In this work the environmental benefits in the atmospheric emissions after the implementation of 3,000 MW nuclear power plants were assessed and presented. To determine the quantity of avoided emissions of CO2, NOx, SO2 and Hg compounds, harmonised stoichiometric combustion model dedicated to solid fuel fired power plant was created. To increase the credibility of the studies, future strict emission standards (Directive 2010/75/EU, BAT documents for LCP) were included as well. In conducted studies, representative samples of 3 different Polish solid fuels were examined (by comprehensive proximate and ultimate analysis) and used in assessment. It was proven that by the replacement of thermal solid fuel power plant by nuclear unit (with annual production rate of 22.4 TWh net) up to 16.4 million tonnes of lignite, 8.9 million tonnes of hard coal or 13.1 million tonnes of solid biomass can be saved. Further, for the case of lignite, the emission, at least, of 21.29 million tonnes of CO2 (6.9% of all Polish emission in 2015), 1,610 tonnes of dust (0.4%), 16,102 tonnes of NOx (2.2%), 16,102 tonnes of SO2 (2.0%) and 564 kg of mercury (5.9%) can be avoided. For selected hard coal, calculated emission savings were equal to 17.60 million tonnes of CO2 (5.7%), 1,357 tonnes of dust (0.4%), 13,566 tonnes of NOx (1.9%), 13,566 tonnes of SO2 (1.7%), 271 kg of mercury (2.9%), and for biomass - equal to 20.04 million tonnes of CO2 (6.5%), 1,471 tonnes of dust (0.4%), 14,712 tonnes of NOx (2.0%), 14,712 tonnes of SO2 (1.8%) and 294 kg of mercury (3.1%).
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