Transition In VO2 Research Articles

Switchable phase modulation and multifunctional metasurface with vanadium dioxide layer

Abstract Metasurface, comprising subwavelength unit cells, offers a flexible modulation of the optical phase. However, traditional metasurfaces are typically engineered to function solely in one mode, limiting their efficiency and adaptability. In this study, we proposed a switchable metasurface consisting of gold bars deposited on polyimide and vanadium dioxide (VO2) layer. Upon the phase transition of VO2, this switchable metasurface exhibits functionality in both transmissive and reflective modes. Specifically, it efficiently converts left circularly polarized (LCP) light into right circularly polarized (RCP) light. For the dielectric (metallic) phases of VO2, the design behaves as metalens with a focal length of 1000 (906) μm at working frequency of 1.2 THz, respectively. Furthermore, the vortex phase can be effectively manipulated with topological number from 1 to 4 through the analysis of the electric field distribution. A directional emission from 12.9° to 42.2° is obtained in the reflective mode and Airy beam paths way can also be well regulated at 1.49 THz. The phase modulation is further achieved by varying the inter-mediums and its thickness. Finally, the sensing ability is explored with different covered solution. Consequently, this multifunctional and adaptable metasurface offers valuable insights for the development of reflectors, modulators, lenses and sensors.

Artificial afferent neurons based on the metal-insulator transition of VO2

Artificial afferent neurons based on the metal-insulator transition of VO2

Subpicosecond Spectroscopic Ellipsometry of the Photoinduced Phase Transition in VO2 Thin Films

Subpicosecond Spectroscopic Ellipsometry of the Photoinduced Phase Transition in VO₂ Thin Films

Highly switchable photonic spin hall effect in vanadium dioxide grating structure

The enhancement and manipulation of the photonic spin Hall effects are essential for the spin photonic applications. The emergence of the phase transition material, vanadium dioxide (VO2), presents a unique chance to explore its conductivity dependent optical properties. However, the explorations on the PSHEs in VO2 based microstructures are quite rare. Here, we report the enhanced and controllable reflected photonic spin Hall effects under the horizontal or vertical polarized wave by establishing the VO2 grating structure. It can be found that associated with the phase transition of VO2, its changed conductivity not only tunes the magnitude of the reflected spin shift but also changes its sign, which even results in a dramatic modulation of the reflected spin shift from the negative maximum value under the vertical polarized wave to the positive maximum value under the horizontal polarized wave at the specific wavelength. Such features can be attributed to the dramatic changes of the reflectances in the VO2 grating structure under different polarizations induced by the changed conductivity of VO2. Our results allow the actively alternative phase transition material based configurations capable of dramatic manipulation of the reflected spin shifts and it constitutes a significant step toward highly switchable spin photonic devices.

In-situ XRD study on phase transition kinetics of vanadium dioxide thin film

Vanadium dioxide (VO2) has great potentials to be used in energy-related fields due to its unique reversible thermochromic metal-insulating properties. In this paper, we used in-situ XRD technique to study the phase transition kinetics of VO2 thin films, which can change phase from monoclinic VO2 (M) to tetragonal rutile VO2 (R). The VO2 thin films were prepared by a simple solution-based sol-gel method followed by spin coating to achieve the nanoscale thickness on a quartz substrate. During heating, the critical phase transition of VO2 (M) occurred at 70 °C, which dropped to 45 °C during cooling. A martensite-like crystal phase transformation kinetic model was established based on the Koistinen and Marburger (KM) technique. The relative content of the two phases was quantitatively analyzed using the Rietveld method, and the transformation rate coefficient α was obtained as 0.20345 and 0.12585, for the heating process from VO2 (M) to VO2 (R) and the cooling process from VO2 (R) to VO2 (M), respectively. This research offers an effective tool for understanding the structural characteristics of thin film VO2, paving the way for its future design and applications towards energy-related fields such as in smart windows.

Multifunctional Radiation Conditioning Emitter for Laser and Infrared with Adaptive Radiative Cooling.

With the development of technology, multifunctional multiband emitters have been paid much attention due to their wide range of applications, such as LIDAR detection, spectroscopic sensing, and infrared thermal management. However, the development of such emitters is impeded by incompatible structural requirements of different electromagnetic wavebands. Here, we demonstrate coupled modulation between near-infrared (NIR) laser-wavelength and long-wavelength-infrared by constructing a multifunctional emitter (MFE) with a structure of Al/HfO2/VO2, utilizing the phase transition of VO2. The MFE displays excellent thermal modulation capability within the 8-14 μm range, achieving a thermal insulation effect (ε8-14μm = 0.18) at low temperatures, and heat dissipation effect (ε8-14μm = 0.64) at high temperatures. The MFE's radiation power regulation capability is 145.06 W m-2 between a temperature of 0 to 60 °C. Moreover, the MFE possesses a large reflectivity modulation value of 0.78 at NIR laser-wavelength (1.06 μm) with a short phase transition time of 1003 ms under 3 W cm-2 laser irradiation. This study provides a guideline for the coordinated control of electromagnetic waves and intelligent collaborative thermal management through simple structural design, thus, having broad implications in energy saving and thermal information processing.

Hidden magnetism and split off flat bands in the insulator metal transition in VO2

Transition metal d-electron oxides with an odd number of electrons per unit cell are expected to form metals with partially occupied energy bands, but exhibit in fact a range of behaviors, being either insulators, or metals, or having insulator-metal transitions. Traditional explanations involved predominantly electron-electron interactions in fixed structural symmetry. The present work focuses instead on the role of symmetry breaking local structural motifs. Viewing the previously observed V-V dimerization in VO2 as a continuous knob, reveals in density functional calculations the splitting of an isolated flat band from the broad conduction band. This leads past a critical percent dimerization to the formation of the insulating phase while lowering the total energy. In VO2 this transition is found to have a rather low energy barrier approaching the thermal energy at room temperature, suggesting energy-efficient switching in neuromorphic computing. Interestingly, sufficient V-V dimerization suppresses magnetism, leading to the nonmagnetic insulating state, whereas magnetism appears when dimerization is reduced, forming a metallic state. This study opens the way to design novel functional quantum materials with symmetry breaking-induced flat bands.

Versatile tunable metastructure based on liquid crystal-VO2 for polarization conversion and refractive index sensing

This paper presents a metastructure device (MSD) modulated by liquid crystal (LC) and vanadium dioxide (VO2), suitable for circular-to-linear polarization conversion and refractive index (RI) sensing. The MSD employs a 2 × 2 array as a unit cell, forming a circular-to-linear polarization conversion. Filling the MSD with analytes of different RIs can cause changes in the electromagnetic properties of the MSD, thus realizing the sensing function. Furthermore, the detection range of the sensing can be modified by changing the long-axis pointing of the LC molecules under an applied voltage, resulting in multi-range detection. The RI unit is denoted as RIU. Without an applied voltage, the RI detection range is 1.949–2.607, with a sensitivity of 199 GHz/RIU; under full-bias conditions, the detection range is 2.828–3.391, with a sensitivity of 143 GHz/RIU. In the initial state of LCs, this paper also explores the use of the phase transition of VO2 to adjust the conductivity of VO2 to achieve changes in the detection range. In the insulating state, the detection range is 2.12–2.607, with a sensitivity of 225 GHz/RIU, while in the metallic state, the detection range is 1–2, with a sensitivity of 183 GHz/RIU. Furthermore, altering the thickness of the analyte also affects the electromagnetic properties of the device, causing a shift in the peak axial ratio frequency, making the MSD suitable for analyte thickness detection. The MSD has a wide detection range, high sensitivity, and adaptability, making it suitable for identifying cancer cells and giving a new method of monitoring human health.

Achieving broadband multifunctional modulation of wavefront via terahertz anisotropic metasurface

Vanadium dioxide (VO2) has become a reliable phase change material (PCM) and is increasingly utilized in multifunctional metasurface design. This study introduces designs of bilayer anisotropic VO2meta-atoms in simulation for multifunctional wavefront modulation in the terahertz band. By leveraging the phase change property of VO2 and incident wave polarization, a reconfigurable metasurface composing anisotropic meta-atoms is proposed with four distinct functions. When VO2 is in its insulating state, the metasurface serves as a hologram generator for the x-polarized wave and a focusing reflector for the y-polarized wave. Upon the transition of VO2 into the metallic state, the metasurface functions as a generator of vortex beam for the x-polarized wave, while as an anomalous reflector for the y-polarized wave. The proposed metasurface showcases an outstanding broadband performance, delivering impressive four-channel wavefront modulation within a frequency range of 2.2–3.0 THz. Depending on the compact structure and integrated multi-functionalities, our design may have immense potential across a wide range of terahertz applications, including communication exchange and multiplexing utilization.

Tunable multifunctional terahertz metamaterial device based on metal-dielectric-vanadium dioxide

The Electromagnetically Induced Transparency (EIT) effect in terahertz (THz) metamaterial devices has garnered extensive attention owing to its distinctive advantages in the slow light devices and quantum communication. However, the application of EIT has been constrained by the limitation to a single transparent window and the fixed intensity of the electromagnetic response at the transmission peak after fabrication. To achieve a dual-frequency EIT effect and enable active tunability, this paper presents a tunable multifunction THz metamaterial device based on vanadium dioxide (VO2). The transition of VO2 from the insulator to the metal allows for the active control of EIT and multi-band absorption switching in the THz range. When VO2 is in its dielectric state, two EIT-like windows could be observed with a maximum value of 86.9 % and 71.7 % of the transmission amplitude, respectively. By adjusting the temperature of the VO2, a modulation depth of up to 99 % can be achieved, enabling active control of the EIT-like effect. In addition, active adjustment of group delay of up to 5.47 ps was demonstrated. When VO2 is in the metallic state, the device serves as a tunable multiband absorber, capable of achieving perfect absorption and modulation amplitude of up to 92 %. The results indicated that the presented devices hold significant value for research in the THz range, particularly for applications related to switching and slow light devices. Therefore, the tunable multifunctional THz metamaterial device is of great significance for THz technology.

Design of an ultra-wideband and switchable VO2-based microwave absorber

We propose a design of an ultra-wideband microwave metamaterial absorber using Vanadium dioxide (VO2) based on a dual-layer structure. The ultra-wideband absorption performance of the proposed structure can switch by using the phase transition of VO2. When the VO2 is in the insulator state, the proposed absorber achieves an ultra-wideband absorption response in the range of 3.7–22.5 GHz with an absorptivity higher than 0.9 and a relative bandwidth of 143.5% at normal incidence, which covers the entire bands from the C to Ku. The designed absorber is polarization insensitive and wide incident angle stable for both transverse electric (TE) and transverse magnetic (TM) modes. Owing to the outstanding merits of absorption performance and frequency-tunable capability, our design structure can be suitable for many promising applications in the microwave range, such as smart radar, camouflage and stealth radome technology.

Electromechanically Reconfigurable Terahertz Stereo Metasurfaces.

Dynamic terahertz devices are vital for the next generation of wireless communication, sensing, and non-destructive imaging technologies. Metasurfaces have emerged as a paradigm-shifting platform, offering varied functionalities, miniaturization, and simplified fabrication compared to their 3D counterparts. However, the presence of in-plane mirror symmetry and reduced degree of freedom impose fundamental limitations on achieving advanced chiral response, beamforming, and reconfiguration capabilities. In this work, a platform composed of electrically actuated resonators that can be colossally reconfigured between planar and 3D geometries is demonstrated. To illustrate the platform, metadevices with 3D Split Ring Resonators are fabricated, wherein two counteracting driving forces are combined: i) folding induced by stress mismatch, which enables non-volatile state design and ii) unfolding triggered by the strain associated with insulator-to-metal transition in VO2, which facilitates volatile structural reconfiguration. This large structural reconfiguration space allows for resonance mode switching, widely tunable magnetic and electric polarizabilities, and increased frequency agility. Moreover, the unique properties of VO2, such as the hysteretic nature of its phase transition is harnessed to demonstrate a multi-state memory. Therefore, these VO2 integrated metadevices are highly attractive for the realization of 6G communication devices such as reconfigurable intelligent surfaces, holographic beam formers, and spatial light modulators.

Metamaterial terahertz device with temperature regulation function that can achieve perfect absorption and complete reflection conversion of ultrawideband

The field of terahertz devices is important in terahertz technology. However, most of the current devices have limited functionality and poor performance. To improve device performance and achieve multifunctionality, we designed a terahertz device based on a combination of VO2 and metamaterials. This device can be tuned using the phase-transition characteristics of VO2, which is included in the triple-layer structure of the device, along with SiO2 and Au. The terahertz device exhibits various advantageous features, including broadband coverage, high absorption capability, dynamic tunability, simple structural design, polarization insensitivity, and incident-angle insensitivity. The simulation results showed that by controlling the temperature, the terahertz device achieved a thermal modulation range of spectral absorption from 0 to 0.99. At 313 K, the device exhibited complete reflection of terahertz waves. As the temperature increased, the absorption rate also increased. When the temperature reached 353 K, the device absorption rate exceeded 97.7% in the range of 5–8.55 THz. This study used the effective medium theory to elucidate the correlation between conductivity and temperature during the phase transition of VO2. Simultaneously, the variation in device performance was further elucidated by analyzing and depicting the intensity distribution of the electric field on the device surface at different temperatures. Furthermore, the impact of various structural parameters on device performance was examined, offering valuable insights and suggestions for selecting suitable parameter values in real-world applications. These characteristics render the device highly promising for applications in stealth technology, energy harvesting, modulation, and other related fields, thus showcasing its significant potential.

Temperature-switchable anti-reflective structure based on vanadium dioxide phase transition in the visible and near-infrared wavelength regions

Nowadays, the anti-reflective (AR) structures are essential in many applications like display screens, photovoltaic structures and light detection and ranging. Traditionally, the AR surfaces are almost multilayer (ML) structures to minimize the reflection value by producing the destructive interference of reflected light beams at the layers’ interfaces. In the new and advanced AR surfaces, nanostructures (NS) are proposed and used for minimizing the reflection. In this paper, we propose a temperature-switchable AR-ML-NS, based on vanadium dioxide (VO2) phase transition from semiconductor to metallic state around the critical temperature of 68 °C. Here, a pyramidal NS of VO2 is considered on top surface of a ML which minimizes the light reflection of the structure. While some AR structures may work in some restricted light wavelengths, here our proposed structure’s AR wavelength region can be tuned between the visible and near-infrared (NIR) region through the thermal phase transition of VO2. VO2 phase control leads to a temperature-switchable AR structure, which is of great importance for investigating different switchable AR structures.

Interfacial second harmonic generation switching with 2D monolayer/VO2 heterostructure

To establish a facile nonlinear optical switching mechanism activated by thermal field, that is compatible with on-chip integration, we develop a physical model to quantify the interfacial second harmonic generation (SHG) of 2D monolayer/3D phase-changing material heterostructure. Our results show that heat-induced phase transition of VO2 can realize temperature-reversible interfacial SHG switching, with an ON-OFF ratio of about 3 and a low temperature threshold of about 60 °C. Experimental results can be well addressed by quantitative calculations based on the physical model. This work constitutes substantial insights into interfacial SHG switching, which will benefit design and construction of on-chip nonlinear optical devices based on 2D monolayers.

Tunable High-Performance Electromagnetic Interference Shielding of VO2 Nanowires-Based Composite.

The unique metal-insulator transition of VO2 is very suitable for dynamic electromagnetic (EM) regulation materials due to its sharp change in electrical conductivity. Here, we have developed an off/on switchable electromagnetic interference (EMI) shielding composite by interconnecting VO2 nanowires (NWs) in poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) to form conductive networks, resulting in outstanding performance at the X and Ku bands with maximum change values of 44.8 and 59.4 dB, respectively. The unique insulator-to-metal transition (IMT) of VO2 NWs has dominated the variation of polarization loss (εp″) and conductivity loss (εσ″) for the composites, which is the mechanism of EMI shielding switching between off and on states. Furthermore, the composite exhibits good cycling stability of the off/on switchable EMI shielding performance and has excellent mechanical properties, especially with 200 times abrasion resistance without obvious weight loss. This study provides a unique approach for dynamic switching of EM response with the potential to construct practical intelligent EM response systems for next-generation smart electromagnetic devices in various scenarios.

Challenges for density functional theory in simulating metal-metal singlet bonding: A case study of dimerized VO2.

VO2 is renowned for its electric transition from an insulating monoclinic (M1) phase, characterized by V-V dimerized structures, to a metallic rutile (R) phase above 340K. This transition is accompanied by a magnetic change: the M1 phase exhibits a non-magnetic spin-singlet state, while the R phase exhibits a state with local magnetic moments. Simultaneous simulation of the structural, electric, and magnetic properties of this compound is of fundamental importance, but the M1 phase alone has posed a significant challenge to the density functional theory (DFT). In this study, we show none of the commonly used DFT functionals, including those combined with on-site Hubbard U to treat 3d electrons better, can accurately predict the V-V dimer length. The spin-restricted method tends to overestimate the strength of the V-V bonds, resulting in a small V-V bond length. Conversely, the spin-symmetry-breaking method exhibits the opposite trends. Each of these two bond-calculation methods underscores one of the two contentious mechanisms, i.e., Peierls lattice distortion or Mott localization due to electron-electron repulsion, involved in the metal-insulator transition in VO2. To elucidate the challenges encountered in DFT, we also employ an effective Hamiltonian that integrates one-dimensional magnetic sites, thereby revealing the inherent difficulties linked with the DFT computations.

Information encryption driven by strength-switchable circular dichroism in vanadium dioxide based chiral metasurfaces

Switchable polarization selectivity in reconfigurable metasurfaces is highly required in the field of information encryption. In this paper, we proposed a scheme of information encryption by using the giant and strength-switchable circular dichroism (CD) in VO2-based chiral metasurfaces in the mid-infrared region. A bar code information is encrypted and hidden into a VO2-based bielliptic cylinder (BC) and bielliptic cylinder enantiomer (BCE) constructed array. The metallic VO2-based BC and BCE arrays with the rotation angles (α=±14°) exhibit opposite CD (−0.94/0.94) at 6330 nm. With the VO2 transition from metallic to insulator phase, the giant polarization selectivity of both BC and BCE arrays will disappear. Hence, only when the specific environment temperature (>68 °C) and polarization state of incident light (LCP) are simultaneously satisfied, the secret information could be decrypted. The reversible CD in VO2-based chiral metasurfaces possesses great potentials for the application of optical information encryption.

Bi-directional extraordinary absorption, transmission multifunctional metamaterial based on circular metal-VO2 composites

Multifunctional metamaterials play a crucial role in advancing terahertz technology. In this paper, a multifunctional metamaterial composed solely of circular metal-vanadium dioxide (VO2) is designed and numerically demonstrated. The device comprises a top layer of circular VO2 ring, two polyimide dielectric layers, with two metal layers etched and filled with VO2, and a bottom embedded silver (Ag) circular ring dielectric layer. The metamaterial serves as a broadband and narrowband absorptive or transmissive substrate, utilizing the phase transition of VO2 between its metal and dielectric states. When VO2 is in its metal phase, the top circular VO2 ring periodic array functions as a broadband absorber, exhibiting a relative absorption bandwidth of approximately 93%. Meanwhile, the bottom circular Ag ring periodic array functions as a narrowband absorber and exhibits high sensitivity. In contrast, when VO2 is in the insulating phase, the metamaterial acts as a broadband transmittance substrate, exhibiting a maximum transmittance greater than 85%. This proposed metamaterial holds tremendous potential for utilization across various applications within the terahertz band, spanning from terahertz stealth radar to tunable biosensors and photodetectors.

Realization of an Adaptive Radiative Cooler with a Multilayer-Filter VO2-Based Fabry–Pérot Cavity

A high-performance adaptive radiative cooler comprising a multilayer-filter VO2-based Fabry–Pérot (FP) cavity is proposed. The bottom FP cavity has four layers, VO2/NaCl/PVC/Ag. Based on the phase transition of VO2, the average emissivity in the transparent window can be switched from 3.7% to 96.3%. Additionally, the average emissivity can also be adjusted with external strain to the PVC layer, providing another way to attain the desired cooling effect. An upper filter is included to block most of the solar radiation and provide a transmittance of 96.7% in the atmospheric window. At high temperature, the adaptive emitter automatically activates radiative cooling. The net cooling power is up to 156.4 W⋅m−2 at an ambient temperature of 303 K. Our adaptive emitter still exhibits stable selective emissivity at different incident angles and heat transfer coefficients. At low temperature, the radiative cooling automatically deactivates, and the average emissivity decreases to only 3.8%. Therefore, our work not only provides new insights into the design of high-performance adaptive radiative coolers but also advances the development of intelligent thermal management.