Trichloroethylene Removal Rate Research Articles

Influence of microbial inoculation site on trichloroethylene degradation in electrokinetic-enhanced bioremediation of low-permeability soils

The integration of electrokinetic and bioremediation (EK-BIO) represents an innovative approach for addressing trichloroethylene (TCE) contamination in low-permeability soil. However, there remains a knowledge gap in the impact of the inoculation approach on TCE dechlorination and the microbial response with the presence of co-existing substances. In this study, four 1-dimensional columns were constructed with different inoculation treatments. Monitoring the operation conditions revealed that a stabilization period (∼40 days) was required to reduce voltage fluctuation. The group with inoculation into the soil middle (Group B) exhibited the highest TCE dechlorination efficiency, achieving a TCE removal rate of 84%, which was 1.1–3.2 fold higher compared to the others. Among degraded products in Group B, 39% was ethylene. The physicochemical properties of the post-soil at different regions illustrated that dechlorination coincided with the Fe(III) and SO42− reduction, meaning that the EK-BIO system promoted the formation of a reducing environment. Microbial community analysis demonstrated that Dehalococcoides was only detected in the treatment of injection at soil middle or near the cathode, with abundance enriched by 2.1%–7.2%. The principal components analysis indicated that the inoculation approach significantly affected the evolution of functional bacteria. Quantitative polymerase chain reaction (qPCR) analysis demonstrated that Group B exhibited at least 2.8 and 4.2-fold higher copies of functional genes (tceA, vcrA) than those of other groups. In conclusion, this study contributes to the development of effective strategies for enhancing TCE biodechlorination in the EK-BIO system, which is particularly beneficial for the remediation of low-permeability soils.

Fe-MOF-derived carbon compounds as catalysts for trichloroethylene degradation via persulfate oxidation: Role of precursor template and pyrolysis temperature

Trichloroethylene (TCE) commonly exists in contaminated water as a persistent toxic pollutant. The advanced oxidation of persulfate (PS) is a promising method for degrading organic pollutants. Heterogeneous Fe-carbon composites prepared by pyrolysis with metal–organic frameworks (MOFs) have attracted attention. However, the intrinsic relationship between the physicochemical properties and catalytic performance of MOF-derived carbon compounds via PS is unclear. This study investigates TCE removal by Fe-MOF-derived carbon (MFC) with PS. The effects of the precursor template structure, pyrolysis temperature, and coexisting substances on TCE removal over the MFC/PS system are examined. Fe-MOF-derived from different precursor templates presented different TCE removal rates of 75.2–85.0%. The pyrolysis temperature of MFC alters the pore size, phase composition, and other properties, thereby affecting electron transport in the materials and catalyzing the degradation process. The total TCE removal reached 85.8% with MFC600, derived from MF88B and pyrolyzed at 600 ℃. This catalyst demonstrated excellent performance for PS degradation over a wide pH range (3−9). Moreover, free-radical and nonradical pathways coexist in the MFC600/PS system. During the TCE degradation process, oxygen vacancies, Fe species (Fe0, Fe3N, Fe3C, and Fe3O4), and N species (pyridinic N and graphitic N) were active centers in the material and played a major role in catalytic degradation. They participated in the subsequent generation of HO•, SO4•-, and •O2-, and 1O2. Furthermore, a possible degradation mechanism is proposed. This study elucidates the control of the physicochemical properties of carbon-based catalysts by exploiting MOF diversity.

Combining electrokinetic treatment with modified zero-valent iron nanoparticles for rapid and thorough dechlorination of trichloroethene

In situ injection of nanoscale zero-valent iron (nZVI) slurry is a promising method to treat chlorinated solvents represented by trichloroethylene (TCE) in groundwater. In this study, the effects of sulfidation and emulsification treatment on the performance of nZVI reductive dechlorination of TCE under enhancement by an external electric field were evaluated. The hydrophobic oil film on the surface of sulfidized and emulsified zero-valent iron (S-EZVI) can sequestrate more than one-fifth of the unreacted TCE in the early stage of the experiment (at 5 min). The FeS layer formed on the surface of S-EZVI can facilitate the electron-transfer process and reduce the degree of corrosion of Fe0 with water by 94.0%. Electric-field-enhanced S-EZVI technology can remove more than 93.1% of TCE in the pH range 6.0–9.0, and the performances in overly acid and overly alkali environments both improved. Under the optimal conditions, the TCE removal rate and reaction constant of the applied electric field group reached 96.7% and 1.6 × 10−2 L g−1 min−1, respectively, which were much higher than those of the group without an electric field (53.2% and 3.3 × 10−3 L g−1 min−1) owing to rapid concurrent hydrogenolysis of dichloroethenes and vinyl chloride, or another transformation pathway, such as direct oxidation by the anode. Thereby, this method avoids accumulation of chlorinated intermediates, especially toxic vinyl chloride. This work shows that combination technology has many characteristics that are favorable for field application, and it is expected to provide a new reference and have application value for development of in situ efficient and thorough treatment of TCE-contaminated groundwater.

Study on the community structure and function of anaerobic granular sludge under trichloroethylene stress.

Trichloroethylene (TCE) is one of the most common groundwater pollutants. It is carcinogenic, teratogenic, mutagenic and poses a serious threat to human health and the environment. Therefore, reducing the environmental toxicity of TCE is of great significance. Anaerobic sludge was cultured and acclimated in an upflow anaerobic sludge blanket (UASB) reactor in this study. The Chemical Oxygen Demand (COD) concentration of the influent was approximately 2500 mg L-1, and the TCE concentration of the influent ranged from 1.46 mg L-1 to 73 mg L-1. After biodegradation of the anaerobic microflora, the COD removal rate was approximately 85%, and the TCE removal rate was over 85%. The microbial community of anaerobic sludge was analysed by 16 S rDNA clone libray and 454 high-throughput sequencing. Through analysis of the sequencing results, we found that there were a variety of acid-forming bacteria, anaerobic dechlorinating bacteria, and methanogenic bacteria. Based on the analysis of microflora function, it was speculated that the TCE metabolic pathway took place in UASB reactors. Desulfovibrio and Syntrophobacter provided an anaerobic environment, and acid-forming bacteria metabolise organic compounds into hydrogen. With Dehalobacter and Geobacter, TCE as an electron acceptor is dechlorinated and reduced under the anaerobic environment, in which hydrogen acts as an electron donor. By this, we clarified the metabolic pathway for improving TCE bioremediation.

Controlled polyethylene glycol and activated carbon interaction with nanoscale zerovalent iron for trichloroethylene degradation

Nanoscale zerovalent iron (Fe0) on carbon materials was successfully synthesized via a simple one-step pyrolysis of coir pith with iron precursor. The Fe0 dispersion over activated carbon (AC) and stability was amended by adding polyethylene glycol (PEG)/carboxymethyl cellulose (CMC). The transmission electron microscopy results reveal the homogeneous distribution of Fe0 (~20 nm) on the surface of AC. In addition, the crystal patterns and valence states of Fe0 nanoparticles were evaluated by X-ray diffraction, and X-ray photoelectron spectroscopy, respectively. Trichloroethylene (TCE), one common pollutant in the groundwater, was used to understand the catalytic ability of Fe/AC. The pseudo-first-order kinetic model was applied for TCE removal rate. Fe/AC shows 80% TCE removal in 24 h reaction time, due to its porous structure and large surface area. PEG-Fe/AC composite demonstrated 90.4% TCE dechlorination efficiency in 45 min (kobs 0.29 min−1). The enhanced dechlorination was recorded due to perfect PEG and Fe0 ratio, in which PEG restricted the arial oxidation of Fe0. The as-synthesized nanocomposite was further evaluated for its high stability and efficacy by consecutive eight successive TCE removal cycles. This study demonstrates that one-pot synthesized PEG-Fe/AC composite can effectively remove chlorinated compounds in water, which can be beneficial to the future research applications.

Core-Shell Fe/FeS Nanoparticles with Controlled Shell Thickness for Enhanced Trichloroethylene Removal.

Zero-valent iron nanoparticles (nZVI) treated by reduced sulfur compounds (i.e., sulfidated nZVI, S-nZVI) have attracted increased attention as promising materials for environmental remediation. While the preparation of S-nZVI and its reactions with various groundwater contaminants such as trichloroethylene (TCE) were already a subject of several studies, nanoparticle synthesis procedures investigated so far were suited mainly for laboratory-scale preparation with only a limited possibility of easy and cost-effective large-scale production and FeS shell property control. This study presents a novel approach for synthesizing S-nZVI using commercially available nZVI particles that are treated with sodium sulfide in a concentrated slurry. This leads to S-nZVI particles that do not contain hazardous boron residues and can be easily prepared off-site. The resulting S-nZVI exhibits a core–shell structure where zero-valent iron is the dominant phase in the core, while the shell contains mostly amorphous iron sulfides. The average FeS shell thickness can be controlled by the applied sulfide concentration. Up to a 12-fold increase in the TCE removal and a 7-fold increase in the electron efficiency were observed upon amending nZVI with sulfide. Although the FeS shell thickness correlated with surface-area-normalized TCE removal rates, sulfidation negatively impacted the particle surface area, resulting in an optimal FeS shell thickness of approximately 7.3 nm. This corresponded to a particle S/Fe mass ratio of 0.0195. At all sulfide doses, the TCE degradation products were only fully dechlorinated hydrocarbons. Moreover, a nearly 100% chlorine balance was found at the end of the experiments, further confirming complete TCE degradation and the absence of chlorinated transformation products. The newly synthesized S-nZVI particles thus represent a promising remedial agent applicable at sites contaminated with TCE.

Effects of co-existing nitrate on TCE removal by mZVI under different pollution load scenarios: Kinetics, electron efficiency and mechanisms.

Microscale zero-valent iron in situ reaction zone (mZVI-IRZ) has proved to be effective and efficient for the removal of chlorinated aliphatic hydrocarbons (CAHs) from groundwater. However, nitrate (NO3-), which is ubiquitous in groundwater, affects the mZVI-based attenuation of CAHs in a complicated manner. Both the reaction rate constant (k) and electron efficiency (EE) of mZVI must be considered to comprehensively reflect the effects of NO3- on the short and long-term remediation performances of mZVI. Therefore, the influence of NO3- on trichloroethylene (TCE) removal under high-pollution-load (iron limited) and low-pollution-load (iron excess) conditions was investigated. Low concentrations of NO3- (10 and 50mgNL-1) were found to enhance the TCE removal rate and efficiency, whereas high concentrations of NO3- (100mgNL-1) inhibited the reaction. Although TCE removal was increased at low concentrations of NO3-, the EE of mZVI was dramatically decreased in the presence of NO3- at all concentration levels. Therefore, both the short-term TCE removal characteristics and the EE of mZVI should be considered when evaluating the long-term remediation effectiveness of mZVI-IRZ technology. The effects of NO3- on the TCE removal trends under high- and low-pollution-load scenarios were similar, but had different magnitudes. NO3- affected the TCE removal mainly by promoting mZVI corrosion, competing for electrons and affecting passivation product evolution. Our results provide guidance for the practical application of mZVI-IRZ technology.

Superior trichloroethylene removal from water by sulfide-modified nanoscale zero-valent iron/graphene aerogel composite

Sulfide-modified nanoscale zero-valent iron (S-nZVI) is a promising material for removal of organic pollutants from water, but S-nZVI nanoparticles (NPs) easily agglomerate and have poor contact with organic contaminants. Herein, we propose a new S-nZVI/graphene aerogel (S-nZVI/GA) composite which exhibits superior removal capability for trichloroethylene (TCE) from water. Three-dimensional porous graphene aerogel (GA) can improve the efficiency of electron transport, enhance the adsorption of organic pollutants and restrain the agglomeration of the core-shell S-nZVI NPs. The TCE removal rates of FeS, nZVI, GA and S-nZVI were 27.8%, 42%, 63% and 75% in 2 hr, respectively. Furthermore, TCE was completely removed within 50 min by S-nZVI/GA. The TCE removal rate increased with increasing pH and temperature, and TCE removal followed the pseudo-first-order kinetic model. The results demonstrate the great potential of S-nZVI/GA composite as a low-cost, easily separated and superior monolithic adsorbent for removal of organic pollutants.

Enhanced simultaneous removal of MTBE and TCE mixture by Paracoccus sp. immobilized on waste silica gel

Contamination of groundwater with the gasoline additive methyl tert-butyl ether (MTBE) is often accompanied by the coexistence of chlorinated aliphatic contaminants such as trichloroethylene (TCE). This study reports for the first time an indigenous Paracoccus sp. using MTBE as a sole carbon source while cometabolizing TCE from the mixture. The culture was originally enriched and isolated from the sludge sample at a regional wastewater treatment plant in Macau Special Administrative Region (SAR), China. Waste silica gel was used as a matrix for the microbial immobilization. The effects of different concentrations of MTBE and TCE on the removal efficiencies were investigated, together with their interactions during the bioremoval process, as well as the effects of pH and temperature on MTBE and TCE removal rates. The adsorption kinetics of contaminants on silica gel was also evaluated and the adsorption capacities of MTBE (50 mg l−1) and TCE (50 mg l−1) were 0.42 mg g−1 and 0.65 mg g−1, respectively. In the immobilized system, TCE (20 mg l−1) was removed to non-detectable level while the highest removal efficiency for MTBE (40 mg l−1) was 70.2 ± 3.1%.

The influence of cathode material on electrochemical degradation of trichloroethylene in aqueous solution

In this study, different cathode materials were evaluated for electrochemical degradation of aqueous phase trichloroethylene (TCE). A cathode followed by an anode electrode sequence was used to support reduction of TCE at the cathode via hydrodechlorination (HDC). The performance of iron (Fe), copper (Cu), nickel (Ni), aluminum (Al) and carbon (C) foam cathodes was evaluated. We tested commercially available foam materials, which provide large electrode surface area and important properties for field application of the technology. Ni foam cathode produced the highest TCE removal (68.4%) due to its high electrocatalytic activity for hydrogen generation and promotion of HDC. Different performances of the cathode materials originate from differences in the bond strength between atomic hydrogen and the material. With a higher electrocatalytic activity than Ni, Pd catalyst (used as cathode coating) increased TCE removal from 43.5% to 99.8% for Fe, from 56.2% to 79.6% for Cu, from 68.4% to 78.4% for Ni, from 42.0% to 63.6% for Al and from 64.9% to 86.2% for C cathode. The performance of the palladized Fe foam cathode was tested for degradation of TCE in the presence of nitrates, as another commonly found groundwater species. TCE removal decreased from 99% to 41.2% in presence of 100 mg L−1 of nitrates due to the competition with TCE for HDC at the cathode.The results indicate that the cathode material affects TCE removal rate while the Pd catalyst significantly enhances cathode activity to degrade TCE via HDC.

Electrochemical degradation of trichloroethylene in aqueous solution by bipolar graphite electrodes

In this study, we tested the use of the bipolar electrodes to enhance electrochemical degradation of trichloroethylene (TCE) in an undivided, flow-through electrochemical reactor. The bipolar electrode forms when an electrically conductive material polarizes between feeder electrodes that are connected to a direct current source and, therefore, creates an additional anode/cathode pair in the system. We hypothesize that bipolar electrodes will generate additional oxidation/reduction zones to enhance TCE degradation. The graphite cathode followed by graphite anode sequence was operated without a bipolar electrode as well as with one and two bipolar graphite electrodes. The system without bipolar electrodes degraded 29% of TCE while the system with one and two bipolar electrodes degraded 38% and 66% of TCE, respectively. It was found that the removal mechanism for TCE in bipolar mode includes hydrodechlorination at the feeder cathode, and oxidation induced by peroxide. The results show that the bipolar electrodes presence enhance TCE removal efficiency and rate and imply that they can be used to improve electrochemical treatment of contaminated groundwater.

Impact of electrode sequence on electrochemical removal of trichloroethylene from aqueous solution

The electrode sequence in a mixed flow-through electrochemical cell is evaluated to improve the hydrodechlorination (HDC) of trichloroethylene (TCE) in aqueous solutions. In a mixed (undivided) electrochemical cell, oxygen generated at the anode competes with the transformation of target contaminants at the cathode. In this study, we evaluate the effect of placing the anode downstream from the cathode and using multiple electrodes to promote TCE reduction. Experiments with a cathode followed by an anode (C→A) and an anode followed by a cathode (A→C) were conducted using mixed metal oxide (MMO) and iron as electrode materials. The TCE removal rates when the anode is placed downstream of the cathode (C→A) were 54% by MMO→MMO, 64% by MMO→Fe and 87% by Fe→MMO sequence. Removal rates when the anode is placed upstream of the cathode (A→C) were 38% by MMO→MMO, 58% by Fe→MMO and 69% by MMO→Fe sequence. Placing the anode downstream of the cathode positively improves (by 26%) the degradation of aqueous TCE in a mixed flow-through cell as it minimizes the influence of oxygen generated at the MMO anode on TCE reduction at the cathode. Furthermore, placing the MMO anode downstream of the cathode neutralizes pH and redox potential of the treated solution. Higher flow velocity under the C→A setup increases TCE mass flux reduction rate. Using multiple cathodes and an iron foam cathode up stream of the anode increase the removal rate by 1.6 and 2.4 times, respectively. More than 99% of TCE was removed in the presence of Pd catalyst on carbon and as an iron foam coating. Enhanced reaction rates found in this study imply that a mixed flow-through electrochemical cell with multiple cathodes up stream of an anode is an effective method to promote the reduction of TCE in groundwater.

Electrochemical transformation of thichloroethylene in groundwater by Ni-containing cathodes

In this study, we evaluate the use of different stainless steel (SS) materials as cost-effective cathode materials for electrochemical transformation of trichloroethylene (TCE) in contaminated groundwater. Ni, which is present in certain SS, has low hydrogen overpotential that promotes fast formation of atomic hydrogen and, therefore, its content can enhance hydrodechlorination (HDC). We a flow-through electrochemical reactor with a SS cathode followed by an anode. The performance of Ni containing foam cathodes (Fe/Ni and Ni foam) was also evaluated for electrochemical transformation of TCE in groundwater. SS type 316 (12% Ni) removed 61.7% of TCE compared to 52.6% removed by SS 304 (9.25% Ni) and 37.5% removed by SS 430 (0.75% Ni). Ni foam cathode produced the highest TCE removal rate (68.4%) compared with other cathodes. The slightly lower performance of SS type 316 mesh is balanced by the reduction in treatment costs for larger-scale systems. The results prove that Ni content in SS highly influences TCE removal rate.

Pump-and-Treat Groundwater Remediation Using Chlorine/Ultraviolet Advanced Oxidation Processes

Comparative studies of the use of chlorine/ultraviolet (Cl2/UV) and hydrogen peroxide/ultraviolet (H2O2/UV) Advanced oxidation processes (AOPs) to remove trichloroethylene (TCE) from groundwater in a pump-and-treat application were conducted for the first time at the full-scale operational level at two water treatment facilities in Northern California. In these studies, aqueous chlorine replaced hydrogen peroxide in the AOP treatment step, where the oxidant is exposed to UV light to produce highly reactive radical species that degrade groundwater contaminants. TCE removal rates as a function of initial chlorine dose and pH were then determined. At the site where the natural pH of the water was 7.1, TCE was removed (to a concentration of less than 0.5 µg/L) for nearly every chlorine dose point tested, and pH adjustment slightly enhanced the treatment process at this facility. The second site had a high natural pH of 7.7, and here, TCE was not completely removed for any chlorine dose up to 5.7 mg/L, although TCE removal did increase when the chlorine dose increased between 0.9 and 3.6 mg/L. Residual TCE remaining in the water post-Cl2/UV was readily removed using active carbon filtration, which is part of the overall treatment train at this facility. These studies also verified that Cl2/UV AOP did not interfere with the photolysis of N-nitrosodimethylamine or result in an effluent acutely toxic toward Ceriodaphnia dubia. Comparative economic analysis revealed that the chemical costs associated with Cl2/UV AOP were 25 to 50% of the costs associated with in place H2O2/UV AOP treatment.

Electrochemical transformation of trichloroethylene in aqueous solution by electrode polarity reversal

Electrode polarity reversal is evaluated for electrochemical transformation of trichloroethylene (TCE) in aqueous solution using flow-through reactors with mixed metal oxide electrodes and Pd catalyst. The study tests the hypothesis that optimizing electrode polarity reversal will generate H2O2 in Pd presence in the system. The effect of polarity reversal frequency, duration of the polarity reversal intervals, current intensity and TCE concentration on TCE removal rate and removal mechanism were evaluated. TCE removal efficiencies under 6 cycles h−1 were similar in the presence of Pd catalyst (50.3%) and without Pd catalyst (49.8%), indicating that Pd has limited impact on TCE degradation under these conditions. The overall removal efficacies after 60 min treatment under polarity reversal frequencies of 6, 10, 15, 30 and 90 cycles h−1 were 50.3%, 56.3%, 69.3%, 34.7% and 23.4%, respectively. Increasing the frequency of polarity reversal increases TCE removal as long as sufficient charge is produced during each cycle for the reaction at the electrode. Electrode polarity reversal shifts oxidation/reduction and reduction/oxidation sequences in the system. The optimized polarity reversal frequency (15 cycles h−1 at 60 mA) enables two reaction zones formation where reduction/oxidation occurs at each electrode surface.

Numerical Analysis of Thermal Remediation in 3D Field-Scale Fractured Geologic Media.

Thermal methods are promising for remediating fractured geologic media contaminated with volatile organic compounds, and the success of this process depends on the coupled heat transfer, multiphase flow, and thermodynamics. This study analyzed field-scale removal of trichloroethylene (TCE) and heat transfer behavior in boiling fractured geologic media using the multiple interacting continua method. This method can resolve local gradients in the matrix and is less computationally demanding than alternative methods like discrete fracture-matrix models. A 2D axisymmetric model was used to simulate a single element of symmetry in a repeated pattern of extraction wells inside a large heated zone and evaluate effects of parameter sensitivity on contaminant recovery. The results showed that the removal of TCE increased with matrix permeability, and the removal rate was more sensitive to matrix permeability than any other parameter. Increasing fracture density promoted TCE removal, especially when the matrix permeability was low (e.g., <10(-17) m(2)). A 3D model was used to simulate an entire treatment zone and the surrounding groundwater in fractured material, with the interaction between them being considered. Boiling was initiated in the center of the upper part of the heated region and expanded toward the boundaries. This boiling process resulted in a large increase in the TCE removal rate and spread of TCE to the vadose zone and the peripheries of the heated zone. The incorporation of extraction wells helped control the contaminant from migrating to far regions. After 22 d, more than 99.3% of TCE mass was recovered in the simulation.

Assessment of potential positive effects of nZVI surface modification and concentration levels on TCE dechlorination in the presence of competing strong oxidants, using an experimental design

Nanoscale zero-valent iron (nZVI) particles are efficient for the remediation of aquifers polluted by trichloroethylene (TCE). But for on-site applications, their reactivity can be affected by the presence of common inorganic co-pollutants, which are equally reduced by nZVI particles. The aim of this study was to assess the potential positive effects of nZVI surface modification and concentration level on TCE removal in the concomitant presence of two strong oxidants, i.e., Cr(VI) and NO3−. A design of experiments, testing four factors (i.e. nZVI concentration, nZVI surface modification, Cr(VI) concentration and NO3− concentration), was used to select the best trials for the identification of the main effects of the factors and of the factors interactions. The effects of these factors were studied by measuring the following responses: TCE removal rates at different times, degradation kinetic rates, and the transformation products formed. As expected, TCE degradation was delayed or inhibited in most of the experiments, due to the presence of inorganics. The negative effects of co-pollutants can be palliated by combining surface modification with a slight increase in nZVI concentration. Encouragingly, complete TCE removal was achieved for some given experimental conditions. Noteworthily, nZVI surface modification was found to promote the efficient degradation of TCE. When degradation occurred, TCE was mainly transformed into innocuous non-chlorinated transformation products, while hazardous chlorinated transformation products accounted for a small percentage of the mass-balance.

Trichloroethylene으로 오염된 지하수 제거공정의 미생물 다양성 및 분리균주 Pseudomonas sp. DHC8의 특성

Trichloroethylene (TCE) is a widely used substance in commercial and industrial applications, yet it must be removed from the contaminated soil and groundwater environment due to its toxic and carcinogenic nature. We investigated bacterial community structure, dominant bacterial strain, and removal efficiency in a TCE contaminated groundwater treatment system using immobilized carrier. The microbial diversity was determined by the nucleotide sequences of 16S rRNA gene library. The major bacterial population of the contaminated groundwater treatment system was belonging to BTEX degradation bacteria. The bacterial community consisted mainly of one genus of Pseudomonas (Pseudomonas putida group). The domination of Pseudomonas putida group may be caused by high concentration of toluene and TCE. Furthermore, we isolated a toluene and TCE degrading bacterium, named Pseudomonas sp. DHC8, from the immobilized carrier in bioreactor which was designed to remove TCE from the contaminated ground water. Based on the results of morphological and physiological characteristics, and 16S rRNA gene sequence analysis, strain DHC8 was identified as a member of Pseudomonas putida group. When TCE (0.83 mg/L) and toluene (60.61 mg/L) were degraded by this strain, removal efficiencies were 72.3% and 100% for 12.5 h, respectively. Toluene removal rate was 2.89 μmol/g-DCW/h and TCE removal rate was 0.02 μmol/g-DCW/h. These findings will be helpful for maintaining maximum TCE removal efficiency of a reactor for bioremediation of TCE.

Development and Fabrication of Heating and Water Sparging Remediation System (HWSRS) for DNAPL-contaminated Groundwater Treatment

The scope of this study was to develop, design, and build an ex-situ remediation system of using the heating and water sparging treatment for the highly volatile DNAPL (Dense Non-Aqueous Phase Liquid) contaminated groundwater, and to conduct pilot testing at the site contaminated with DNAPL. The TCE (Trichloroethylene) removal was at the highest rate of 94.6% with the water sparging at in the lab-scale test. The pilot-scale remediation system was developed, designed, and fabricated based on the results of the lab-scale test conducted. During the pilot-scale testing, DNAPL-contaminated groundwater was detained at heat exchanger for the certain period of time for pre-heating through the heat exchanger using the thermal energy supplied from the heater. The heating system supplies thermal energy to the preheated DNAPL-contaminated groundwater directly and its highly volatile TCE, (Carbontetrachloride), Chloroform are vaporized, and its vaporized and treated water is return edback to the heat exchanger. In the pilot testing the optimum condition of the HWSRS was when the water temperature at the and operated with water sparging concurrently, and its TCE removal rate was 90%. The efficiency of the optimized HWSRS has been confirmed through the long-term performance evaluation process.

Removal of trichloroethylene (TCE) from groundwater by GAC and ZVI

ABSTRACTDynamic and static test methods were used to investigate the removal efficiency of trichloroethylene (TCE) from ground water by different media of zero-valent iron (ZVI), two kinds of granular activated carbon (GAC), and a mixture of ZVI and GAC. The test results showed that ZVI, GAC, and the mixture of ZVI and GAC could effectively remove TCE. Under static conditions, the TCE removal rate by ZVI was 68.32%, the TCE removal rate by coconut shell GAC was 55.2%, and the TCE removal rate by ZVI + GAC was 90%. Under dynamic station, the mass ratio of one mixture of ZVI and GAC had the best TCE removal rate of over 85% at a flow rate of 25 ml/min.