Titan's Methane Research Articles

Methane-saturated Layers Limit the Observability of Impact Craters on Titan

Abstract As the only icy satellite with a thick atmosphere and liquids on its surface, Titan represents a unique end-member to study the impact cratering process. Unlike craters on other Saturnian satellites, Titan’s craters are preferentially located in high-elevation regions near the equator. This led to the hypothesis that the presence of liquid methane in Titan’s lowlands affects crater morphology, making it difficult to identify. This is because surfaces covered by weak fluid-saturated sediment limit the topographic expression of impact craters, as sediment moves into the crater cavity shortly after formation. Here we simulate crater-forming impacts on Titan’s surface, exploring how a methane-saturated layer overlying a methane-clathrate layer affects crater formation. Our numerical results show that impacts form smaller craters in a methane-clathrate basement than a water-ice basement due to the differences in strength. We find that the addition of a methane-saturated layer atop this basement reduces crater depths and influences crater morphology. The morphology of impact craters formed in a thin methane-saturated layer is similar to that in a “dry” target, but a thick saturated layer produces an impact structure with little to no topography. A thick methane-saturated layer (thicker than 40% of the impactor diameter) could explain the dearth of craters in the low-elevation regions on Titan.

Cassini-Huygens' exploration of the Saturn system: 13 years of discovery.

The Cassini-Huygens mission to Saturn provided a close-up study of the gas giant planet, as well as its rings, moons, and magnetosphere. The Cassini spacecraft arrived at Saturn in 2004, dropped the Huygens probe to study the atmosphere and surface of Saturn's planet-sized moon Titan, and orbited Saturn for the next 13 years. In 2017, when it was running low on fuel, Cassini was intentionally vaporized in Saturn's atmosphere to protect the ocean moons, Enceladus and Titan, where it had discovered habitats potentially suitable for life. Mission findings include Enceladus' south polar geysers, the source of Saturn's E ring; Titan's methane cycle, including rain that creates hydrocarbon lakes; dynamic rings containing ice, silicates, and organics; and Saturn's differential rotation. This Review discusses highlights of Cassini's investigations, including the mission's final year.

A model intercomparison of Titan's climate and low-latitude environment

Cassini-Huygens provided a wealth of data with which to constrain numerical models of Titan. Such models have been employed over the last decade to investigate various aspects of Titan's atmosphere and climate, and several three-dimensional general circulation models (GCMs) now exist that simulate Titan with a high degree of fidelity. However, substantial uncertainties persist, and at the same time no dedicated intercomparisons have assessed the degree to which these models agree with each other or the observations. To address this gap, and motivated by the proposed Dragonfly Titan lander mission, we directly compare three Titan GCMs to each other and to in situ observations, and also provide multi-model expectations for the low-latitude environment during the early northern winter season. Globally, the models qualitatively agree in their representation of the atmospheric structure and circulation, though one model severely underestimates meridional temperature gradients and zonal winds. We find that, at low latitudes, simulated and observed atmospheric temperatures closely agree in all cases, while the measured winds above the boundary layer are only quantitatively matched by one model. Nevertheless, the models simulate similar near-surface winds, and all indicate these are weak. Likewise, temperatures and methane content at low latitudes are similar between models, with some differences that are largely attributable to modeling assumptions. All models predict environments that closely resemble that encountered by the Huygens probe, including little or no precipitation at low latitudes during northern winter. The most significant differences concern the methane cycle, though the models are least comparable in this area and substantial uncertainties remain. We suggest that, while the overall low-latitude environment on Titan at this season is now fairly well constrained, future in situ measurements and monitoring will transform our understanding of regional and temporal variability, atmosphere-surface coupling, Titan's methane cycle, and modeling thereof.

Cryolava flow destabilization of crustal methane clathrate hydrate on Titan

To date, there has been no conclusive observation of ongoing endogenous volcanic activity on Saturn's moon Titan. However, with time, Titan's atmospheric methane is lost and must be replenished. We have modeled one possible mechanism for the replenishment of Titan's methane loss. Cryolavas can supply enough heat to release large amounts of methane from methane clathrate hydrates (MCH). The volume of methane released is controlled by the flow thickness and its areal extent. The depth of the destabilisation layer is typically ≈30% of the thickness of the lava flow (≈3m for a 10-m thick flow). For this flow example, a maximum of 372kg of methane is released per m2 of flow area. Such an event would release methane for nearly a year. One or two events per year covering ∼20km2 would be sufficient to resupply atmospheric methane. A much larger effusive event covering an area of ≈9000km2 with flows 200m thick would release enough methane to sustain current methane concentrations for 10,000 years. The minimum size of “cryo-flows” sufficient to maintain the current atmospheric methane is small enough that their detection with current instruments (e.g., Cassini) could be challenging. We do not suggest that Titan's original atmosphere was generated by this mechanism. It is unlikely that small-scale surface MCH destabilisation is solely responsible for long-term (> a few Myr) sustenance of Titan's atmospheric methane, but rather we present it as a possible contributor to Titan's past and current atmospheric methane.

When the Sun Goes Quiet, Titan Gets Gassy

Observations from NASA's Cassini probe show that the level of methane in Titan's atmosphere depends on the Sun's 11-year cycle of magnetic activity.

Snowball theory may explain Titan's methane and lakes

Snowball theory may explain Titan's methane and lakes

Experimental investigation of methane hydrates dissociation up to 5 GPa: Implications for Titan’s interior

Methane may be present in significant amounts in the interior of Titan and other icy moons, as well as in water-rich exoplanets, potentially stored in the form of clathrate hydrates. Here we report a high-pressure investigation of methane hydrates stability using a diamond-anvil cell combined with Raman spectroscopy and X-ray diffraction. The phase changes with increasing pressure and temperature were determined using Raman spectroscopy and X-ray diffraction. Raman shifts in the C–H symmetric stretching mode signature (ν1 mode) for both MHs and solid methane were established for pressures ranging between 0.2 and 5GPa. From the observed differences in Raman shifts and X-ray diffraction peaks, we determined the dissociation temperatures of MHs for pressures between 1.5 and 5GPa. Our results show that, in this pressure range, MHs dissociate into solid methane and liquid water at temperatures close to the melting curves of water ices. The implications of these new results for the fate of methane in Titan and in water-rich exoplanets are briefly discussed.

The distribution of methane in Titan’s stratosphere from Cassini/CIRS observations

Cassini/CIRS spectra in the far- and mid-infrared region are used to determine the abundance of methane in Titan’s lower stratosphere and investigate its distribution with latitude. The CIRS spectra include emission from both the CH4 ν4 band at 7.7μm and pure rotational lines longwards of 50μm, which show differential sensitivities to thermal profile and methane mole fraction. We analyze nadir and limb data taken over the first part of the Cassini mission (August 2005 to June 2010), including a selection of 12 latitudes that provides a reasonably complete and regular sampling of both hemispheres. Unexpectedly, but in a consistent manner for limb and nadir geometries, large variations of the methane mole fraction near 15mbar (∼85km) are found, with values ranging from ∼1.0% (at low latitudes and near ±50–55°) to ∼1.5% (at ±30–35° and polar latitudes). Error bars on the retrieved methane mole fraction are 0.07–0.12% at low latitudes in the Southern hemisphere and 0.14–0.21% northward of 40°N. A 1.0% methane mole fraction at low latitudes permits us to reconcile the HASI-measured temperatures below 147km altitude (2.7mbar) with inferences from CIRS. The roughly hemispherically-symmetric distribution of methane gas is reminiscent of that observed or predicted for the tropospheric methane clouds, which on a yearly-averaged basis, show preferential occurrences at tropical and polar latitudes. We speculate that convective events at these latitudes result into local stratospheric methane enrichment, which may persist year-round due to dynamical mixing times in the lower stratosphere only moderately shorter than a Titan year.

IN SITU MEASUREMENTS OF THE SIZE AND DENSITY OF TITAN AEROSOL ANALOGS

The organic haze produced from complex CH4/N2 chemistry in the atmosphere of Titan plays an important role in processes that occur in the atmosphere and on its surface. The haze particles act as condensation nuclei and are therefore involved in Titan's methane hydrological cycle. They also may behave like sediment on Titan's surface and participate in both fluvial and aeolian processes. Models that seek to understand these processes require information about the physical properties of the particles including their size and density. Although measurements obtained by Cassini-Huygens have placed constraints on the size of the haze particles, their densities remain unknown. We have conducted a series of Titan atmosphere simulation experiments and measured the size, number density, and particle density of Titan aerosol analogues, or tholins, for CH4 concentrations from 0.01% to 10% using two different energy sources, spark discharge and UV. We find that the densities currently in use by many Titan models are higher than the measured densities of our tholins.

TITAN'S TRANSPORT-DRIVEN METHANE CYCLE

The strength of Titan's methane cycle, as measured by precipitation and evaporation, is key to interpreting fluvial erosion and other indicators of the surface-atmosphere exchange of liquids. But the mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A gobal- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or $\sim$0.04 W/m$^2$, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and precipitation even rarer, even if evaporation globally dominates the surface-atmosphere energy exchange. In contrast, climate simulations that allow atmospheric motion indicate a robust methane cycle with substantial cloud formation and/or precipitation. We argue the top-of-atmosphere radiative imbalance -- a readily observable quantity -- is diagnostic of horizontal heat transport by Titan's atmosphere, and thus constrains the strength of the methane cycle. Simple calculations show the top-of-atmosphere radiative imbalance is $\sim$0.5-1 W/m$^2$ in Titan's equatorial region, which implies 2-3 MW of latitudinal heat transport by the atmosphere. Our simulation of Titan's climate suggests this transport may occur primarily as latent heat, with net evaporation at the equator and net accumulation at higher latitudes. Thus the methane cycle could be 10-20 times previous estimates. Opposing seasonal transport at solstices, compensation by sensible heat transport, and focusing of precipitation by large-scale dynamics could further enhance the local, instantaneous strength of Titan's methane cycle by a factor of several.

Hydrogen and methane in Titan’s atmosphere: chemistry, diffusion, escape, and the Hunten limiting flux principle 1This article is part of a Special Issue that honours the work of Dr. Donald M. Hunten FRSC who passed away in December 2010 after a very illustrious career.

One of Professor Donald M. Hunten’s lasting contributions to the field of planetary atmospheres was the principle of the (Hunten) limiting flux, where the escape of light species is limited by the rate at which they can diffuse through the atmosphere. While his limiting flux expression has been well tested for hydrogen’s escape from the Earth’s atmosphere (e.g., Hunten and Strobel (J. Atmos. Sci. 31, 305 (1974)); Hunten and Donahue (Ann. Rev. Earth Planet Sci. 4, 265 (1976))), it has not been tested for Titan’s atmosphere, which was the original motivation for the principle. The Cassini–Huygens mission has provided sufficient data on the variation of the H2 mole fraction with altitude to test its applicability and validity. Only in the vicinity of the homopause does the limiting flux expression yield the actual H2 escape flux, because the mole fraction varies with altitude. This paper deals also with our current understanding of the three major constituents of Titan’s atmosphere (N2, CH4, and H2) from the various measurements by instruments on the Cassini orbiter and the Huygens probe. Specific problems addressed are additional required sources of H2, the CH4 escape rate, and the possible role of energetic electron and ion precipitation from Saturn’s magnetosphere.

Possible tropical lakes on Titan from observations of dark terrain

Titan has clouds, rain and lakes--like Earth--but composed of methane rather than water. Unlike Earth, most of the condensable methane (the equivalent of 5 m depth globally averaged) lies in the atmosphere. Liquid detected on the surface (about 2 m deep) has been found by radar images only poleward of 50° latitude, while dune fields pervade the tropics. General circulation models explain this dichotomy, predicting that methane efficiently migrates to the poles from these lower latitudes. Here we report an analysis of near-infrared spectral images of the region between 20° N and 20° S latitude. The data reveal that the lowest fluxes in seven wavelength bands that probe Titan's surface occur in an oval region of about 60 × 40 km(2), which has been observed repeatedly since 2004. Radiative transfer analyses demonstrate that the resulting spectrum is consistent with a black surface, indicative of liquid methane on the surface. Enduring low-latitude lakes are best explained as supplied by subterranean sources (within the last 10,000 years), which may be responsible for Titan's methane, the continual photochemical depletion of which furnishes Titan's organic chemistry.

Titan's methane maybe very old

Titan's methane maybe very old

THE12C/13C RATIO ON TITAN FROMCASSINIINMS MEASUREMENTS AND IMPLICATIONS FOR THE EVOLUTION OF METHANE

We have re-evaluated the Cassini Ion Neutral Mass Spectrometer (INMS) 12 C/ 13 C ratios in the upper atmosphere of Titan based on new calibration sensitivities and an improved model for the NH3 background in the 13 CH4 mass channel. The INMS measurements extrapolated to the surface give a 12 C/ 13 Ci n CH4 of 88.5 ± 1.4. We compare the results to a revised ratio of 91.1 ± 1.4 provided by the Huygens Gas Chromatograph Mass Spectrometer and 86.5 ± 7.9 provided by the Cassini Infrared Spectrometer and determine implications of the revised ratios for the evolution of methane in Titan’s atmosphere. Because the measured 12 C/ 13 C is within the probable range of primordial values, we can only determine an upper boundary for the length of time since methane began outgassing from the interior, assuming that outgassing of methane (e.g., cryovolcanic activity) has been continuous ever since. We find that three factors play a crucial role in this timescale: (1) the escape rate of methane, (2) the difference between the current and initial ratios and the rate of methane, and (3) production or resupply due to cryovolcanic activity. We estimate an upper limit for the outgassing timescale of 470 Myr. This duration can be extended to 940 Myr if production rates are large enough to counteract the fractionation due to escape and photochemistry. There is no lower limit to the timescale because the current ratios are within the range of possible primordial values.

ISOTOPIC RATIOS IN TITAN's METHANE: MEASUREMENTS AND MODELING

The existence of methane in Titan’s atmosphere (∼ 6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of ∼20 Myr. In this paper, we examine the clues available from isotopic ratios ( 12 C/ 13 C and D/H) in Titan’s methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: 13 CH4, 12 CH3D, and 13 CH3D. From these we compute estimates of 12 C/ 13 C = 86.5 ± 8.2 and D/H = (1.59 ± 0.33) × 10 −4 , in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan’s methane: CH4 +C 2H → CH3 +C 2H2. Using these new measurements and predictions we proceed to model the time evolution of 12 C/ 13 C and D/H in Titan’s methane under several prototypical replenishment scenarios. In our Model 1 (no resupply of CH4), we find that the present-day 12 C/ 13 C implies that the CH4 entered the atmosphere 60–1600 Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently—most likely less than 10 Myr ago—if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane.

Evolution of Icy Satellites

Evolutionary scenarios for the major satellites of Jupiter, Saturn, Neptune, and Pluto-Charon are discussed. In the Jovian system the challenge is to understand how the present Laplace resonance of Io, Europa, and Ganymede was established and to determine whether the heat being radiated by Io is in balance with the present tidal dissipation in the moon. In the Saturnian system, Enceladus and Titan are the centers of attention. Tidal heating is the likely source of activity at the south pole of Enceladus, although the details of how the heating occurs are not understood. An evolutionary scenario based on accretion and internal differentiation is presented for Titan, whose present substantial orbital eccentricity is not associated with any dynamical resonance. The source and maintenance of methane in Titan’s present atmosphere remain uncertain. Though most attention on the Saturnian moons focuses on Titan and Enceladus, the mid-size satellites Iapetus, Rhea, Tethys, and the irregular satellite Phoebe also draw our interest. An evolutionary scenario for Iapetus is presented in which spin down from an early rapidly rotating state is called upon to explain the satellite’s present oblate shape. The prominent equatorial ridge on Iapetus is unexplained by the spin down scenario. A buckling instability provides another possible explanation for the oblateness and equatorial ridge of Iapetus. Rhea is the only medium-size Saturnian satellite for which there are gravity data at present. The interpretation of these data are uncertain, however, since it is not known if Rhea is in hydrostatic equilibrium. Pluto and Charon are representative of the icy dwarf planets of the Kuiper belt. Did they differentiate as they evolved, and do either of them have a subsurface liquid water ocean? New Horizons might provide some answers when it arrives at these bodies.

Titan lakes: characterization of physical properties by combined electromagnetic models of SAR and radiometric data

From the analysis derived from the SAR imagery acquired by the Cassini RADAR, Titan reveals a complex surface with dark and bright areas, periodic structures and dark lake-like features, which resemble terrestrial lakes. The abundant methane in Titan’s atmosphere combined with the low temperature, around 89 K, lead scientists to interpret them as lakes of liquid methane or ethane. This paper presents an electromagnetic model of liquid surfaces combined with an inversion algorithm in order to retrieve information on liquid surface. The inferred physical surface parameters are then used as input to a forward radiative transfer model to obtain simulated brightness temperatures. The observed and computed brightness temperatures are compared to address the consistency of the observations from these two different Cassini RADAR modes.

Towards a quantitative study of the VUV photolysis of methane: preliminary experiment on trichloromethane

Photolysis of methane in Titan's stratosphere is the starting point of gas phase carbon chemistry. Quantitative studies of methane photolytic products are of utmost importance for Titan atmosphere models. With this aim, two experimental strategies are presented in this article. Preliminary results demonstrate the possibility of using CRDS absorption coupled with pulsed photolysis on the example of a halogenated derivative of methane: Trichloromethane (CHCl3 ).

Stability of methane clathrate hydrates under pressure: Influence on outgassing processes of methane on Titan

We have conducted high-pressure experiments in the H 2O–CH 4 and H 2O–CH 4–NH 3 systems in order to investigate the stability of methane clathrate hydrates, with an optical sapphire-anvil cell coupled to a Raman spectrometer for sample characterization. The results obtained confirm that three factors determine the stability of methane clathrate hydrates: (1) the bulk methane content of the samples; (2) the presence of additional gas compounds such as nitrogen; (3) the concentration of ammonia in the aqueous solution. We show that ammonia has a strong effect on the stability of methane clathrates. For example, a 10 wt.% NH 3 solution decreases the dissociation temperature of methane clathrates by 14–25 K at pressures above 5 MPa. Then, we apply these new results to Titan’s conditions. Dissociation of methane clathrate hydrates and subsequent outgassing can only occur in Titan’s icy crust, in presence of locally large amounts of ammonia and in a warm context. We propose a model of cryomagma chamber within the crust that provides the required conditions for methane outgassing: emplacement of an ice plume triggers the melting (if solid) or heating (if liquid) of large ammonia–water pockets trapped at shallow depth, and the generated cryomagmas dissociate surrounding methane clathrate hydrates. We show that this model may allow for the outgassing of significant amounts of methane, which would be sufficient to maintain the presence of methane in Titan’s atmosphere for several tens of thousands of years after a large cryovolcanic event.

A primordial origin for the atmospheric methane of Saturn’s moon Titan

The origin of Titan’s atmospheric methane is a key issue for understanding the origin of the saturnian satellite system. It has been proposed that serpentinization reactions in Titan’s interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan’s planetesimals before its formation. Here, we point out that serpentinization reactions in Titan’s interior are not able to reproduce the deuterium over hydrogen ( D/ H) ratio observed at present in methane in its atmosphere, and would require a maximum D/ H ratio in Titan’s water ice 30% lower than the value likely acquired by the satellite during its formation, based on Cassini observations at Enceladus. Alternatively, production of methane in Titan’s interior via radiolytic reactions with water can be envisaged but the associated production rates remain uncertain. On the other hand, a mechanism that easily explains the presence of large amounts of methane trapped in Titan in a way consistent with its measured atmospheric D/ H ratio is its direct capture in the satellite’s planetesimals at the time of their formation in the solar nebula. In this case, the mass of methane trapped in Titan’s interior can be up to ∼1300 times the current mass of atmospheric methane.