Treatment Of Paper Mill Wastewater Research Articles

Microbial Community Organization during Anaerobic Pulp and Paper Mill Wastewater Treatment

Microbial Community Organization during Anaerobic Pulp and Paper Mill Wastewater Treatment

Advancing cobalt ferrite-supported activated carbon from orange peels for real pulp and paper mill wastewater treatment

The utilization of agriculture waste-based adsorbents in the treatment of real industrial wastewater represents an unexplored frontier with significant potential. In this study, the cobalt ferrite-supported activated carbon derived from orange peels (CF40-AC) was used as a magnetic adsorbent for the treatment of real pulp and paper mill effluent (PPME). Detailed insights into the properties and functionalities of the CoFe2O4-AC adsorbent were obtained through an accurate characterization analysis that included X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), BET and pore size histogram techniques. Both pure activated carbon (AC) and CF40-AC displayed excellent textural properties with surface area (SBET) equal 2014 and 1345 m2.g−1, respectively. TEM and SEM images display that the magnetic ferrites were well dispersed on the surface of AC. Following the characterization process, the CoFe2O4-AC adsorbent was evaluated for its ability to remove several key pollutants from PPME, including chemical oxygen demand (COD), total dissolved solids (TDS) and turbidity. Moreover, various operational parameters, such as pH, adsorbent dosage, contact time, and stirring rate, were investigated to achieve optimal contaminants removal rates. Remarkably, the CoFe2O4-AC adsorbent demonstrated highly efficient removal rates, with 86.9%, 59,9% and 93.1% for COD, TDS and turbidity, respectively, under optimal conditions (pH 7, adsorbent dose 0.4 gm, contact time 60 min, and stirring rate 150 rpm). The CoFe2O4-AC composite material exhibits promising potential for multiple applications reached 5 cycles without a significant loss in its adsorption or functional properties over successive uses. These results favor the promising potential of CoFe2O4-AC as a sustainable and efficient solution for addressing wastewater treatment challenges in the pulp and paper industry, contributing to both environmental protection and resource conservation.

Optimization and PID Control of pH and Temperature in an Electrocoagulation Process

In this work, effects of temperature and pH in batch treatment of pulp and paper mill wastewater using electrocoagulation has been investigated. Conductivity, temperature, and pH are selected as controlled variables; supporting electrolyte, cooling water, acid and base flow rates are selected as manipulated variables, respectively. Real time experimental multi input-multi output (MIMO) control of conductivity, temperature, and pH under constant current conditions are achieved using MIMO Proportional Integral Derivative (PID) control algorithms coded in MATLAB™. A central composite design (CCD) has been applied to the system under controlled conditions and optimum pH and temperature values are obtained using response surface methodology (RSM). Both controlled and uncontrolled experiments are performed using optimum values and results are compared in terms of removal efficiencies of pollutants. Results show that 34.47% chemical oxygen demand (COD), 98.06% total suspended solids (TSS), 99.80% turbidity, 99.93% color, and 13.40% SO42- removal is achieved in 45 minutes of process operation under controlled conditions and COD, TSS, turbidity, color and SO42- removal are increased by 10.92, 2.97, 4.06, 2.89, 3.17 respectively in comparison with uncontrolled operation. The highest removal percentages are obtained under controlled operating conditions as 98.5% and 98.3% for turbidity and color, respectively, for 10 minutes operation. It is concluded that optimum process operating conditions for removal of turbidity and color of pulp and paper mill wastewater is obtained under constant 6.45 pH, 23.24 °C temperature, 1.78 mS/cm conductivity, and power consumption is reduced by 25.3% under controlled conditions.

Porous ceramsite catalytic ozonation for the treatment of pulp and paper mill wastewater in a continuous-flow reactor

The pollutants in wastewater can be degraded effectively by heterogeneous catalytic ozonation due to the production of hydroxyl radical (•OH) with strong oxidation power. For the natures of low weight, large specific surface area, excellent physical strength and stable chemical characteristics, the porous ceramsite was chosen for catalytic ozonation of wastewater in the present study, and the practical application parameters of the system were investigated for the actual pulp and paper mill wastewater (PPMW) in the continuous-flow reactor including temperatures, feeding flow rate, O3 flow rate and O3 dosage. The optimum experimental conditions were obtained (T = 25 ℃, feeding flow rate = 0.25 L/min, O3 flow rate = 0.5 L/min, O3 dosage = 15 g/L) for the process of catalytic ozonation. The results show that the effluent concentration of COD decreases from about 200 mg/L to 10 mg/L, namely the removal efficiency is about 95 %. The stability of the catalyst over time was tested in the continuous-flow reactor for 48 days, confirming that the porous ceramsite exhibits good performance in 30 days. The reusability of the catalyst was studied after the used catalyst was washed with Milli-Q water and ethanol, exhibiting good catalytic activity of the regenerated catalyst in three cycles. The fluorescent excitation-emission matrix (EEM), UV–vis analysis and GC–MS analysis were used for analyzing the organic pollutants in raw PPMW and after treatment. These results indicate that the process of catalytic ozonation with porous ceramsite has a high treatment efficiency on PPMW, and the continuous-flow reactor can be more practically used for a full-scale community PPMW application at a mill level.

Effect of temperature on product properties and synergies during the co-pyrolysis of paper sludge and corn stover

Paper sludge (PS), a by-product of paper mill wastewater treatment, has attracted increasing attention due to the dual nature of resources and pollution. This study focused on investigating the effect of temperature on the product properties and synergies of the co-pyrolysis process involving PS and corn stover (CS) using a fixed bed reactor. The results showed that co-pyrolysis led to an increase in the production of bio-oil, while reducing the formation of char and gases. Notably, the most significant synergistic effect was observed at 600 °C, where the experimental bio-oil yield surpassed the calculated value by 8.9%. At temperatures below 500 °C, ketones, aldehydes, and acids were the predominant products in the co-pyrolysis, which shifted towards phenols and aromatics as the temperature increased. Moreover, a promotion of CO content and an inhibition of CO2 content with temperature were also observed during co-pyrolysis, suggesting that higher temperatures facilitated synergistic decarbonylation. The co-pyrolysis biochar exhibited a higher abundance of carbonyl and alkyl groups compared to the biochar derived from PS pyrolysis, and the synergistic effect at higher temperatures promoted the development of micropores within the co-pyrolysis biochar. These findings emphasize the temperature-dependent nature of the co-pyrolysis process, offering valuable insights into the potential resource utilization of PS and CS wastes.

Autogenous iron-based peroxidase-like nanozyme from paper mill sludge for ascorbic acid detection

The high-value conversion of waste resources to carbon materials offers an opportunity to alleviate the resource crisis. Owing to their low cost and easy preservation, iron-based nanoenzymes are receiving increasing attention in the fields of catalysis, detection and biomedicine. In this work, for the first time, paper mill sludge (PMS), which contains iron ions from a flocculant used in paper mill wastewater treatment, is used as a precursor to produce iron-doped carbon quantum dots (Fe-CQDs) by oil bath pyrolysis process. The synthesized Fe-CQDs with carboxyl groups and abundant carbon-deficient structure, exhibit higher peroxidase-like activity. Compared to horseradish peroxidase (HRP), Fe-CQDs have a better affinity for the substrate and better stability. Based on the good affinity of Fe-CQDs for H2O2, a rapid colourimetric assay for ascorbic acid (AA) detection was developed with a wide range of 1–120 μM and a detection limit of 0.435 μM (3σ/k). The peroxidase-like activity of Fe-CQDs has been proved to originate from their ability to catalyze H2O2 to produce·OH, and successfully applied to determine AA content in the roots and leaves of sweet potato. This work indicates the reliability of the method in practical application and provides a greening strategy for the value-added utilization of solid sludge.

제지폐수 3차처리를 위한 전해산화공정 적용성 평가

제지폐수 3차처리를 위한 전해산화공정 적용성 평가

Catalytic Ozonation for Pulp and Paper Mill Wastewater Treatment: COD Reduction and Organic Matter Degradation Mechanism

Rapid degradation of pulping and papermaking wastewater in a pulp and paper mill is crucial for recycling purposes yet challenging to achieve. The purpose of this research is to provide a technical guide for the ozone degradation treatment process of pulp and paper mill wastewater and to explore the reaction mechanism of dissolved and colloidal substances (DCSs). This study is vital for effectively treating pulp and paper mill wastewater through ozonation. In the catalytic ozonation process to treat pulp and paper mill wastewater, a polyurethane sponge loaded with titanium dioxide was used as a catalyst. The optimal process conditions were determined to be 8 min of treatment time, a 16 mg/L ozone concentration, pH 9, and a 7.5% catalyst filling ratio. The COD reduction under these conditions is approximately 52%. The catalytic ozonation system, according to the FI-IR and GC-MS analyses, could degrade the large-molecule volatile organic compounds in the raw wastewater into small-molecule substances. Furthermore, the relative content of common DCSs in paper wastewater, such as palmitic acid and stilbene, could be reduced. The catalytic ozonation system is more effective for treating refractory organic compounds and has a higher COD reduction than the ozonation system.

Ultrasound‐assisted photo‐Fenton process for treatment of pulp and paper mill wastewater and reduction of phytotoxicity

AbstractThe efficiency of classical Fenton (CF) and modified Fenton (MF) as well as photo‐Fenton processes in real wastewater treatment of pulp and paper (P&P) mill was investigated in this study. The chemical oxygen demand (COD) was chosen as the reference measurement for evaluating the treatment's efficiency. After determining the optimum parameters for each process, the effect of adding ultrasound (US) on improving treatment efficiency was examined. In addition, kinetic study and phytotoxicity analysis were conducted under optimum conditions for all processes. With pH 4, reaction time 50 min, 1.2 g/L Fe2+ and 8 g/L H2O2 dosages, the best removal efficiency (RE) of COD was determined to be 82.18% in CF process, and this rate rose to 90.1% when US was added. The best RE in MF process was 84.16% with the application of UV‐C, pH 4, reaction time 50 min, 1 g/L Fe0 and 8 g/L H2O2 doses, although it increased to 93.4% when US was applied. The greatest results in the seed germination test were achieved in US processes with 100% of germination percentage (GP) for spinach and tomato and 90% for cress. In the economic evaluation, when conducting the treatment without US, the estimated relative cost decreased in a 15 and 16%, for CF/UV‐C and CF processes respectively, whereas the CF process was 64% cheaper than the MF process in all applications. The US contributed to enhanced water treatment efficiency by having a significant synergistic impact on Fenton applications. Hence, the combination of photo‐Fenton and ultrasound to treat effluent from P&P mills proved to be an effective and promising technique.

The Ability of a Bacterial Strain to Remove a Phenolic Structure as an Approach to Pulp and Paper Mill Wastewater Treatment: Optimization by Experimental Design

High-colored wastewater generated during the cellulose bleaching process causes the inhibition of biological activity when released into the environment. This study aimed to evaluate the bacterium’s capacity, identified as RGM2262, to degrade a complex phenolic structure such as lignin, which is found in high concentrations in the effluents generated during the production of cellulose, raw material for the manufacture of paper. To determine the values of the experimental variables that allow for a greater degradation of organic matter, an experimental model was carried out through experimental design. Thus, the experimental matrix was obtained with the variables pH 7 (−1) to 9 (+1) and a treatment time of 1 day (−1) to 5 days (+1). The results show that, at pH 8 and pH 9, both treatments—with bacteria in bio-films and without bio-films—were efficient. On the second day of treatment, 100% of the color and the phenolic structure were removed, with a similar rate constant, and at the same time, 80% COD and 70% of TOC, respectively.

Cometabolic bacterial and fungal remediation as a promising strategy for recycled paper and cardboard mill wastewater treatment

PurposeThis paper aims to study the application of high-tolerance and flexible indigenous bacteria and fungi, along with the co-metabolism in recycled paper and cardboard mill (RPCM) wastewater treatment (WWT).Design/methodology/approachThe molecular characterization of isolated indigenous bacteria and fungi was performed by 16S rRNA and 18S rRNA gene sequencing, respectively. Glucose was used as a cometabolic substrate to enhance the bioremediation process.FindingsThe highest removal efficiency was achieved for both chemical oxygen demand (COD) and color [78% COD and 45% color removal by Pseudomonas aeruginosa RW-2 (MZ603673), as well as approximately 70% COD and 48% color removal by Geotrichum candidum RW-4 (ON024394)]. The corresponding percentages were higher in comparison with the efficiency obtained from the oxidation ditch unit in the full-scale RPCM WWT plant.Originality/valueIndigenous P. aeruginosa RW-2 and G. candidum RW-4 demonstrated effective capability in RPCM WWT despite the highly toxic and low biodegradable nature, especially with the assistance of glucose.

Indigenous bacteria as an alternative for promoting recycled paper and cardboard mill wastewater treatment

The present study aimed to investigate indigenous bacteria possibility in recycled paper and cardboard mill (RPCM) wastewater treatment through the isolation and identification of full-scale RPCM indigenous bacteria. The molecular characterization of the isolated bacteria was performed by 16S rRNA gene sequencing. Klebsiella pneumoniae AT-1 (MZ599583), Citrobacter freundii AT-4 (OK178569), and Bacillus subtilis AT-5 (MZ323975) were dominant strains used for RPCM wastewater bioremediation experiments. Under optimal conditions, the maximum values of chemical oxygen demand (COD) and color biodegradation by C. freundii AT-4 were 79.54% and 43.81% after 10 days of incubation, respectively. In the case of B. subtilis strain AT-5 and K. pneumoniae AT-1, the maximum values of COD and color biodegradation were 70.08%, 45.96%, 71.26%, and 32.06%, respectively. The results from optimal conditions regarding efficiency were higher in comparison with the efficiency obtained from the oxidation ditch treatment unit in full-scale RPCM-WWTP. Therefore, the present study introduces the isolated indigenous bacteria strains as a promising candidate for improving the RPCM-WWTP efficiency using bioremediation.

Response Surface Methodology for Treatment of Paper Mill Wastewater by Using Inorganic Polymeric Coagulant

Response Surface Methodology for Treatment of Paper Mill Wastewater by Using Inorganic Polymeric Coagulant

Developing the nitrogen handprint approach to quantify the positive impacts of industrial symbiosis on nitrogen cycles

Excessive nitrogen (N) uptake for nutrient use in food production and industry and increased N losses to the environment severely interfere with nutrient cycles and harm the environment and thus, closing N cycles through N recovery and recycling is required to improve N use efficiency. To quantify positive impacts enhancing N cycles, this study suggests a novel N handprint approach, which combines life cycle assessment based nutrient footprint and carbon handprint approaches. The N handprint comprises of a set of indicators providing a wide systemic view on changes in N cycles. The case study demonstrates that the N handprint is created when a recycled N nutrient product is used instead of a virgin N nutrient for the needs of a pulp and paper mill wastewater treatment. According to our results, the handprint equals a reduction of 454 kg of virgin N inputs, and 5.6 kg of total N inputs for daily treated wastewater. Additionally, global warming potential is 91%, and the eutrophication potential 48% lower for the recycled N nutrient than for the virgin N nutrient. These results can be used to promote the use of recycled N on similar occasions in order to improve nutrient use efficiency. • The nitrogen (N) handprint approach aims to highlight efficient nutrient use. • The approach is combining carbon handprint and nutrient footprint. • The approach is applied to N recycling in an industrial symbiosis. • N handprint enables to show positive environmental impacts of circular N solutions.

Batch Electrochemical Treatment of Raw Pulp and Paper Mill Wastewater Using Electrode Combinations

SS and Cu electrodes were used in the electrochemical coagulation to treat pulp and paper mill wastewater using 4SS and 3SS 1Cu electrodes by applying cell voltages 12 – 24 V. Optimal cell voltage 18V showed COD removal of 89.64% for 4SS electrode and 84.74% for 3SS 1Cu electrode with simultaneous color removal of 99% and 90%. Other control factors used for optimal operation are sludge volume index (SVI), filterability, etc. SVI values were <100 mL/g for 4SS electrodes. The filtration characteristics of the ECC-treated sludge were established to determine the specific cake resistance (α) and the resistance of the filter medium (Rm). Lower α and Rm values for 4SS and 3SS-1Cu electrodes were found at 60 min ET. Proximate and ultimate analyses showed that 4SS and 3SS-1Cu sludge could be used as additive as well as adsorbent material for treating low strength wastewater.

Influence of the characteristics of paper mill sludges on their anaerobic digestion.

The objective of this study was to characterise the anaerobic degradation of three paper mill waste water treatment residues in the shape of sludges and to correlate this anaerobic digestion to the physico-chemical characteristics of the paper sludges. After a deep characterisation of each paper sludge in their initial stage, several parameters were analysed on each paper sludge in mesophilic conditions for 40-50 days: pH, conductivity, chemical oxygen demand, total organic acids and organic fibres degradation. A special care was taken to identify and quantify the volatile fatty acids (VFAs) produced by the digestion using gas chromatography coupled with a mass spectrometer. The results showed that in paper sludges, cellulose mainly degrades over time while the degradation of the other fibres (hemicellulose and lignin) is limited. Consequently, the greater the cellulose content in a paper sludge, the greater the digestion and formation of VFAs. However, not all the cellulose degrades because of a shielding effect of lignin on cellulose, and a pH buffering effect of the calcium carbonate present in the paper sludges limits the hydrolysis-acidogenesis step of the anaerobic digestion. Finally, the gas chromatography-mass spectrometry (GC-MS) investigations showed that acetic acid is the main VFA produced by the anaerobic digestion of paper sludges. This work helps predicting paper mill sludge evolution in the purpose of using them in circular economy.

Removal of colour and lignin from paper mill wastewater using activated carbon from plastic mix waste

The study aimed at the use of char produced during pyrolysis of mix plastic waste. It further focused on producing activated carbon from char and also found its efficacy as efficient adsorbent for treatment of pulp and paper mill wastewater. The activated carbon was characterized in comparison with raw char for their physical, surface and adsorptive properties. Batch type adsorption experiments were carried out using 100 ml wastewater to observe the individual effectiveness using five different variables such as adsorbent dose (0.25–2.0 g), pH (6–10), time (5–24 h), agitation speed (100–200 rpm) and temperature (30–50 °C) by keeping other variables constant which helped to find out the effective range of all the variables. The competency was evaluated on the basis of colour and lignin content of pulp and paper industry wastewater. Once the effective range of different variables was identified, the statistical analysis was conducted to monitor the mutual impact on the reduction in colour and lignin contents in wastewater. From the statistical design applied, the best result was obtained at activated carbon dose (1.25 g), pH (8.0), contact time (7 h), agitation speed (184 rpm) and temperature (40 °C). The study resulted in reduction of 96.48% in colour and 94.25% in lignin at optimized condition in comparison with 87.37 and 80.44%, respectively, at unoptimized conditions. A potential increase in reduction of 9.0% in colour and 14.0% in lignin content was achieved after optimization through statistical design that confirmed its usefulness.

Bioelectrochemical treatment of real-field bagasse-based paper mill wastewater in dual-chambered microbial fuel cell.

The present study is aimed at analysing the feasibility of bioelectrochemical treatment of bagasse-based paper mill wastewater. Bioelectrochemical treatment was carried out in dual-chambered microbial fuel cell with plain graphite plates as electrodes. Wastewater from sugarcane bagasse storage and washing units of paper mill was used as anolyte. High power density and current density of 53 mW m-2 and 173mAm-2 at 470Ω, respectively, could be produced with wastewater treatment efficiency of 85% and coulumbic efficiency of 6%. Whereas, wastewater from pulping and bleaching units of bagasse-based paper mill was not suitable for bioelectrochemical treatment, yielding low power density and current density of 4mWm-2 and 16mAm-2 respectively at 10,000Ω. Later, treating blended wastewater containing bagasse wash water and pulping wastewater in the ratio of 9:1v/v generated higher power density and current density of 73 mW m-2/202mAm-2, respectively, at 470Ω, with wastewater treatment efficiency and coulumbic efficiency of 82% and 18%, respectively. Lignin and its derivatives present in pulping wastewater mediated electron transfer leading to high power density. Further, compounds in pulping wastewater were also toxic to methanogens growth in anode chamber of MFC, resulting in improved coulumbic efficiency of the blended wastewater treatment.

Application of TiO2 nanoparticle for solar photocatalytic oxidation system

The main purpose of this study is to optimize the applicability of TiO2 nanoparticles for paper mill and pulp wastewater treatment under solar irradiation using response surface methodology, provided by the software package DOE. The principle independent parameters were TiO2 loading, pH, time and H2O2 concentration, and COD removal efficiency was chosen as desire response. To evaluate the influence of the parameters on the outputs, the quadratic formulation was applied and for determining the validation of developed models analysis of variance was utilized. The results represented the greatest COD removal was achieved 82%, approximately at pH of 8.1, TiO2 fraction of 0.83 g/L, H2O2 concentration of 2.4 ml/L and the contact time of 196 min.

Paper mill wastewater treatment by Fe2+ and heat‐activated persulfate oxidation: Process modeling and optimization

AbstractThis study investigated Chemical Oxygen Demand (COD) and turbidity removal from paper mill industry wastewater via Fe2+/heat‐activated persulfate oxidation. A mathematical model was developed, and the process variables (pH, reaction time, PS/COD, Fe2+ concentration for Fe2+‐activated PS, and temperature for heat‐activated PS) were optimized using the Response Surface Methodology and Central Composite Design methods. Under the optimum conditions, respectively, 70.9 and 99.4% COD and turbidity removal efficiencies were obtained for Fe2+‐activated PS oxidation, while 56.1 and 98.9% COD and turbidity removal efficiencies were determined for heat‐activated PS oxidation. The results indicated that both processes are efficient for paper mill industry wastewater treatment, and central composite design is an appropriate method for designing and optimizing process parameters.