Transitions Of Molecular Iodine Research Articles

Precision spectroscopy and frequency determination of the hyperfine components of the P(63) 4-4 transition of molecular iodine near 652 nm

Precision spectroscopy and frequency determination of the hyperfine components of the P(63) 4-4 transition of molecular iodine near 652 nm

Measurement of transition frequencies and hyperfine constants of molecular iodine at 520.2 nm

We measured the transition frequencies of the hyperfine components in the four lines (P(34) 39-0, R(36) 39-0, P(33) 39-0, and R(35) 39-0) of the B-X transitions of molecular iodine at 520.2 nm. The 520.2 nm laser was generated by wavelength-converting the output of a 1560.6 nm external-cavity diode laser using a dual-pitch periodically poled lithium niobate (PPLN) waveguide. The frequencies were measured by counting the heterodyne beats between the laser stabilized at the frequencies of the hyperfine components and a frequency comb synchronized with a hydrogen maser. We determined the transition frequencies of the a1 components with relative uncertainties of 1×10−11; the uncertainty was limited by the impurity of the molecular iodine in the cell. From the measured hyperfine splitting frequencies, we calculated the hyperfine constants of these four transitions to obtain the rotational dependence of the excited-state hyperfine constants.

The CCL-K11 ongoing key comparison. Final report for 2022

Main textTwo lasers from two national metrological institutes (NMIs) were compared in the year 2022 as part of the CCL-K11 ongoing key comparison, initiated by the 13th meeting of the Comité Consultative des Longuers (CCL) in 2007. The absolute frequency of R(127) 11-5 (≈633 nm) transitions of molecular iodine was measured for these lasers following the technical protocol for CCL-K11. The results of these measurements are compiled in the present report. The comparison reports, as communicated by each participant, are included in the main document.This document constitutes the twelfth final report for the ongoing key comparison CCL-K11.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

An ultra-stable laser based on molecular iodine with a short-term instability of 3.3 × 10−15 for space based gravity missions

Many space based gravity missions require frequency stabilized lasers with stringent requirements. Toward those requirements, we develop a compact frequency-stabilized laser which is referenced to the R(56)32−0: a1 transition of molecular iodine based on the modulation transfer spectroscopy technique. The stability of the laser is limited by the beam pointing noise, the electronic servo noise, and the residual amplitude modulation (RAM) noise. To improve the beam pointing stability, the system is constructed by gluing most components of the optical system on an ultra-low expansion glass base. We use a pre-amplifier to suppress the electronic servo noise, and use a wedged electro-optic phase modulator to suppress the RAM noise. The fractional frequency instability of the system is evaluated to be 3.3 × 10−15 at 2 s and 4 s averaging time, and is lower than 6 × 10−15 at averaging times from 1 s to 10 000 s. To our knowledge, this is the best short-term (1–4 s) instability reported so far for an iodine stabilized laser. The stability fully meets the requirements of next generation gravity mission and laser interferometer space antenna mission.

Stabilizing Frequency of a Diode Laser to a Reference Transition of Molecular Iodine through Modulation Transfer Spectroscopy

We report the frequency stabilization of an external cavity diode laser (ECDL) to a reference molecular iodine (I2) transition at 13,531.18 cm−1 (739.03382 nm). Using the Modulation Transfer Spectroscopy (MTS) method for the highly sensitive detection of weak absorption signals, the Doppler-free absorption peaks of I2 corresponding to the hot band transition R(78) (1–11) are resolved. The ECDL’s frequency is stabilized with respect to one of the lines lying within the reference absorption band. For this, the iodine vapor cell is heated to 450 °C and the corresponding circularly polarized pump and probe beam powers are maintained at 10 mW and 1 mW, respectively, to avoid power broadening. The short (100 ms) and long-term (50 h) linewidths of the frequency stabilized laser are measured to be 0.75(3) MHz and 0.5(2) MHz, respectively, whereas the natural linewidth of the specific I2-transitions lie within a range of tens of MHz.

Frequency references based on molecular iodine for the study of Yb atoms using the 1S0 - 3P1 intercombination transition at 556 nm.

We used precision spectroscopy to analyze the R(53)24-1, P(49)24-1, and R(95)25-1 lines of molecular iodine (127I2) to establish optical frequency references for the laser cooling of Yb atoms using the 1S0 - 3P1 intercombination transition at 556 nm. A laser frequency instability of < 2 × 10-12 (for 0.01 s < τ < 3000 s, τ is the average time of the measurement) was attained using the observed Doppler-free hyperfine transitions of the iodine lines. The absolute frequencies of the observed 63 hyperfine transitions were determined with an uncertainty of 7 kHz (fractional uncertainty of 1.3 × 10-11). Highly accurate hyperfine constants were determined by fitting the measured hyperfine splittings to a four-term Hamiltonian that includes the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions with an uncertainty of approximately 1 kHz. The observed hyperfine transitions of molecular iodine provide new frequency references for research using atomic Yb, because these transitions are close to the intercombination transition of Yb at 556 nm.

The CCL-K11 ongoing key comparison. Final report for 2021

Main textFour lasers from three national metrological institutes (NMIs) were compared in the year 2021 as part of the CCL-K11 ongoing key comparison, initiated by the 13th meeting of the Comité Consultative des Longuers (CCL) in 2007. The absolute frequency of R(127) 11-5 (≈633 nm) and of R(56) 32-0 (≈532 nm) transitions of molecular iodine was measured for these lasers following the technical protocol for CCL-K11. The results of these measurements are compiled in the present report. The comparison reports, as communicated by each participant, are included in the main document.For the very first time in this key-comparison a standard working on a different operating principle is reported. CMI participated with a frequency doubled Nd:YAG laser stabilized to an iodine transition (Designation: CMI-YAG1). The technical protocol was deliberately designed to accommodate artefacts of different wavelengths in a common framework. Moreover, CMI participated with a second laser standard also. The institute has different CMC entries for the two laser types. Both entries refer to the same service category of highest metrological level, but are technically well separated. Due to the layout of CCL-K11 the KCRV is immune to a multiple participation of a single NMI. It was thus considered to include both measurements in this report.This document constitutes the 11th final report for the ongoing key comparison CCL-K11.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Long-term stable optical cavity for special relativity tests in space.

BOOST (BOOst Symmetry Test) is a proposed space mission to search for Lorentz invariance violations and aims to improve the Kennedy-Thorndike parameter constraint by two orders of magnitude. The mission consists of comparing two optical frequency references of different nature, an optical cavity and a hyperfine transition in molecular iodine, in a low Earth orbit. Naturally, the stability of the frequency references at the orbit period of 5400 s (f=0.18 mHz) is essential for the mission success. Here we present our experimental efforts to achieve the required fractional frequency stability of 7.4×10-14 Hz -1/2 at 0.18 mHz (in units of the square root of the power spectral density), using a high-finesse optical cavity. We have demonstrated a frequency stability of (9±3)×10-14 Hz -1/2 at 0.18 mHz, which corresponds to an Allan deviation of 10-14 at 5400 s. A thorough noise source breakdown is presented, which allows us to identify the critical aspects to consider for a future space-qualified optical cavity for BOOST. The major noise contributor at sub-milli-Hertz frequency was related to intensity fluctuations, followed by thermal noise and beam pointing. Other noise sources had a negligible effect on the frequency stability, including temperature fluctuations, which were strongly attenuated by a five-layer thermal shield.

Absolute laser frequency stabilization for LISA

The LISA space mission requires laser frequency pre-stabilization of the 1064[Formula: see text]nm laser sources. While cavity-based systems are the current baseline, laser frequencies stabilized to a hyperfine transition in molecular iodine near 532[Formula: see text]nm are a possible alternative. Several setups with respect to space applications were developed, putting special emphasis on compactness and mechanical and thermal stability of the optical setup. Vibration testing and thermal cycling were performed. These setups show frequency noise below 20[Formula: see text]Hz/[Formula: see text] for frequencies between 4[Formula: see text]mHz and 1[Formula: see text]Hz with an absolute frequency reproducibility better than 1[Formula: see text]kHz. They fulfil the LISA requirements and offer an absolute laser frequency simplifying the initial spacecraft acquisition procedure. We present the current status of iodine-based frequency references and their applicability in space missions, especially within the LISA mission.

Absolute frequency measurements for emission transitions of molecular iodine in the range of 1053 – 1068 nm

Results of high-precision frequency measurements are presented for certain components of the 127I2 hyperfine structure, which correspond to emission transitions of the B – X band in the range of 1053 – 1068 nm. The frequencies are measured by using a femtosecond optical frequency synthesiser based on a Ti:sapphire laser. The hyperfine structure is resolved by the method of three-level laser spectroscopy. The frequency-doubled cw Nd : YAG laser is used as an excitation radiation source, and the probe radiation in the range of 1050 – 1070 nm is generated by an external-cavity diode laser. The frequencies of both lasers are simultaneously locked to those of two adjacent hyperfine structure components of iodine lines, which have a common upper level. Correspondingly, the frequency of the Nd : YAG laser is locked to the frequency of the absorption transition component, and the diode laser frequency – to the frequency of the emission transition component. The radiation frequency of the diode laser ‘locked’ in this way is measured. Frequencies of 18 hyperfine structure components for six emission lines corresponding to the bands (32 – 54) and (32 – 53) are measured. The relative uncertainty of the measurement is 8 × 10–10.

Absolute frequency measurement of molecular iodine hyperfine transition at 534 nm

We report absolute frequency measurements of 19 hyperfine components of the rovibrational transition of molecular iodine R(53) 31-0 transitions at 534 nm with an optical frequency comb. The 534 nm laser, which is frequency-doubled from a 1068 nm external-cavity diode laser, is frequency stabilized to a hyperfine component of the I2127 R(53) 31-0 transition using modulation transfer spectroscopy. A frequency stability of 8×10−12 at 1 s averaging time is achieved when its frequency is stabilized to the a21 component. To obtain the absolute frequency, the pressure shift and power shift of the a21 component are investigated. The absolute frequency of the laser locked to the a21 hyperfine component of the R(53) 31-0 transition is measured to be 561 420 951 318±8 (type-A) ±12 (type-B) kHz. The observed hyperfine transitions of the iodine can be good frequency references at 534 nm and are especially useful for research on the aluminum ion optical clock, because the frequency of the iodine hyperfine transitions is close to the second sub-harmonic frequency of the S01-P13 transition of the aluminum ion at 267 nm.

BOOST: A satellite mission to test Lorentz invariance using high-performance optical frequency references

BOOST (BOOst Symmetry Test) is a proposed satellite mission to search for violations of Lorentz invariance by comparing two optical frequency references. One is based on a long-term stable optical resonator, and the other is based on a hyperfine transition in molecular iodine. This mission will allow us to determine several parameters of the standard model extension in the electron sector up to 2 orders of magnitude better than with the current best experiments. Here, we will give an overview of the mission, the science case, and the payload.

The CCL-K11 on-going key comparison. Final report for the year 2016

Lasers from two national metrological institutes (NMIs) were compared in 2016 as part of the CCL-K11 on-going key comparison, initiated by the 13th meeting of the Comité Consultative des Longueurs (CCL) in 2007. The absolute frequency of R(127) 11-5 transitions of molecular iodine was measured for these lasers following the technical protocol for CCL-K11. The results of these measurements are compiled in the present report. The comparison reports, as communicated by each participant, are included as appendices.This document constitutes the eighth final report for the on-going key comparison CCL-K11.Main textTo reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

The CCL-K11 on-going key comparison. Final report for the year 2017

A laser from one national metrological institute (NMI) was compared in 2017 as part of the CCL-K11 on-going key comparison, initiated by the 13th meeting of the Comité Consultative des Longueurs (CCL) in 2007. The absolute frequency of R(127) 11-5 transitions of molecular iodine was measured following the technical protocol for CCL-K11. The result of this measurement is compiled in the present report. The comparison report, as communicated by the participant, is included as an appendix.This document constitutes the ninth final report for the on-going key comparison CCL-K11.Main textTo reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Iodine frequency references for space

Optical frequency references are a key element for the realization of future space missions. They are needed for missions related to tests of fundamental physics, gravitational wave detection, Earth observation and navigation and ranging. In missions such as GRACE follow-on or LISA the optical frequency reference is used as light source for high-sensitivity inter-satellite distance metrology. While cavity-based systems are current baseline e.g. for LISA, frequency stabilization on a hyperfine transition in molecular iodine near 532 nm is a promising alternative. Due to its absolute frequency, iodine standards crucially simplify the initial spacecraft acquisition procedures. Current setups fulfill the GRACE-FO and LISA frequency stability requirements and are realized near Engineering Model level. We present the current status of our developments on Elegant Breadboard (EBB) and Engineering Model (EM) level taking into account specific design criteria for space compatibility such as compactness (size iodine spectroscopy EM: 38 × 18 × 10 cm3) and robustness. Both setups achieved similar frequency stabilities of ∼ 1 · 10−14 at an integration time of 1 s and below 5 · 10−15 at integration times between 10 s and 1000 s. Furthermore, we present an even more compact design currently developed for a sounding rocket mission with launch in 2017.

The CCL-K11 ongoing key comparison. Final report for the year 2014

Lasers from four national metrological institutes (NMIs) were compared in 2014 as part of the CCL-K11 ongoing key comparison, initiated by the 13th meeting of the Comité Consultative des Longuers (CCL) in 2007. The absolute frequency of R(127) 11-5 transitions of molecular iodine was measured for these lasers following the technical protocol for CCL-K11. The results of these measurements are compiled in the present report. The comparison reports, as communicated by each participant, are included as appendices.This document constitutes the sixth final report for the ongoing key comparison CCL-K11.Main textTo reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Absolute frequency measurements and hyperfine structures of the molecular iodine transitions at 578 nm

We report absolute frequency measurements of 81 hyperfine components of the rovibrational transitions of molecular iodine at 578 nm using the second harmonic generation of an 1156-nm external-cavity diode laser and a fiber-based optical frequency comb. The relative uncertainties of the measured absolute frequencies are typically $1.4\times10^{-11}$. Accurate hyperfine constants of four rovibrational transitions are obtained by fitting the measured hyperfine splittings to a four-term effective Hamiltonian including the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions. The observed transitions can be good frequency references at 578 nm, and are especially useful for research using atomic ytterbium since the transitions are close to the $^{1}S_{0}-^{3}P_{0}$ clock transition of ytterbium.

The CCL-K11 ongoing key comparison. Final report for the year 2015

Lasers from two national metrological institutes (NMIs) were compared in 2015 as part of the CCL-K11 ongoing key comparison, initiated by the 13th meeting of the Comité Consultative des Longuers (CCL) in 2007. The absolute frequency of R(127) 11-5 transitions of molecular iodine was measured for these lasers following the technical protocol for CCL-K11. The results of these measurements are compiled in the present report. The comparison reports, as communicated by each participant, are included as appendices.This document constitutes the seventh final report for the ongoing key comparison CCL-K11.Main textTo reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Compact iodine-stabilized laser operating at 531 nm with stability at the 10(-12) level and using a coin-sized laser module.

We demonstrate a compact iodine-stabilized laser operating at 531 nm using a coin-sized light source consisting of a 1062-nm distributed-feedback diode laser and a frequency-doubling element. A hyperfine transition of molecular iodine is observed using the light source with saturated absorption spectroscopy. The light source is frequency stabilized to the observed iodine transition and achieves frequency stability at the 10(-12) level. The absolute frequency of the compact laser stabilized to the a(1) hyperfine component of the R(36)32 - 0 transition is determined as 564074632419(8) kHz with a relative uncertainty of 1.4×10(-11). The iodine-stabilized laser can be used for various applications including interferometric measurements.

The CCL-K11 ongoing key comparison. Final report for the year 2013

Lasers from three national metrological institutes (NMIs) were compared in 2013 as part of the CCL-K11 ongoing key comparison, initiated by the 13th meeting of the Comité Consultative des Longuers (CCL) in 2007. The absolute frequency of R(127) 11-5 transitions of molecular iodine was measured for these lasers following the technical protocol for CCL-K11. The results of these measurements are compiled in this report. The comparison reports, as communicated by each participant, are included as appendices.This document constitutes the fifth final report for the ongoing key comparison CCL-K11.Main text.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).