We used a hybrid probabilistic geometric shaping scheme that uses a probabilistic shaping method with labels and a pairwise optimization (PO) algorithm to transmit signals in a 2 × 2 MIMO Photon-assisted millimeter wave (MMW) radio-over-fiber (RoF) system in the D-band. This scheme has low complexity and a simple recovery method. This scheme optimizes 16-ary quadrature amplitude modulation (16QAM) to probabilistically shaped 9-ary quadrature amplitude modulation (PS-9QAM) by adding labels, and optimizes it to hybrid probabilistically and geometrically shaped 9-ary quadrature amplitude modulation (PGS-9QAM) by geometric shaping using the PO algorithm. The experimental results prove the optimization effect of this scheme. Under the bit error rate threshold of 0.0038, when the net bit rate is the same, compared with 16QAM, PS-9QAM and PGS-9QAM, the optical power at the transmitter can be reduced by 0.8 dB and 1.45 dB respectively. When the transmission power is the same, compared with 16QAM, the net rates of PS-9QAM and PGS-9QAM can be increased by 7.5Gbit/s and 9Gbit/s respectively.
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