Polar codes are one of the most effective methods of error correction coding. Currently, these codes are used in 5G communication systems and are the main candidate for 6G. Symmetry plays an important role in coding and decoding algorithms for polar codes. Modulation and multiple access methods are the basis for a physical layer along with error correction codes. Non-Orthogonal Multiple Access (NOMA) methods are a promising technology for future telecommunication systems. They allow the increase of both spectral efficiency and the quantity of subscribers of a communication system. In this paper, we consider a communication system with polar codes, traditional orthogonal multiple access (OMA), and NOMA. The channel with multipath propagation, which can be defined by the Rayleigh channel model, is especially difficult to transmit. We propose a method for adapting signals with polar codes to a channel state based on the analysis of channel matrix and permutation of logical subchannels. The results obtained demonstrate efficiency compared to classical solutions and do not really increase the computational complexity of signal processing and decoding.