The separation of land surface temperature (LST) and land surface emissivity (LSE) is an ill-posed problem in thermal infrared (TIR) remote sensing. By building a new observation matrix to compress the LSE unknows and a dictionary training method to reconstruct complete LSE spectra, a new dictionary-based sparse representation for emissivity (DSRE) method has been proposed to retrieve LST and LSE from the atmospherically corrected hyperspectral TIR data. The proposed method fully utilizes the sparsity of compressed sensing and the empirical knowledge of the trained emissivity dictionary. The sensitivity analysis shows that the modeling accuracies of the proposed method are 0.215 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> and 0.0060 for LST and LSE, respectively. Even with the instrument noise of 0.3 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> and the uncertainties in atmospheric transmittance, atmospheric upwelling, and downwelling radiance of 10 %, the retrieval accuracies are 0.811 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> for LST and 0.0241 for LSE, respectively. Then a field experiment was conducted to validate the proposed method, and a comparison was executed to three published methods, including ASTER temperature-emissivity separation (ASTERTES), linear spectral emissivity constraint TES (LSECTES), and iterative spectrally smooth TES (ISSTES). The accuracies of retrieved LST and spectral LSE are 1.41 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> / 0.009, 2.57 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> / 0.071, 1.59 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> / 0.038, and 2.00 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">K</i> / 0.077 for DSRE, ASTERTES, LSECTES, and ISSTES. In contrast to the three published methods, our proposed method is more accurate and effective than other published methods. Especially in the atmospheric absorption band, the proposed method has a strong anti-noise capability to the residuals of environmental downwelling radiance.
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