In response to the imperative to reduce greenhouse gas emissions, global efforts are focusing on electrifying transportation and adopting renewable energy sources. This necessitates establishing reliable fast-charging stations (FCSs) for the widespread integration of electric vehicles (EVs). Indeed, the arbitrary distribution of FCSs can detrimentally affect the efficiency of traffic movement. Thus, this paper presents a planning methodology aimed at optimizing the allocation of FCSs within large-scale transportation networks. The energy system proposed includes an autonomous photovoltaic (PV)-powered FCS based on a DC microgrid, supplemented by a stationary battery energy storage system for backup power. The behavior of EVs within the traffic flow is modeled using a realistic traffic simulation software called Dynamic Network Assignment Simulation for Advanced Road Telematics (DYNASMAT). The conflicting objectives of minimizing total annual costs and EV average waiting time at stations are addressed through multi-objective optimization. To solve this optimization problem, the GAMS software is employed. A transportation network with 92 nodes and 284 links is utilized to test the proposed approach. The proposed autonomous PV-powered FCS is compared with Natural Gas-fired Distributed Generators (NGDG)-powered FCS. The simulation results show that while the NGDG-powered FCS exhibits higher emissions, the autonomous PV-powered equivalent operates emission-free. However, the annual cost of the autonomous PV-powered FCS is higher than that of the NGDG-powered FCS.