The Irece Basin is a relatively small late Proterozoic basin within the São Francisco craton of northeast-central Brazil. Stratabound Zn-Pb-Ag sulfide and phosphate-rich units occur within a 50-m-thick tidal-flat sequence of dolomitic limestone and cherty dolostone within the lower Salitre Formation of the Una Group. Phosphate is concentrated in stromatolitic structures; metallic mineralization is represented by stratiform masses and disseminations of sulfide minerals in a tidal-flat sequence that has relict evaporitic structures. Zn-Pb-Ag sulfide concentrations in the Irece area are associated with parallel laminated, silty dolostone with shallow-water sedimentary structures, including laminar stromatolites, mud cracks, tepee structures, collapse breccias, length-slow quartz nodules, and pseudomorphs after evaporitic sulfates. Sulfide minerals include pyrite, sphalerite, galena, marcasite, jordanite, tetrahedrite, and covellite, in order of decreasing abundance. Nodular and bladed sulfide forms are pseudomorphous after evaporitic sulfate minerals. Replacement textures, such as corroded grain boundaries between sulfide minerals, are common. Sulfur-isotope analysis indicates relatively uniform heavy δ34S values. Barite has a δ34S range from +25 to +31‰, CDT. Pyrite, sphalerite, galena, and jordanite-representative of a variety of textural types-have a δ34S range of +19 to + 23‰; δ34S values for Irece barite probably represent original late Proterozoic sea-water sulfate values. The consistently heavy δ34S values of the Irece sulfides likely are the result of thermochemical reduction of a limited evaporitic sulfate source by organic matter that is abundant in the Salitre carbonates. Major Zn-Pb-Ag concentrations appear to be an overprint on the earlier iron sulfide-rich zone. Limited fluid-inclusion data suggest precipitation in the range of 140 to 200°C from formation waters with salinities ranging from 3 to 12 wt%. Deep fluid circulation may have been promoted by reactivation of basement faults originally related to the Irece Basin's development. Petrographic and fluid-inclusion data suggest that sulfide mineralization may have occurred within a mixing zone of metal-bearing, high-temperature basinal brines with meteoric water. Metallic mineralization scavenged sulfur from pre-existing sulfides or from direct reduction of evaporitic sulfate minerals. The metal and phosphate concentrations in the Irece Basin possess some similiar geologic characteristics that result from a common host-rock depositional environment. However, existing information indicates that the two deposit types are not directly related genetically, although the origin of both is related to the organic-rich nature of the host sequence.
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