Total Metal Concentrations Research Articles

Impact of Flooding on Lands with Emerging Contaminants on the Quality of Receiving Water Bodies

Among crucial factors that control flooding events are extreme climate, urban growth, and mismanagement. Islands in the Nile River have experienced successive cycles of flooding and drying due to recent rainy years in the Nile Basin countries. This paper focuses on the impact of floods on the amounts of ammonium-N released, total concentrations of heavy metals, enzyme activities, and microbial biomass (C and N) in flood soils of 11 Nile River islands. Field moist soils and their airdried counterparts were collected from the outskirts of the island and incubated for 15 days at 30 °C to be analyzed. Results reflected that the amounts of released NH4-N were higher in airdried than in wet soils. The average hydrolysis rates of the studied six enzyme substrates were correlated significantly with organic C, organic N, microbial bio-mass C and N in the field moist soils. The highest correlation coefficients (r) were with rates of hydrolysis of substrates of asparaginase, amidase, and β-glycosaminidase. A significant intercorrelation between rates of hydrolysis of the six studied enzyme substrates and r values which range from 0.81 to 0.98. At 10 mmol kg−1 soil, Co+2, Cd+2, Pb+2, Cu+2, Cr+3, and Ni+2 inhibited the release of NH4-N. Arginine hydrolysis was inhibited by the six heavy metals at 5 mmol kg−1 soil; the most effective inhibitors were Pb+2, Ni+2, and Cr+3. Due to the complex soil enzymatic and organic nitrogen hydrolase activities that occur during floods, fertile fields on the Nile River islands should not be fertilized before the summer flood seasons, which will prevent contamination of the Nile River water and loss of its island soil fertility.

Tailoring Hydrogen Adsorption via Charge Transfer at Bimetallic Cr0.48Ru0.52 Alloy Nanoparticles Decorated on Carbon Nanofiber for Enhanced Hydrogen Evolution Catalysis

Designing and synthesizing highly efficient and stable electrocatalysts for the hydrogen evolution reaction (HER) is crucial for the practical and large-scale application of hydrogen sources. Recent research has focused on tuning the electronic structure of electrocatalysts to achieve optimal HER activity, with particular emphasis on interfacial engineering to induce electron transfer and optimize HER kinetics. In this study, as part of research into heterointerface engineering, bimetallic Cr0.48Ru0.52 alloy nanoparticles decorated on carbon nanofibers (Cr0.48Ru0.52/CNFs) were fabricated through a simple electrospinning and post-calcination process to serve as an efficient alkaline HER catalyst. The Cr0.48Ru0.52/CNFs demonstrated exceptional electrocatalytic HER performance, with an overpotential of only 13 mV at −10 mA cm−2 and a Tafel slope of 60.8 mV dec−1, indicating high catalytic activity compared to commercial benchmark catalysts (i.e., Ru/C and Pt/C). First-principles density functional theory calculations support these results, revealing that Cr0.48Ru0.52 balances proton reduction (Volmer step) and H* desorption (Tafel/Heyrovsky step) processes during electrocatalysis, as evidenced by the near-zero hydrogen adsorption (ΔGH*) value (ca. −0.11 eV). Therefore, this study highlights that Cr0.48Ru0.52/CNFs, with noble Ru comprising only half of the total metal content, can promote optimal HER kinetics under alkaline condition.

Impact of Metal-Containing Industrial Effluents on Leafy Vegetables and Associated Human Health Risk.

One of the primary sources of trace elements in the environment is wastewater used for irrigation. However, the effects of untreated wastewater containing high concentrations of chromium and zinc on vegetables and the potential human health risks associated with their consumption are poorly understood. This pot experiment aimed to address this research gap. The accumulation of chromium and zinc and their effect on the biochemical parameters of lettuce (Lactuca sativa) and green onion (Allium fistulosum L.) irrigated with untreated industrial effluents were assessed. The average concentrations of chromium and zinc in the edible parts of the vegetables ranged between 7.36 and 7.58 mg/kg dry weight and 59.8 and 833 mg/kg dry weight, respectively. The irrigation of the lettuce with the effluent containing zinc at a concentration of 2.95 mg/L led to a significant increase in the content of phenols and the antioxidant activity. A significant reduction in the chlorophyll content of the lettuce leaves and the antioxidant activity of the onion leaves was observed when the plants were irrigated with the effluent containing zinc at a concentration of 78 mg/L. No non-carcinogenic health risk from the intake of chromium and zinc was identified through the consumption of lettuce and green onion, primarily due to the fact that a smaller proportion of the total metal content was transferred to their edible parts.

NATECH POTENTIAL DUE TO EMERGING CLIMATE HAZARDS AND AWARENESS OF THE LOCAL STAKEHOLDERS IN THE COASTAL INDUSTRIAL SITE OF KUALA SELANGOR, MALAYSIA

Climate change may put more industrial sites at risk of Natech incidents, particularly in coastal areas due to the compounding effects of climate hazards. This study investigates industrial facilities with potential for Natech due to emerging floods and delineates awareness of the exposed stakeholders, using the best available information, to strengthen local level climate change adaptation and disaster resilience in IKS Kuala Selangor, Malaysia. Two major methods were employed, conceptual site modelling using the source-pathway-receptor-consequence approach and semi-structured interviews to get insights from the local stakeholders. Findings reveal that in the worst-case scenario, manufacturing industries are exposed to floods, have limited flood protection and unknown containment and storage measures of hazardous materials within their facilities. While the high concentration of total metals in the surrounding topsoil has not been linked directly to the manufacturing industries, they have potential for Natech in future flood events. An area with environmentally available lead and arsenic accumulation linked to agricultural activities is also a potential point source for pollution during flood events in the worst-case scenario. Although most of the exposed local stakeholders are aware of climate hazards, they are not prepared for the risks of Natech. The local adaptation plan should include awareness building on Natech targeting the exposed local stakeholders as well as adequate flood protection and updated guidance on managing the safety of hazardous materials at manufacturing industry facilities.

Assessment of Heavy Metal Contamination in Combretum micranthum Leaves and Decoctions: Implications for Human Health

Combretum micranthum is a well-known medicinal plant in Africa and the decoction of its leaves is used as a drink or to treat various diseases such as malaria, high blood pressure and liver disorders, among others. Due to its high consumption by all sections of the Senegalese population, we felt that its heavy metal intake should be examined to see its impact on health. Leaves of two species of Combretum micranthum produced in the central (I) and southern (II) regions of Senegal and their decoctions in ultrapure water (Ii) and (IIi) were analyzed for 12 elements (Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Ag, Cd, Pb, Bi) by inductively coupled plasma optical emission spectrometer (ICP-OES). The concentrations of heavy metals (μg/g) are in the ranges 2.55 – 84.19 for Cr, 5.21 – 379.72 for Mn, 0.00 – 317.80 for Fe, 0.08 – 1.08 for Co, 1.54 – 8.88 for Ni, 1.75 – 8.08 for Cu, 0.91 – 9.70 for Zn, 0.00 – 0.16 for Cd, 0.46 – 0.84 for Pb. As, Ag and Bi are below detectable limits in any of the samples by ICP-OES analysis. Among all samples, manganese content was highest and represented 46.85% for I , 64.18% for II , 86.88% for Ii and 46.27% for IIi , of the total heavy metal concentrations. The results showed that the leaves of both varieties of Combretum micranthum and decoctions made from these leaves contain heavy metal levels lower than the values recommended by the WHO for consumed medicinal plants. Overall, Variety I harvested from peri-urban areas contains more metals than Variety II harvested from forest.

Renewable Diesel Production over Mo-Ni Catalysts Supported on Silica

Nickel catalysts promoted with Mo and supported on silica were studied for renewable diesel production from triglyceride biomass, through the selective deoxygenation process. The catalysts were prepared by wet co-impregnation of the SiO2 with different Ni/(Ni + Mo) atomic ratios (0/0.84/0.91/0.95/0.98/1) and a total metal content equal to 50%. They were characterized by XRD, XPS, N2 physisorption, H2-TPR, and NH3-TPD. Evaluation of the catalysts for the transformation of sunflower oil to renewable (green) diesel took place in a high-pressure semi-batch reactor, under solvent-free conditions. A very small addition of Mo, namely the synergistic Ni/(Ni + Mo) atomic ratio equal to 0.95, proved to be the optimum one for a significant enhancement of the catalytic performance of the metallic Ni/SiO2 catalyst, achieving 98 wt.% renewable diesel production. This promoting action of Mo has been attributed to the significant increase of the metallic Ni active phase surface area, the suitable regulation of surface acidity, the acceleration of the hydro-deoxygenation pathway (HDO), the creation of surface oxygen vacancies, and the diminution of coke formation provoked by Mo addition.

An improvement for enrichment and purification of germanium using carbonyl acid extractants

Germanium is a strategic metal that is challenging to enrich and purify without any side effects, especially stability and selectivity. Here the role of carbonyl acid in selective separation of germanium from complex industrial liquids was highlighted. Integrating theoretical and experimental analyses, carbonyl acids exhibit strong binding ability and high selectivity to germanium was demonstrated. The first set of carbonyl acid extractant (CAE) for germanium extraction was successfully synthesized with a solubility of less than 50 mg/L at pH = 0. The process analysis exhibits the extraction rate of germanium in a single stage by CAEs exceeds 99.9 %, while the separation factor surpasses 103, far beyond 101 of hydroxamic acids. Furthermore, the stripping rate for germanium in a single stage exceeds 83.0 %, with germanium accounting for over 99.9 % of the total metal content in the stripping solution. The CAE extraction process is straightforward and characterized by high germanium separation efficiency. The development of CAE not only realises the stable, green, low-carbon, and high-efficiency purification of germanium, but also the universality and inspiration of CAE make it highly significant and valuable in both theoretical research and practical applications.

Smartphone-assisted colorimetric sensor arrays based on nanozymes for high throughput identification of heavy metal ions in salmon

The rapid, precise, and high-throughput identification of multiple heavy metals ions holds immense importance in ensuring food safety and promoting public health. This study presents a novel smartphone-assisted colorimetric sensor array for the rapid and precise detection of multiple heavy metals ions. The sensor array is based on three signal recognition elements (AuPt@Fe-N-C, AuPt@N-C, and Fe-N-C) and the presence of different heavy metal ions affects the nanozymes-chromogenic substrate (TMB) catalytic color production, enabling the differentiation and quantification of various heavy metal ions. Combined with a smartphone-based RGB mode, the colorimetric sensor array can successfully identify five different heavy metal ions (Hg2+, Pb2+, Co2+, Cr6+, and Fe3+) as low as 0.5 μM and different ratios of binary and ternary mixed heavy metal ions in just 5 min. The sensor array successfully tested seawater and salmon samples with a total heavy metal content of 10 μM in the South China Sea (Haikou and Wenchang). Overall, this study highlights the potential of smartphone-assisted colorimetric sensor arrays for the rapid and precise detection of multiple heavy metal ions, which could significantly contribute to food safety and public health monitoring.

Assessing soil remediation effect of Cr and Pb based on bioavailability using DGT, BCR and standardized determination method

In the field of soil remediation, the importance of bioavailability of pollutants has not received adequate attention, leading to the excessive application of remediation measures. Therefore, to ensure the safe use of farmland soil, a scientific method is needed to assess labile contaminants and their translocation in plants. To evaluate soil remediation effect based on bioavailability, the concentrations of these heavy metals in soil were analyzed using by the method for total metal content, the Community Bureau of Reference (BCR) extraction, and the diffusive gradients in thin films (DGT) technique. The results reveal that the correlation coefficients between metal concentrations measured by DGT and those accumulated in rice grains are the highest (Cr-R2 = 0.8966, Pb-R2 = 0.9045). However, the capability of method for total metal content to evaluate the remediation effect of heavy metals is very limited. In contrast, although Cr and Pb measured by BCR show a high correlation with HMs in rice plants, the method still falls short in precisely assessing bioavailability. Significantly, DGT proves to be more effective, successfully distinguishing the remediation effects of different treatments. Generally, DGT offers a more accurate and simpler assessment method, underscoring its practical significance for monitoring soil remediation and environmental management.

Sources Analysis and Health Risk Assessment of Heavy Metals in Street Dust from Urban Core of Zhengzhou, China

Fifty-one street dust samples were systematically collected from the urban core of Zhengzhou, China, and analyzed for potentially toxic metals. The concentrations of vanadium (V), manganese (Mn), copper (Cu), zinc (Zn), arsenic (As), lead (Pb), and nickel (Ni) in the samples surpassed the background values of the local soil, indicating a notable potential for contamination. Spatially, the traffic area was the most polluted with a total heavy metal concentration of Cu, Zn, As, Pb, and Ni, while the pollution levels were lower in the culture and education area and commercial area with total concentrations of V and Mn. Seasonal variations were discerned in the concentrations of heavy metals, with V, Cu, Zn, and As exhibiting heightened levels during the fall and winter, while Mn, Ni, and Pb reached peaks in the spring season. Zn exhibited the highest mean geo-accumulation index (Igeo) value at 2.247, followed by Cu at 2.019, Pb at 0.961, As at 0.590, Ni at 0.126, Mn at −0.178, and V at −0.359. The potential ecological risk index (RI) in the traffic-intensive area markedly exceeded other functional areas. Health risk assessments showed that children were more vulnerable to heavy metal exposure than adults, particularly through the ingestion pathway. Correlation analysis, principal component analysis (PCA), and cluster analysis (CA) were applied in conjunction with the spatial–temporal concentration patterns across various functional areas to ascertain the plausible sources of heavy metal pollutants. The results indicated that heavy metals in the urban street dust of Zhengzhou were multifaceted, stemming from natural processes and diverse anthropogenic activities such as coal burning, industrial emissions, traffic, and construction operations.

Long-term agricultural reuse of treated wastewater and sewage sludge: developing a Time to Critical Content Index for metal species

This study evaluates the sustainability of spreading wastewater or sewage sludge on agricultural land, balancing benefits with contamination risks. Conventional ecological risk indices often fail to address the long-term accumulation of metals in soils. We investigate the feasibility of spreading based on current knowledge of potentially contaminating metals and their behavior in soil. We analyzed the speciation of metals (Ag, Cd, Co, Cr, Cu, Ni, Pb, Ti, Zn) through sequential extraction in sludge, treated wastewater, and soils after 14 years of application of sewage sludge and treated wastewater issued from an Algerian wastewater treatment plant. We introduce a Time to Critical Content Index (TCCI) that calculates the time required to reach critical levels of potentially mobile metals, considering total metal content and speciation. The TCCI takes into account product knowledge, soil characteristics, metal behavior, ecological/toxicological thresholds, and regulations. Applied to our case study, the TCCI indicates that spreading sewage sludge can continue despite metal contents exceeding regulatory ceiling values. The index serves as a precautionary measure, adaptable to evolving knowledge, providing a comprehensive framework for sustainable agricultural practices.Graphical

Assessing heavy metal contamination and health risks in playground dust near cement factory: exposure levels in children

Heavy metals pose significant threats to human health, particularly children. This study aimed to assess heavy metal pollution in children's playgrounds using surface dust as an indicator and to ascertain the associated exposure levels and health risks. A total of one hundred twenty dust samples were collected from the surface of playground toys in areas surrounding the cement factory in Bursa, Türkiye, on precipitation-free days. The heavy metal content of the samples was analyzed using ICP-MS. The average total concentration of heavy metals ranged from 2401 to 6832 mg/kg across the sampling sites, with the highest values observed at PG4, PG3, PG2, and PG1, respectively. The most commonly detected heavy metals in the samples included Cr, Mn, Fe, Co, Cu, Zn, Pb, Cd, As, and Ni. Statistical analysis revealed significant positive correlations (p < 0.01) among Cr, Mn, Fe, Co, Cu, Pb, As, and Ni, with Cu and Pb also showing correlation (p < 0.05). PCA analysis identified three principal components explaining 79.905% of the total variance. The Hazard Quotient (HQ) and Hazard Index values for heavy metals were found to be below the safe threshold (HQ < 1). Quantitative techniques such as the geoaccumulation index and enrichment factor are used to determine pollution levels at the sampling sites. Overall, the results indicate that cement factories significantly contribute to heavy metal pollution, with observed values varying based on proximity to the emission source.

Heavy Metals in the Cultivated Soils of Central and Western Serbia

Concern over the harmful impacts of heavy metal pollution in soil has increased dramatically on a global scale. For the sake of environmental preservation, accurate estimates of the heavy metal concentrations in soil are essential. This study provides valuable data regarding heavy metal concentrations in soil collected from field crops production area in Central and Western Serbia. Five wider localities in the zones of Central and Western Serbia were selected for the collection of soil samples. Based on our research, focused on determining the total contents of heavy metals in the soil and the degree of pollution in the environment caused by their behavior, distribution, and origin, it can be concluded that there is pronounced variability in relation to localities. Heavy metal contents were mostly within the same ranges as those in similar soils from Europe and around the world. Any pollution control system must include heavy metal monitoring, including the methodical collection of data on the concentrations of heavy metals in a particular environment. Before environmental degradation occurs, it is crucial to set pollution limits and implement efficient monitoring procedures.

Investigating Cobalt Degradation in Acidic Environments for Oxygen and Hydrogen Electrocatalysis with Time-Resolved Mass Spectrometry Techniques

Cobalt is an important additive within commercially available energy devices including hydrogen fuel cell vehicles, lithium-ion batteries for electric vehicles and portable devices, and electrolyzers for water splitting. Regarding devices that include a proton exchange membrane (PEM), such as proton exchange membrane fuel cells (PEMFCs) and proton exchange membrane water electrolyzers (PEMWEs), cobalt-based materials are commonly used to perform the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER), respectively. However, given the acidic environment induced by the PEM (pH = 1), cobalt is thermodynamically unstable at ORR and HER relevant potentials, which results in cobalt dissolution and consequently decreases in device performance and lifetime. Minimizing electrode degradation of cobalt-based materials in acidic environments therefore requires a holistic understanding of cobalt’s degradation mechanisms, as it would be necessary to simultaneously monitor electrochemical output (current/voltage), cobalt dissolution, and product formation, which is not possible with one technique alone. To gain such an understanding, in this presentation I will discuss our work on developing comparable time-resolved techniques such as on-line inductively coupled plasma mass spectrometry (ICP-MS) and electrochemical mass spectrometry (EC-MS) to investigate the relationship between applied potential, time, cobalt dissolution, and product formation.With usage of EC-MS, it was observed that cobalt is active for HER in 0.1 M HClO4. and undergoes little to no cobalt dissolution (< 1 ng s-1) at potentials where cobalt is evolving H2 per ICP-MS measurements. This suggests that cobalt stability in acid strongly coincides with hydrogen evolution. In addition, when comparing cobalt’s material stability from the on-line ICP-MS experiments with its thermodynamic stability from its Pourbaix diagram, there is little to no cobalt dissolution at potentials outside its thermodynamic stability window. This is unexpected, as cobalt is projected to be thermodynamically stable only at potentials less than -0.277 VRHE (Co2+/Co = -0.277 VRHE for a dissolved total metal ion concentration of 1 M at pH = 1), whereas our data shows that cobalt dissolution is suppressed until -0.05 VRHE. Through combining findings from both EC-MS and ICP-MS, we have postulated a stability mechanism related to surface hydrogen coverage on cobalt that can be used to explain why cobalt is stable during HER and at potentials it is thermodynamically expected to be unstable.In addition to cobalt being HER active, we also uncovered its activity for ORR in O2 saturated 0.1 M HClO4. Cobalt dissolution under O2 versus N2 saturated 0.1 M HClO4 was then compared, and it was observed that in the presence of O2, cobalt dissolution occurs faster (~3x more dissolution), likely due to O2 induced chemical dissolution. However, after 3 cycles, the observed cobalt dissolution rates under both gas types are equivalent (~225 ng s-1), indicating an important relationship between time, potential, and electrochemical environment. Altogether, this work showcases how time-resolved techniques such as ICP-MS and EC-MS can be connected to unravel stability mechanisms of materials and motivative future studies to apply a holistic approach when evaluating material stability.

Health Risk Assessment of Road-Dust-Bound Heavy Metals via Ingestion Exposure from One Typical Inland City of Northern China: Incorporation of Sources and Bioaccessibility

Heavy metals in road dust pose potential health risks to humans, while oral bioaccessibility and sources are all important factors influencing this health risk. However, few prior studies have combined them for health risk analysis. In this study, road dust samples were collected from different geographical locations of Jinan (west area, WA; central area, CA; and east area, EA) to analyze the source-specific and bioaccessibility-based health risks of heavy metals. The mean concentrations of heavy metals in the three areas were CA &gt; EA &gt; WA, with Cd, Cu, Mn, Pb, and Zn exceeding their corresponding background values. A source analysis using a Positive Matrix Factorization (PMF) model showed that traffic emissions were the main source of heavy metals in the WA and CA, while industrial activities were the main source in the EA. The mean bioaccessibility of heavy metals extracted using the Solubility Bioaccessibility Research Consortium (SBRC) method followed the order of Cd (75.5%) &gt; Zn (42.2%) &gt; Mn (42.1%) &gt; Pb (42.0%) &gt; Cu (32.9%) &gt; As (23.6%) &gt; Ni (20.1%) &gt; V (16.8%) &gt; Cr (13.3%). According to the combined source analysis, traffic was the primary risk factor in the WA (54.5 and 58.3% of NCR and CR, respectively) and CA (61.8 and 51.2%), with solid waste being the main risk factor in the EA (41.9 and 51.3%). In oral bioaccessibility testing, lower non-carcinogenic (&lt;1.0) and carcinogenic risks (&lt;1 × 10−6) of heavy metals were observed than those based on the total metal content. More importantly, As (43.4%) was replaced by V (29.7%) as the main contributor to NCR. Source-specific and bioaccessibility-based health risk assessments can accurately identify priority pollutants and heavy metals in urban road dust that need to be controlled. This provides more effective and accurate urban environmental risk management recommendations for sustainable urban development and population health.

Impact of COVID-19 on temporal trends and health risks of urinary metal concentrations among residents of Guangzhou, China

Long-term biomonitoring of urinary metal ions is an essential tool for the epidemiological assessment of chronic exposure levels, enabling us to track changes in metal exposure over time and better understand its health implications. In this study, we evaluated the temporal trends of urinary metal ions among 1962 residents of Guangzhou, China, from 2018 to 2022. The total metal ion concentrations in the urine of the population did not change significantly between 2018 and 2019. With the onset of the COVID-19 pandemic in 2020, urinary total metal ion concentrations began to decline dramatically, reaching their lowest level in 2021. A rebound in concentrations was observed in 2022, which returned to the initial levels observed in 2018. Urine chromium and cadmium concentrations peaked in 2020, while urinary lead levels were the highest in 2021, and urinary nickel concentrations were the highest in 2022. Males consistently displayed higher urinary concentrations of lead and arsenic throughout each year of the study. Furthermore, minors consistently had higher urinary nickel levels than adults, whereas adults consistently had higher urinary cadmium concentrations than minors. Cluster analyses were conducted annually on urinary metal ions to examine the differences in their distribution and to evaluate changes in metal exposure patterns over time. The Monte Carlo simulations indicate that the whole population exhibits a high non-carcinogenic risk from arsenic exposure and significant carcinogenic risks associated with exposure to nickel, arsenic, chromium, and cadmium. The next two years were predicted by a gray prediction model, and the results are tested using mean absolute percentage error which demonstrating high accuracy.

Refined Cumulative Risk Assessment of Pb, Cd, and as in TCM Decoction Based on Bioavailability through In Vitro Digestion/MDCK Cells.

In this study, the oral bioavailability of Pb, Cd, and As in three types of traditional Chinese medicines (TCMs) and TCM decoctions were investigated through in vitro PBET digestion/MDKC cell model. Furthermore, a novel cumulative risk assessment model associated with co-exposure of heavy metal(loid)s in TCM and TCM decoction based on bioavailability was developed using hazard index (HI) for rapid screening and target organ toxicity dose modification of the HI (TTD) method for precise assessment. The results revealed that the bioavailability of Pb, Cd, and As in three types of TCM and TCM decoction was 5.32-72.49% and 4.98-51.97%, respectively. After rapid screening of the co-exposure health risks of heavy metal(loid)s by the HI method, cumulative risk assessment results acquired by TTD method based on total metal contents in TCMs indicated that potential health risks associated with the co-exposure of Pb, Cd, and As in Pheretima aspergillum (E. Perrier) and Oldenlandia diffusa (Willd.) Roxb were of concern. However, considering both the factors of decoction and bioavailability, TTD-adjusted HI outcomes for TCMs in this study were <1, indicating acceptable health risks. Collectively, our innovation on cumulative risk assessment of TCM and TCM decoction provides a novel strategy with the main purpose of improving population health.

Digestate from an Agricultural Biogas Plant as a Factor Shaping Soil Properties

In the context of a circular economy, special attention should be paid to the rational management of biodegradable waste. Currently, a potentially valuable waste material, rich in ingredients available to plants, is digestate, obtained as a by-product in agricultural biogas plants. The presented study aimed to determine the impact of digestate (DIG) from an agricultural biogas plant on soil reaction (pH), electrical conductivity (EC), sorption properties (SBC, HAC, CEC, BS), and chemical composition of soil. The research was based on a pot experiment in which increasing doses of liquid (LD) and solid (SD) forms of DIG were used in corn cultivation, balanced in terms of the amount of N introduced into the soil. The composition of DIG varied and depended on the LD or SD form. The LD was characterized by a lower pH value and higher EC compared to the SD form. The LD contained much less TC, fewer macroelements, and fewer trace elements. The application of LD significantly increased in the soil the content of TC, Ntot, available K, P, Fe, and Mn, and exchangeable cations K+. The SD significantly increased the content of available P, Mg, and Mn and exchangeable cations Ca2+ and Mg2+ in the soil. Both forms of digestate increased the total content of heavy metals (Cu, Cr, Pb, and Ni) in the soil. However, they did not pose a threat to the environment concerning their legally permissible levels.

Spatio-Temporal Evolution of Fogwater Chemistry in Alsace

For the current article, forty-two fogwater samples are collected at four sites in Alsace (Strasbourg, Geispolsheim, Erstein, and Cronenbourg) between 2015 and 2021, except 2019 and 2020. Spatio-temporal evolution is studied for their inorganic fraction (ions and heavy metals), and physico-chemical properties (pH, conductivity (K), liquid water content (LWC), and dissolved organic carbon (DOC)). The analyses show a remarkable shifting in pH from acidic to basic mainly due to the significant decrease in sulfate and nitrate levels. The calculated median LWC is somehow low (37.8–69.5 g m3) in fog samples, preventing the collection of large fog volumes. The median DOC varies between 14.3 and 24.4 ppm, whereas the median conductivity varies from 97.8 to 169.8 µS cm−1. Total ionic concentration (TIC) varies from 1338.3 to 1952.4 µEq L−1, whereas the total concentration of metals varies in the range of 1547.2 and 2860.3 µg L−1. The marine contribution is found to be negligible at all sites for the investigated elements. NH4+, in most samples, is capable alone to neutralize the acidity. On one hand, NH4+, Ca2+, NO3−, and SO42− are the dominant ions found in all samples, accounting for more than 80% of the TIC. On the other hand, Zn and Ni are the dominant metals accounting for more than 78% of the total elemental concentration. Heavy metals are found to primarily originate from crust as well as human-made activities. The median concentrations of individual elements either decrease or increase over the sampling period due to the wet deposition phenomenon or weather conditions. A Pearson analysis proves some of the suggested pollutant sources due to the presence of strong and significant correlations between elements.

Spatial distribution, bioaccessibility, and human health implications of potentially toxic elements in mining-impacted topsoils in Obuasi Municipality of Ghana.

Potential toxic elements emanating from extracted ores during gold processing present occupational and unintentional health hazards in communities, the general populace, and the environment. This study investigated the concentrations and potential health effects of metal content in the topsoils of Obuasi municipality, which has been mined for gold over the past century. Surface topsoil samples, sieved to 250µm, were initially scanned for metals using x-ray fluorescence techniques, followed by confirmation via ICP-MS. In vitro bioaccessibility assays were conducted using standard methods. The geoaccumulation indices (Igeo) indicate high enrichment of As (Igeo = 6.28) and Cd (Igeo = 3.80) in the soils, especially in the eastern part of the municipality where illegal artisanal mining is prevalent. Additionally, the southern corridor, situated near a gold mine, exhibited significant levels of As and Mn. Results obtained for the total metal concentrations and contamination indices confirmed the elevation of the studied potential toxic elements in the Obuasi community. A hazard index value of 4.42 and 3.30 among children and adults, respectively, indicates that indigens, especially children, are susceptible to non-cancer health effects.