Total Production Research Articles

Total Synthesis and Anti-inflammatory Activity of Asperjinone and Asperimide C.

Total syntheses of two γ-butenolide natural products, asperjinone (1) and asperimide C (2) in both racemic and chiral forms have been accomplished utilizing Basavaiah's one-pot Friedel-Crafts/maleic anhydride formation protocol as a key strategy. Our syntheses verified the revised structure of 1 proposed by Williams et al. and the structure and absolute configuration of 2 reported by the Li group. This work also discloses the unprecedented anti-inflammatory activity of 1. Synthetic 1 exhibited significant anti-inflammatory activity in renal proximal tubular epithelial cells (RPTEC) by suppression of gene expression of pro-inflammatory cytokines TNF-α, IL-1β and IL-6 under LPS-induced renal inflammation condition and was superior to (S)-1, rac-2, 2, and a positive drug control, indomethacin. Moreover, compound 1 inhibited downstream signaling of inflammation by significantly reducing iNOS and COX-2 gene expression and total NO production. The anti-inflammatory activity of asperjinone (1) renders it a potential and promising candidate for developing novel anti-inflammatory agents against inflammation worsening acute kidney injury.

DOPO chemically modified mesoporous silica composites: Preparation, flame retardancy, and thermodynamic properties

AbstractOrganic flame retardant 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) was used to decorate the pores of mesoporous silica (m‐SiO2) nanospheres to prepare a new composite flame retardant (DK‐SiO2). The content of DOPO in DK‐SiO2 is about 17 wt%. Due to the chemical bonding, DK‐SiO2 not only enhances the flame retardant performance, but also effectively avoids adverse effects of DOPO on the glass transition temperature and mechanical properties of epoxy resin (EP). At 9 wt% loading, the limiting oxygen index of the EP increased from 25.7 to 31.2, and successfully passed the UL‐94 V‐0 rating. Besides, DK‐SiO2 can significantly reduce the peak heat release rate, total heat release, and total smoke production of EP, with reductions of 26%, 32%, and 20.8%, respectively. Compared with the simple blended sample, DK‐SiO2 not only has better flame retardant performance but also shows significant advantages in thermodynamic properties. The glass transition temperature, impact, and tensile strength, as well as storage and flexural modulus have been improved. This excellent flame retardant performance is mainly attributed to the gas‐condensed synergistic flame retardant mechanism between DOPO and m‐SiO2. The good thermodynamic performance is due to the excellent dispersion of DK‐SiO2 nanospheres in the EP.

Effects of the use of phytonutrients in the diet of dairy ruminants: Systematic review

Objective. This systematic review examines the effects of essential oils used as phytonutrients in the diet of dairy animals, considering parameters such as feed consumption, total apparent digestibility, methane emissions and milk production, based on studies published between 2018 and 2023. Material and methods. Bibliographic research electronic method resulted in a careful selection of articles, which were reviewed and tabulated for evaluation. Results. The results show that 51.35% of the articles did not report significant effects of phytonutrients on milk production. However, 66.67% of the studies observed an increase in feed efficiency and 50% reported the presence of effects on apparent digestibility. Furthermore, there was a reduction in methane emissions in animals treated with phytonutrients. Conclusions. Sharing these results with dairy farming professionals can promote more sustainable and effective practices, as well as support future research and innovations in animal nutrition, aiming for both productive efficiency and environmental sustainability.

Thermodynamic Bounds on Generalized Transport: From Single-Molecule to Bulk Observables

We prove that the transport of any differentiable scalar observable in d-dimensional nonequilibrium systems is bounded from above by the total entropy production scaled by the amount the observation “stretches” microscopic coordinates. The result—a time-integrated generalized speed limit—reflects the thermodynamic cost of transport of observables, and places underdamped and overdamped stochastic dynamics on equal footing with deterministic motion. Our work allows for stochastic thermodynamics to make contact with bulk experiments, and fills an important gap in thermodynamic inference, since microscopic dynamics is, at least for short times, underdamped. Requiring only averages but not sample-to-sample fluctuations, the proven transport bound is practical and applicable not only to single-molecule but also bulk experiments where only averages are observed, which we demonstrate by examples. Our results may facilitate thermodynamic inference on molecular machines without an obvious directionality from bulk observations of transients probed, e.g., in time-resolved x-ray scattering. Published by the American Physical Society 2024

New Nitrogen Use Efficiency Indices for Biomass Formation and Productivity in Green Beans Under Foliar Fertilization with Molybdenum Nanofertilizer

Most crops are fertilized with high amounts of nitrogen, and have an alarmingly low utilization efficiency. For this reason, the coordination between the fertilizer contribution and the nitrogen requirements of the crop is very important. Therefore, the objective of the present study was to establish new indices to determine nitrogen use efficiency (NUE), and to define the amount of assimilated nitrogen, which is used for the formation of green bean plant organs, fertilized with molybdenum nanofertilizer applied foliarly, and combined with edaphic fertilization of ammonium nitrate. The plants were grown in a greenhouse covered with anti-aphid mesh and irrigated with nutrient solution. Three sources of foliar molybdenum (Nanofertilizer, molybdenum Chelate and Sodium Molybdate) were applied in four doses of 0, 5, 10 and 20 ppm Mo, complemented with edaphic fertilization of NH4NO3 (0, 3, 6 and 12 mM of N). As results, the NUE indices showed that with the application of the nanofertilizer, the total biomass production increased 41.65% more than with the application of the chelate, and 36.84% more than with the application of molybdate. In summary, the dose that presented the highest efficiency was 6 mM-N with 10 ppm-Mo. Finally, it is concluded that the use of NUE indices is an important approach that evaluates the fate of nitrogen and accurately estimates plant yield.

Effects of a liquid and dry Saccharomyces cerevisiae fermentation product (SCFP) feeding program on ruminal fermentation, total tract digestibility, and plasma metabolome of Holstein steers receiving a grain-based diet.

The study aimed to determine the effects of a postbiotic feeding program consisting of liquid and dry Saccharomyces cerevisiae fermentation product (SCFP) on ruminal fermentation, digestibility, and plasma metabolome of Holstein steers receiving a grain-based diet. Eight Holstein steers (Body weight; BW 467 ± 13.9kg) equipped with rumen cannulas were used in a crossover design study, with 21 d per period and a 7 d washout period in between periods. Steers were stratified by initial BW and assigned to one of two treatments. The treatments were (1) Control, basal finishing diet only (CON); (2) SCFP, one-day feeding of liquid SCFP (infused into the rumen via the cannula at 11mL/100kg BW) followed by daily feeding of dry SCFP (12g/d, top-dressed). Feed and spot fecal samples were collected during d 17 to 20 for determination of digestibility and fecal excretion of N, P, Cu, and Zn. Digestibility was measured using acid-insoluble ash as an internal marker. Blood samples were collected on d 21 before the morning feeding. Rumen fluid samples were collected on d 0, 1, 2, 3, 5 and 21 via rumen cannula. Results were analyzed with the GLIMMIX procedure of SAS 9.4 (SAS, 2023). Treatment did not affect DMI (P = 0.15) and digestibility (P ≥ 0.62). The fecal output and absorption of Zn, Cu, P, and N were not affected (P > 0.22) by treatment. On d 1, the liquid SCFP supplementation tended to reduce (P = 0.07) ruminal VFA concentration and increased (P < 0.01) the molar proportion of valerate. Feeding SCFP tended to increase total ruminal VFA on d 5 (P = 0.08) and significantly increased total VFA on d 21 (P = 0.05). Ruminal NH3-N was reduced (P = 0.02) on d 21 by supplementing SCFP. Treatment did not affect the production of proinflammatory cytokines, IL-1β (P > 0.19) and IL-6 (P > 0.12) in the whole blood in response to various toll-like receptor stimulants in vitro. Feeding SCFP enriched (P ≤ 0.05) plasma metabolic pathways, including citric acid cycle, pyrimidine metabolism, glycolysis/gluconeogenesis, retinol metabolism, and inositol phosphate metabolism pathways. In summary, supplementing liquid SCFP with subsequent dry SCFP enhanced ruminal total VFA production and reduced NH3-N concentration nitrogen in the rumen. Furthermore, feeding SCFP enriched several important pathways in lipid, protein, and glucose metabolism, which may improve feed efficiency of energy and protein in Holstein steers.

Design considerations of a new freezer construction in the tubular ice machine by experimental study

The need to improve the structure of components to create a new system compacter and cheaper, but still ensuring the system's consistent operation is always necessary and urgent. This study found the consistent of a new integrated freezer construction in the tubular ice machine by experimental study. The measuring instruments were been set for this air-cooled experimental model to validate the system stability when integrating the freezer, accumulator and heat exchanger into an integrated freezer. At a typical experiment 50 Hz inverter control, the R404a refrigerant used to evaporate at −15 °C, achieved the duration of total ice production cycle is around 29.5 min whereas the duration of ice production process takes around 24.5 min (rated 2.88 min/°C) and the defrost takes 5 min. The experimental coefficient of performance decreases from 1.77 to 1.51 and gets averagely 1.55 in the ice production process. From three others experimental results, coefficient of performance, the duration of ice production process, and saturation temperature of refrigerant in freezer change corresponding to the supplied power by inverter control for compressor.

Chitosan and inulin synergized with Lactiplantibacillus plantarum LPP95 to improve the quality characteristics of low-salt pickled tuber mustard

Low-salt pickled vegetables are in line with a healthier diet, yet ensuring consistent quality of such products is challenging. In this study, low-salt tuber mustard pickles fermented with Lactiplantibacillus plantarum LPP95 in the presence of chitosan and inulin were analyzed over a 30-day period, and quality changes were evaluated. Total acid productions along with high bacterial counts (106 CFU/mL) were observed in the initial 20 days during indoor storage temperature, in which the reduced fiber aperture was found significantly lead to an increase in crispness (16.94 ± 1.87 N) and the maintenance of a low nitrate content (1.23 ± 0.01 mg/kg). Moreover, the combined pickling treatment resulted in higher malic acid content, lower tartaric acid content, and a decrease in the content of bitter amino acids (e.g., isoleucine and leucine), thus leading to an increase in the proportion of sweet amino acids. Additionally, combined pickling led to the production of unique volatile flavor compounds, especially the distinct spicy flavor compounds isothiocyanates. Moreover, the combined pickling treatment resulted in an increase in the abundance of Lactiplantibacillus and promoted microbial diversity within the fermentation system. Thus, the synergistic effect among chitosan, inulin, and L. plantarum LPP95 significantly enhanced the quality of pickles. The study offers a promising strategy to standardize the quality of low-salt fermented vegetables.

Analysis of hydrogen supply and demand in China's energy transition towards carbon neutrality

The role of hydrogen in the transition to carbon-neutral energy systems will be influenced by key factors such as carbon neutrality pathways, hydrogen production technology costs, and hydrogen transportation costs. Existing studies have not comprehensively analyzed and compared the impact of these key factors on the development of hydrogen supply and demand under China's carbon neutrality pathways. This study uses the Global Change Assessment Model (GCAM) with an upgraded hydrogen module to evaluate the development potential of China's hydrogen industry, considering various carbon neutrality pathways as well as hydrogen production and transportation costs. The findings indicate that, by 2050, hydrogen could account for 8%–14% of final energy, averting 1.0–1.7 Bt of carbon emissions annually at an average mitigation cost of 85–183$ t−1CO2. The total hydrogen production is projected to reach 75–135 Mt, with 34%–56% from renewable energy electrolysis and about 15%–29% from fossil fuel-based CCS. On a sectoral level, by 2050, the hydrogen demand in the industrial and transportation sectors is expected to reach 37–63 Mt and 30–42 Mt, with a potential reduction of about 0.6–0.9 BtCO2 and 0.5–0.6 BtCO2. The share of hydrogen in the final energy of the steel and chemical sectors is estimated to be 9%–19% and 17%–25%, collectively accounting for 36%–42% of total hydrogen demand and 46%–50% of total emission reduction potential. Realizing hydrogen's emission reduction potential relies on the rapid development of hydrogen production, transportation, and utilization technologies. Firstly, the development of on-site electrolysis for hydrogen production and early deployment of industrial hydrogen applications should be prioritized to stimulate overall growth of hydrogen industry and cost reduction. Secondly, vigorous development of renewable energy electrolysis and hydrogen end-use technologies like fuel cells should be pursued, along with the demonstration and promotion of hydrogen transportation technologies. Lastly, further advancement of carbon market mechanisms is essential to support the widespread adoption of hydrogen technologies.

Forage boost or grain blues? Legume choices shape Kernza intermediate wheatgrass dual-purpose crop performance

Context or problemKernza intermediate wheatgrass is a new perennial grain crop with the potential to produce high nutritive value forage when intercropped with legumes. Understanding the potential benefits of intercropping systems requires considering the interaction between different legume species intercropped, intermediate wheatgrass row spacing, and environments encompassing spatial and temporal variation. Objective or research questionWe aimed to evaluate the effect of these factors on the biomass allocation to harvestable (grain, intermediate wheatgrass forage, legume forage) and non-harvestable (weed biomass) outputs. MethodsIn four environments, given by the combination of two sites (Wisconsin, USA) and two establishment years, we sowed intermediate wheatgrass in two row spacings in eight cropping systems: three intermediate wheatgrass monocultures [control without N fertilization, intermediate wheatgrass fertilized with 45 or 90 kg N ha−1 as urea], and four intermediate wheatgrass-legume intercrops (intermediate wheatgrass with alfalfa, Berseem clover, Kura clover, or red clover). We evaluate grain yields, intermediate wheatgrass and legume forage, and weed biomass over three consecutive years. ResultsOur results suggest that intercropping legumes does not affect Kernza grain yield in the first grain production year, which is the year with the highest yield potential. In subsequent production years, grain yields were lower in red clover intercrops than in intermediate wheatgrass monoculture control or fertilized, depending on the environment. Among the legumes tested in our study, red clover and alfalfa were suitable for increasing total biomass production in most of the environments and red clover reduced weed biomass compared to intermediate wheatgrass monocultures. ConclusionsOur results encourage intercropping legumes with intermediate wheatgrass because of the increase in forage yield and quality. These benefits can compensate for lower Kernza grain yields commonly observed in the second and third production years. Implications or significanceOur study provides valuable insights into the intermediate wheatgrass potential as a dual-use crop for grain and forage production. Improving our understanding of the factors that influence grain yield and forage production such as post-harvest management, multiple forage harvests or grazing, may optimize the productivity and sustainability of these cropping systems.

The impact of the informal sector on supply chains in Africa

ABSTRACT The informal sector adds a systemic layer of uncertainty and risk for the performance of Food Supply Chains in sub-Saharan Africa. Based on interviews conducted among all the agents directly involved in the FSCs and international statistics, we analysed how the informal sector affects five mango FSCs in Burkina Faso in their economic, social and environmental performance. The informal sector accounts for about 30% of the total FSCs value, 67% of the total production, and 99% of the workforce. The lack of statistics, lack of legal compliance, lack of public infrastructure, increases the probability and severity of any given risk and therefore hinders investments. Firms internalise the risks with horizontal and vertical integration, the support of subsidies, or by avoiding the costs of international standards compliance. As a result, we distinguish subsidised resilience from informal resilience. FSC's resilience in sub-Saharan Africa will depend on how the level of state intervention, legal compliance and law enforcement will affect the informal sector.

National trends in the use of aquatic bioresources

The article examines the domestic trends in the use of aquatic biological resources for more than a century. Until the early 1950s, inland waters, primarily the Caspian and Azov Seas, played a key role. Total catch volumes did not exceed 2 million tons. Anthropogenic impact has led to global negative changes in the ecosystems of the south seas of our country. The fishery importance of inland reservoirs has significantly decreased. The active development of oceanic fishing in the 1960s and 1980s made it possible to increase the volume of extraction of aquatic biological resources to 10−11 million tons. Starting in 2018 Access to the use of aquatic biological resources largely depends on the involvement of domestic industrial companies in the construction of new ships at Russian shipyards. The proven reserves of even traditionally mined hydrobionts make it possible to fully ensure the fishing capacities of all vessels currently under construction and under design. The contribution of commercial fish farming to the total production of domestic fish products in the foreseeable future, apparently, will not exceed 10%.

Deciphering the role of Moringa oleifera seeds and probiotic bacteria on mitigation of biogas production from ruminants

Maintaining cleaner and more sustainable ecosystems by mitigating greenhouse gas (GHG) emissions from livestock through dietary manipulation is in demand. This study was aimed to assess the effect of Moringa oleifera seeds and probiotics (Pediococcus acidilactici BX-B122 and Bacillus coagulans BX-B118) as feed supplements on GHG production and fermentation profile from steers and sheep. The treatments included diets containing 0, 6, 12, and 18% of M. oleifera seeds meal and a mixture of probiotic bacteria (0.2 ml/g of diet). Total biogas production, CH4, CO, and H2S emission from animals (up to 48 h), rumen fermentation profile, and CH4 conversion efficiency were recorded using standard protocols. Results showed interaction among M. oleifera seeds and probiotics on asymptotic biogas production and total biogas production up to 48 h (P < 0.05). The rate of CH4 emission in steers was reduced from 0.1694 to 0.0447 ml/h using 6 and 18% of M. oleifera seeds (P < 0.05). Asymptotic CO and the rate of CO production were increased (P < 0.05) by supplementing different doses of M. oleifera seeds and probiotics. Adding 12% of M. oleifera seeds and probiotics reduced H2S production from 0.0675 to 0.0112 ml H2S/g DM (at 48 h of fermentation) in steers. In sheep, the additives mitigated H2S production from 0.0364 to 0.0029 ml H2S/g DM (at 48 h of fermentation), however there were not interaction (P = 0.7744). In addition, M. oleifera seeds and probiotics reduced the pH level and dry matter degradability (DMD) in steers and sheep (P < 0.0001) showing a positive impact on CH4:ME and CH4:OM (in steers) and CH4:SCFA (in sheep), while the interaction was not significant (P > 0.05) for CH4:SCFA (in steers) and CH4:ME and CH4:OM (in sheep). In conclusion, the interaction of M. oleifera seeds and probiotics in the feeding diet reduced GHG emissions and affected the fermentation profile of steers and sheep.

Impact of the Deletion of Genes of the Nitrogen Metabolism on Triacylglycerol, Cardiolipin and Actinorhodin Biosynthesis in Streptomyces coelicolor

Since nitrogen limitation is known to be an important trigger of triacylglycerol (TAG) accumulation in most microorganisms, we first assessed the global lipid content of 21 strains derived from Streptomyces coelicolor M145 deleted for genes involved in nitrogen metabolism. Seven of these strains deleted for genes encoding proteins involved in polyamine (GlnA2/SCO2241, GlnA3/SCO6962, GlnA4/SCO1613), or protein (Pup/SCO1646) degradation, in the regulation of nitrogen metabolism (GlnE/SCO2234 and GlnK/SCO5584), or the global regulator DasR/SCO5231 that controls negatively the degradation of N-acetylglucosamine, a constituent of peptidoglycan, had a higher TAG content than the original strain, whereas five of these strains (except the glnA2 and pup mutants) had a lower cardiolipin (CL) content. The production of the blue polyketide actinorhodin (ACT) was totally abolished in the dasR mutant in both Pi conditions, whereas the deletion of pup, glnA2, glnA3, and glnA4 was correlated with a significant increase in total ACT production, but mainly in Pi limitation. Unexpectedly, ACT production was strongly reduced in the glnA3 mutant in Pi proficiency. Altogether, our data suggest that high TAG and ACT biosynthesis and low CL biosynthesis might all contribute to the lowering of oxidative stress resulting from nitrogen limitation or from other causes.

Pruning inflorescences reduces the yield of neutral-day strawberry cultivars

The lack of information on inflorescence pruning of strawberry cultivars can compromise fruit yield and quality. The aim of this study was to investigate whether inflorescence pruning intensities interfere with the horticultural potential of strawberry cultivars. The treatments studied were three cultivars (‘Albion’, ‘Monterey’, and ‘San Andreas’) and four inflorescence pruning intensities (no pruning, removal of the first inflorescence, removal of the first two inflorescences, and removal of the first three inflorescences). The experiment was laid out in randomized blocks, with four replications. Fruit production and quality were assessed. ‘Monterey’ produced the most fruit and had the highest total strawberry production. Regardless of the cultivar, the total number of fruits and the total yield decreased linearly as the intensity of inflorescence pruning increased. In conclusion, increasing the intensity of inflorescence pruning reduces the productive potential of strawberry plants. Regardless of pruning, ‘Monterey’ has the best productive performance. The chemical quality of strawberries is not influenced by the pruning and cultivars studied.

Impact of Sediment Accumulation in the Operation on Hydro Plant: A Case Study of the Nam Sana Hydropower Plant Lao PDR

The annual electricity production in Laos amounts to $1.98 billion, representing 12.8% of the country's GDP, with hydropower accounting for 80% of the total production. However, the run-of-river hydroelectric power facility has been facing issues with sediment accumulation in its reservoir. This accumulation leads to system inefficiency and corrosion of turbine components. This paper examines the impact of sediment accumulation on electricity productivity, turbine efficiency, and sediment management within the reservoir. The Nam Sana Hydropower Plant (NSN HPP) in Lao PDR serves as the case study, with data collected from 2015 to 2023. The average annual sedimentation volume is 6,459 cubic meters, which is 28.3% of the total reservoir volume, and has been removed using heavy machinery. The proposed method in the study compares monthly production before and after sediment removal, showing a 12.1% increase in production over a 30-day period. As a long-term solution to mitigate sediment accumulation, the construction of a sediment trap is suggested. This trap, with a volume of 4,000 cubic meters, can be installed by NSN HPP before the reservoir, capturing 62% of the average annual sediment accumulation.

Quantifying the biogenic silica production of picoplankton in the oligotrophic ocean: A case study in the South China Sea

Silicon (Si) utilization is not limited to eukaryotes. Recent research has suggested that the pattern of a large contribution of picocyanobacteria to biogenic silica (bSi) stocks might be widespread in the oligotrophic open ocean. We are the first to measure the size-fractionated bSi standing stocks and production rates in the oligotrophic South China Sea (SCS), which has obvious characteristics of oligotrophic waters. The 150 m integrated bSi standing stocks in the pico-sized fractions averaged 23 % of the total; the contribution of picoplankton to the total bSi production rate was 44 %. Interestingly, our estimated contributions of Synechococcus alone to the <2 μm bSi standing stock and < 2 μm bSi production rates averaged 14 % and 66 %, respectively, indicating that the significant and persistent contribution of bSi was strongly associated with marine picocyanobacteria. Furthermore, the dynamic changes in nutrient concentrations, especially in DIN and DIP, also potentially affected the variability in picoplankton bSi stocks and production rates, while the effects of temperature and salinity were not obvious. In this study, we have provided new information on measurable bSi in the picoplankton size fraction and its production rate in the SCS. We have demonstrated that picoplankton contributes a measurable, and at times significant, proportion to both the total bSi standing stock and its production rate in the SCS. A high silicon content within picocyanobacteria has important implications for understanding both their ecology and their contribution to biogeochemistry.

Evaluating the agronomic and economic viability of biochar in sustainable crop production

This paper examines the economic viability of biochar application in crop production, focusing on varying application rates of 0, 4, 8, 12, 16, 20, 24, and 28 tons per hectare. Biochar, produced through biomass pyrolysis, has shown promise in improving crop yields and contributing to environmental sustainability. The biochar production financial metrics were analyzed, and it shows that the economic parameters such as Operational Expenditure (OPEX) amounting to $2339.40, feedstock cost of $2420.25, and transport cost of $293.71. The total biochar production cost was $232.87 per ton, with labour costs comprising 27.07 % of the overall production and application expenses. The analysis revealed that the maximum annual revenue from crop production (peas in the rabi season and maize in the kharif season) reached $525.88 per hectare at a biochar application rate of 12 tons/ha. Carbon sequestration revenue was estimated at $186.6 per ton of biochar. Economic indicators revealed that the benefit-cost ratio (BCR) was the highest at 1.476, with an 8 ton/ha biochar application rate. At the same time, the net present worth (NPW) and internal rate of return (IRR) also maximized at this rate, reaching $932.85 and 85.71 %, respectively. Conversely, higher biochar application rates of 24 and 28 tons/ha resulted in negative NPW and IRR values and BCR values below 1, indicating economic infeasibility at these levels. These findings highlight the economic viability and potential agronomic benefits of biochar application at optimal rates of 8 tons/ha for promoting sustainable crop production.

Assessment of hydrogen production technologies from agricultural residues in Vietnam

Green hydrogen is one of the alternative options to decarbonize the energy sector and limit the global temperature rise below 1.5 °C. Vietnam has various biomass resources, including agricultural and forestry by-products. However, this country has not had any research to evaluate the suitability of hydrogen production technologies using biomass sources in general and agricultural residues in particular with all relevant factors as a basis for investment and development. The paper assesses three green hydrogen production technologies from agricultural residue, including pyrolysis, gasification, and fermentation, by simultaneously applying the Strength Weakness Opportunity Threat (SWOT) analysis and Analytic Hierarchy Process (AHP). The hydrogen production technologies and agricultural residues in Vietnam are used as case studies. The obtained results on the weighting factors indicate that the economic indicator accounts for 50.7 %, followed by the technical indicator at 27.8 % and the environmental indicator at 21.5 %. Among the hydrogen production technologies, gasification is the most prioritized technology, at 43.3 %. The priorities of pyrolysis and fermentation are not considerably different, at 29.6 % and 27.1 %, respectively. Rice straw has the highest hydrogen production capacity with a total potential of about 50.43 billion m3 while the lowest total hydrogen production potential is cassava pomace with a value of 0.26 billion m3. Designing and simulating the hydrogen production process from agricultural waste using selected technologies will be studied in further work to finalize and verify the used assumptions, methods, and information in this study.

An Analysis of Greenhouse Gas Emissions in Electrolysis for Certifying Clean Hydrogen

The drive for carbon neutrality has led to legislative measures targeting reduced greenhouse gas emissions across the transportation, construction, and industry sectors. Renewable energy sources, especially solar and wind power, play a pivotal role in this transition. However, their intermittent nature necessitates effective storage solutions. Green hydrogen and ammonia have gained attention for their potential to store renewable energy while producing minimal emissions. Despite their theoretical promise of zero greenhouse gas emissions during production, real-world emissions vary based on system configurations and lifecycle assessments, highlighting the need for detailed evaluations of their environmental impact. Therefore, in this study, calculations were performed for the actual amount of produced greenhouse gas emissions that are associated with the production of green hydrogen using electrolysis, from raw material extraction and processing to hydrogen production, with these assessed from well-to-gate emission estimates. Emissions were also evaluated based on various types of renewable energy sources in South Korea, as well as hydrogen production volumes, capacities, and types. Using these data, the following factors were examined in this study: carbon dioxide emissions from the manufacturing stage of electrolysis equipment production, the correlation between materials and carbon dioxide emissions, and process emissions. Current grades of clean hydrogen were verified, and the greenhouse gas reduction effects of green hydrogen were confirmed. These findings are significant against the backdrop of a country such as South Korea, where the proportion of renewable energy in total electricity production is very low at 5.51%. Based on the domestic greenhouse gas emission efficiency standard of 55 kWh/kgH2, it was found that producing 1 kg of hydrogen emits 0.076 kg of carbon dioxide for hydropower, 0.283 kg for wind power, and 0.924 kg for solar power. The carbon dioxide emissions for AWE and PEM stacks were 8434 kg CO2 and 3695 kg CO2, respectively, demonstrating that an alkaline water electrolysis (AWE) system emits about 2.3 times more greenhouse gasses than a proton exchange membrane (PEM) system. This indicates that the total carbon dioxide emissions of green hydrogen are significantly influenced by the type of renewable energy and the type of electrolysis used.