Large flexible radar satellites are widely used in space–based remote sensing for wide–area target observation and high–capacity information transmission. To achieve accurate earth observation and structural stability of an ultra–large flexible satellite in hundred–meter length concurrently, this paper presents two–time–scale collaboration for attitude stabilization and vibration suppression. First, the coupling dynamic model of the satellite with ultra–large flexible antenna is established under space disturbances. Next, singular perturbation with boundary layer correction is employed to decompose attitude and vibration controls in different time scales, respectively. Given the respective decoupling models, the slow subsystem employs an angles–only terminal sliding–mode controller with adaptive switching and input saturation to accomplish high–robustness triaxial attitude stabilization in finite time. For the fast subsystem, distributed piezoelectric actuators with leader–follower consensus and feedback control are applicable to rapid and stable vibration suppression of the ultra–large structure. Finally, simulation results validate the effectiveness and superiority of these control methods on the satellite, where collaborative control effects on multiple key indices including attitude and vibration control accuracy and settling time are significant. This work facilitates high–accuracy and –stability collaborative control of future ultra–large satellites.