Phase Transformation Research Articles

Effects of ion irradiation induced phase transformations and oxygen vacancies on the leakage current characteristics of HfO2 thin films deposited on GaAs

Abstract We report on the ion-induced phase transformations, defect dynamics related to oxygen vacancies and the resulting leakage current characteristics of RF sputtered HfO2 thin films grown on GaAs. A systematic growth of HfO2 grains and Ion prompted phase transformations of HfO2 to crystalline phases such as monoclinic and tetragonal/orthorhombic (mixed phase) in otherwise amorphous HfO2 thin films have been observed after irradiation. At lower fluences, Ion induced enhancement in the dielectric properties of HfO2 thin films resulted in a reduction in the leakage current, whereas ion prompted defect formation at higher fluences caused a systematic increase in the leakage current density. Further, the effects of Poole-Frenkel (PF) tunneling and Fowler-Nordheim (FN) tunneling on the leakage current have also been investigated. These mechanisms showed the existence of impurities in the as-grown films. Photoluminescence (PL) study suggests the variation in the defect configuration related to O-vacancies and slight shift in the peak positions due to SHI irradiation are responsible for the observed changes in electrical characteristics. This study offers worthwhile information for considering the effects of electronic excitation prompted defect annealing or defect creation on the performance of HfO2/GaAs based photonic and optoelectronic devices, particularly, when such devices are operated in a radiation harsh environment.

Influence of Cold Drawing on Phase Transformation and Tensile Properties of FeCrMn Austenitic Stainless Steel 201

Manganese stabilizes the austenite and reduces the stacking fault energy in face‐centered cubic (FCC) structures, promoting the formation of hexagonal and cubic structures. This study investigates the phase transformation and mechanical behavior of extremely low‐carbon FeCrMn austenitic stainless AISI 201 steel subjected to cold drawing in three stages, ultimately reaching a true strain of 0.93. The objective is to examine the transformation from the parent FCC structure to hexagonal close‐packed and body‐centered cubic structures as a combination of transformation‐induced plasticity and twinning‐induced plasticity phenomena. X‐ray diffraction and electron backscatter diffraction analyses are utilized to investigate phase transformations under significant plastic deformation and the crystallographic orientation relationships between phases. Additionally, tensile and hardness tests are performed to assess the impact of plastic deformation on mechanical properties. Results indicate that a true strain of 50% is optimal for balancing strength and ductility in CrMnFe austenitic stainless steel. After applying a true strain of ε1 = 26.7%, yield strength (YS) increases by 192% and ultimate tensile strength (UTS) by 35%, while elongation reduces by 41%. With a further strain of ε2 = 57.5%, YS increases by 71% and UTS by 44%, but elongation drastically decreases by 94%. Applying the final strain of ε3 = 94.0%, YS and UTS only increase by 3% and 2%, respectively, while elongation further reduced by 40%. These findings suggest that a true strain of 50% shall be considered the maximum reduction for maintaining a balance between strength and ductility in CrMnFe austenitic stainless steel.

Properties of Al0.5CoCrFeNi2Ti High-Entropy Alloy System: From Gas-Atomized Powders to Atmospheric Plasma-Sprayed Coatings

AbstractThe performance of the Al0.5CoCrFeNi2Ti HEA atmospheric plasma-sprayed coating was extended from characterizing the properties of its powder prepared via the gas atomization method. It was observed that the gas-atomized HEA powders possessed a solid solution BCC phase, while a major phase transformation to a FCC-L21 intermetallic phase occurred during the annealing process. The formation of the intermetallic phase resulted in an increase in average hardness from 6.28 to 7.64 GPa after annealing at 900 °C for 1 h. Afterward, HEA powders were applied in the atmospheric plasma spray technology. The phase constitution of Al0.5CoCrFeNi2Ti HEA coatings was investigated by varying powder size and applied current. It was observed that the smaller powder sizes prone to oxidation, whereas higher applied current facilitated the phase transformation from BCC to FCC phase. The nanoindentation test indicated distinct average microhardness values for the interlamellar oxide region, BCC unmelted particle and FCC phase lamellar region, which was measured at 12.35, 8.68 and 5.97 GPa, respectively. As a result, the adjustability of coating hardness was achieved by manipulating the relative phase ratio.

Impact of Partitioning Temperature Parameters during the Quenching and Partitioning Process on Medium Carbon Steels with Two Different Alloying Strategies

Quenching and partitioning (Q&P) heat treatments have recently gained attention as promising methods for the third generation of advanced high‐strength steels, particularly in industrial applications like automotive. This study investigates the microstructural evolution during Q&P in two medium‐carbon high‐silicon and aluminum‐alloyed steels, exploring potential additional phase transformations controlling the final structure. The choice to focus on Si and Al‐ medium‐carbon steel is linked to the lower cost of these elements compared to commonly alloying elements like Ti, Cr, Mo, and V, while still achieving high mechanical properties through Q&P. The Q&P process is analyzed by varying the volume fraction of primary martensite (M1) at 0.25, 0.50, and 0.75, with partitioning temperatures ranging from 350 to 550 °C for 30 min. At 350 °C, a significant volume fraction of stabilized austenite (up to 0.3) is observed. However, concurrent reactions such as nanostructured bainite and martensite formation lead to deviations from the theoretical constrained carbon equilibrium (CCE). At higher temperatures (450–550 °C), tempering reactions, including cementite precipitation and pearlite formation, reduced the austenite final fraction. The study highlights that heat treatment design, particularly partitioning temperature, must be tailored to the specific steel composition due to the varying effects of Si and Al.

Effect of Vanadium on Phase Transformation, Cold Drawing, and Torsion of High-Carbon Steel

Effect of Vanadium on Phase Transformation, Cold Drawing, and Torsion of High-Carbon Steel

Mullite Synthesis Using Porous 3D Structures Consisting of Nanofibrils of Aluminum Oxyhydroxide Chemically Modified with Ethoxysilanes

Nanocrystalline mullite was synthetized by annealing a highly porous 3D structure consisting of nanofibrous aluminum oxyhydroxides treated with ethoxysilanes. The chemical, structural, and phase transformations in the aluminosilicate nanosystem were studied in the temperature range between 100 and 1600 °C. The features of the solid-phase synthesis of mullite at the interface of crystalline alumina with a liquid silica layer are discussed. It was established that chemical modification of the alumina surface with ethoxysilanes significantly limits the interphase mass transport and delays the phase transformation of the amorphous oxide into γ-Al2O3, which begins at temperatures above 1000 °C, while the basic structural nanofibrils are already crystallized at ~850 °C. The formation of mullite was completed at temperatures ≥ 1200 °C, where the fraction of γ-Al2O3 sharply decreased.

Nickel Vanadate Cathode Induced In Situ Phase Transition for Improved Zinc Storage by Low Migration Barrier and Zn2+/H+ Co‐Insertion Mechanism

AbstractDesigning cathode materials that exhibit excellent rate performance and extended cycle life is crucial for the commercial viability of aqueous zinc (Zn)‐ion batteries (ZIBs). This report presents a hydrothermal synthesis of stable Ni0.22V2O5·1.22H2O (NVOH) cathode material, demonstrating high‐rate performance and extended cycle life. A successful in situ phase transformation yields Zn3(OH)2V2O7·nH2O (ZVO), which undergoes an irreversible phase transition and exhibits exceptional energy storage properties. The procedure maintains the lattice structure of ZVO and ensures high structural stability throughout the phase transformation. The NVOH cathode material exhibits the discharge capacities of 399 mA h g−1 at a rate of 1 A g−1 after 400 cycles and 303 mA h g−1 at 10 A g−1 after 2000 cycles. Density functional theory calculations indicate that the material is protected by electrostatic forces and exhibits structural stability, with a Zn‐ion migration barrier of 0.32 eV across the host lattice and the electrode–electrolyte interface. Due to these properties, NVOH also exhibits high energy/power densities of 395 Wh kg−1/406 W kg−1 at 0.5 A g−1 and 288 Wh kg−1/8830 W kg−1 at 10 A g−1. Ex situ characterizations indicate structural modifications and irreversible phase changes of NVOH, highlighting the potential of H+ intercalation and in situ phase transitions for high‐performance aqueous ZIBs.

Influence of Thermomechanical Treatments and Chemical Composition on the Phase Transformation of Cu-Al-Mn Shape Memory Alloy Thin Sheets

This paper investigates the interrelated effects of thermomechanical treatments and chemical composition on the phase transformation capabilities of thin sheets made from Cu-Al-Mn shape memory alloys. The transformation capacity and transition temperatures were determined using DSC and DMA testing, while composition measurements were performed using SEM/EDX analysis. The results demonstrate that applying hot-rolling treatments to alloys of reduced thickness leads to manganese oxidation and modifications in chemical composition, adversely impacting the phase transformation performance. This effect can be mitigated by the use of cold rolling. Additionally, the presence of phosphorus impurities can create inclusions that bind manganese, preventing it from remaining in the solid solution and further affecting phase transformation capabilities.

Solid-State Phase Transformation Kinetics and Mechanisms in Additively Manufactured Ti–6Al–4V Studied Using In-Situ High-Energy Synchrotron X-ray Diffraction

Solid-State Phase Transformation Kinetics and Mechanisms in Additively Manufactured Ti–6Al–4V Studied Using In-Situ High-Energy Synchrotron X-ray Diffraction

MEMS-tunable topological bilayer metasurfaces for reconfigurable dual-state phase control

Tunable optical metasurfaces (MSs) have demonstrated exceptional capabilities in actively manipulating light fields. However, most existing tunable MSs are limited to controlling only one functionality. Here, by combining a MEMS mirror with a plasmonic bilayer MS (BMS), we develop an electrically driven MEMS-BMS platform enabling complete reflection phase transformation and switching between two encoded functionalities by actuating the MEMS mirror. This capability stems from different optical responses of each MS layer at distinct MEMS-BMS separations, due to evolving topological singularities in a defined parameter space. With this tunable topological MEMS-BMS platform, we demonstrate polarization-independent MEMS-BMS for reconfigurable diffraction gratings, achieving ∼25% efficiency, ∼0.75 contrast at 850-nm wavelength, and fast response (∼5µs). The MEMS-BMS arrangement for generating vortex beams with switchable topological charges of ±1 is also demonstrated, evidenced by distinct near- and far-field interferograms. Our work expands the scope of tunable MSs by exploiting dynamic topological phases in the MEMS-BMS arrangement, paving the way for multifunctional tunable meta-optics.

EFFECT OF HEAT TREATMENT OVER THE MECHANICAL PROPERTIES AND THE RESISTANCE TO CORROSION OF THE TERNARY Cu-Al-Ag ALLOY

Abstract In the present work, the manufacture of a Cu-9Al-3Ag alloy was carried out easily through a green molding process. After dimensioning and slitting, the alloy samples were subjected to quenching, normalizing, and annealing heat treatments, to exert phase transformations that would, in return, aid into clarifying the influence of the phases present on the mechanical properties, such as hardness, as well as the behavior when exposed to a commonly known mildly corrosive media such as NaCl. The results obtained reveal an increase in hardness (assessed through either HRB) and (microhardness HV) in the quenched and annealed sample, as well as better corrosion resistance. The characterization was carried out through optical microscopy, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), potentiodynamic polarization tests and electrochemical impedance spectroscopy.

Microstructural Aspects on Brazing Stainless Steels for High Temperature Applications

A wide range of applications request components that work in an environment where they are subject to high temperatures, combined with a corrosive action of the same environment. The components with a complex geometry can be obtained only using some assembling processes, among which are welding and brazing. One of the most important advantages of these processes is the possibility to obtain a sealed joint, that guarantees it to be waterproof. In comparison with welding process, brazing process has also an important technological advantage: it is a process that is able to produce a quality joint in a very small, narrow and tight places., where is very difficult or almost impossible to reach with other welding processes (e.g. GMAW/MIG – Gas Metal Arc Welding, GTAW/TIG – Gas Tungsten Arc Welding, SMAW – Shield Metal Arc Welding, FCAW - Flux Cored Arc Welding, SAW – Submerged Arc Welding). The research in this direction carried out in University Politehnica Timisoara, was focused on using brazing as a joining process to obtain a complex geometry part working in these environments. The brazed joint will create a dissimilar joint, putting in contact stainless steel with a Ag-Cu brazing alloy, which creates diffusion processes at microstructural level as well as phase transformations (due to thermal cycle and diffusion) which have a large impact on operating behavior of these joints. This paper presents some results on investigation phase and microstructural constituents transformations that took place in these brazed joints.

FEATURES OF ELEMENTAL ANALYSIS OF DOLOMITES OF THE LOWER PERMIAN DEPOSITS BY X-RAY FLUORESCENCE SPECTROSCOPY

In this work, using the methods of scanning electron microscopy (SEM), X-ray phase analysis (XRF), X-ray fluorescence spectrometry (XFS) and thermogravimetric analysis (TGA), the physicochemical properties of dolomite rocks selected from one well at different depths of occurrence were studied. The SEM method shows that, depending on the depth of occurrence, dolomite is characterized by both ordinary crystals of rhombohedral morphology, the size of which varies from 50 to 80 microns along the diagonal axis, and unusual shapes, in the form of hexagonal plates up to 1 microns thick and 1 to 10 microns in diameter. It has been found that dolomite plates in places form spherical aggregates ranging in size from 20 to 40 microns. According to the RF analysis data, it was found that in samples of dolomite rock (of ordinary and unusual shape), after calcination at 1000 °C for 5 hours, there is a twofold increase in the molar stoichiometric ratio of Mg and Ca, compared with the initial (non-calcined) state of dolomite. By the XRD method, it was found that during calcination of dolomite samples, a phase transformation (CaMg(CO3)2 → CaO + MgO + 2CO2) is observed, in which lime (CaO) and periclase (MgO) phases are formed. Precision SEM studies have shown that periclase nanocrystals, whose size varies from 100 nm to 300 nm, are evenly distributed on the surface of larger lime fragments. As a result of numerous measurements of the X-ray spectra of the RF, it was found that the overlap of lime fragments with numerous periclase nanocrystals is the cause of a significant overestimation of the magnesium content after calcination of dolomite samples. It is concluded that in order to correctly conduct elemental analysis and obtain adequate information about the weight fraction of rock-forming oxides in dolomite samples, they must first be dissolved in hydrochloric acid. The method of sample preparation proposed by the authors for the correct elemental analysis of dolomite rocks has been tested on numerous samples, which showed convincing convergence of the data obtained by XRF (decomposition into rock-forming oxides) and XRF analysis.

SIMULATION OF PREHEATING AND HEATING WHEN CONNECTING POLYETHYLENE PIPES WITH ELECTROFUSION COUPLINGS

Existing machines for electrofusion welding of polyethylene pipes provide a high-quality connection at air temperatures no lower than minus 10 °C. However, if welding is required at lower temperatures, a layer of heat-insulating material is used to reduce the cooling rate. This insulation is selected based on the air temperature and the size of the welded pipes. This paper investigates the dynamics of temperature fields at the stages of heating, temperature equalization and heating using a new technology of welding at low temperatures. The proposed technology eliminates the use of thermal insulation material and allows welding to be carried out automatically.The paper presents a mathematical model that describes the thermal process when performing all welding operations at low temperatures. The model describes the thermal process with and without phase transformation. The well-known method of end-to-end calculation with the introduction of effective heat capacity is used to consider the heat of phase transition in the temperature range. The model also considers the dependence of the thermophysical properties of polyethylene on the degree of crystallinity.The following text presents the results of preheating and temperature equalization calculations for welding polyethylene pipes of the PE 100 SDR 11 brand with a diameter of 160 mm at an air temperature of minus 40 °C. To accurately describe the thermal process of real welding, experimental temperature data was used for parametric identification. It is shown that as a result of preheating and temperature equalization in the weld and thermally affected zones and outside them at a distance of more than 10 mm, the temperature values do not exceed acceptable limits. The resulting temperature distribution allows heating according to the standard welding mode. Calculations show that when the heating is completed, the volume of the polyethylene melt corresponds to the volume of the welding melt at the allowed air temperature.These findings can be used to develop a technique for controlling the movement of the crystallization front during welding at low temperatures.

Chalcopyrite CuFeS2: Solid-State Synthesis and Thermoelectric Properties

The optimal conditions for synthesizing a pure chalcopyrite CuFeS2 phase were thoroughly investigated through the combination of mechanical alloying (MA) and hot pressing (HP) processes. The MA process was performed at a rotational speed of 350 rpm for durations ranging from 6 to 24 h under an Ar atmosphere, ensuring proper mixing and alloying of the starting materials. Afterward, MA-synthesized chalcopyrite powder was subjected to HP at temperatures between 723 K and 823 K under a pressure of 70 MPa for 2 h in a vacuum. This approach aimed to achieve phase consolidation and densification. A thermal analysis via differential scanning calorimetry (DSC) revealed distinct endothermic peaks at the range of 740–749 K and 1169–1170 K, corresponding to the synthesis of the chalcopyrite phase and its melting point, respectively. An X-ray diffraction (XRD) analysis confirmed the successful synthesis of the tetragonal chalcopyrite phase across all samples. However, a minor secondary phase, identified as Cu1.1Fe1.1S2 (talnakhite), was observed in the sample hot-pressed at the highest temperature of 823 K. This secondary phase could result from slight compositional deviations or local phase transformations at elevated temperatures. The thermoelectric properties of the CuFeS2 samples were evaluated as a function of the HP temperatures. As the HP temperature increased, the electrical conductivity exhibited a corresponding rise, likely due to enhanced densification and reduced grain boundary resistance. However, this increase in electrical conductivity was accompanied by a decrease in both the Seebeck coefficient and thermal conductivity. The reduction in the Seebeck coefficient could be attributed to the higher carrier concentration resulting from improved electrical conductivity, while the decrease in thermal conductivity was likely due to reduced phonon scattering facilitated by the grain boundaries. Among the samples, the one that was hot-pressed at 773 K displayed the most favorable thermoelectric performance. It achieved the highest power factor of 0.81 mWm−1K−1 at 523 K, indicating a good balance between the Seebeck coefficient and electrical conductivity. Additionally, this sample achieved a maximum figure-of-merit (ZT) of 0.32 at 723 K, a notable value for chalcopyrite-based thermoelectric materials, indicating its potential for mid-range temperature applications.

STRUCTURAL FEATURES OF DRILLING EQUIPMENT COMPONENTS USING MATERIALS WITH THERMOELASTIC PHASE TRANSFORMATIONS

Alloys exhibiting thermoelastic phase transformations are increasingly being used in various industries. This is due to their shape memory effect and the phenomenon of pseudoelasticity (superelasticity), which can significantly improve the performance of various technical systems. Equipment for drilling oil and gas wells is one of the most demanding in terms of reliability and service life, in connection with which the gradual introduction of the above-described intelligent materials and the phenomena they manifest in the oil and gas industry began. This article analyzes the developed design and proposes methods of mounting/dismounting roller bit elements made according to the proposed design using an alloy with thermoelastic phase transformations, namely the shape memory effect, and compares them with existing designs. Computational studies and computational analysis of the design of the fastening of drilling equipment elements using the Solid Works program and the Solid Works Simulation module were carried out, which showed significant advantages of the proposed method when applying the shape memory effect as a method of geometric fixation during installation compared to interference fit. Tests were also carried out on the IR-200-0 breaking machine in order to verify and confirm the theoretical results obtained using special equipment, with the use of which the reliability of fixation due to the intermediate bushing with taper was determined. As an example, sleeves with an inclination angle to the axis of the cone of 3 degrees were made, fixed in the hole with a reverse taper with a response angle of inclination. The tests confirmed the assumptions made and the results obtained in the course of theoretical calculations and computer modeling, showing that even in the martensitic state this alloy fixes the teeth in special holes of the rolling cutter more reliably compared to the interference fit, which, in turn, makes it possible to conclude that it is advisable to use the proposed installation method, which gives obvious advantages over existing ones.

Modeling martensitic transformation temperatures in Zirconia–Ceria solid solutions using machine learning interatomic potentials

Abstract Shape memory ceramics (SMCs), while exhibiting high strength, sizeable recoverable strain, and substantial energy damping, tend to shatter under load and have low reversibility. Recent developments in SMCs have shown significant promise in enhancing the reversibility of the shape memory phase transformation by tuning the lattice parameters and transformation temperatures through alloying. While first-principles methods, such as density functional theory (DFT), can predict the lattice parameters and enthalpy at zero Kelvin, calculating the transformation temperature from free energy at high temperatures is impractical. Empirical potentials can calculate transformation temperatures efficiently for large system sizes but lack compositional transferability. In this work, we develop a model to predict transformation temperatures and lattice parameters for the Zirconia–Ceria solid solutions. We construct a machine learning inter-atomic potential (MLIAP) using an initial dataset of DFT simulations, which is then iteratively expanded using active learning. We utilize reversible scaling to compute the free energy as a function of composition and temperature, from which the transformation temperatures are determined. These transformation temperatures match experimental trends and accurately predict the phase boundary. Finally, we compare other relevant design parameters (e.g. transformation volume change) to demonstrate the applicability of MLIAPs in designing SMCs.

Geothermo-mechanical energy conversion using shape memory alloy heat engine

AbstractThe shift towards renewable energy sources like geothermal energy has become desirable due to the recurrent energy crisis and global warming challenges influenced by fossil fuels. Geothermo-mechanical energy conversion using shape memory alloy (SMA) heat engines presents a novel and sustainable approach for harnessing geothermal energy. Shape memory alloys, known for their ability to undergo reversible phase transformations driven by temperature changes, are ideal for thermal-to-mechanical energy conversion. This paper explores the design and performance of an SMA heat engine that utilizes geothermal heat sources to drive mechanical work. The engine operates by cycling between the high-temperature geothermal environment and a cooler sink, exploiting the shape memory effect to generate mechanical motion. By integrating geothermal energy and SMA technology, this system offers a potential solution for renewable energy generation, with applications in remote or off-grid locations. The paper also investigates output power and the thermodynamic efficiency. A model is formulated and the engine behavior is simulated. A series of experiments are conducted for engine output power and efficiency. The model is compared to the experimental data for validation. The engine developed a maximum power of 3.5, 8.5, and 11.5 watts at 60, 80, and 90 °C respectively. The proposed SMA-based geothermo-mechanical energy conversion system offers a promising solution for efficient, reliable, and scalable geothermal energy harvesting. This research contributes to the development of innovative, efficient geothermal energy conversion technologies, supporting global renewable energy goals and reducing greenhouse gas emissions. This innovative energy conversion mechanism could play a key role in the future of sustainable power generation.

Low Temperature and Rapid Synthesis of Li‐Rich Li(Li0.17Mn0.83)2O4 Spinel Cathodes Derived from Metal‐Organic Frameworks for Lithium‐Ion Batteries

AbstractLi‐rich spinel materials (Li1+xMn2−xO4) have shown promise for lithium‐ion batteries. Nevertheless, the preparation of Li1+xMn2−xO4 faces significant challenges due to the difficulty in achieving a balance between well‐crystallized phases and stoichiometric chemistry. Moreover, the synthesis process is highly sensitive to calcination temperature and time, making it susceptible to phase transformations. Therefore, the rational selection of precursors and corresponding calcination procedures is absolutely essential. Herein, we make full use of the nature of metal‐organic frameworks (MOFs) to achieve phase‐controlled synthesis of Li(Li0.17Mn0.83)2O4 (LMO−F) spinel cathodes in 8 minutes at 500 °C. The composition and structural evolution during the pyrolysis process were systematically investigated to clarify the relationship between precursors and derivatives. Notably, the LMO−F achieved good electrochemical performance with 100.4 mAh g−1 at 50 mA g−1 after 100 cycles.

Characteristics of Solid Mineral Phase Transitions During Sulfuric Acid Production from Gaseous-Sulphur-Reduced Gypsum

The acid co-production of cement is a prominent research focus for the large-scale, high-value utilization of phosphogypsum in the context of dual-carbon strategies. This paper builds on extensive research conducted by its authors on the co-production of sulphoaluminate cement clinker through acid production from gaseous-sulphur-reduced phosphogypsum. The solid mineral phase transformations occurring in the kiln during this process are systematically studied, and the effects of various calcination regimes (temperature, time, and atmosphere) on the evolution of clinker mineral phases are elucidated. This paper provides basic data support for the gas-sulfur-reduced phosphogypsum-acid cogeneration of sulfoaluminate cement clinker processes, and promotes the realization of the large-scale high-value utilization of phosphogypsum resources. The generation of the clinker mineral phase anhydrous calcium sulphoaluminate (C4A3S̅) begins at 1100 °C. Increasing the calcination temperature and extending the calcination time promote C4A3S̅ formation. However, when the calcination temperature exceeds 1350 °C, C4A3S̅ decomposes, leading to the formation of low-activity C2AS. In a CO atmosphere, the main mineral phases in the clinker transform into C2AS and 12CaO·7Al2O3, owing to the decomposition of CaSO4, which inhibits C4A3S̅ formation. At calcination temperatures exceeding 1300 °C, a significant amount of C2AS appears in the calcined material, and 12CaO·7Al2O3 begins to form.