Transport Of Suspended Particulate Matter Research Articles

Physical mechanisms, dynamics and interconnections of multiple estuarine turbidity maximum in the Pearl River estuary

The formation and dynamics of individual estuarine turbidity maximum (ETM) in the Pearl River estuary (PRE) have been investigated but the temporal variability of the ETMs and interconnections among them remain poorly understood. To address these open questions, the distribution and transport of suspended particulate matter (SPM) in the PRE for the period of 2017–2020 are investigated by numerical modeling. The simulated sediment transport flux is decomposed into several major components associated with specific physical processes. Then, the relative contribution of each component to the formation of the ETMs is evaluated. Results suggest the coexistence of three prominent ETMs in the Lingding Bay of the PRE. They are formed by different physical mechanisms and characterized by remarkable seasonality in the spatial extension. In the two ETMs located at the west shoal and middle shoal, advection dominates the sediment transport flux, whilst tidal pumping plays a crucial role in maintaining the ETMs. A sharp bathymetric gradient leads to an entrapment of sediment flux within the bottom layer in the west channel ETM, a phenomenon referred to as topographical trapping. The interconnection analysis shows that the sediment transport between the ETMs varies with seasons, which is attributed to the variation of stratification driven by the monsoon-mediated river runoff. Our results provide new insights into the physical dynamics and interconnections of the ETMs in the PRE, which can serve as scientific base for estuarine sediment management and engineering.

Confounding effects of seasonality and anthropogenic river regulation on suspended particulate matter-driven mercury transport to coastal seas

Riverine mercury (Hg) is mainly transported to coastal areas in suspended particulate matter (SPM)-bound form, posing a potential threat to human health. Water discharge and SPM characteristics in rivers vary naturally with seasonality and can also be arbitrarily disrupted by anthropogenic regulation events, but their effects on Hg transport remain unresolved. Aiming to understand the confounding effects of seasonality and anthropogenic river regulation on Hg and SPM transport, this study selected the highly sediment-laden Yellow River as a representative conduit. Significant variations in SPM concentrations (108 − 7097 mg/L) resulted in fluctuations in total mercury (THg, 3.79 − 111 ng/L) in river water corresponding to seasonality and anthropogenic water/sediment regulation. Principal component analysis and structural equation model revealed that SPM was the essential factor controlling THg and particulate Hg (PHg) in river water. While SPM exhibited equilibrium state in the dry season, a net resuspension during the anthropogenic regulation and net deposition in the wet season demonstrated the impact of SPM dynamics on Hg distribution and transport to coastal regions. Combining water discharge, SPM, and Hg concentrations, a modified model was developed to quantify Hg flux (2256 kg), over 98% of which was in particulate phase.

Composition and sources of suspended particles in the Pacific Arctic region

During the 6th (2014) and 7th (2016) Chinese Arctic Expedition (CHINARE), samples of suspended particulate matter (SPM) were collected from both surface (depth: <1.0 m) and subsurface (depth: approximately between 10 and 150 m) waters over the northern shelf of the Bering Sea and in the western Arctic Ocean. To investigate the distribution and sources of organic matter in both the surface water and the vertical profile, the concentration and stable carbon isotopic composition of SPM, particulate organic carbon (POC), and particulate nitrogen (only in surface water samples) were determined, and some particle samples were selected for examination using scanning electron microscopy. Results showed apparent geographical partitioning and temporal variation in both the concentration and the composition of SPM. Higher SPM concentrations were observed in nearshore, shelf break, and sea ice edge areas; the distribution of POC concentration displayed a similar pattern, with higher values found from the northern part of the Bering Shelf to southern parts of the Chukchi Shelf. In surface water, SPM mainly comprised clay and detrital minerals with higher POC contents, lighter δ13C values, and higher POC/PN ratios, indicating organic matter predominantly derived from terrestrial sources in areas south of St. Lawrence Island and north of 73°N. The downward trend of heavier δ13C values, together with reduction in clay and detrital minerals, suggests that vertical transport of SPM is hindered by stratification, resulting in transport of terrestrial materials toward northern basin areas. In the Chukchi Slope and Canada Basin areas, extremely light δ13C values (as low as −33.41‰ PDB) were mainly observed at depths of 20–60 m, where the Polar Mixed Layer (PML) intersects with the Upper Halocline Layer (UHL). Under the condition of low sea ice extent in 2016, the POC-δ13C values were heavier in the PML than in the UHL in the Chukchi Slope and Canada Basin areas. These findings provide insights into the sources, transport, and fate of organic matter in the Pacific Arctic region, which have important implications for understanding the biogeochemical cycles and ecosystem dynamics in this remote and rapidly changing environment.

The effect of aggregation/disaggregation on suspended particulate matter transport in a tidal strait

Predicting net suspended sediment fluxes in coastal regions is important for promoting good water quality, maritime transport and marine industries. Aggregation and disaggregation of suspended particulate matter responding to spatial and temporal variations in turbulence can control particle size and hence settling speed; little is currently known about how this influences the net suspended sediment flux. A tidal strait, in which the flux is confined to be in one of two directions, makes a good site for observing the effect of changes in particle size on the suspended sediment flux. The Menai Strait in North Wales is a narrow tidal strait in which the flow speeds increase to a maximum in the narrowest central region, the Swellies. Observations at sites on either side of the Swellies show that the median size of suspended particles varies with the speed of the tidal current, but also depends on the direction of the flow, with the smallest particles seen when the current is flowing out of the Swellies. The implication (supported by model results) is that the strong currents in the centre of the strait tear up flocs into small pieces which are then carried out towards both ends of the strait by the tide. Averaged over a tidal cycle, there is a net flux of larger particles into the Swellies and a net flux of small particles out. These results are relevant to the formation of isolated turbidity maxima around a region of strong turbulence.

Ocean Color Remote Sensing of Suspended Sediments along a Continuum from Rivers to River Plumes: Concentration, Transport, Fluxes and Dynamics

This study investigates the capability of high and medium spatial resolution ocean color satellite data to monitor the transport of suspended particulate matter (SPM) along a continuum from river to river mouth to river plume. An existing switching algorithm combining the use of green, red and near-infrared satellite wavebands was improved to retrieve SPM concentrations over the very wide range (from 1 to more than 1000 g.m−3) encountered over such a continuum. The method was applied to time series of OLI, MSI, and MODIS satellite data. Satisfactory validation results were obtained even at the river gauging station. The river liquid discharge is not only related to the SPM concentration at the gauging station and at the river mouth, but also to the turbid plume area and SPM mass estimated within the surface of the plume. The overall results highlight the potential of combined field and ocean color satellite observations to monitor the transport and fluxes of SPM discharged by rivers into the coastal ocean.

Key role of suspended particulate matter in assessing fate and risk of endocrine disrupting compounds in a complex river-lake system

Endocrine-disrupting compounds (EDCs) enter lakes mainly through river inflow. However, the occurrence, transport and fate of EDCs in the overlying water, suspended particulate matter (SPM) and sediment of inflowing rivers remain unclear. This study investigated the load of seven EDCs in a complex river-lake system of the Taihu Lake Basin during different seasons, with the aims of revealing the transport routes of EDCs and identifying the contributions from different sources. The results indicated that the levels of the seven EDCs in the wet season with high temperature and dilution effects were generally lower than those in the other seasons. EDC enrichment in the sediment was largely affected by the transport and fate of SPM. Moreover, the estrogenic activity and risks of EDCs were the highest in SPM. The mass loadings of particulate EDCs carried by SPM were 2.6 times that of overlying water. SPM plays a vital role in the transport and fate of EDCs in complex river-lake systems and thereby deserves more attention. Nonpoint sources, particularly animal husbandry activities and untreated domestic sewage, were the main sources of EDCs, amounting to 61.5% of the total load.

Impact of Flash Flood Events on the Coastal Waters Around Madeira Island: The “Land Mass Effect”

The Island Mass Effect has been primarily attributed to nutrient enhancement of waters surrounding oceanic islands due to physical processes, whereas the role of land runoff has seldom been considered. Land runoff can be particularly relevant in mountainous islands, highly susceptible to torrential rainfall that rapidly leads to flash floods. Madeira Island, located in the Northeast Atlantic Ocean, is historically known for its flash flood events, when steep streams transport high volumes of water and terrigenous material downstream. A 22-year analysis of satellite data revealed that a recent catastrophic flash flood (20 February 2010) was responsible for the most significant concentration of non-algal Suspended Particulate Matter (SPM) and Chlorophyll-a at the coast. In this context, our study aims to understand the impact of the February 2010 flash flood events on coastal waters, by assessing the impact of spatial and temporal variability of wind, precipitation, and river discharges. Two specific flash floods events are investigated in detail (2 and 20 February 2010), which coincided with northeasterly and southwesterly winds, respectively. Given the lack of in situ data documenting these events, a coupled air-sea-land numerical framework was used, including hydrological modeling. The dynamics of the modeled river plumes induced by flash floods were strongly influenced by the wind regimes subsequently affecting coastal circulation, which may help to explain the differences between observed SPM and Chlorophyll-a distributions. Model simulations showed that during northeasterly winds, coastal confinement of the buoyant river plume persisted on the island’s north coast, preventing offshore transport of SPM. This mechanism may have contributed to favorable conditions for phytoplankton growth, as captured by satellite-derived Chlorophyll-a in the northeastern coastal waters. On the island’s south coast, strong ocean currents generated in the eastern island flank promoted strong vertical shear, contributing to vertical mixing. During southwesterly winds, coastal confinement of the plume with strong vertical density gradient was observed on the south side. The switch to eastward winds spread the south river plume offshore, forming a filament of high Chlorophyll-a extending 70 km offshore. Our framework demonstrates a novel methodology to investigate ocean productivity around remote islands with sparse or absent field observations.

Suspended particulate matter in a submarine canyon (Whittard Canyon, Bay of Biscay, NE Atlantic Ocean): Assessment of commonly used instruments to record turbidity

Nepheloid layers with elevated concentrations of suspended particulate matter (SPM) are found throughout the world's oceans. They are generated by both natural processes, involving resuspension of seabed sediment by bottom currents, and anthropogenic sediment resuspension due to bottom trawling, dredging and in the future potentially due to deep-sea mining. These nepheloid layers represent pathways of lateral SPM transport, including lithogenic and biogenic sediment, organic matter, (trace) metals, organic pollutants and plastics. For assessment of the dispersion of these materials, it is essential that SPM mass concentrations can be accurately quantified. However, this is not straightforward as the detected turbidity signal, which is used as a proxy for SPM mass concentration, not only depends on the concentration of particles, but also on physical characteristics of these particles, such as particle size, substance and shape. Here we present a comparative study of turbidity data to assess the potential implications different sensors have on the estimates of SPM mass concentration. Optical backscatter sensors (OBSs), transmissometers and both low- and high-frequency ADCPs were deployed simultaneously in the Whittard Canyon (North Atlantic Ocean), and water samples were collected for quantification of SPM mass concentration and ex-situ particle size analysis. We found that SPM mass concentrations inferred from the transmissometer are easily overestimated in the biologically productive surface layer due to higher light absorption by chlorophyll-bearing phytoplankton, compared to suspended detritic particles. Furthermore, we observed that depending on sensor type some particles are not, or less well, detected. This is due to differences in particle size sensitivities of these sensors towards the diverse range of particle sizes found in the Whittard Canyon, whereby the low-frequency ADCP was most sensitive for coarse-grained material and the high-frequency ADCP and OBSs most sensitive for fine-grained material. In future studies, we suggest to use a combination of different sensors as the use of only one type of sensor could potentially lead to misinterpretation and mis-quantification of particle transport processes and fluxes.

Temporal and Spatial Variations in Particle Fluxes on the Chukchi Sea and East Siberian Sea Slopes From 2017 to 2018

Time-series sediment traps were deployed on the Chukchi Sea and East Siberian Sea slopes from August 2017 to August 2018 with the aim of elucidating the temporal and spatial variations in particle fluxes and identifying the main processes affecting those variations. Particle fluxes showed a typical seasonal pattern, with high values in summer and low values in other seasons, and a large inter-annual variation was observed only on the East Siberian Sea slope, where particle fluxes were one order of magnitude higher in early August 2018 than in late August 2017. This large inter-annual variation in particle flux resulted from the episodic intrusion of nutrient-enriched shelf water in the East Siberian Sea, which enhanced biological production at the surface and particle fluxes. The Chukchi Sea slope was influenced by the inflow of Anadyr Water, with high salinity and high nutrient concentrations, which had little annual variability. Therefore, particle flux showed little inter-annual variation on the Chukchi Sea slope. Under-ice phytoplankton blooms were observed in both the Chukchi Sea and East Siberian Sea slopes, and increases in particulate organic carbon (POC) flux and the C:N ratio under the sea ice were related to transparent exopolymer (TEP) production by ice algae. On the East Siberian Sea slope, particle fluxes increased slightly from 115 to 335 m, indicating lateral transport of suspended particulate matter; POC and lithogenic particles may be laterally transported to the slope as nutrient-rich shelf waters flowed from the East Siberian Sea to the Makarov Basin. Annual POC fluxes were 2.3 and 2.0 g C m–2 year–1 at 115 and 335 m, respectively, on the East Siberian Sea slope and was 2.1 g C m–2 year–1 at 325 m on the Chukchi Sea slope. Annual POC fluxes were higher on the Chukchi Sea and East Siberian Sea slopes than in Arctic basins, lower than on Arctic shelves, and generally similar to those on western Arctic slopes.

Human impact on suspended particulate matter in the Yellow River Estuary, China: Evidence from remote sensing data fusion using an improved spatiotemporal fusion method

Transport of suspended particulate matter (SPM) in estuarine waters plays an important role in regulating erosion-accretion and biogeochemical processes. In the Yellow River Estuary (YRE), artificial water and sediment regulation scheme (WSRS) and coastal engineering structures are the 2 typical anthropogenic activities affecting the spatiotemporal dynamics of estuarine SPM. The monitoring of SPM transport affected by such human activities requires SPM mapping at both high spatial and high temporal resolutions. In this study, we presented an improved Flexible Spatiotemporal Data Fusion (FSDAF) strategy with consideration of highly dynamic SPM variations in estuarine waters, and generated 30-m hourly SPM concentrations based on Landsat 8 OLI and GOCI datasets. The new strategy produced higher SPM estimation accuracy than the original FSDAF, with the relative percentage difference (RPD) decreasing from 29.75% to 5.31% using GOCI-derived hourly SPM as reference. With in situ SPM measurements as reference, the fused SPM concentrations had an RMSE of 12.09 mg/L and an RPD of 27.17%. Investigation of interday SPM variations before, during, and after the WSRS in 2018 revealed that the first WSRS significantly increased the SPM concentration and plume extent; new wetland with an area of 12.56 km2 was formed due to sediment accretion near the river mouth. The two groins offshore from the coastlines on the north and south sides of YRE exhibited obvious sediment trapping effects in that higher SPM concentrations on one side of each groin were found regardless of the turbidity modes and diurnal SPM variations; the trapping effects were associated with the number of groins and groin length. Intraday variations of SPM were influenced by tidal currents, with plume direction following the ebb and flooding tidal current direction. The inter- and intraday characteristics of the 30-m hourly SPM dynamics facilitate the detailed analysis of the sediment transport associated with human activities.

Intratidal and spatial variability over a slope in the Ems estuary: Robust along-channel SPM transport versus episodic events

Results from measurements are presented that were collected during a full tidal cycle in the Ems estuary, involving two landers and an anchored research vessel. The conditions were characterized by very weak winds, no wave effects, and low river run-off, so that the state was close to tide-only. We find that the lateral (i.e., cross-slope) transport of water and suspended particulate matter (SPM) much of the time shows a vertically layered structure, which is however subject to sudden transitions. Moreover, even on the small spatial scale of these measurements (i.e., within a distance of 200 m), a strong lateral variability is observed in the circulation patterns. We analyze its dynamics by means of dimensionless parameters. In addition, near-bottom peaks in SPM concentration are observed, notably during early flood. However, these episodic events have little effect on the overall transport of SPM, which involves the whole water column: the measurements show a high vertically integrated SPM signal during late ebb, resulting in an ebb-dominance in the transport at this position in the tidal channel.

Role of biogenic Fe(III) minerals as a sink and carrier of heavy metals in the Rio Tinto, Spain

Oxidation of sulfide ores in the Iberian Pyrite Belt region leads to the presence of extremely high concentration of dissolved heavy metals (HMs) in the acidic water of the Rio Tinto. Fe(II) is microbially oxidized resulting in the formation of suspended particulate matter (SPM) consisting of microbial cells and Fe(III) minerals with co-precipitated HMs. Although substantial amount of HM-bearing SPM is likely deposited to river sediment, a portion can still be transported through estuary to the coastal ocean. Therefore, the mechanisms of SPM formation and transport along the Rio Tinto are important for coastal-estuarine zone. In order to reveal these mechanisms, we performed diurnal sampling of Rio Tinto water, mineralogical and elemental analysis of sediment from the middle course and the estuary of the river. We identified two divergent but interrelated pathways of HM transfer. The first longitudinal pathway is the transport of SPM-associated metals such as As (6.58 μg/L), Pb (3.51 μg/L) and Cr (1.30 μg/L) to the coastal ocean. The second sedimentation pathway contributes to the continuous burial of HMs in the sediment throughout the river. In the middle course, sediment undergoes mineralogical transformations during early diagenesis and traps HMs (e.g. 1.6 mg/g of As, 1.23 mg/g of Pb and 0.1 mg/g of Cr). In the estuary, HMs are accumulated in a distinct anoxic layer of sediment (e.g. 1.5 mg/g of As, 2.09 mg/g of Pb and 0.04 mg/g of Cr). Our results indicate that microbially precipitated Fe(III) minerals (identified as ferrihydrite and schwertmannite) play a key role in maintaining these divergent HM pathways and as a consequence are crucial for HM mobility in the Rio Tinto.

Indication of size distribution of suspended particulate matter for sediment transport in the South Yellow Sea

The Yellow Sea is a key area for studying source-to-sink sediment transport systems in East China shelf seas. However, the sediment transport and dispersal patterns in the Yellow Sea are not fully understood because of the significant seasonal variation in ocean circulation. In this study, we identify the ocean circulation patterns in the South Yellow Sea based on temperature, salinity and depth data collected from 52 hydrographic stations during the winter of 2016. The mass concentrations and particle size distributions of suspended particulate matter are also determined to decipher the sediment transport pattern in the South Yellow Sea. The results show that particles from the Yellow Sea Coastal Current and Shandong Peninsula Coastal Current display a bimodal size distribution, with peaks at approximately 2.5 μm and 32–64 μm, while particles from the Yellow Sea Warm Current and residual Yellow Sea Cold Water Mass display a trimodal size distribution, with peaks at 2.5 μm, 32–64 μm and 391 μm. The fine and medium particles (<256 μm) are mainly inorganic particles, while the coarse particles (>256 μm) include organic materials. The peak at 391 μm is dominated by organic particles and reflects the influence of the Yellow Sea Warm Current in the surface layer. The Yellow Sea Warm Current enhances the nutrient and temperature conditions in the South Yellow Sea, which facilitates phytoplankton growth under appropriate light conditions. The content of inorganic particles with sizes of 64–159 μm decreases sharply in the central South Yellow Sea, which reflects the transport of suspended particulate matter from the southern study area to the central Yellow Sea mud area. The synthesized evidence suggests that the Yellow Sea Warm Current, as the main driving force, transports particles from the Jiangsu coast or the Changjiang River into the central Yellow Sea mud area in winter.

Hydrodynamics and SPM transport in an engineered tidal estuary: The Adour river (France)

The present paper reports on a series of field experiments aiming to characterise the functioning of a man-engineered strongly forced salt-wedge estuary: the lower estuary of the Adour river, France. Bottom-moored velocity measurements and surface boat surveys have been performed under low river discharge conditions, for both neap and spring tides, in order to provide a well-documented reference framework to understand the dynamics of water masses, turbulence and suspended particulate matter (SPM) transport in the lower estuary. An additional campaign has been carried out in high river discharge conditions. This first documented in-situ study of the Adour lower estuary demonstrates its variability in terms of hydrological regimes, from salt-wedge to partially mixed regimes depending on tidal and discharge conditions. Turbulent properties showed a significant response to the variations of salinity structure, with higher values when stratification is minimal. At spring tide, a tidal variation between mixing conditions on the ebb and the flood is revealed by ADCP measurements, with higher values extended up to the surface during the ebb. The link between turbulent mixing and suspended sediment concentration is straightforward during the ebb. During the flood, the suspended sediment concentration (SSC) seems related to the salt-wedge entrance re-suspension and stratification-induced turbulence damping. No stable Estuarine Turbidity Maximum (ETM) has been observed during the field experiment in the lower Adour estuary.

Modelling Transport of Heavy Metals in Geita Wetland along Mamubi River

The modelling of heavy metals in rivers is highly dependent on hydrodynamics, the transport of suspended particulate matter and the partition between dissolved and particulate phases. This paper presents the development of hydrodynamic model DUFLOW, which is a one dimensional flow and water quality simulation package, that describes the processes governing transformations and transport of heavy metals (Hg, Ni and Cu) along Mabubi River in the Geita wetland. Two monitoring stations were established along Mabubi River at the inlet (MBSP1) and outlet (MBSP2) of the wetland. A set of DUFLOW model inputs representative of the water conditions were collected from the established monitoring stations. The model was calibrated and validated for the prediction of flow and heavy metals (Hg, Ni, and Cu) transport, against a set of measured mean monthly monitoring data. Sensitive model parameters were adjusted within their feasible ranges during calibration to minimize model prediction errors. At the gauging station MBSP2, the calibration results showed the model predicted mean monthly flow within 17% of the measured mean monthly flow while the r2 coefficient and Nash-Sutcliffe (NSE) were 0.83 and 0.79 respectively. At the water quality monitoring station MBSP2, the calibration results showed the model predicted heavy metals (Hg, Ni and Cu) concentrations within 13% and 17% of their respective measured mean monthly concentrations. The mean monthly comparisons r 2 values for heavy metals ranged from 0.75 to 0.88 while the NSE values were between 0.70 and 0.82. The model results and field measurements demonstrated that about 40% of the annual heavy metals loadings which would otherwise reach the Lake Victoria are retained in the wetland. The Mabubi river model can therefore be used for prediction of heavy metals (Hg. Ni and Cu) transformation processes in the Geita wetland.

Evaluating the role of particle size on urban environmental geochemistry of metals in surface sediments

In this study, non-destructive techniques (X-ray Diffraction, Infrared and Scanning Electron Microscopy with Energy Dispersive spectroscopies) and invasive procedures (pseudo-total and sequential metal extraction methodologies) were used to highlight the significance of evaluating different particle sizes of sediments for assessing the potential environmental and health implications of metal geochemistry in an urban ecosystem.The variability in composition and properties between bulk (<2 mm) and fine (<63 μm) fractions influenced the availability, and by extension, the toxicity of metals. Indeed, the fine fraction presented not only higher metal pseudo-contents, but also greater available metal percentages. Besides the larger surface area per unit of mass and the high content of clay minerals, it was observed that it was principally Fe/Mn oxyhydroxides that favour adsorption of metals on the fine surface sediments. However, although we demonstrated that the origin of metals in the bulk surface sediments was predominantly lithogenic, use of the <2 mm fraction proved to be a useful tool for identifying different sources of available metals throughout the Deba River catchment. Specifically, discharges of untreated industrial and urban wastewaters, and even effluents from wastewater treatment plants were considered to greatly increase the health risk associated with metal availability. Finally, an evaluation of sediment dynamics in different hydrological conditions has highlighted the role played by each particle size as a vector of metal transport towards the coastal area. While resuspension of fine surface sediments notably induced significantly higher particulate metal concentrations in water during the dry season, resuspension of bulk surface sediments and, fundamentally, downstream transport of suspended particulate matter became more relevant and lowered the ecological risk during the wet season. Greater attention therefore needs to be paid to the new hydrological scenarios forecast to result from climate change, in which longer seasons with low river discharges are forecast.

Seasonal Exchanges of Salt and Suspended Particulates between the Sol Bay and the Pará River, Amazonian Coast

Mascarenhas, A.C.C.; Correa, A.W.R.; Carneiro, A.C.; Costa, M.S.; Rollnic, M., and Medeiros, C., 2018. Seasonal Exchanges of Salt and Suspended Particulates between the Sol Bay and the Para River, Amazonian Coast. In: Shim, J.-S.; Chun, I., and Lim, H.S. (eds.), Proceedings from the International Coastal Symposium (ICS) 2018 (Busan, Republic of Korea). Journal of Coastal Research, Special Issue No. 85, pp. 111–115. Coconut Creek (Florida), ISSN 0749-0208.Salt and suspended particulate matter (SPM) exchange between the Sol Bay and the Para River and their tidal/seasonal variability was investigated along the interface cross-section (1°4′30.37″S 48°19′37.48″W), over spring tidal cycles, during the wet (Apr/2015) and dry (Oct/2015) seasons. Advective transport of salt and SPM was analyzed to evaluate trends and contributions of involved mechanism. Overall, salinity was low (S<2) during dry and absent during the wet season. Mean SPM concentrations where higher at flood tides during both seasons. Higher flow velocities were 1.29 m.s−1 (ebb/wet) and 1.17 m.s−1 (flood/dry). During the dry season net salt transport was 8.10 kg.s−1 seawards mainly due to a baywards Stokes drift transport (−193.7 kg.s−1) against a seawards transport by the river discharge, tidal correlation and turbulent shear components ( 179.0; 11.98; 7.72 kg.s−1). However, SPM was stored into Sol Bay at a rate of 2.06 kg.s−1 (90 ton per tidal cycle), as result of the baywards transport by the Stokes drift river discharge (−3.14; −0.82 kg.s−1) in opposition to the seawards transport due to gravitational circulation tidal correlation components ( 1.69; 0.48 kg.s−1). During the wet season the river discharge (29.8 kg.s−1) fluxes out SPM from Sol Bay while the Stokes drift (3.19 kg.s−1) and the turbulent shear (0.65 kg.s−1) components tends to move SPM back into the bay with a net exportation of SPM to the Para River of 26 kg.s−1 (129.8 ton per tidal cycle). In conclusion, matter exchange between the Sol Bay and the Para River is mainly governed by the river discharge and Stokes drift flow components. The relative contributions by the gravitation circulation, tidal correlation and turbulent shear tend to increase under low river discharge. A small salt exportation ( 8.10 kg.s−1) during the dry season

Tide Influence on Suspended Matter Transport in an Amazonian Estuary

Rollnic, M.; Costa, M.S.; Medeiros, P.R.L., and Monteiro, S.M., 2018. Tide Influence on Suspended Matter in an Amazonian Estuary. In: Shim, J.-S.; Chun, I., and Lim, H.S. (eds.), Proceedings from the International Coastal Symposium (ICS) 2018 (Busan, Republic of Korea). Journal of Coastal Research, Special Issue No. 85, pp. 121–125. Coconut Creek (Florida), ISSN 0749-0208.The aim of this study is to check which tidal component (dispersive or diffuse) dominates suspended particulate matter transport (SPM) in the Mojuim River estuary. This estuary comprises the eastern sector of the Amazon coast, characterized by mangrove-vegetated tidal flats. Measurements of current intensity and direction, SPM, and tide level over a tidal cycle (13 h) were performed in a section of the lower estuary. Samplings were conducted in March (wet season) and September (dry season), 2014, during spring tide. The resulting transport and relative contribution of advective transport (SPM diffusion and dispersion) were calculated. Mojuim estuary has a macrotidal regime, with mean height of 4.9 m during spring tide and 3.2 m during neap tide. As it is a shallow environment, the water column is homogeneous, and hydrological parameters do not significantly vary along the water column. SPM ranged from 12 to 92 mg.L−1 during dry season and from 20.4 to 94.8 mg.L−1 during wet season. The highest SPM concentrations occurred during ebb tide, and this determined the maximum instantaneous transport, both during wet season (127.8 kg.s−1) and dry season (159 kg.s−1). This estuary is characterized as an exporter environment. During dry season, it had a residual transport of 4.1 kg.s−1 and a total transport of 191.9 tons downstream of the estuary. However, during wet season, it showed an inversion in advective transport due to equinoctial tidal influence, which caused a higher tidal prism thus resulting in a residual transport of 1.92 kg.s−1 and a total transport of 90 tons upstream of the estuary. The dominant SPM transport component downstream of the estuary was river discharge, whereas SPM transport upstream of the estuary was dominated by Stokes Transport.

Antimony in the Lot–Garonne river system: a 14-year record of solid–liquid partitioning and fluxes

Environmental contextAntimony is a trace element ubiquitously present in the environment, but data are lacking on its spatio-temporal distribution in aquatic environments. Long-term records serve as essential tools to decipher temporal patterns, historical sources and sinks and background concentrations in an area. We characterise the temporal concentrations, transport and behaviour of antimony in the Garonne River watershed, the main tributary to the Gironde Estuary, the largest estuary in south-west Europe. AbstractKnowledge of the environmental chemistry of antimony (Sb) in aquatic systems is limited, and a better understanding of its geochemical behaviour is needed. Based on a fourteen-year survey (2003–2016) with monthly measurements of dissolved and particulate Sb at five sites in the Lot–Garonne river system, combined with daily measurements of water discharge and suspended particulate matter, this work characterises Sb behaviour in the upstream major river watershed of the Gironde Estuary. The survey provides a first regional geochemical Sb background in the Garonne River watershed for dissolved (~0.2 µg L−1) and Th-normalised particulate Sb (Sbp/Thp ~0.25) concentrations. Observed decreasing temporal trends (&lt;1 ng L−1 in dissolved and &lt;0.02 mg kg−1 in particulate concentrations per month) at sites representing natural concentrations probably reflect global atmospheric Sb dynamics at the watershed scale. Regular seasonal cycles of solid/liquid partitioning, with higher solubility in summer (matching high dissolved and low particulate concentrations), reflect water-discharge and suspended particulate matter transport dynamics and possibly seasonal (bio)geochemical processes. Furthermore, this coefficient decreases from the river to the estuarine reaches (from average log10Kd 4.3 to minimum 3.7 L kg−1), suggesting an increased solubility of Sb in estuarine systems. Flux estimates indicate the relevance of the dissolved fraction in Sb transport (with negligible influence of the colloidal fraction) and a total flux (dissolved + particulate) entering the Gironde Estuary of 5.66 ± 2.96 t year−1 (~50 % particulate). These results highlight the importance of timescales and environmental parameters for understanding and prediction of future Sb biogeochemistry.

Isoprenoid tetraether lipids in suspended particulate matter from the East China Sea and implication for sedimentary records

A total of 90 samples of suspended particulate matter (SPM) collected in surface waters of the East China Sea (ECS) in summer and winter were studied for archaeal isoprenoid glycerol dialkyl glycerol tetraether lipids (iGDGTs) and the derived sea surface temperature (SST) proxy, i.e. TEX86H. Our data showed that in summer SPM TEX86H correlated well with in-situ measured SST, but in winter the relationship became much poorer. We found that the bottom water depth (BWD) of 70 m was a critical depth when studying the TEX86H-SST relationship in winter SPM. In locations with BWD < 70 m, concentrations of iGDGTs in SPM were > 5x higher in winter than in summer, but TEX86H showed a much weaker correlation with in-situ measured SST. This was speculated to be caused by lateral transport of SPM and resuspension of surface sediments in winter due to strong winds. Whereas in locations with BWD > 70 m, TEX86H correlated well with in-situ measured SST, suggesting a minor influence of SPM lateral transport and sediment resuspension. Moreover, although only core iGDGTs were analyzed, we found that both summer and winter TEX86H values correlated better with in-situ measured SST than with seasonal and annual mean SST, suggesting that SPM iGDGTs were dominantly produced around the sampling time rather than encompassing longer time input. The linear relationships of SPM TEX86H with in-situ measured SST were different between winter (BWD > 70 m) and summer, likely due to seasonal archaeal community change. Published sedimentary TEX86H data in the ECS were reexamined here, and a BWD of 70 m was also found to be a critical depth. At sites with BWD > 70 m, TEX86H in sediments correlated well with annual mean SST, whereas the correlation became poor at BWD < 70 m, suggesting that sedimentary GDGTs were also greatly influenced by resuspension and lateral transport, and hence complicating the application of the proxy to shallow locations in the ECS.