This study critically examines the influence of freeway toll pricing on the travel behavior of intercity commuters in Iran, focusing on mode choice, route selection, and departure times. A survey of 921 commuters was conducted to gather data, which was then analyzed using a mixed logit model. The key findings reveal that a one percent increase in toll prices leads to a 1.5101 percent decrease in the likelihood of commuters maintaining their usual travel mode. Conversely, the probability of selecting alternative travel options rises by 2.5129 percent. A notable change is observed in route choice, with a 1000 toman increase in tolls raising the likelihood of route change by 0.320 percent. Furthermore, increased tolls are associated with a higher probability of changes in travel mode (0.1188%) and departure time (0.1078%). This research highlights the significant behavioral shifts among commuters in response to toll pricing adjustments and underscores the need for strategic toll management in transportation planning.