Municipal Solid Waste Treatment Research Articles

Influence of moisture content and inlet temperature on the incineration characteristics of municipal solid waste (MSW)

Incineration is an effective method for the treatment of municipal solid waste, pre-treatment reduces the waste moisture content to increase the incineration performance. However, the inlet temperature variation influenced by the environment is often ignored at this stage, and the coupling of moisture content and inlet temperature directly affects the incineration performance. To investigate the optimal inlet conditions for the incineration, the numerical model of a 600 t/d incinerator was established according to a reference case. Detailed analyses of the combustion characteristics of the bed and furnace is conducted under various moisture contents and inlet temperatures. The incineration efficiency under multiple factors is analyzed using response surface methodology, with sensitivity to these factors derived from the surface derivative. The results indicate that at an inlet temperature of 30 °C, the rates of volatile release and fixed carbon combustion are negatively correlated with the moisture content, and maximum incineration efficiency of 39.02 % is reached at a moisture content of 28.12 %. At a moisture content of 33.26 %, The rates of moisture evaporation, volatile release, and fixed carbon combustion are positively correlated with inlet temperature, and the maximum incineration efficiency of 38.76 % is achieved at an inlet temperature of 40 °C. The incineration efficiency exhibits a negative sensitivity to moisture content, whereas its sensitivity to inlet temperature is contingent upon the specific temperature range. The combination of 26.53 % moisture content and 40.86 °C inlet temperature yields the highest incineration efficiency of 40.69 %. The findings of this study provide useful information for the pre-treatment of municipal solid waste, contributing to the enhancement of operational efficiency in waste-to-energy plants.

Detecting and sourcing GHGs and atmospheric trace gases in a municipal waste treatment plant using coupled chemistry and isotope compositions

Landfill operations and waste processing facilities are important and highly heterogeneous sources of both greenhouse gases (GHGs) and non-GHG air pollutants in the atmosphere. This arises the need for detailed apportionment of waste sources in order to locate and subsequently reduce emissions from landfills. Here, a time series of in situ measurements of atmospheric trace gases and spatial allocation of specific emission source types under different processing phases and environmental conditions were conducted in and in the surroundings of a Municipal Solid Waste Treatment Plant (MSWTP) in south-western Poland. Results revealed that several individual GHG sources dominated across the waste processing facility and that GHGs concentrations displayed spatial seasonality. An increase in the ground-level CH4 concentrations, from ∼ 30.3 to 56.3 ppmv, was observed close (∼5 – 10 m) to the major emission sources within the MSWTP. While hotspot areas generally yielded elevated CH4 concentrations near the soil surface, these were relatively low (2.4 to 8.9 ppmv) along the facility’s fence line. The study of the corresponding δ13C delineated the extent of dispersion plumes downwind emission hotspots, characterized by a 13C depletion (around 4.0 ‰) in the atmospheric CH4 and CO2. For CH4, emissions were isotopically discriminated between the extraction wells at active quarters/cells (δ13C = –58.3 ± 1.1 ‰) and biogas produced in the biological waste treatment installation (δ13C = –62.7 ± 0.7 ‰). Most of the trace compounds (non-methane hydrocarbons, halocarbons, oxygen-bearing organic gases, ketones, nitrogenous and sulphurous gases, and other admixture compounds) detected at the ground surface were linked to the CH4- and CO2-rich spots. Despite the relatively high variability in the concentrations of organic and inorganic compounds observed at the MSWTP active zones, our results suggest that they do not have a meaningful impact on the surrounding air quality.

Improving biodegradability of dissolved organic matter (DOM) in old landfill leachate by electrochemical pretreatment: The effect mechanism of polarity

Enhancing the biodegradability of old landfill leachate is vital for the efficient treatment or resource utilization of municipal solid waste. Electrochemical pretreatment emerges as a promising technology for transformation of refractory dissolved organic matter (DOM). However, the specific impact of polarity on improving biodegradability of DOM remains unclear. In this study, a divided electrolyzer was used to explore the changes in the biodegradability of DOM in old landfill leachate during electrolysis. Meanwhile, the correlation mechanism between BOD5 variation and DOM evolution was explored by spectroscopy and Maldi-TOF-MS analysis. Results shown that different polarities all have positive effect on enhancing the biodegradability of DOM, while the structural changes related with BOD5 are depending on the polarity. In the anode chamber, electrochemical oxidation (EO) generates and eliminates carboxyl groups. Additionally, EO concurrently eliminates humic-like substances, which are challenging for microorganisms to degrade, and protein-like substances, which are easily degradable by microorganisms. This creates a competitive mechanism that coexist the promotion and inhibition for biodegradability. In the cathode chamber, electrochemical reduction (ER) transforms DOM components, accumulating easily useable protein components for microorganisms. Kinetic studies show that EO related BOD5 changes are aptly described by a competition model, considering both generation and removal of bioavailable components. ER related BOD5 changes suit a pseudo-first-order kinetic model. These insights into the transformation of old leachate DOM support the development of methods predicting BOD5 evolution, crucial for future process optimization.

Unveiling dioxin dynamics: A whole-process simulation study of municipal solid waste incineration

Theoretical research has explained the process of dioxin (DXN) formation in the municipal solid waste incineration (MSWI). This process includes the generation, adsorption, and emission of DXN. Actual DXN concentrations often significantly deviate from theoretical models. This discrepancy is influenced by several key factors: the type of integrated municipal solid waste (MSW) treatment process, the characteristics of the waste, and the operational controls. The progression of DXN generation, adsorption, and emission concentrations within the MSWI process remains unclear. This lack of clarity is especially pronounced when examining the accounting for the specific components of the MSW. To unravel the evolution of DXN, this article proposes a comprehensive numerical simulation model for the entire process of DXN concentration in an MSWI plant. The model is designed based on existing knowledge of MSW combustion and DXN mechanisms, leveraging FLIC and ASPEN simulation software. It incorporates six key stages to facilitate the DXN simulation: precipitation and formation, high-temperature pyrolysis, high-temperature gas-phase synthesis, low-temperature catalytic synthesis, adsorption on activated carbon, and emission to the atmosphere. Under both benchmark and multiple operating conditions, the simulated experiments confirm the effective representation of the evolution of DXN concentrations throughout the process. Consequently, this study presents a model designed to enhance the development of strategies aimed at reducing DXN emissions and to foster innovation in intelligent control technologies.

Study on the Preparation and Performance of Lightweight Wallboards from MSWIBA Foam Concrete.

To reduce land use and avoid further pollution, incineration for power generation has become the main method for municipal solid waste treatment. This research focused on the potential for transforming Municipal Solid Waste Incineration Bottom Ash (MSWIBA) into a finely ground powder. The impact of the powder's fineness and the amount of water used on its effectiveness was analyzed using a method called grey theory. MSWIBA was used as a partial substitute for cement in making MSWIBA foam concrete and lightweight wall panels. By modifying the fineness and water utilization of the recycled micro-powder, its maximum activity index can be increased to 90.1. This study determined the influence of factors including apparent dry density, water-cement ratio, foaming agent dilution ratio, and admixture dosage on the strength of the recycled foam concrete, and established the optimal mix ratio. This study employed a combination of physical experiments and numerical simulations to elucidate the impact of panel material, core layer thickness, and layer sequence on sound insulation performance. The simulation results were in close agreement with the experimental findings.

Influence of Aeration, Introduction of Probiotics, and Supply of Water on Landfill Gas Production—Study of Models

When municipal solid waste (MSW) is placed in a landfill, it undergoes anaerobic decomposition, leading to the production of landfill gas, which primarily consists of methane (CH4) and carbon dioxide (CO2). Reducing methane emissions is essential in the fight against climate change. It must be implemented at global and European levels, as set out in 2030 in the impact assessment of the climate goal plan. This assessment states that to achieve the goal by 2030 and to reduce greenhouse gas emissions by at least 55%, the methane emissions must be reduced, considering the goals of the Paris Agreement. The Glasgow Climate Pact includes a global mitigation target of the year 2030: to reduce CO2 emissions by 45%, and the emissions of methane and other greenhouse gasses. For that purpose, looking for new, more advanced ways of managing such waste is necessary. The main objective of this experimental study was to evaluate the influence of aeration, probiotic introduction, and water supply on the production of landfill gasses (CO2, CH4, N2, H2, etc.) in five different landfill models during the management of MSW and to propose the best solutions for reducing environmental pollution. The results of the research showed that the first and second models of landfills, using only anaerobic conditions, can be used for the treatment of MSW for the production of biogas (CH4, CO2), as up to 40–60% of it was released during the 120-experiment period. The third landfill model can be applied in old, already closed landfills, where the rapid stabilization and aeration of MSW are required to minimize pollutant emissions (N2, etc.) and unwanted odors and shorten biodegradation processes. The results of the fourth and fifth landfill models, in which aerobic–anaerobic conditions were applied, showed that the developing nitrification–denitrification processes resulted in complete nitrogen removal (from 20% to 0%), and overall waste stabilization improved the biodegradation of the MSW. Later, relatively good (on average, 30%) results of biogas (CH4, CO2) emissions are achieved during anaerobic condition formation results. Summarizing all experiment results of all landfill models for the further evaluation of the processes, all models can be applied in real practice depending on where they will be used and what result they want to achieve.

Sustainability Indicators to MSW Treatment Assessment: The Rio de Janeiro Case Study

The Brazilian Policy foresees the waste management hierarchy, according to which energy reuse from waste is preferred to final disposal. However, less than 0.2% of the country’s waste goes to energy production. This paper proposes sustainability indicators to support the decision to choose the best process to treat municipal solid waste (MSW) through bioenergy generation technologies. Then, we conduct a case study for Rio de Janeiro. Incineration and gasification were not economically feasible—despite TRL 9 and 8. However, the projects presented a null net present value by increasing the gate fee to 94.69 and 255.39 USD/ton of MSW, respectively. The social indicators (job creation, salary increase with the absorption of waste pickers, population served, reduction in MSW sent to landfill) did not indicate the best technology. The results of the environmental indicators for incineration and gasification were, respectively, 0.45 and 0.37 t CO2eq/tMSW for GWP, 1.49 and 1.23 MWh/tMSW for energy intensity, 1.24 and 6.14 m3/tMSW for water intensity, 39.3 and 27.9 m2/tMSW for land use and 0.135 and 0.088 t SO2eq/tMSW for acidification. Gasification presented better results on 60% of the environmental indicators. However, incineration scored better in the important ones, water and energy intensities, in addition to the technical–economic aspect.

Data-driven multi-objective intelligent optimal control of municipal solid waste incineration process

The municipal solid waste incineration (MSWI) process has become the primary technology for municipal solid waste (MSW) treatment worldwide due to its advantages of harmlessness, reduction, and resource recovery. However, the automatic combustion control (ACC) system developed in developed countries are often not effectively applicable to other countries, particularly China, due to regional differences in MSW composition. To achieve intelligent development of MSWI plants, it is crucial to develop intelligent optimal control technology tailored to national conditions to reduce comprehensive pollutant emission concentration (CPEC) and improve combustion efficiency (CE). This article proposes a data-driven multi-objective intelligent optimal control strategy. Firstly, based on the analysis of the whole process, the Tikhonov regularization-least regression decision tree (TR-LRDT) algorithm is used to establish a MSWI whole process model, incorporating serial controlled objects and parallel pollutant indicators, to support a multi-objective optimization model. Then, leveraging the ACC system and expert experience, a multi-input multi-output loop controller is established using the single neuron adaptive PID (SNA-PID) algorithm to achieve stable control of key controlled variables. Next, a mutation crossover strategy and termination condition are integrated with the multi-objective particle swarm optimization (MOPSO) algorithm to solve the multi-objective optimization model, and domain expert rules are applied to determine the optimal setpoints for key controlled variables in the Pareto front, aiming to reduce CPEC and improve CE. Finally, the effectiveness of the proposed intelligent optimal control strategy is validated using actual data. The experimental results demonstrate that this strategy not only maintains the stability of key controlled variables but also decreases CPEC by 1.82% and increases CE by 2.38%, laying a foundation for further research into intelligent optimization control of the MSWI process. Further, the software system based on the proposed strategy is developed and validated on a hardware-in-loop simulation platform.

Dual roles of odor cleaners and pollutant producers for chemical scrubbing and biological treatment: Evidence in a food waste anaerobic digestion plant

The odor generated during municipal solid waste and wastewater treatment is a major source of public complaints worldwide. Chemical scrubbing and biological treatment are commonly used to control the odor. However, in this study, such odor control measures were found to produce derived odorous compounds and greenhouse gases, leading to reduced efficiency or uncertainty in odor treatment. In a food waste anaerobic digestion plant, a series of site and lab investigations were conducted on the odor control performance and mechanisms, as well as secondary pollutants of chemical scrubbing and biotrickling. Methanethiol, hydrogen sulfide (H2S), propanethiol, and acetaldehyde were identified as the top four odor contributors to the gas collected in the plant. The mechanisms of acetaldehyde and propanethiol removal in the chemical scrubbers were studied using gas-washing bottles. Acetaldehyde was mainly removed via physical absorption, whereas propanethiol could be completely removed via oxidation by sodium hypochlorite (NaClO). However, acetaldehyde was desorbed from the absorption solution and generated from the oxidation of ethanol by NaClO in the chemical scrubbers, leading to low, or even negative removal efficiency. H2S, methanethiol, propanethiol, and acetaldehyde could be abated by the biotrickling filters. However, H2S, methanethiol, propanethiol, and greenhouse gases could be also produced under anaerobic conditions, particularly when the packings were compacted. Furthermore, acetaldehyde could be produced from ethanol by bacteria possessing dehydrogenase under aerobic conditions. Both chemical scrubbers and biotrickling filters demonstrated the dual roles of odor removal and pollutant production.

Assessment of 150 TPD mechanical biological treatment (MBT) based municipal solid waste treatment and disposal facility

Assessment of 150 TPD mechanical biological treatment (MBT) based municipal solid waste treatment and disposal facility

Integrated assessment of environmental and economic impact of municipal solid waste incineration for power generation: A case study in China

Municipal solid waste incineration for power generation is significant for reducing and reusing solid waste. The study conducted an integrated assessment of environment and economy on municipal solid waste incineration in China, from a “cradle to grave” perspective using 1 tonne of municipal solid waste incineration as the functional unit. The environmental impacts of each month are also calculated to analyze the dynamic change throughout one year. The results indicate that the environmental impacts are mainly concentrated in marine ecotoxicity, freshwater ecotoxicity, human carcinogenic toxicity, and human non-carcinogenic toxicity. Flue gas purification, waste incineration and transportation are the key processes, which account for 65.61 %, 18.50 %, and 11.93 % of the overall environmental impact, respectively. Urea, activated carbon, chelating agent (EDTA) and diesel fuel for transportation are key factors. The life cycle cost (LCC) is 132.26 RMB/t of waste, of which the initial capital causes the largest economic cost. When considering power generated from municipal solid waste incineration to replace electricity supply from the power grid, it achieves significant environmental benefits and the normalized environmental impact value changes from 0.85 to −12.19. The findings provide references for municipal solid waste treatment to mitigate the environmental impact and reduce the economic burden across the entire life cycle.

New insight into the spatio-temporal patterns of functional groups of hotspot inside the composting aggregates by synchrotron-based FTIR in hyperthermophilic composting

Hyperthermophilic composting (HTC) is a recently developed and highly promising organic fraction of municipal solid waste (OFMSW) treatment technology. Investigation of organic matter (OM) dynamics in compost particle is thus crucial for the understanding of humification of HTC process. Herein, this work aimed to study the chemical and structural changes of OM at the molecular level during HTC of OFMSW using EEM and SR-FTIR analyses. Additionally, two-dimensional correlation spectroscopy (2D-COS) was also utilized to probe and identify the changes in chemical constituents and functional groups of organic compounds on the surface of compost particles during different composting periods. Results show that SR-FTIR can detect fine-scale (~μm) changes in functional groups from the edges to the interior of compost particles during different composting periods by mapping the particles in situ. In the hyperthermophilic stage (day 9), the extracted μ-FTIR spectrum reveals a distinct boundary between anaerobic and aerobic regions within the compost particle, with a thickness of anaerobic zone (1460 cm−1) of approximately 30 μm inside the particle's core. This provides direct evidence of anaerobic trends at compost microscales level within compost particles. 2D-COS analysis indicated that organic functional groups gradually agglomerated in the order of 1330 > 2930 > 3320 > 1600 > 1030 > 895 cm−1 to the core skeleton of cellulose degradation residues, forming compost aggregates with well physicochemical properties. Overall, the first combination of SR-FTIR and EEM provides complementary explanations for the humification mechanism of HTC, potentially introducing a novel methodology for investigating the environmental behaviors and fates of various organic contaminants associated with OM during the in-situ composting biochemical process.

Carbon emission of municipal solid waste under different classification methods in the context of carbon neutrality: A case study of Yunnan Province, China

Carbon emissions from municipal solid waste (MSW) are one of the major sources of greenhouse gases. As the world’s largest emitter of carbon, China faces a critical challenge in reducing its carbon footprint. This study first employed the STIRPAT model to forecast the production of MSW in Yunnan Province, then followed the Intergovernmental Panel on Climate Change (IPCC) recommended methodologies to calculate and predict the carbon emissions from MSW under four scenarios based on different waste classification methods. The research found that per capita Gross Domestic Product (GDP) and urbanization rate positively influence the generation of MSW, while the proportion of the secondary industry had the opposite effect. Front-end sorting in MSW management is crucial, as enhancing the recycling rate of MSW was a determinative factor in reducing carbon emissions from MSW management. Scenario 1, based on the current situation, resulted in carbon emissions of 3.62 MtCO2-eq; whereas, adopting new classification methods in Scenario 4, carbon emissions were reduced to −1.42 MtCO2-eq. In Scenario 1, landfilling remained the primary source of carbon emissions in waste treatment, accounting for 70.69%. Achieving carbon neutrality in the MSW treatment process is possible when the recycling rate approaches 50%, and the landfill proportion does not exceed 6%. The study indicates that Scenario 4 offers the best carbon reduction outcome, and the results reveal that promoting waste classification to improve recycling rates is the most effective carbon reduction strategy in MSW management. This study proposed a practical MSW classification pathway to achieve negative carbon emission, which provides valuable guidance for the MSW management.

Optimizing life cycle sustainability based on municipal solid waste streams and treatment potentials

Optimizing life cycle sustainability based on municipal solid waste streams and treatment potentials

Graphene Derived from Municipal Solid Waste.

Landfilling is long the most common method of disposal for municipal solid waste (MSW). However, many countries seek to implement different methods of MSW treatment due to the high global warming potential associated with landfilling. Other methods such as recycling and incineration are either limited to only a fraction of generated MSW or still produce large greenhouse gas emissions, thereby providing an unsustainable disposal method. Here, the production of graphene from treated MSW is reported that including treated wood waste, using flash Joule heating. Results indicated a 71%-83% reduction in global warming potential compared to traditional disposal methods at a net cost of -$282 of MSW, presuming the graphene is sold at just 5% of its current market value to offset the cost of the flash Joule heating process.

Anaerobic digestion or composting? Small-scale plants design and holistic evaluations in a Sub-Saharan African context

In small developing settings, is it worth building anaerobic digestion (AD) or composting plants? This study explores the economic, management, and environmental dimensions of two small-scale alternatives for organic fraction municipal solid waste (OFMSW) treatment within the context of Lacor Hospital (Uganda): aerated static pile composting (S1) and AD with digestate composting (S2), both designed to manage approximately 347.5 tOFMSW annually. In the optimistic scenario, S1 achieves a cost savings of about −2.9 USD tOFMSW−1, while S2 incurs costs of 2.1 USD tOFMSW−1. In the pessimistic scenario, S1's costs rise to 3.9 USD tOFMSW−1, while S2 becomes more expensive at 9.5 USD tOFMSW−1. Management analysis underlines S2's complexity due to AD operations and digestate drying. Total normalized environmental impacts of S1 can be quantified with about 0.125 mPt tOFMSW−1, whereas S2 is equal to about −6.163 mPt tOFMSW−1. However, in an optimistic scenario, climate change endpoint category results are similar. On balance, the LCA analysis indicates that AD can be better than standalone composting. However, in developing settings serving approximately 3000 inhabitants, it is crucial to prioritize economic and management sustainability that can be obtained only by small-scale composting plants. These findings provide definite insights for small-scale waste management projects in low-income regions, offering valuable data and references for plant design and their replicability. The study sets the ultimate definition of the most feasible option to treat OFMSW in low-income settings: community composting. Unfortunately, economic barriers remain the main challenge: citizens should pay for the service and landfill management fees should be set by local governments.

Prediction and Feed-In Tariffs of Municipal Solid Waste Generation in Beijing: Based on a GRA-BiLSTM Model

To cope with the increasing energy demand of people and solve the problem of a “Garbage Siege”, most cities have begun to adopt waste power generation (WTE). Compared to other WTE technologies, incineration has proven to be the most efficient technology for municipal solid waste (MSW) treatment. Therefore, to further explore the economic feasibility of MSW incineration plant construction, this study established a multi-factor prediction of MSW generation based on the GRA-BiLSTM model. By fully considering the relationship between the change in feed-in tariff (FIT) and the building of an incineration plant in Beijing, the economic feasibility of building an incineration plant is discussed based on the three scenarios set. The experimental results showed that (1) the combined model based on the GRA-BiLSTM showed good applicability for predicting MSW generation in Beijing, with MAE, MAPE, RMSE, and R2 values of 12.47, 5.97%, 18.5580, and 0.8950, respectively. (2) Based on the three scenarios set, the incineration power generation of Beijing MSW will show varying degrees of growth in 2022–2035. In order to meet future development, Beijing needs to build seven new incinerators, and the incineration rate should reach 100%. (3) According to setting different feed-in tariffs, based on the economic feasibility analysis, it is found that the feed-in tariff of MSW incineration for power generation in Beijing should be no less than $0.522/kWh. The government should encourage the construction of incineration plants and give policy support to enterprises that build incineration plants.

Cooperative treatment and resource utilization of municipal solid waste by industrial coke ovens: Effects of doping ratio and management

For the collaborative treatment and resource utilization of an industrial coke oven on municipal solid waste (MSW), this study used MSW to prepare refuse-derived fuel (RDF). The influence of different mix ratio between RDF and coal on coking products was considered, and technical and economic analyses were conducted. The results showed that under the low mixture ratio (3%), the pyrolytic carbon obtained basically met the class III standard of metallurgical carbon. In the experiment of medium mixture ratio (25%, 30%, 35%), the product contained a certain amount of calorific value, lower than that of the metallurgical coke. It might be that the ash content increased, and such product can be used for civil coke or chemical coke. When the mixture ratio was 100%, the calorific value of pyrolysis carbon was 7.53 MJ/kg, representing 25.7% of the calorific value of ordinary coke. The gas production rate of the discharged gas was 0.35, and the calorific value is 14.0 MJ/kg, reaching 73.6% of the coke oven gas. Under the condition of no coal input, the MSW was converted into usable energy. The results demonstrated that coke oven pyrolysis with 100% RDF addition is the most feasible way to recycle resources and energy.

Forecasting the Mitigation Potential of Greenhouse Gas Emissions in Shenzhen through Municipal Solid Waste Treatment: A Combined Weight Forecasting Model

As a significant source of anthropogenic greenhouse gas emissions, the municipal solid waste sector’s greenhouse gas emission mode remains unknown, hampering effective decision-making on possible greenhouse gas emission reductions. Rapid urbanization and economic growth have resulted in massive volumes of municipal solid trash. As a result, identifying emission reduction routes for municipal solid waste treatment is critical. In this research, we investigate the potential of municipal solid waste treatment methods in lowering greenhouse gas (GHG) emissions in Shenzhen, a typical Chinese major city. The results showed that the combined treatment of 58% incineration, 2% landfill, and 40% anaerobic digestion (AD) had the lowest greenhouse gas emissions of about 5.91 million tons under all scenarios. The implementation of waste sorting and anaerobic digestion treatment of organic municipal solid waste after separate collection can reduce greenhouse gas emissions by simply increasing the incineration ratio.

Pyrolysis, a recovery solution to reduce landfilling of residual organic waste generated from mixed municipal waste

Despite policies to restrict the mixing of organic waste with other general waste and improve its separation at source, municipal solid waste still contains a high proportion of organic waste. The residual organic waste is generated as a by-product of the mechanical treatment of municipal solid waste (MSW) and is mainly disposed in landfills after composting. Its reuse and recovery status varies across European countries. Most countries restrict the use of biostabilised residual waste (BSRW) to landfill cover, whereas others have regulated it as marketable compost. Crucially, BSRW is set to lose its “recycled” status under the revised European Union waste framework, with probably tighter restrictions and increased costs imposed for the landfilling of organic waste. Our research aimed to investigate pyrolysis as an alternative technology to treat the 10–40 mm fraction of BSRW (representing 50% of BSRW generated). Pyrolysis at 700 °C was carried out and feedstock and pyrolysis products were characterized. Mass and energy balances showed that pyrolysis produced hot vapour/gas whose combustion may render the pyrolysis process energetically sustainable. Biochar comprises 30–50% of BRSW mass after removal of glass, metal and stones. Our results indicate that pyrolysis has the potential to create options for contributing to reduce the landfilling of BSRW; however, the presence of residual impurities may limit biochar applications.