Transesterification Of Used Cooking Oil Research Articles

Pathogenicity of Entomopathogenic Fungi as Bioinsecticides for Controlling Green Leaf Hoppers(Nephotettix virescens)

Transesterification of used cooking oil (UCO) using NaN3/modified clay catalyst and investigation of the acetone effect have been done.The modified clay catalyst was synthesized by destructing the Merauke clay with8M HCl solution, then fusion by NaOH pellet, followed by treating with AlCl3.6H2O, CTAB and distilled water.Then the mixture was regulated to pH of 11.5. Next, the mixture was then poured into a reactor for hydrothermal process at 140 oC for 48 h. The results of the dealumination of clay was characterized byX-ray Fluorescence and the synthesized zeolite was characterized using surface area analyzer and X-Ray Diffraction.The synthesized zeolite was impregnated by NaN3 as a precussor produced the NaN3/modified clay catalyst sample.Rasio of catalyst :UCO : methanol was 1.0 : 20.0 : 13.3 and the ratio of aceton to methanol was 2:1. The transesterificationprocess was carried out at 60 and 65oC. The liquid product was analyzed using Gas Chromatography Mass Spectrometer.The resulted showed that themodified clay had surface area of 5.5685 m2/g, pore volume of 0.0126 cm3/g, and pore diameter of 8.871 nm. The results of measurements with XRD produced a different form of chromatogram and type of mineral. The main mineral was gismondine.In this research, The transesterification of UCO using NaN3/MC catalyst at 60 oC resulted methyl esters of 65.3 wt %.Furthermore, after adding acetone to the same treatment, the resulting methyl ester was 82.7 wt%.The transesterification of UCO at 65 ° C using NaN3/MC catalyst and acetone produced the highest content of methyl esters or biodiesel that was equal to 94.4 wt %.

Biodiesel Synthesis Through Transesterification of Used Cooking Oil Using NaN3/Modified Clay Catalyst and The effect of Acetone as Co-Solvent

Transesterification of used cooking oil (UCO) using NaN3/modified clay catalyst and investigation of the acetone effect have been done.The modified clay catalyst was synthesized by destructing the Merauke clay with8M HCl solution, then fusion by NaOH pellet, followed by treating with AlCl3.6H2O, CTAB and distilled water.Then the mixture was regulated to pH of 11.5. Next, the mixture was then poured into a reactor for hydrothermal process at 140 oC for 48 h. The results of the dealumination of clay was characterized byX-ray Fluorescence and the synthesized zeolite was characterized using surface area analyzer and X-Ray Diffraction.The synthesized zeolite was impregnated by NaN3 as a precussor produced the NaN3/modified clay catalyst sample.Rasio of catalyst :UCO : methanol was 1.0 : 20.0 : 13.3 and the ratio of aceton to methanol was 2:1. The transesterificationprocess was carried out at 60 and 65oC. The liquid product was analyzed using Gas Chromatography Mass Spectrometer.The resulted showed that themodified clay had surface area of 5.5685 m2/g, pore volume of 0.0126 cm3/g, and pore diameter of 8.871 nm. The results of measurements with XRD produced a different form of chromatogram and type of mineral. The main mineral was gismondine.In this research, The transesterification of UCO using NaN3/MC catalyst at 60 oC resulted methyl esters of 65.3 wt %.Furthermore, after adding acetone to the same treatment, the resulting methyl ester was 82.7 wt%.The transesterification of UCO at 65 ° C using NaN3/MC catalyst and acetone produced the highest content of methyl esters or biodiesel that was equal to 94.4 wt %.

Life cycle assessment (LCA) and exergetic life cycle assessment (ELCA) of the production of biodiesel from used cooking oil (UCO)

The paper assesses the life cycle of biodiesel from used cooking oil (UCO). Such life cycle involves 4 stages: 1) collection, 2) pre-treatment, 3) delivery and 4) transesterification of UCO. Generally, UCO is collected from restaurants, food industries and recycling centres by authorised companies. Then, UCO is pre-treated to remove solid particles and water to increase its quality. After that, it is charged in cistern trucks and delivered to the biodiesel facility to be then transesterified with methanol to biodiesel. The production of 1 ton of biodiesel is evaluated by a Life Cycle Assessment (LCA) to assess the environmental impact and by an Exergetic Life Cycle Assessment (ELCA) to account for the exergy input to the system. A detailed list of material and energy inputs is done using data from local companies and completed using Ecoinvent 1.2 database. The results show that the transesterification stage causes 68% of the total environmental impact. The major exergy inputs are uranium and natural gas. If targets set by the Spanish Renewable Energy Plan are achieved, the exergy input for producing biodiesel would be reduced by 8% in the present system and consequently environmental impacts and exergy input reduced up to 36% in 2010.