation, along with a stationary conversion of four parallel DC digital signals into 16 analog intensity levels in a 4-bit PDAC configuration. The study encompasses a proof-of-concept experimental demonstration of 8 Gbps data conversion, along with a 50 Gbps data conversion rate using the optimized design in the simulation, affirming the accuracy and quality of the PDAC architecture. These findings contribute to the advancement of PDAC technology, providing insights into performance characteristics, limitations, and potential applications.