Triglycine Sulfate Crystals Research Articles

Direct capture of the alanine ghost in alanine-doped triglycine sulfate crystals.

In this report, ghostly ultra-trace amounts of alanine in alanine-doped triglycine sulfate crystal were directly observed by solid-state nuclear magnetic resonance, and the presence of two chemical states in the cation form and neutral form in the doped alanine was revealed. As the result, the crystal structure of alanine-doped triglycine sulfate was determined for the first time.

Hardness, VSM, cyclic voltammetric and DFT studies of Cesium Sulphate-doped TGS crystals

The creation of capacitors, transducers, sensors, and infrared detectors utilise the nonlinear, ferroelectric triglycine sulphate (TGS) crystal. Cesium sulphate is incorporated into the lattice of TGS crystal to change its characteristics. Cesium sulfate-doped triglycine sulphate (CSTGS) single crystals were produced using a solution approach and a slow evaporation process. The title crystal was studied by single crystal XRD, FTIR, hardness, VSM, cyclic voltammetric and density functional theoretical (DFT) studies and the results are discussed in this paper.

Pyro‐Phototronic Circularly Polarized Light Detection Based on Deuterated L‐Alanine Doped Triglycine Sulfate's Bulk Photovoltaic Effect

AbstractIn this study, a detector is developed using deuterated L‐alanine doped triglycine sulfate (DLATGS) crystals capable of detecting circularly polarized light (CPL) and various polarization states. As a primary pyroelectric detection crystal, DLATGS has exhibited notable optical responses to both linearly and circularly polarized light during the tests, demonstrating a favorable polarization ratio of 3.86 and an anisotropic factor of 0.529. The research discovers the broad‐spectrum bulk photovoltaic (BPVE) characteristics in DLATGS, highlighting its potential for CPL detection. By integrating linear and circular bulk photovoltaic effect theories (LBPV and CBPV), the crystal's ability to differentiate between various polarization modes, including left‐/right‐handed polarized light, is confirmed. The BPVE and pyro‐phototronic coupling responses is characterized, laying a theoretical foundation for a rare pyroelectric effect‐based multifunctional polarization detector. The overall consistency of phenomena and theoretical framework bridges the gap between theoretical predictions and experimental validation. This work not only advances the understanding of DLATGS crystals but also sets the stage for further exploration into chiral materials and the development of TGS‐type crystals in future photoelectronic detectors.

Crystal Growth of Triglycine Sulfate Crystals Under 40-GHz Irradiation and the Infrared Detection of their Device Characteristics

Crystal Growth of Triglycine Sulfate Crystals Under 40-GHz Irradiation and the Infrared Detection of their Device Characteristics

Investigations on theoretical models describing the load-indentation size dependence for (001), (010), (101), (1̄1̄1) and (1̄11) faces of triglycine sulphate

Ferroelectric triglycine sulphate (TGS) single crystals were grown by slow evaporation technique over a period of 30–40 days. The Vickers microhardness studies have been carried out on (001), (010), (101), ([Formula: see text][Formula: see text]1) and ([Formula: see text]11) faces of the TGS crystal. The as-grown (001) face and (010) face with the ferroelectric phase were used to study the temperature dependence of hardness. The indentation size effect (ISE) described using the five theoretical models viz., Meyer’s law, Hays–Kendall, elastic/plastic deformation (EPD), proportional specimen resistance (PSR) and modified PSR model has been investigated on all the crystal faces under study. The experimental results show that the modified PSR model is more accurate at generating load-independent hardness data and also for explaining the origin of ISE.

Effect of adding technologically processed antibodies to interferon-gamma into a parent solution on the structural features of triglycine sulfate crystals grown from this solution

Objectives. Ferroelectric triglycine sulfate (TGS) belongs to a group of crystals whose properties are sensitive even to minor changes in growth conditions. The mechanism of spontaneous polarization in TGS is associated with the adjustment of protons which participate in the formation of hydrogen bonds. Therefore, the state of the parent solution plays an important role in the crystal formation. The study aims to investigate the structural features of TGS crystals grown using aqueous alcoholic solutions of technologically processed antibodies to interferon-gamma, in comparison with those of the crystals grown using the control solutions (technologically processed phosphate-buffered saline and intact aqueous alcoholic solution).Methods. X-ray diffraction assay and Raman spectroscopy.Results. The effect of solutions of the technologically processed antibodies to interferongamma added to a parent solution on the growth of TGS single crystals is established. This effect manifests in the changing in occupancy of the proton sublattice of the crystal grown from the parent solution containing technologically processed antibodies to interferon-gamma, as compared with the crystals grown from the control solutions. In the case of the crystal grown from the solution containing technologically processed antibodies to interferon-gamma, this change in the occupancy of the proton lattice is expressed in an increase in the length of N2–C3 bonds.Conclusions. Adding the technologically processed antibodies in the parent solution before the crystal growth can affect the structure of TGS crystals.

Magnetically Induced Effects in Ferroelectric Triglycine Sulfate Crystals with Chromium Impurity

Magnetically Induced Effects in Ferroelectric Triglycine Sulfate Crystals with Chromium Impurity

Magnetically Induced Effects in Ferroelectric Triglycine Sulfate Crystals with Chromium Impurity

The influence of a permanent magnetic field on macro- and nanoscopic properties of triglycine sulfate (TGS) crystals with impurity chromium (TGS-Cr) has been investigated. This work continues the previous studies of magnetically induced effects in ferroelectrics. A specific feature of TGS crystals is the presence of a nanoscale relief on a polar (010) cleavage; this nanorelief is a qualitative characteristic of the crystal defect structure. It is shown that the exposure of a crystal in a magnetic field of 2 T leads to a change in its dielectric properties, accompanied by a long-term transformation of the nanorelief. The results obtained are indicative of a magnetically induced change in the defect crystal structure. A qualitative difference is found between the magnetically induced effects in TGS-Cr crystals and undoped TGS crystals. The relationship between the magnetically induced effects and structural defects is discussed.

The effect of a static magnetic field on the low-frequency dielectric permittivity of nominally pure and Co<sup>2+</sup> ions doped triglycine sulfate crystals

The effect of a weak static magnetic field on the low-frequency dielectric permittivity of the crystals of nominally pure triglycine sulfate (TGS): and TGS containing cobalt ions (TGS + Co2+) is investigated. In TGS, the magnetic effect is essentially anisotropic: it is completely absent when the vectors \(\vec {B}\) and \({{\vec {P}}_{{\text{s}}}}\) are collinear and is most pronounced when \(\vec {B} \bot {{\vec {P}}_{{\text{s}}}}\) and the magnetic field is oriented along the crystallophysical axis \(\vec {a}\). In TGS + Co2+ magnetic effect is noticeably stronger than in TGS, but practically does not depend on the mutual orientation of vectors \(\vec {B}\) and \({{\vec {P}}_{{\text{s}}}}\).

Effect of a Static Magnetic Field on the Low-Frequency Dielectric Permittivity of Triglycine Sulfate Crystals Nominally Pure or Doped with Со2+ Ions

Effect of a Static Magnetic Field on the Low-Frequency Dielectric Permittivity of Triglycine Sulfate Crystals Nominally Pure or Doped with Со2+ Ions

Ferroelectric properties of triglycine sulfate crystals doped with glycine analogs

Single crystals of ferroelectric triglycine sulfate doped with glycine analogs serine, threonine, lactic acid, and alaninol were grown via the slow solvent evaporation method. The resulting ferroelectric domain structures and polarization–electric field hysteresis loops revealed that these dopants caused triglycine sulfate to form a multidomain structure. This was attributed to hydrogen bonds not being formed, which is significant in polarization reversal, due to the side chains and the substituents of the dopant molecules. Therefore, the dopants did not affect the surrounding dipoles enough to cause cooperative phenomena, such as dipole‒dipole interactions, and do not result in the formation of a single- domain, unlike alanine in our previous study.

A Polymorph of Dipeptide Halide Glycyl-L-Alanine Hydroiodide Monohydrate: Crystal Structure, Optical Second Harmonic Generation, Piezoelectricity and Pyroelectricity.

A polymorph of glycyl-L-alanine HI.H2O is synthesized from chiral cyclo-glycyl-L-alanine dipeptide. The dipeptide is known to show molecular flexibility in different environments, which leads to polymorphism. The crystal structure of the glycyl-L-alanine HI.H2O polymorph is determined at room temperature and indicates that the space group is polar (P21), with two molecules per unit cell and unit cell parameters a = 7.747 Å, b = 6.435 Å, c = 10.941 Å, α = 90°, β = 107.53(3)°, γ = 90° and V = 520.1(7) Å3. Crystallization in the polar point group 2, with one polar axis parallel to the b axis, allows pyroelectricity and optical second harmonic generation. Thermal melting of the glycyl-L-alanine HI.H2O polymorph starts at 533 K, close to the melting temperature reported for cyclo-glycyl-L-alanine (531 K) and 32 K lower than that reported for linear glycyl-L-alanine dipeptide (563 K), suggesting that although the dipeptide, when crystallized in the polymorphic form, is not anymore in its cyclic form, it keeps a memory of its initial closed chain and therefore shows a thermal memory effect. Here, we report a pyroelectric coefficient as high as 45 µC/m2K occurring at 345 K, one order of magnitude smaller than that of semi-organic ferroelectric triglycine sulphate (TGS) crystal. Moreover, the glycyl-L-alanine HI.H2O polymorph displays a nonlinear optical effective coefficient of 0.14 pm/V, around 14 times smaller than the value from a phase-matched inorganic barium borate (BBO) single crystal. The new polymorph displays an effective piezoelectric coefficient equal to deff=280 pCN-1, when embedded into electrospun polymer fibers, indicating its suitability as an active system for energy harvesting.

Physicochemical Analytical Studies on Yttrium‐Doped Triglycine Sulfate Single Crystals

Single crystals of pure triglycine sulfate (TGS) and yttrium-acetate (0.5 mol%)-doped triglycine sulfate (YTGS) crystals are synthesized and the crystals are grown from aqueous solution by slow evaporation solution growth method. The grown crystals are subjected to single crystal and powder X-ray diffraction studies to identify the morphology and structure. Both the grown crystals are packed in a monoclinic crystal system and the lattice parameters of YTGS crystal are a = 9.138 Å, b = 12.72 Å, and c = 5.728 Å, whereas the doped TGS are, a = 9.134 Å, b = 12.61 Å, and c = 5.723 Å. The lattice parameters are slightly distorted due to the incorporation of yttrium ion into the lattice sites of the TGS crystal. The thermal stability of the grown crystals is investigated by differential thermal analysis (DTA) and thermogravimetric studies. DTA curve shows a lower decomposition temperature for YTGS crystal than for pure TGS crystal. The functional groups of the grown crystals are identified by Fourier transform infrared spectral studies. The surface morphology of the crystals is examined by scanning electron microscopy. Dielectric studies are carried out to identify the phase transition temperature and to find the dielectric constant of the YTGS crystals.

Dynamics of the Phase Transition in the Dielectric Spectra of Pure and Chrome-Doped Triglycine Sulfate Crystals

Dynamics of the Phase Transition in the Dielectric Spectra of Pure and Chrome-Doped Triglycine Sulfate Crystals

Structural and Dielectric Investigations on Pure and Doped Triglycine Sulfate (TGS) Crystals

Abstract: In this paper, a single crystal triglycine sulfate (TGS) doped with copper sulfate was synthesized using the slow evaporation technique. Structural characterization was carried out using X-ray diffraction and FTIR techniques. Thermal studies revealed that the addition of copper sulfate did not affect the thermal stability of the TGS. In addition, intensive dielectric investigation has been carried out, which showed that the addition of copper sulfate enhances the dielectric permittivity. A change in Curie temperature has been observed upon doping TGS with copper sulfate. Keywords: TGS doping, Copper sulfate, Dielectrics, Cole-Cole plot.

Croconic Acid Doped Triglycine Sulfate: Crystal Structure, UV-Vis, FTIR, Raman, Photoluminescence Spectroscopy, and Dielectric Properties

Triglycine sulfate (TGS) single crystals doped with croconic acid (CA) were grown by evaporation from aqueous solutions. X-ray diffraction analysis shows a slight reduction in unit cell volume in TGS:CA compared to pure TGS crystals. The polarized Raman and near-infrared absorption spectra show that the positions of most lines resulting from inter- and intramolecular vibrations are in good agreement with those in spectra of undoped TGS crystals. The inclusion of CA in TGS is confirmed by the presence of bands characteristic of CA in the infrared-Fourier transform spectra. The ultraviolet-visible absorption spectra of TGS:CA are characterized by the presence of additional absorption bands (compared to the spectra of pure TGS) located in the transparent region of pure TGS. In the photon energy region 1.6–3.6 eV, a strong “green” luminescence band is present in TGS:CA upon excitation at λ = 325 nm. The position of the emission band depends on the wavelength of the exciting light. Doping of TGS with CA causes pinning of domain walls, which is accompanied by a decrease in amplitude and frequency dispersion of the dielectric anomaly at the phase transition, a decrease in the switchable polarization and an increase in the coercive field of hysteresis loops.

Unusual domain growth during local switching in triglycine sulfate crystals

Formation and growth of isolated lenticular domains created by local switching using a biased tip of the scanning probe microscope in nominally pure triglycine sulfate single crystals have been studied experimentally. The obtained unusual change in the domain shape during growth has been considered in terms of a kinetic approach and attributed to simultaneous stochastic step generation for domain widening and deterministic nucleation (step generation at the domain vertices) for domain elongation. The main parameters of the domain wall motion have been extracted by fitting of the field dependence of the domain length and width. The obtained results provide a useful insight into the features of the domain structure kinetics in the uniaxial ferroelectrics and can be used for development of the domain engineering methods.

Formation of a quasi-equilibrium domain structure of crystals of the TGS group near TC

In the temperature range ΔT ≈ 321 K ÷ 322 K, the kinetics of the nonequilibrium domain structure of triglycine sulphate crystals, both pure and with specially introduced defects, has been studied by means of piezoresponse force microscopy technique. The temporal change in the domain structure as a set of regions with a scalar order parameter of P (r, t) = +1 and −1 for oppositely polarized domains was analysed by the behaviour of the space-time correlation function C(r,t) = ·Р(r,t)Р(0,t)Ò. At different distances from the Curie point Tc, the characteristic length Lc, as a scale measure of the average domain size, increases with time according to the power law Lc(t)~(t−t0)a. A decrease of the exponent a with distance from Tc can be a consequence of the transition of the domain structure of TGS crystals from a non-conservative state to aconservative one.

Parameters in the ferroelectric phase of TGS

Polarization P(T) of triglycine sulfate (TGS) crystal shows distinct properties versus temperature, between 28 °C and the Curie point Tc. Carefully measured polarization versus temperature on several ranges is presented. The slopes on the curve P(T) on three temperature ranges between 28 ÷ 46 °C appear quite normal, while near the Curie point (47 °C ÷ Tc) behave abnormally, due to the domain walls. The relaxation time LOW, MIDDLE and HIGH appear very interesting. The MIDDLE relaxation time τM, between 40 ÷ 46 °C behave like the HIGH relaxation time τ H between 47 and 48 °C and between −20 ÷ 10 °C (25 KBT) similar to LOW relaxation time τL (28KBT). The diagrams Cole-Cole of TGS are analyzed here for the first time. Roughly, several parameters change their slopes at 30, 42, and 47 °C. The values of ε′H and εʺH show about the same slope on the zones 42–47 °C and 30–42 °C. For the same zones, ε′L shows several increasing activation energies toward Curie point, except εʺL and R L whose activation energy decreases. Finally, we mention the opposite variation of the negative ordinate Y CH, Y CL of both arcs Cole-Cole and of the radius R H and R L.

Preferences of chirality and polarity in triglycine sulfate crystals

Preferences of chirality and polarity in triglycine sulfate crystals