Thermal Activation Energy Research Articles

Study on non-radiative recombination centers in GaInP sub-cell of electron-irradiated triple junction solar cells based on photoluminescence measurements

The radiation damage induced by energetic particles on GaInP sub-cell in GaInP/GaAs/Ge triple junction solar cell (TJSC) has a significant impact on its performance. Thus, in this paper, we measured the photoluminescence (PL) spectra for GaInP sub-cell in TJSC irradiated by 11.5 MeV electron at temperature range 10 –300 K. By analyzing the variation of PL intensity with temperature, the thermal activation energy for nonradiative recombination center was determined as 8.43 meV, and its minority carrier capture cross-section is about 3.63 × 10−13 cm2. Further confirmed that the nonradiative recombination center in GaInP is H2 (EV + 0.55 eV) defect. Furthermore, by using multi-peaks curve-fittings to analyze PL spectra, the carrier recombination processes in electron irradiated GaInP sub-cell are determined, and a phenomenological model was given for explaining carrier recombination processes.

EFFECT OF NITROGEN ON THE THERMAL DEFORMATION BEHAVIOR OF MARTENSITIC STAINLESS BEARING STEEL

The thermal deformation behaviors of martensitic stainless bearing steels (0.16N, 0N) in the temperature range 850–1150 °C, strain rate 0.01–10 s–1, and deformation of 60 % were studied using a single-pass compression experiment. After adding 0.16 % nitrogen, the peak stress of the martensitic stainless bearing steel increased under all thermal forming conditions, and the average peak stress increased by about 33.724 MPa. The strain-rate sensitivity diagram, power dissipation diagram, instability factor diagram, and thermal processing diagram under different strains were constructed based on the stress-strain curve. The thermal deformation activation energy under different strains was constructed and combined with a metallographic structure analysis. The results show that under the same conditions, the occurrence of DRX in 0.16N bearing steel is less than that of 0N bearing steel, but the grains are finer than those of 0N bearing steel.

Study on high temperature tensile constitutive behavior and deformation mechanism of Ti-47.5Al-2.5 V-1.0Cr-0.2Zr alloy

The high temperature tensile test of Ti-47.5Al-2.5 V-1.0Cr-0.2Zr alloy was carried out by electronic universal testing machine under the condition of 750–900 °C/10−5–10−3 s−1. The hot tensile stress-strain curves were analyzed, and the constitutive model under hot tensile conditions was established. The microstructure transformation rule and deformation mechanism during tensile process were determined. The results show that the hot tensile curve is longer in the steady-state flow stage corresponding to lower strain rate and higher tensile temperature, the true stress declines and the elongation at break increases. The constitutive equation was established based on the tensile curve data, and the corresponding thermal activation energy was 310.3 kJ/mol. As the rise of tensile temperature and the decline of strain rate, the proportion about cross-layer fracture in the tensile fracture morphology decreases, the number of dimples increases, more lamellar structures change into recrystallized structures, and the softening effect of the alloy is more obvious. The dislocation deformation mechanism mainly includes the existence of dislocation slip and climb, dislocation intersection and dislocation ring or dislocation network formation. Twinning deformation is also another important mechanism of high temperature tensile deformation of TiAl alloy. Twins are formed in parallel with each other, so that the deformation can be further carried out. The dislocations and twins in the deformed microstructure will provide nucleation conditions for recrystallized grains. The dynamic recrystallization(DRX) grains are preferentially formed around the grain boundary and the vicinity of dislocation and twin is also preferred nucleation site for DRX. The DRX behavior is the main softening mechanism, and DRX size and volume fraction corresponding to lower tensile rate and higher tensile temperature are larger.

Development of epoxy/flyash composites containing Halloysite nanotubes: Mechanical, morphological, and thermal degradation kinetics

This research article investigates the development of a composite material by the inclusion of halloysite nanotubes (HNTs) into an epoxy/flyash matrix using a solution blending technique. The HNTs were added at different loadings and were effectively dispersed throughout the epoxy/flyash matrix. The thermal properties and degradation kinetics of the epoxy/flyash composites were studied with a thermogravimetric analyzer (TGA) at different heating speeds (10, 15, 20, and 25 °C/min). TGA measurements showed a considerable improvement in the thermal stability of the composites. Incorporating 3phr of HNTs into epoxy/flyash composites increased thermal stability by 13°C, 16°C, and 18°C, with weight losses of 5%, 10%, and 50%, respectively, as compared to composites without HNTs. The thermal degradation activation energy (E) was calculated using the model-free Kissinger Akahir-Sunose (KAS) and Flynn-Wall-Ozawa (FWO), and it was revealed that epoxy/flyash composites containing 3phr HNTs have the highest E, 77.52 and 79.89 kJ/mol, respectively. The SEM micrographs of 3phr HNTs show uniform dispersion of HNTs onto epoxy/flyash composites, resulting in a tensile strength increase from 37.2 MPa to 43.6 MPa and modulus increase from 1238.4 MPa to 1463.6 MPa. The obtained results show that the addition of flyash and nanofiller (HNTs) to the epoxy matrix greatly increases the mechanical and thermal properties.

Physiochemical, Radiative Transitions and Thermoluminescence Characterizations of Nano Ce-doped Monoclinic Barium Titanate

AbstractThis article reports the preparation, analytical, and thermoluminescence (TL) characterization of BaTi5O11 doped with different amounts of Ce. The Sol–gel technique was used to synthesize the doped nanocrystals. The prepared samples were examined by XRD, EDX, UV–Vis spectrophotometry, SEM, and TEM techniques to determine their analytical features. The samples with 0.7% Ce doping showed the best thermoluminescent behavior among the samples we made. The glow curves analysis showed that there were seven peaks that overlapped with each other. The thermal activation energy values of the carrier traps are 0.93, 1.08, 1.16, 1.23, 1.29, 1.35, and 1.38 eV. This study displayed that 0.7% Ce-doped BaTi5O11 can be used in monitoring high doses radiation applications.

Nutrient enrichment can increase the thermal performance of Galápagos seaweeds

Thermal sensitivity in ectothermic organisms is often contingent upon environmental factors. Nutrient availability in particular is believed to influence the physiological responses of primary producers to global warming and is thus relevant to consider when forecasting the structure and functioning of future marine ecosystems. This study measured the effect of nutrient enrichment on the thermal sensitivity of 4 genera of Galápagos seaweeds (Ulva, Caulerpa, Padina, and Ochtodes), estimated as the thermal optimum (Topt), performance maximum (Pmax), activation energy, and deactivation energy. These parameters were quantified by modeling thermal performance curves for net photosynthesis under ambient and nutrient-enriched conditions. Our findings revealed variation in Topt among genera, ranging from 27.6° to 36.0°C. Nutrient additions enhanced Topt by ~2°C for 2 (Padina and Caulerpa) of the 4 taxa and also significantly increased Pmax in Padina, suggesting the ability for warming-induced ocean stratification and associated effects (i.e. decreasing nutrient availability) to reduce the capacities of these populations to maintain and support new growth. No significant differences in Topt or Pmax were observed for either Ulva or Ochtodes with enrichment. Ambient net photosynthesis and respiration rates were also compared across genera; Pmax rates for net photosynthesis were consistently higher than those for respiration (i.e. until just beyond Topt); however, photosynthetic Topt values were lower. Thus, this study suggests that further warming could reduce overall net primary productivity, with potentially far-reaching implications for marine food webs.

Thermoanalytical and Kinetic Studies for the Thermal Stability of Emerging Pharmaceutical Pollutants Under Different Heating Rates.

Emerging pharmaceutical pollutants like ciprofloxacin (CIP) and ibuprofen (IBU) are frequently detected in aquatic environments, posing risks to ecosystems and human health. Since pollutants rarely exist alone in the environment, understanding the thermal stability and degradation kinetics of these compounds, especially in mixtures, is crucial for developing effective removal strategies. This study therefore investigates the thermal stability and degradation kinetics of CIP and IBU, under different heating rates. Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) were employed to examine the thermal behavior of these compounds individually and in mixture (CIP + IBU) at heating rates of 10, 20, and 30 °C/min. The kinetics of thermal degradation were analyzed using both model-fitting (Coats-Redfern (CR)) and model-free (Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO), and Friedman (FR)) methods. The results showed distinct degradation patterns, with CIP decomposing between 280 and 550 °C and IBU between 152 and 350 °C, while the mixture exhibited multistep decomposition in the 157-500 °C range. The CR model indicated first-order kinetics as a better fit for the degradation (except for IBU). Furthermore, CIP exhibits higher thermal stability and activation energy compared to IBU, with the KAS model yielding activation energies of 58.09 kJ/mol for CIP, 11.37 kJ/mol for IBU, and 41.09 kJ/mol for CIP + IBU mixture. The CIP + IBU mixture generally showed intermediate thermal properties, suggesting synergistic and antagonistic interactions between the compounds. Thermodynamic parameters (ΔH°, ΔG°, ΔS°) were calculated, revealing non-spontaneous, endothermic processes for all samples (except in the FWO method) with a decrease in molecular disorder and positive ΔG° values across all models and heating rates. The study found that higher heating rates led to less thermodynamically favorable conditions for degradation. These findings provide important information concerning the thermal behavior of these pharmaceutical pollutants, which can inform strategies for their removal from the environment and the development of more effective waste-treatment processes.

Exploring concentration-dependent transport properties on an unsteady Riga plate by incorporating thermal radiation with activation energy and gyrotactic microorganisms

Abstract The aim of this study is to examine the entropy generation (EG) associated with the transfer of mass and heat in a concentration-dependent fluid with thermal radiation and activation energy, specifically in the context of an unsteady Riga Plate with gyrotactic microorganism. It is important to solve the ordinary differential equations generated from the controlling partial differential equations using Lie symmetry scaling to verify their quality and reliability. The system’s anticipated physical behavior is compared to Mathematica’s Runge–Kutta–Fehlberg numerical solution. Source parameters are essential for validation since they offer accurate results. Methodically change these values as a percentage to determine how they affect the unsteady fluid’s density, mass, and heat transfer over the Riga plate. Velocity, temperature, nanoparticle concentration and microorganism concentration profiles decrease with varying values of the unsteadiness parameter. EG increases with increasing values of concentration difference, thermal radiation, and Reynold number parameters. The Nusselt number experiences a 26.11% rise as a result of radiation when the unsteadiness parameter is A = − 0.25 A=-0.25 , in comparison with the scenario without radiation. Mass transfer upsurges with increasing values of the Brownian motion parameter and reduces with increasing values of thermophoresis parameter. To verify our conclusions, we compare calculated data, specifically the skin friction factor, to theoretical predictions. Tabular and graphical data can show how physical limits affect flow characteristics.

Studies of Kinetics and Non-Isothermal Decomposition of Synthesized Novel Organic Terpolymer Resin

Abstract: The terpolymer resin 2,4-DHP-4-PAF-III was prepared by condensation of 2,4-dihydroxypropiophenone, 4- pyridylamine and formaldehyde in the presence of 2M hydrochloric acid as a catalyst in the temperature range 125 ± 2 0C for 5 hrs in 3:1:5 molar ratios of reactants. Elemental analysis, FT-IR, and 1H-NMR spectral studies have been carried out to confirm the structure of the resin. The thermal degradation behavior of terpolymer was studied using thermogravimetric analysis (TGA) in air atmosphere at a heating rate of 10 0C/min. Sharp-Wentworth and Freeman-Carroll methods were used to calculate thermal activation energy (Ea), entropy change (∆S), free energy change (∆F), apparent entropy change (S*), frequency factor (Z) and order of reaction (n). Thermal activation energy (Ea) calculated by Sharp-Wentworth (28.81 KJ/mole) method and Freeman-Carroll (29.47 KJ/mole) method are in good agreement.

Gate-driven transition temperatures of electron hopping behaviors in Hubbard bands formed by dopant-induced QD array in silicon nanowire

Abstract Dopant atoms confined in silicon nanoscale channel can be ionized to form quantum dots (QDs). Several dopant atoms couple with each other forming energy bands, where the electron hopping behavior can be described by the Hubbard model. This characteristic renders dopant-induced QDs particularly appealing for applications in nanoelectronic and quantum devices. Herein we study the gate-driven transition temperatures of electron hopping behavior in the upper Hubbard bands (UHBs) and lower Hubbard bands (LHBs) formed by dopant-induced QD array in junctionless silicon nanowire transistors. The gate-dependent transition temperatures are calculated for three stages of electron hopping behaviors including Efros–Shklovskii Variable Range Hopping (ES-VRH), Mott VRH and Nearest Neighbor Hopping (NNH). Our experimental results indicate that the ES-VRH in arrays of dopant atoms occurs in the domination of a long-range Coulomb interaction, in which the hopping distance relies on the Coulomb gap. Furthermore, the localization length of ES-VRH can be modulated by gate voltages. Those factors lead to the significant difference of transition temperatures between the UHBs and LHBs. In addition, we find that the source–drain bias voltage can effectively modulate the transition temperatures between VRH and NNH by thermal activation energies under different bias voltages Vds.

Microstructure and hot deformation behavior of Cu–Ti–Zr(-Mg) alloys

In this study, the thermal deformation behavior of Cu–Ti–Zr(-Mg) alloys were investigated by Gleeble-1500D. The two alloys were deformed at 700–900 °C with 0.003–10 s−1 strain rate. The intrinsic equations of the two alloys were constructed and calculated thermal activation energies, which indicates that it is improved from 325.67 kJ/mol to 344.03 kJ/mol after Mg addition. The result showed that the hot working area of Cu–Ti–Zr alloy is greatly extended after Mg addition, and rheological instability area is reduced. The morphology of the alloys was observed to analyze thermal behavior. It revealed that Mg elements inhibited the occurrence of dynamic recrystallization and shifted the texture types in the alloys by characterization of EBSD. TEM results showed that the phases during hot deformation in Cu–Ti–Zr–Mg are Cu4Ti and Cu10Zr7, which are in a semi-coherent relationship with the Cu matrix.

A magnetohydrodynamic flow of a water-based hybrid nanofluid past a convectively heated rotating disk surface: A passive control of nanoparticles

Abstract One of the basic fluid mechanics problems of fluid flows over a revolving disk has both theoretical and real-world applications. The flow over a rotating disk has been the subject of numerous theoretical studies because it has many real-world applications in areas like rotating machinery, medical equipment, electronic devices, and computer storage. It is also crucial for engineering processes. Therefore, this article deals with a time-independent water-based hybrid nanofluid flow containing copper oxide and silver nanoparticles past a spinning disk. The Newtonian flow is taken into consideration in this analysis. The influence of magnetic field, thermophoresis, nonlinear thermal radiation, Brownian motion, and activation energy has been considered. The present analysis is modeled in a partial differential equation form and is then converted to ordinary differential equations using appropriate variables. A numerical solution using the bvp4c technique is accomplished using MATLAB software. The current results are matched with the previous literature and established a close relationship with previous studies. The purpose of this investigation is to numerically investigate the time-independent hybrid nanofluid flow comprising copper oxide and silver nanoparticles over a rotating disk surface. The results show that the increased magnetic parameters increase the friction force at the surface, which decreases the radial and azimuthal velocity distribution. At the sheet surface, the radial velocity of the hybrid nanofluid shows dominant performance compared to the nanofluid. On the other hand, the magnetic factor has dominant behavior on the azimuthal velocity component of the nanofluid flow compared to the hybrid nanofluid flow. The higher volume fraction and magnetic factor enhance the skin friction at the disk surface. Furthermore, greater surface drag is found for the hybrid nanofluid flow. The higher solid volume fraction, temperature ratio, and Biot number enhance the rate of heat transmission. Also, a higher rate of heat transmission is observed for the hybrid nanofluid flow.

Effects of Arrhenius activation energy and melting heat transfer on Carreau fluid through a stretching sheet

ABSTRACT This article investigates the effect of activation energy on Carreau fluid flow in the presence of variable thermal conductivity, inclined magnetic field, melting heat transfer, and Soret and Dufour phenomena. A set of suitable similarity transformations is applied for transforming the governing partial differential equations (PDEs) considered for the physical phenomena into non-linear ordinary differential equations (ODEs). We obtained the results by solving the non-linear ODEs numerically which describe the behavior of the velocity, temperature, and concentration profiles of the fluid against the governing parameters and illustrated these graphically. The velocity distribution decreases for angle of inclination while it is increasing against higher melting parameter. The temperature distribution enhances with higher modified Dufour parameter and Prandtl number while it declines for thermal conductivity, activation energy, and melting parameters. The concentration distribution increases for melting parameter, Soret number, and activation energy parameter while decreasing for temperature difference parameter, Schmidt number, and reaction rate parameter. Skin friction, Nusselt and Sherwood numbers are evaluated numerically against the various governing parameters. Accuracy of the present work is illustrated and established through comparison carried out for skin friction versus magnetic parameter with existing results in the literature.

Broadband NIR‐II Emission Generated by Tetrahedral Cr3+/Cr4+ in SrLaGa3O7

AbstractBroadband near‐infrared (NIR) phosphors have garnered significant attention due to their potential applications in phosphor‐concerted NIR light‐emitting diodes (pc‐NIR‐LEDs). Cr3+‐doped NIR phosphors are particularly intriguing because of their broad NIR emission and high efficiency. However, reports on Cr3+‐doped NIR‐II (900–1700 nm) phosphors are scarce. In this study, a novel Cr3+‐doped SrLaGa3O7 NIR‐II phosphor is presented, where the Cr3+ ions are located at tetrahedral sites. The full width at half maximum (FWHM), peak wavelength, internal quantum efficiency (IQE), and thermal activation energy (ΔE) for the synthesized SrLaGa3O7:0.9%Cr3+ phosphor are 194 nm, 1167 nm, 76.12%, and 0.269 eV, respectively. The substitution of Sc3+ for Ga3+ enhances the luminescence performance, and the 0.9%Cr3+/3%Sc3+ co‐doped SrLaGa3O7 phosphor exhibits a peak wavelength of 1208 nm, an IQE of 92.78%, and a ΔE of 0.285 eV. Furthermore, the sintering process in the air induces a transition from Cr3+ to Cr4+, resulting in the formation of SrLaGa3O7:0.9%Cr4+ phosphor, which has a peak wavelength of 1270 nm and an FWHM of 305 nm. The potential application of the 0.9%Cr3+/3%Sc3+ co‐doped SrLaGa3O7 phosphor in pc‐NIR‐LEDs is also evaluated.

NiCoCr2O4 as a potential catalyst for the thermal decomposition of ammonium nitrate: a kinetic investigation

The thermal decomposition of high energetic materials plays an important role in their thermal performance. Use of the catalyst is one of the efficient ways improve the thermal performance of the high energetic materials. Therefore, in this work nickel cobalt chromite (NiCoCr2O4) prepared using precipitation approach was utilized as a catalyst for decreasing the thermal decomposition temperature and activation energy of high energetic material ammonium nitrate (AN). The results suggest that AN/NiCoCr2O4 decomposes at lower temperature (240 °C) within a short temperature range (Thermo gravimetry decomposition curve = 180–250 °C). The kinetic study was investigated using Kissinger-Akahira-Sunose (KAS) and Kissinger method (5, 10, and 15 °C min−1 heating rates). The activation energy of AN was reduced from 158.0 to 141.5 kJ mol−1 and decrease in the pre-exponential factor was observed upon addition of NiCoCr2O4. The outcome of the present work can be used to design AN based high energetic formulations containing NiCoCr2O4 catalyst with better thermal decomposition performance.

Thermal stable NaMgLaTeO6:Dy3+ double perovskite yellow phosphors for w-LEDs and latent fingerprint visualization

The novel Dy3+-doped NaMgLaTeO6 (NaMgLaTeO6:Dy3+) phosphors were produced through a high-temperature solid-state reaction. X-ray diffraction (XRD) analysis and Rietveld refinement manifest that the pure phosphor was committed to the space group (P21/m (11)) and features the double perovskite structure. The band gap (Eg) of the direct semiconductor NaMgLaTeO6 is calculated to be 2.065 eV. Under 388 nm excitation, the 4F9/2→6H13/2 energy level transition contributes to the maximum emission peak at 572 nm. Other properties of the phosphor include optimal concentration (x = 5 mol %), high thermal stability, activation energy (Ea = 0.31 eV), and internal quantum efficiency (IQE = 31.44 %). The relevant color coordinate of the white light emitting diode (w-LED) prepared by the phosphor is (0.298, 0.311). The features of the latent fingerprint (LFP) created by NaMgLaTeO6:Dy3+ can be clearly reflected on different surfaces. In summary, NaMgLaTeO6:Dy3+ phosphor has proven high potential in w-LEDs production and LFP detection.

Probing variation of the structure and electrical conductivity of functionalized PVA based composite films doped with silver nanoparticles and irradiated by gamma rays

Polyvinyl alcohol/sulfuric acid/ethanol films doped with nano-silver particles are prepared using in-situ chemical reduction method. The as-prepared films are irradiated with gamma rays at dose range 0–50 kGy. The elemental analysis of as-prepared samples using energy dispersive x-ray spectroscopy (EDXS) showed presence of oxygen and silver peaks which refers to the probable formation of silver oxide nano-particle (Ag2O NPs) phase. Moreover, scanning electron microscope (SEM) analysis confirmed that the inserted Ag nanoparticles have regular and uniformly distributed pores within the PVA network. X-ray diffraction (XRD) measurements indicated that of Ag2O and Ag nanoparticles are embedded in the PVA matrix in cubic face-centered structure. Structural variations due to gamma irradiation are also probed by high-resolution transmission electron microscopy (HR-TEM) which displayed that the diameter of encapsulated Ag nanoparticles increases from ∼15 nm up to 34 nm against irradiation dose. The measured dc electrical conductivity results indicated that the thermal activation energy decreased from 0.95 eV to 0.56 eV as a sequence of irradiation dose in the range 0–50 kGy The evaluation of the frequency exponent factor, s, derived from the measured ac conductivity data indicated that correlated barrier hopping (CBH) is the most probable conduction mechanism for the present films. The measured dielectric constants and Cole-Cole diagrams are employed in the analysis of the dependence of the dielectric constant on the irradiation dose.

Partially Bio-Based and Biodegradable Poly(Propylene Terephthalate-Co-Adipate) Copolymers: Synthesis, Thermal Properties, and Enzymatic Degradation Behavior.

A series of partially bio-based and biodegradable poly(propylene terephthalate-co-adipate) (PPTA) random copolymers with different components were prepared by the melt polycondensation of petro-based adipic acid and terephthalic acid with bio-based 1,3-propanediol. The microstructure, crystallization behavior, thermal properties, and enzymatic degradation properties were further investigated. The thermal decomposition kinetics was deeply analyzed using Friedman's method, with the thermal degradation activation energy ranging from 297.8 to 302.1 kJ/mol. The crystallinity and wettability of the copolymers decreased with the increase in the content of the third unit, but they were lower than those of the homopolymer. The thermal degradation activation energy E, carbon residue, and reaction level n all showed a decreasing trend. Meanwhile, the initial thermal decomposition temperature (Td) was higher than 350 °C, which can meet the requirements for processing and use. The PPTA copolymer material still showed excellent thermal stability. Adding PA units could regulate the crystallinity, wettability, and degradation rate of PPTA copolymers. The composition of PPTA copolymers in different degradation cycles was characterized by 1H NMR analysis. Further, the copolymers' surface morphology during the process of enzymatic degradation also was observed by scanning electron microscopy (SEM). The copolymers' enzymatic degradation accorded with the surface degradation mechanism. The copolymers showed significant degradation behavior within 30 days, and the rate increased with increasing PA content when the PA content exceeded 45.36%.

Thermal stability and thermal degradation kinetics of urea-formaldehyde resin modified by sodium lignosulfonate

ABSTRACT In this paper, an environmentally friendly urea-formaldehyde resin (UF) was prepared by using sodium lignosulfonate (SL) as a modifier. According to the basic properties of the resin, the strength of the plywood and the formaldehyde emission, the optimum addition amount of SL was determined. At the same time, the thermal curing and thermal degradation behavior of the resin were studied. The results show that the addition of SL can significantly reduce the formaldehyde emission of plywood. When the addition amount of SL was 1%, the wet bonding strength and formaldehyde emission of SL-modified UF (SL-UF) resin were 1.28 MPa and 0.35 mg·L−1, respectively, which were 23% higher and 71% lower than those of UF resin. Moreover, the initial curing temperature of SL-UF resin is lower, but the thermal curing activation energy is higher. SL also has a significant effect on the thermal degradation performance of UF resin. SL is a modifier that can effectively improve the performance of UF.

Rational growth of highly luminescent CsPbBr3 nanoparticles via alkali metal doping-enabled modification of glass networks

Embedding halide perovskite nanoparticles (NPs) into glasses can be regarded as a feasible approach to improve their long-term stability when they are exposed to air or moisture. However, it remains elusive to rationally grow highly luminescent halide perovskite NPs owing to poor understanding of the relationship between glass network topology and NP precipitation. Here, by introducing alkali metal ions as “B-phase structural scissors”, the precipitation and aggregation of NPs are optimized based on glass network topology modulation, which boosts their photoluminescence performance. After Li doping, the photoluminescence quantum yield of CsPbBr3 perovskite NPs embedded in glass increases by 39% with respect to that of the undoped counterpart. The alkali metal ions are utilized to reduce thermal activation energy from 130.04 KJ mol-1 to 125.35 KJ mol-1 according to thermodynamics analysis, which corresponds to an increase in the size of the NPs. Benefiting from excellent chemical inertness, the luminescence intensity of as-made CsPbBr3 NP embedded glass retains near unity after soaking them in water for 180 days. The utilization of alkali metals as a facile strategy to modify the glass network enables improved performance of target NPs, thereby providing deeper insights into the design of host-dependent NP-functionalized glass.