Transitions Of HCN Research Articles

Tracing dense gas in six resolved GMCs of the Andromeda Galaxy

ABSTRACT We present dense-gas-tracing molecular observations of six resolved Giant Molecular Clouds (GMCs) in the Andromeda Galaxy (M31). Using the NOEMA interferometer, we observed the transitions of HCN(1–0), HCO+(1–0), and HNC(1–0), as well as 13CO(1–0) and 100 GHz continuum emission. This complements our earlier work with the Submillimetre Array, including resolved dust continuum detections of these clouds at 230 GHz. In this work, we first compare different continuum measurements to conclude that the average free–free contamination of the observed flux is 71 per cent at 3 mm but only 13 per cent at 1 mm, confirming that emission at 3 mm is less reliable than that at 1 mm for calculating dust masses of star-forming clouds. While the 13CO emission is more extended than both HCN and HCO+ emission, which in turn is more extended than HNC emission, we find that both HCN and HCO+ are spatially coincident with, and similarly extended as, the 230 GHz dust emission. This suggests that both the 230 GHz dust continuum and most importantly the HCN emission traces the dense gas component of these GMCs. From comparison of the molecular emission with dust masses derived from the 230 GHz continuum emission, we obtain the first direct measurements of the dust-mass-to-light ratios ($\alpha ^\prime _{\rm HCN}$ and $\alpha ^\prime _{\rm HCO^+}$) in GMCs of an external galaxy. For HCN, the result is broadly similar to a measurement in the local Perseus cloud suggesting that these are indeed dense gas conversion factors. A larger cloud sample will be required to assess whether HCN is tracing comparable cloud-scale density regimes across the environments of M31.

Research on Physical Properties in NGC 1068 Nuclear Region Based on ALMA High-resolution Multi-spectral Lines

Using the multi-spectral lines from ALMA (Atacama Large Millimeter/submillimeter Array) with high-resolution (∼ 0.2″–0.7″) and the continuum data, this work studies the physical properties of the nuclear region of nearby galaxy NGC 1068. The spectral lines include CO (1-0), CO (2-1), CO (3-2), HCN (1-0), HCO+ (1-0), HCN (3-2), HCO+ (3-2), HCN (4-3) and HCO+ (4-3). The CND (CircumNuclear Disk) shows an asymmetric ring structure with a size of ∼ 300 pc in the velocity-integrated intensity images. All the molecular lines of the CND show stronger emission at the eastern knot (E-knot) than the western knot (W-knot) of the CND. Furthermore, the E-knot shows larger velocities than the W-knot, which indicates that there is significant rotational pattern in the CND. The dense gas fraction (traced by the different transitions of HCN or HCO+ to CO (1-0) integrated intensity ratios) and dense gas ratio (HCN/HCO+) are higher at the E-knot, implying that the E- and W-knots have different physical environments or chemical compositions. The HCN emission in the CND show enhancement compared with HCO+, which could be affected by the AGN (Active Galactic Nucleus) radiation and starburst activity. The CO (3-2)/CO (1-0) integrated intensity ratio is a significant indicator of gas excitation. CO (3-2)/CO (1-0) ratios show much higher values at the E-knot, suggesting that there is molecular excitation enhancement caused by the extreme physical environment. Compared with the fluxes of HCN (4-3) and HCO+ (4-3) from the single-dish telescope JCMT (James Clerk Maxwell Telescope), the ALMA missing fluxes of dense molecular gas on 1 kpc scale are about 10%–20%. The spectral lines show that the flux ratios between E-knot and W-knot are ∼ 1.8–3.9. These differences shown between E-knot and W-knot may be associated with the AGN feedback. In addition, the CO (2-1), CO (1-0) and HCO+ (1-0) spectra show absorption features in the position of AGN. This absorption could be caused by the strong background of continuum emissions, and the gas inflow around the AGN can produce self-absorption in spectra.

Signatures of Reaction Mechanisms Encoded in the Vibrational Population Distribution of Small-Molecule Products: Photodissociation of Symmetric-Triazine Using 266 nm Radiation

We utilize rotationally resolved Chirped-Pulse Fourier Transform millimeter-wave spectroscopy to study photodissociation dynamics of 1,3,5-Triazine (symmetric-Triazine) to form 3 HCN molecules. The state-specific vibrational population distribution (VPD) of the photofragments contains mechanistic details of the reaction. This photodissociation is performed using 266 nm radiation transverse to a seeded supersonic jet. The vibrational cooling inefficiency in the jet preserves the VPD of the photofragments, while rotational cooling enhances the signal of low-J pure-rotational transitions. The multiplexed nature of the spectrometer enables simultaneous sampling of several "vibrational satellites" of the J = 1 ← 0 transition of HCN. Excited state populations along the HCN bend (v2) and CN stretch (v3) modes are observed, which show ≥3.2% vibrational excitation of the photofragments. Observation of an at least bimodal VPD, along the even-v states of v2, implies an asymmetric partitioning of vibrational energy among the HCN photofragments. This suggests a sequential dissociation mechanism of symmetric-Triazine initiated by 266 nm radiation.

Central molecular zones in galaxies: Multitransition survey of dense gas tracers HCN, HNC, and HCO+

New measurements of 46 nearby galaxy centers in up to three transitions of HCN, HNC, and HCO+ combined with literature surveys establish a database of 130 galaxies measured in both HCN and HCO+, and 94 galaxies in HNC as well, allowing a systematic exploration of the relations between normalized luminosities and line ratios. The almost linear relations between luminosities are predominantly caused by distance effects and do not reflect galaxy physical properties. Individual galaxies show significant dispersion in both their luminosity and line ratio, which will be analyzed in more detail in a later paper. Very few line ratios correlate either with luminosities or with other line ratios. Only the normalized transition ladders of HCN and HCO+ and the J = 1 − 0 12CO/13CO isotopologue ratio are positively correlated with CO and far infrared (FIR) luminosity. On average, HCN and HCO+ have very similar intensities and trace the same gas. In galaxies dominated by an active nucleus, HCO+ intensities appear to be depressed relative to HCN intensities. Only a small fraction of CO emission is associated with gas emitting in HCN and HCO+, yet a significant fraction of even that gas appears to be translucent molecular gas. In the observed galaxy centers, the HCN/CO line intensity ratio is not a proxy for the dense gas fraction, and the FIR/HCN and FIR/CO ratios are not proxies for the star formation efficiency. A proper understandig of star formation requires a more appropriate determination of gas mass than provided by the intensities of individual HCN or CO transitions. The observed molecular line emission is fully consistent with UV-photon heating boosted by significant mechanical heating. The molecular gas sampled by HCN and HCO+ has low kinetic temperatures Tkin = 10 − 50 K, low densities nH = 104 − 105 cm−3, and low optical depths in the ground-state lines. Most of the gas sampled by CO has densities lower by one to two orders of magnitude. For a mechanical heating fraction of 0.5, a modest energy input of only G = 300 G0 is required.

A Complete HCN Survey of the Perseus Molecular Cloud

We present a survey of the Perseus molecular cloud in the J = 1 → 0 transition of HCN, a widely used tracer of dense molecular gas. The survey was conducted with the CfA 1.2 m telescope, which at 89 GHz has a beamwidth of 11′ and a spectral resolution of 0.85 km s−1. A total of 8.1 deg2 was surveyed on a uniform 10′ grid to a sensitivity of 14 mK per channel. We compared the survey with similar surveys of CO and dust in order to study and calibrate the HCN line as a dense-gas tracer. We find the HCN emission to extend over a considerable fraction of the cloud. We show that the HCN intensity remains linear with H2 column density well into the regime where the CO line saturates. We use radiative-transfer modeling to show that this likely results from subthermal excitation of HCN in a cloud where the column and volume densities of H2 are positively correlated. To match our HCN observations the model requires an exponential decrease in HCN abundance with increasing extinction, consistent with HCN depletion onto grains. The modeling also reveals that the mean volume density of H2 in the HCN-emitting regions is ∼104 cm−3, well below the HCN critical density. For the first time, we obtain a direct measurement of the ratio of dense-gas mass to HCN luminosity for an entire nearby molecular cloud: α(HCN) = 92 M ⊙/(K km s−1 pc2).

PRUSSIC

Dusty star-forming galaxies (DSFGs) at redshiftz ≥ 1 are among the most vigorously star-forming galaxies in the Universe. However, their dense (≥105cm−3) gas phase – typically traced by HCN(1–0) – remains almost entirely unexplored: only two DSFGs have been detected in HCN(1–0) to date. We present the results of aKarl G. JanskyVery Large Array survey of theJ = 1–0 transition of HCN, HCO+, and HNC(1–0) in six strongly lensed DSFGs atz = 2.5 − 3.3, effectively doubling the number of DSFGs with deep observations of these lines. We detect HCN(1–0) emission in one source (J1202+5354, 4.6σ), with a tentative HCO+(1–0) detection in another (J1609+6045, 3.3σ). Spectral stacking yields strict upper limits on the HCN/FIR (≤3.6 × 10−4) and HCN/CO(1–0) ratios (≤0.045). The inferred HCN/FIR ratios (a proxy for the star-formation efficiency) are consistent with those inz ∼ 0 far-infrared-luminous starbursts. However, the HCN/CO ratios – a proxy for the dense-gas fraction – are a factor of a few lower than suggested by the two previous DSFG detections. Our results imply that most DSFGs have low dense-gas fractions. A comparison with theoretical models of star-forming galaxies indicates that the bulk of gas in DSFGs is at lower densities (≈102cm−3), similar to ‘normal’ star-forming galaxies, rather than ultraluminous starbursts.

Vibrationally excited HCN transitions in circumstellar envelopes of carbon-rich AGB stars

Context. The most abundant molecule after H2 and CO in the circumstellar envelopes (CSEs) of carbon-rich asymptotic giant branch (AGB) stars is HCN. Its rotational lines within vibrationally excited states are exceptional tracers of the innermost region of carbon-rich CSEs. Aims. We aim to constrain the physical conditions of CSEs of carbon-rich stars using thermal lines of the HCN molecule. Additionally, we also search for new HCN masers and probe the temporal variations for HCN masers, which should shed light on their pumping mechanisms. Methods. We observed 16 carbon-rich AGB stars in various HCN rotational transitions, within the ground and 12 vibrationally excited states, with the Atacama Pathfinder Experiment (APEX) 12-metre sub-millimetre telescope. Results. We detect 68 vibrationally excited HCN lines from 13 carbon-rich stars, including 39 thermal transitions and 29 maser lines, suggesting that vibrationally excited HCN lines are ubiquitous in carbon-rich stars. Population diagrams constructed for two objects from the sample, for thermal transitions from different vibrationally excited states, give excitation temperatures around 800–900 K, confirming that they arise from the hot innermost regions of CSEs (i.e. r <20 R*). Among the detected masers, 23 are newly detected, and the results expand the total number of known HCN masers lines towards carbon-rich stars by 47%. In particular, the J = 2−1 (0, 3le, 0), J = 3−2 (0, 2, 0), and J = 4−3 (0, 11f, 0) masers are detected in an astronomical source for the first time. Our observations confirm temporal variations of the 2−1 (0, 11e, 0) maser on a timescale of a few years. Our analysis of the data suggests that all detected HCN masers are unsaturated. A gas kinetic temperature of ≳700 K and an H2 number density of >108 cm−3 are required to excite the HCN masers. In some ways, HCN masers in carbon-rich stars might be regarded as an analogy of SiO masers in oxygen-rich stars.

Spatially resolved star-formation relations of dense molecular gas in NGC 1068

Context. According to the current understanding of star formation (SF), the regulation of this phenomenon in galaxy disks reflects a complex balance between processes that operate in molecular gas on local cloud scales as well as on global disk scales. Aims. We analyse the influence of the dynamical environment on the SF relations of the dense molecular gas in the starburst (SB) ring of the Seyfert 2 galaxy NGC 1068. Methods. We used ALMA to image the emission of the 1–0 transitions of HCN and HCO+, which trace dense molecular gas in the r ∼ 1.3 kpc SB ring of NGC 1068, with a resolution of 56 pc. We also used ancillary data of CO(1–0) as well as CO(3–2) and its underlying continuum emission at the resolutions of ∼100 pc and ∼40 pc, respectively. These observations allow us to probe a wide range of molecular gas densities (nH2 ∼ 103 − 5 cm−3). The star-formation rate (SFR) in the SB ring of NGC 1068 is derived from Paα line emission imaged by HST/NICMOS. We analyse how different formulations of SF relations change depending on the adopted aperture sizes and on the choice of molecular gas tracer. Results. The scatter in the Kennicutt–Schmidt relation, linking the SFR density (ΣSFR) with the (dense) molecular gas surface density (Σdense), is about a factor of two to three lower for the HCN and HCO+ lines compared to that derived from CO(1–0) for a common aperture. Correlations lose statistical significance below a critical spatial scale of ≈300−400 pc for all gas tracers. The SF efficiency of the dense molecular gas, defined as SFEdense ≡ ΣSFR/Σdense, shows a scattered distribution as a function of the HCN luminosity (L′(HCN)) around a mean value of ≃0.01 Myr−1. An alternative prescription for SF relations, which includes the dependence of SFEdense on the combination of Σdense and the velocity dispersion (σ), resolves the degeneracy associated with the SFEdense − L′(HCN) plot. The SFEdense values show a positive trend with the boundedness of the gas, measured by the parameter b ≡ Σdense/σ2. We identify two branches in the SFEdense − b plot that correspond to two dynamical environments within the SB ring; they are defined by their proximity to the region where the spiral structure is connected to the stellar bar. This region corresponds to the crossing of two overlapping density wave resonances, where an increased rate of cloud-cloud collisions would favour an enhanced compression of molecular gas. Conclusions. These results suggest that galactic dynamics plays a major role in the efficiency of the conversion of gas into stars. Our work adds supporting evidence that density-threshold SF models, which argue that the SFEdense should be roughly constant, fail to account for spatially resolved SF relations of dense gas in the SB ring of NGC 1068.

Emission from HCN and CH3OH in comets

Aims. The aim of this work is to characterise HCN and CH3OH emission from recent comets. Methods. We used the Onsala 20-m telescope to search for millimetre transitions of HCN towards a sample of 11 recent and mostly bright comets in the period from December 2016 to November 2019. Also, CH3OH was searched for in two comets. The HCN sample includes the interstellar comet 2I/Borisov. For the short-period comet 46P/Wirtanen, we were able to monitor the variation of HCN emission over a time-span of about one month. We performed radiative transfer modelling for the observed molecular emission by also including time-dependent effects due to the outgassing of molecules. Results. HCN was detected in six comets. Two of these are short-period comets and four are long-period. Six methanol transitions were detected in 46P/Wirtanen, enabling us to determine the gas kinetic temperature. From the observations, we determined the molecular production rates using time-dependent radiative transfer modelling. For five comets, we were able to determine that the HCN mixing ratios lie near 0.1% using contemporary water production rates, ${Q_{{{\rm{H}}_2}{\rm{O}}}}$, taken from other studies. This HCN mixing ratio was also found to be typical in our monitoring observations of 46P/Wirtanen but here we notice deviations of up to 0.2% on a daily timescale which could indicate short-time changes in outgassing activity. From our radiative transfer modelling of cometary comae, we find that time-dependent effects on the HCN level populations are of the order of 5–15% when ${Q_{{{\rm{H}}_2}{\rm{O}}}}$ is around 2 × 1028 mol s−1. The effects may be stronger for comets with lower ${Q_{{{\rm{H}}_2}{\rm{O}}}}$. The exact details of the time-dependent effects depend on the amount of neutral and electron collisions, radiative pumping, and molecular parameters such as the spontaneous rate coefficient.

Early science with the LMT: molecular torus in UGC 5101

ABSTRACT As part of the Early Science Large Millimeter Telescope projects, we report the detection of nine double-peaked molecular lines, produced by a rotating molecular torus, in the ultraluminous infrared galaxies (ULIRG) – Compton-thick active galactic nuclei (AGN) galaxy UGC 5101. The double-peaked lines we report correspond to molecular transitions of HCN, HCO+, HNC, N2H+, CS, C18O, 13CO, and two CN lines; plus the detection of C2H that is a blend of six lines. The redshift search receiver spectra covers the 73–113 GHz frequency window. Low- and high-density gas tracers of the torus have different implied rotational velocities, with a rotational velocity of 149 ± 3 km s−1 for the low-density ones (C18O, 13CO) and 174 ± 3 km s−1 for high-density tracers (HCN, HCO+, HNC, N2H+, CS, and CN). In UGC 5101, we find that the ratio of integrated intensities of HCN to 13CO to be unusually large, probably indicating that the gas in the torus is very dense. Both the column densities and abundances are consistent with values found in AGN, starburst, and ULIRG galaxies. The observed abundance ratios cannot discriminate between X-ray and UV-field-dominated regions.

James Clerk Maxwell Telescope Spectral and Continuum Imaging of Hyperactive Comet 46P/Wirtanen

Abstract The Jupiter-family comet (JFC) 46P/Wirtanen passed the Earth at a distance of 0.077 au on 2018 December 16 UT, presenting a rare opportunity to study the chemical structure of its coma. With the James Clerk Maxwell Telescope we achieved a resolution of 800 km, which is smaller than the scale lengths of some distributed cometary molecules at the comet’s heliocentric distance of 1 au. Spectroscopic observations of the J = 4 − 3 transition of HCN showed generally uniform levels of outgassing activity during the observing period, 2018 December 14–20. Gas expansion velocities were ∼0.6 km s−1, and the derived average HCN production rate was 7.4 × 1024 mol s−1. HCN and CH3OH emissions were detected at least 30″ (1600 km) from the nucleus, and the abundances of these species were typical for a JFC. The radial distribution of CH3OH is consistent with an extended source of sublimation such as a population of icy grains—cometary halo ice primaries, or CHIPs—as has been invoked previously to explain hyperactivity in comets. The abundance of H2CO is normal if it is a daughter species. HNC and CO were not detected, but a sensitive nondetection of CS implies an unusually low CS:H2O ratio of <0.02%. The peak brightness of the 850 μm continuum emissions from icy coma dust particles of size ∼1 mm fell from (52 ± 6) to (40 ± 3) mJy beam−1 through the week, while the size of the dust coma remained essentially constant, with dust extending to ∼1000 km from the nucleus. The total mass of those particles was ∼2 × 108 kg.

LEGO – II. A 3 mm molecular line study covering 100 pc of one of the most actively star-forming portions within the Milky Way disc

ABSTRACT The current generation of (sub)mm-telescopes has allowed molecular line emission to become a major tool for studying the physical, kinematic, and chemical properties of extragalactic systems, yet exploiting these observations requires a detailed understanding of where emission lines originate within the Milky Way. In this paper, we present 60 arcsec (∼3 pc) resolution observations of many 3 mm band molecular lines across a large map of the W49 massive star-forming region (∼100 pc × 100 pc at 11 kpc), which were taken as part of the ‘LEGO’ IRAM-30m large project. We find that the spatial extent or brightness of the molecular line transitions are not well correlated with their critical densities, highlighting abundance and optical depth must be considered when estimating line emission characteristics. We explore how the total emission and emission efficiency (i.e. line brightness per H2 column density) of the line emission vary as a function of molecular hydrogen column density and dust temperature. We find that there is not a single region of this parameter space responsible for the brightest and most efficiently emitting gas for all species. For example, we find that the HCN transition shows high emission efficiency at high column density (1022 cm−2) and moderate temperatures (35 K), whilst e.g. N2H+ emits most efficiently towards lower temperatures (1022 cm−2; <20 K). We determine $X_{\mathrm{CO} (1-0)} \sim 0.3 \times 10^{20} \, \mathrm{cm^{-2}\, (K\, km\, s^{-1})^{-1}}$, and $\alpha _{\mathrm{HCN} (1-0)} \sim 30\, \mathrm{M_\odot \, (K\, km\, s^{-1}\, pc^2)^{-1}}$, which both differ significantly from the commonly adopted values. In all, these results suggest caution should be taken when interpreting molecular line emission.

Weak CS emission in an extremely metal-poor galaxy DDO 70

ABSTRACT In most galaxies like the Milky Way, stars form in clouds of molecular gas. Unlike the CO emission that traces the bulk of molecular gas, the rotational transitions of HCN and CS molecules mainly probe the dense phase of molecular gas, which has a tight and almost linear relation with the far-infrared luminosity and star formation rate (SFR). However, it is unclear whether dense molecular gas exists at very low metallicity, and if exists, how it is related to star formation. In this work, we report ALMA observations of the CS J = 5 → 4 emission line of DDO 70, a nearby gas-rich dwarf galaxy with $\sim \!7{{\ \rm per\ cent}}$ solar metallicity. We did not detect CS emission from all regions with strong CO emission. After stacking all CS spectra from CO-bright clumps, we find no more than a marginal detection of CS J = 5 → 4 transition, at a signal-to-noise ratio of ∼3.3. This 3σ upper limit deviates from the $L^\prime _{\rm CS}$–LIR and $L^\prime _{\rm CS}$–SFR relationships found in local star-forming galaxies and dense clumps in the Milky Way, implying weaker CS emission at given infrared luminosity and SFR. We discuss the possible mechanisms that suppress CS emission at low metallicity.

Multiple nitrogen reservoirs in a protoplanetary disk at the epoch of comet and giant planet formation

The isotopic ratio of nitrogen measured in primitive Solar System bodies shows a broad range of values, the origin of which remains unknown. One key question is whether these isotopic reservoirs of nitrogen predate the comet formation stage or are posterior to it. Another central question is elucidating the processes that can produce the observed variations in the 14N/15N isotopic ratio. Disks that orbit pre-main-sequence (T Tauri) stars provide unique opportunities for observing the chemical content of analogs of the protosolar nebula and therefore for building a comprehensive scenario that can explain the origin of nitrogen in the Solar System and in planet-forming disks. With ALMA, it has become possible to measure isotopic ratios of nitrogen-bearing species in such environments. We present spectrally and spatially resolved observations of the hyperfine structure of the 4−3 rotational transition of HCN and its main isotopologs H13CN and HC15N in the disk orbiting the 8 Myr old T Tauri star TW Hya. The sensitivity allows directly measuring the HCN/H13CN and HCN/HC15N abundance ratios with minimal assumptions. Averaged spatially over the disks, the ratios are 86 ± 4 and 223 ± 21, respectively. The latter value is significantly lower than the CN/C15N ratio of 323 ± 30 in this disk and thus provides the first evidence that two isotopic reservoirs of nitrogen are present in a disk at the stage of giant planet and comet formation. Furthermore, we find clear evidence for an increase in the ratio of HCN to HC15N with radius. The ratio in the outer disk, at 45 au, is 339 ± 28, in excellent agreement with direct measurements in the local interstellar medium, and with the bulk nitrogen isotopic ratio predicted from galactic evolution calculations. In the comet formation region at r = 20 au, the ratio is a factor ≈3 lower, 121 ± 11. This radial increase qualitatively agrees with the scenario in which selective photodissociation of N2 is the dominant fractionation process. However, our isotopic ratios and kinetic temperature of the HCN-emitting layers quantitatively disagree with models of nitrogen chemistry in disks.

A new spectroscopically-determined potential energy surface and ab initio dipole moment surface for high accuracy HCN intensity calculations

Calculations of transition intensities for small molecules like H2O, CO, CO2 based on s high-quality potential energy surface (PES) and dipole moment surface (DMS) can nowadays reach sub-percent accuracy. An extension of this treatment to a system with more complicated internal structure – HCN/HNC (hydrogen cyanide/hydrogen isocyanide) is presented. A highly accurate spectroscopically-determined PES is built based on a recent ab initio PES of the HCN/HNC isomerizing system. 588 levels of HCN with J = (0, 2, 5, 9, 10) are reproduced with a standard deviation from the experimental values of σ=0.0373 cm−1 and 101 HNC levels with J = (0, 2) are reproduced with σ=0.37 cm−1. The dependence of the HCN rovibrational transition intensities on the PES is tested for the wavenumbers below 7200 cm−1. Intensities are computed using wavefunctions generated from an ab initio and our optimized PES. These intensities differ from each other by more than 1% for about 11% of the transitions tested, showing the need to use an optimized PES to obtain wavefunctions for high-accuracy predictions of transition intensities. An ab initio DMS is computed for HCN geometries lying below 11,200 cm−1. Intensities for HCN transitions are calculated using a new fitted PES and newly calculated DMS. The resulting intensities compare much better with experiment than previous calculations. In particular, intensities of the HC stretching and bending fundamental transitions are predicted with the subpercent accuracy.

Exploring the volatile composition of comets C/2012 F6 (Lemmon) and C/2012 S1 (ISON) with ALMA

Comets formed in the outer and cold parts of the disk which eventually evolved into our Solar System. Assuming that the comets have undergone no major processing, studying their composition provides insight in the pristine composition of the Solar Nebula. We derive production rates for a number of volatile coma species and explore how molecular line ratios can help constrain the uncertainties of these rates. We analyse observations obtained with the Atacama Large Millimetre/Submillimetre Array of the volatile composition of the comae of comets C/2012 F6 (Lemmon) and C/2012 S1 (ISON) at heliocentric distances of ~1.45 AU and ~0.56 AU, respectively. Assuming a Haser profile with constant outflow velocity, we model the line intensity of each transition using a 3D radiative transfer code and derive molecular production rates and parent scale lengths. We report the first detection of CS in comet ISON obtained with the ALMA array and derive a parent scale length for CS of ~200 km. Due to the high spatial resolution of ALMA, resulting in a synthesised beam with a size slightly smaller than the derived parent scale length, we are able to tentatively identify CS as a daughter species, i.e., a species produced in the coma and/or sublimated from icy grains, rather than a parent species. In addition we report the detection of several CH3OH transitions and confirm the previously reported detections of HCN, HNC and H2CO as well as dust in the coma of each comet, and report 3sigma upper limits for HCO+. We derive molecular production rates relative to water of 0.2% for CS, 0.06-0.1% for HCN, 0.003-0.05% for HNC, 0.1-0.2% for H2CO and 0.5-1.0% for CH3OH, and show that the modelling uncertainties due to unknown collision rates and kinematic temperatures are modest and can be mitigated by available observations of different transitions of HCN.

Testing the universality of the star-formation efficiency in dense molecular gas

Context. Recent studies with, for example, Spitzer and Herschel have suggested that star formation in dense molecular gas may be governed by essentially the same “law” in Galactic clouds and external galaxies. This conclusion remains controversial, however, in large part because different tracers have been used to probe the mass of dense molecular gas in Galactic and extragalactic studies. Aims. We aimed to calibrate the HCN and HCO+ lines commonly used as dense gas tracers in extragalactic studies and to test the possible universality of the star-formation efficiency in dense gas (≳104 cm-3), SFEdense. Methods. We conducted wide-field mapping of the Aquila, Ophiuchus, and Orion B clouds at ~0.04 pc resolution in the J = 1 − 0 transition of HCN, HCO+, and their isotopomers. For each cloud, we derived a reference estimate of the dense gas mass MHerschelAV > 8, as well as the strength of the local far-ultraviolet (FUV) radiation field, using Herschel Gould Belt survey data products, and estimated the star-formation rate from direct counting of the number of Spitzer young stellar objects. Results. The H13CO+(1–0) and H13CN(1–0) lines were observed to be good tracers of the dense star-forming filaments detected with Herschel. Comparing the luminosities LHCN and LHCO+ measured in the HCN and HCO+ lines with the reference masses MHerschelAV > 8, the empirical conversion factors αHerschel − HCN (=MHerschelAV > 8/LHCN) and αHerschel − HCO+ (=MHerschelAV > 8/LHCO+) were found to be significantly anti-correlated with the local FUV strength. In agreement with a recent independent study of Orion B by Pety et al., the HCN and HCO+ lines were found to trace gas down to AV ≳ 2. As a result, published extragalactic HCN studies must be tracing all of the moderate density gas down to nH2 ≲ 103 cm-3. Estimating the contribution of this moderate density gas from the typical column density probability distribution functions in nearby clouds, we obtained the following G0-dependent HCN conversion factor for external galaxies: αHerschel − HCNfit′ = 64 × G0-0.34. Re-estimating the dense gas masses in external galaxies with αHerschel − HCNfit′(G0), we found that SFEdense is remarkably constant, with a scatter of less than 1.5 orders of magnitude around 4.5 × 10-8 yr-1, over eight orders of magnitude in dense gas mass. Conclusions. Our results confirm that SFEdense of galaxies is quasi-universal on a wide range of scales from ~ 1–10 pc to > 10 kpc. Based on the tight link between star formation and filamentary structure found in Herschel studies of nearby clouds, we argue that SFEdense is primarily set by the “microphysics” of core and star formation along filaments.

15N fractionation in infrared-dark cloud cores

Nitrogen is one of the most abundant elements in the Universe and its 14N/15N isotopic ratio has the potential to provide information about the initial environment in which our Sun formed. Recent findings suggest that the Solar System may have formed in a massive cluster since the presence of short-lived radioisotopes in meteorites can only be explained by the influence of a supernova. The aim of this project is to determine the 14N/15N ratio towards a sample of cold, massive dense cores at the initial stages in their evolution. We have observed the J=1-0 transitions of HCN, H13CN, HC15N, HN13C and H15NC toward a sample of 22 cores in 4 Infrared-Dark Clouds (IRDCs). IRDCs are believed to be the precursors of high-mass stars and star clusters. Assuming LTE and a temperature of 15K, the column densities of HCN, H13CN, HC15N, HN13C and H15NC are calculated and their 14N/15N ratio is determined for each core. The 14N/15N ratio measured in our sample of IRDC cores range between ~70 and >763 in HCN and between ~161 and ~541 in HNC. They are consistent with the terrestrial atmosphere (TA) and protosolar nebula (PSN) values, and with the ratios measured in low-mass pre-stellar cores. However, the 14N/15N ratios measured in cores C1, C3, F1, F2 and G2 do not agree with the results from similar studies toward the same massive cores using nitrogen bearing molecules with nitrile functional group (-CN) and nitrogen hydrides (-NH) although the ratio spread covers a similar range. Amongst the 4 IRDCs we measured relatively low 14N/15N ratios towards IRDC G which are comparable to those measured in small cosmomaterials and protoplanetary disks. The low average gas density of this cloud suggests that the gas density, rather than the gas temperature, may be the dominant parameter influencing the initial nitrogen isotopic composition in young PSN.

JCMT Spectral and Continuum Imaging of Comet 252P/LINEAR

Abstract Comet 252P/LINEAR passed the Earth at a distance of 0.035 au on 2016 March 21, presenting a rare opportunity to study a comet at high spatial resolution. Even with a single dish facility such as JCMT, the chemical structure of the coma could be observed on scales of 500–1000 km, which are smaller than the scale lengths of known distributed cometary molecules. Our week-long observing campaign at JCMT started on March 27 (UT), 12 days after perihelion, and ended on April 3, during which time the comet's distance from Earth increased from 0.045 to 0.078 au. Our observations of the J = 4 − 3 transition of HCN showed generally uniform levels of activity. Expansion velocities were ∼0.6 km s−1 (±10%), and the derived mean HCN production rate during the week was 6.4 × 1024 mol s−1. Comparison with independent estimates of the water production rate during the same period yields a mixing ratio of 0.12% with respect to water. Methanol emissions appear to arise from an extended source—probably in the form of an ice halo—suggesting that all the gases from 252P may originate in large part from the sublimation of icy grains in the coma. Adopting a mean dust particle size of 1 mm, the mass of dust in the coma at the same time is estimated at 4 × 107 kg, implying a total dust production rate of 4 kg s−1. The dust-to-gas mass ratio of ∼0.025 is one of the lowest values ever observed for a comet.

Constraining cloud parameters using high density gas tracers in galaxies

Far-infrared molecular emission is an important tool used to understand the excitation mechanisms of the gas in the inter-stellar medium of star-forming galaxies. In the present work, we model the emission from rotational transitions with critical densities n >~ 10^4 cm-3. We include 4-3 < J <= 15-14 transitions of CO and 13CO, in addition to J <= 7-6 transitions of HCN, HNC, and HCO+ on galactic scales. We do this by re-sampling high density gas in a hydrodynamic model of a gas-rich disk galaxy, assuming that the density field of the interstellar medium of the model galaxy follows the probability density function (PDF) inferred from the resolved low density scales. We find that in a narrow gas density PDF, with a mean density of ~10 cm-3 and a dispersion \sigma = 2.1 in the log of the density, most of the emission of molecular lines, emanates from the 10-1000 cm-3 part of the PDF. We construct synthetic emission maps for the central 2 kpc of the galaxy and fit the line ratios of CO and 13CO up to J = 15-14, as well as HCN, HNC, and HCO+ up to J = 7-6, using one photo-dissociation region (PDR) model. We attribute the goodness of the one component fits for our model galaxy to the fact that the distribution of the luminosity, as a function of density, is peaked at gas densities between 10 and 1000 cm-3. We explore the impact of different log-normal density PDFs on the distribution of the line-luminosity as a function of density, and we show that it is necessary to have a broad dispersion, corresponding to Mach numbers >~ 30 in order to obtain significant emission from n > 10^4 cm-3 gas. Such Mach numbers are expected in star-forming galaxies, LIRGS, and ULIRGS. By fitting line ratios of HCN(1-0), HNC(1-0), and HCO+(1-0) for a sample of LIRGS and ULIRGS using mechanically heated PDRs, we constrain the Mach number of these galaxies to 29 < M < 77.