Treatment Of Coal Mine Waste Water Research Articles

UV-initiated polymerization of cationic organic flocculants and its application and mechanism in coal mine wastewater treatment

In this study, in order to improve the flocculation efficiency of natural organic flocculant in coal mine wastewater, guar gum (GG) and [2-(methacryloyloxy) ethyl] trimethyl ammonium chloride (DMC)were used to synthesize a type of graft copolymer of GG with DMC (GG-g-DMC) with flocculating function by free radical polymerization under ultraviolet (UV) light initiation conditions. Performance testing and structural characterization of the composites including FTIR, NMR, XRD, SEM, TG, and XPS were conducted to verify the synthesis of the graft polymer. The GG-g-DMC was applied to treat coal mine wastewater, according to the sedimentation index and the optimal flocculation solution was determined, and the flocculation settling mechanism was studied using focused beam reflectance measurement (FBRM), Zeta potentiometer and adhesion force meter. The results indicated that GG-g-DMC synthesis by UV-initiated polymerization was feasible and the settling effect increased significantly; 0.5 mg/g(s) GG-g-DMC 4 was excellent in all aspects, its sedimentation speed reached 20.64 cm/min, the light transmittance was 95.00%, and the compression layer thickness was 1.89 cm; the mechanism is mainly the synergy of charge neutralization, bridging, and improve hydrophobicity.

Numerical modeling of geological sequestration of brine wastewater due to coal mining in the Ordos Basin, China

The coal resources play an indispensable role in the development of heavy industry in China, and coal mining activity leads to brine wastewater drainage, causing major risks for the aquatic environmental system. Thus, the effective and economic treatment of coal mine wastewater is vital to mitigate the environmental burdens, and geological sequestration by deep-well injection is a promising treatment technique. This study elucidates the physical and geochemical processes of coal mine wastewater transport in deep reservoirs and proposes an optimized injection scheme to satisfy environmental and economic benefits simultaneously in the Ordos Basin, China. First, a variable density and variable parameter groundwater reactive transport model is constructed to simulate the long-term process of deep-well injection for coal mine wastewater treatment. Then, the environmental metrics, i.e., the percentage of permeability reduction, the total mass and spatial second moment of the wastewater plume, and the economic metric defined as achieving a higher concentration at a higher injection rate are proposed to evaluate the performance of the injection scheme. The simulation results show that the secondary mineral anhydrite dominates the reduction of reservoir permeability due to the precipitation reactions with SO42− in the brine wastewater, and the permeability in the reaction zone decreases by 0.66 % ~ 1.26 % after 10 years in the basic scenario. Moreover, higher concentrations negatively affect reservoir permeability and increase total dissolved solids, while higher injection rates decrease reservoir permeability and increase the brine wastewater plume. The study also identifies promising schemes that can achieve an optimal trade-off between the conflicting metrics. Based on the economic and environmental benefits demanded in this study, an injection scenario with a concentration of C4 and an injection volume of 800 m3/d is recommended to maximize environmental benefits. Overall, this numerical study offers significant implications for designing an economically and environmentally sustainable treatment injection scheme for coal mining wastewater drainage.

Flocculating Activity of a Bioflocculant from Bacillus megaterium BMBF in Treatment of Domestic and Coal Mine Wastewater

Attention has been paid to bioflocculants production because of their effectiveness, innocuousness and environmental friendliness. This study aimed to characterise a bioflocculant from Bacillus megaterium BMBF and apply it in wastewater treatment. The proteins, carbohydrates and uronic acid were calculated using the Bradford, phenol–sulphuric acid and carbazole assays, respectively. An energy-dispersive X-ray (EDX) and infrared spectrometry were employed for the identification of the elemental composition and effective units, respectively. Cytotoxicity was carried out against Vero (African green monkey kidney) and bovine dermis cells using a colorimetric cytotoxicity assay. The reduction in chemical oxygen demand (COD) and biological oxygen demand (BOD) in domestic and coal mine wastewater was studied using the Jar test. The flocculant was composed of 12% protein, 27% carbohydrates and 61% uronic acid. Infrared spectrometry indicated hydroxyl, carboxyl and amino groups. EDX indicated C (61%) and O (17.5%) as the main elements. The bioflocculant revealed the mean inhibition concentration of 59 ug/mL against bovine dermis and 240 µg/mL on Vero cells. Maximum COD and BOD removal percentages of 97% and 99.3% were recorded on coal mine wastewater treatment and about 99.2% (COD) and 93% (BOD) on domestic wastewater. In conclusion, the bioflocculant from B. megaterium has potential industrial utility.

Synthesis and Application of FeCu Bimetallic Nanoparticles in Coal Mine Wastewater Treatment

Wastewater treatment has become a global challenge with wastewater treatment cost fast increasing. Industrial processes such as downstream processes, wastewater treatment, and several fermentation processes depend largely on the use of flocculants. Synthetic flocculants, which are conventionally used in wastewater treatment, are hazardous to the environment and are carcinogenic to human health. Therefore, bioflocculants can be used as an alternative due to their biodegradable and environmentally friendly nature. However, low efficacy hinders their industrial application. This necessitates the need for a new technology to combat wastewater treatment challenges. Nanotechnology provides the platform to explore the possible solutions to these problems. The combination of two different metals results in the formation of bimetallic nanoparticles (BNPs). Due to better properties, bimetallic nanoparticles have attracted huge attention as compared to monometallic nanoparticles from both technological and scientific views. Iron copper bimetallic nanoparticles (FeCu BNPs) were successfully stabilized by bioflocculant and used in the coal mine wastewater treatment. Infrared spectrometric analysis showed the presence of carboxyl (COO−), hydroxyl (−OH), and amino (−NH2) functional groups. SEM images showed irregular and crystalline like morphology. Meanwhile, TEM analysis revealed chain like agglomerated nanoparticles. FeCu BNPs exhibited a wide pH stability range from 3, 7, and 11 with 99% flocculation activity at pH 7 and at lowest dosage of 0.2 mg/mL. After treating wastewater, the FeCu BNPs could remove pollutants such as phosphate, sulfate, calcium, chemical oxygen demand (COD), and biological oxygen demand (BOD) with phosphate having the highest removal efficacy of 99%.

Synthesis of the Hydrophobic Cationic Polyacrylamide (PADD) Initiated by Ultrasonic and its Flocculation and Treatment of Coal Mine Wastewater

In this study, a new type of hydrophobic cationic polyacrylamide P (AM-DMC-DABC) (PADD) was synthesized by ultrasonic (US)-initiated polymerization, which is used for the separation and removal of coal mine wastewater. The acrylamide (AM), methacryloyloxyethyl trimethyl ammonium chloride (DMC) and acryloyloxyethyl dimethylbenzyl ammonium chloride (DABC) were used as monomers to prepare). The factors that affecting the US initiated polymerization of PADD were analyzed. Fourier transform infrared spectroscopy (FT-IR), 1H nuclear magnetic resonance (1H NMR) and scanning electron microscopy (SEM) were used to characterize the chemical structure, thermal decomposition performance and surface morphology of the polymers. FT-IR and 1H NMR results showed that PADD was successfully synthesized. In addition, irregular porous surface morphology of PADD were observed by SEM analysis. Under the optimum conditions (pH = 7.0, flocculant dosage = 16.0 mg/L), the excellent flocculation performance (turbidity removal rate (TR) = 98.8%), floc size d50 = 513.467 μm, fractal dimension (Df) = 1.61, flocculation kinetics (KN0) = 27.24 × 10−3·s−1) was obtained by using high-efficiency flocculant PADD. Zeta potential analysis was used to further explore the possible flocculation mechanism of removal. The zeta potential and flocculation analytical results displayed that the flocculation removal process of coal mine wastewater mainly included hydrophobic effect, adsorption, bridging and charge neutralization, and electric patching when PADD was used. The PADD showed more excellent coal mine wastewater flocculation performance than PAD, commercial cationic polyacrylamide (CPAM) CCPAM and PAM. Thus PADD, with its good flocculation effect on coal mine wastewater under relatively wide pH range, had bright practical application value.

A novel polyamidine-grafted carboxymethylcellulose: Synthesis, characterization and flocculation performance test

AbstractThis study facilitates the synthesis process of a novel graft copolymer (flocculant) using carboxymethyl cellulose, acrylonitrile and N-vinyl formamide as raw materials. The carboxymethyl cellulose graft polyamidine (CMC-g-PAMD) can be used as new flocculant to replace the traditional polyacrylamide flocculant, which manifested its excellent flocculation and degradation efficiency. A five-membered cyclic copolymer was prepared by the graft copolymerization, and the synthesized flocculants were characterized by EA, TG-DTG, FT-IR, SEM and NMR, confirming the successful synthesis of the desired copolymers. The operation conditions for copolymerization were experimentally investigated, and the results indicated that the optimal initiator dosage, copolymerization temperature, amidinization temperature, acidification time and flocculant dosage were 4 g/L, 50°C, 90°C, 3 h and 60 mg/L, respectively. Compared with the traditional polyacrylamide flocculant, the CMC-g-PAMD presented an outstanding flocculation ability of 96.1% under its optimal operation conditions, which showed an enormous potential in the application of coalmine waste-water treatment.

Treatment and reuse of coalmine wastewater in Vietnam: application of microfiltration

Abstract Due to stringent local regulations and adverse environmental impacts, Vietnamese coal mining industries are under pressure to reuse the large volume of wastewater they produce. To this end, the aim of this study was to add microfiltration (MF) membranes after the conventional Vietnamese coalmine wastewater treatment systems (coagulation/sedimentation/filtration) to assess the feasibility of effluent reuse. The pilot-scale test was performed at a coalmine plant located in Quang Ninh province, Vietnam. Results indicate that precipitation with slaked lime (Ca(OH)2) and polyaluminum chloride (PACl) followed by sand filtration are important pre-treatment steps, prior to microfiltration. To achieve high Mn removals the sand in the filter had to be replaced by a KMnO4 coated sand. The MF membrane produced a stable and high quality effluent that meets the Vietnamese National Technical Regulations for Drinking Water quality (Fe < 0.5 mg/L, Mn < 0.3 mg/L, hardness <350 mg/L as CaCO3). Complete membrane recovery was achieved by sequential 24 h soakings in NaOCl, citric acid and a surfactant.

Polyacrylamide-grafted legume starch for wastewater treatment: synthesis and performance comparison

Polyacrylamide as traditional flocculant begins to draw the public awareness because of its non-biodegradable nature which may cause the long-term environmental degradation problems. A new high-efficient flocculant was synthesized by legume starch and acrylamide to satisfy the demand of coalmine wastewater treatment. Grafting acrylamide onto mung bean starch was investigated and the characterizations of elemental analysis, scanning electron microscopy, gel permeation chromatography, Fourier transform infrared, X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry and nuclear magnetic resonance spectrometer were conducted. The characterization results of the new flocculant prove that acrylamide has grafted onto the mung bean starch molecule chains successfully. Experimental results indicate the optimal synthesis parameters of the new flocculant are: mung bean starch 50 g/L (ethanol solvent), acrylamide 100 g/L, ceric ammonium nitrate 12 g/L, gelatinization temperature 70 °C and copolymerization temperature 70 °C. We also measured and evaluated the performance of the new flocculant on wastewater treatment, and the optimal dosage of the new flocculant is 20 mg/L, with a prominent transmittance of 98.1% and turbidity of 7.82. Experimental results have demonstrated the graft copolymer of acrylamide and mung bean starch owns an outstanding flocculation effect than the traditional polyacrylamide and polyaluminum chloride. The new flocculant has a few features such as environmentally friendly, easy to degrade, fasting sedimentation and low cost, which is especially suitable for the occasions of rigorous environmental requirements and is bound to have broad application prospect for coalmine wastewater treatment.

Identification of the microbial community composition and structure of coal-mine wastewater treatment plants

The wastewater from coal-mine industry varies greatly and is resistant to biodegradation for containing large quantities of inorganic and organic pollutants. Microorganisms in activated sludge are responsible for the pollutants’ removal, whereas the microbial community composition and structure are far from understood. In the present study, the sludges from five coal-mine wastewater treatment plants were collected and the microbial communities were analyzed by Illumina high-throughput sequencing. The diversities of these sludges were lower than that of the municipal wastewater treatment systems. The most abundant phylum was Proteobacteria ranging from 63.64% to 96.10%, followed by Bacteroidetes (7.26%), Firmicutes (5.12%), Nitrospira (2.02%), Acidobacteria (1.31%), Actinobacteria (1.30%) and Planctomycetes (0.95%). At genus level, Thiobacillus and Comamonas were the two primary genera in all sludges, other major genera included Azoarcus, Thauera, Pseudomonas, Ohtaekwangia, Nitrosomonas and Nitrospira. Most of these core genera were closely related with aromatic hydrocarbon degradation and denitrification processes. Identification of the microbial communities in coal-mine wastewater treatment plants will be helpful for wastewater management and control.

A Survey of Experience Gained from the Treatment of Coal Mine Wastewater

During coal mining, water resources may be polluted by acid mine drainage (AMD) if appropriate measures are not taken. AMD releases metals to the environment, which can be harmful to aquatic species and reduce biodiversity. There is a great deal of information available in the literature on the generation and treatment of AMD and this paper tries to summarize some of them in order to facilitate the choice of the most appropriate method for AMD treatment at a specific mining site. The objective of this study was to identify and describe different methods of treating polluted water from coal mining, and to discuss the choice of suitable methods at specific mining sites. Both active and passive methods of AMD treatment are discussed in order to provide a general picture of the measures that have been taken around the world by coal mining companies. From this study, we were able to conclude that in order to choose the appropriate method for a specific mining site it is necessary to analyze the chemistry of the acid water and the flow rate from that site. The cost, implementability and effectiveness of the method should also be considered. Minimizing the amount of drainage water generated is naturally the first choice of management strategy and the containment of the AMD is the second choice. The third alternative is the treatment of the wastewater.

Development of novel polymeric flocculant based on grafted sodium alginate for the treatment of coal mine wastewater

Development of novel polymeric flocculant based on grafted sodium alginate for the treatment of coal mine wastewater

Development of novel polymeric flocculant based on grafted sodium alginate for the treatment of coal mine wastewater

AbstractSodium alginate‐g‐polyacrylamide (SAG) was synthesized by ceric ion induced redox polymerization technique. Six grades of graft copolymers were prepared by varying as well as monomer concentrations. The graft copolymers were characterized by intrinsic viscosity measurements, IR, and 13C‐NMR spectroscopies. Of the above grades, the graft copolymer of grade six (SAG‐VI), which has longer polyacrylamide chains, was used for flocculation study. Two coking and noncoking coal fine suspensions were selected for the flocculation study. The flocculation performance of the graft copolymer was compared with commercial flocculants. In all cases, it was found that the graft copolymer showed better performance than the commercial flocculants. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 375–382, 2001