Diverse biomass sources from the Canary Islands (vineyard, tomato plant residues, Canary pine needles and Pennisetum setaceum) were assessed due to their local abundance, availability, and low supply cost. Based on their physico-chemical properties, various thermochemical processes were conducted to assess their thermal degradation behaviour, using simultaneous thermal analysis, and their potential for energy production. The results indicate that while tomato plant biomass is unsuitable for thermochemical processes because of its elevated ash content and limited volatile matter, the other biomass sources show promising potential for pyrolysis and gasification, characterized by high fixed carbon content and reactivity. The yearly production of residual biomass in the Canary Islands was quantified at 87,253 tonnes. This biomass could generate an estimated 88.5 GWh of electricity annually. Considering that electricity consumption in the Canary Islands reached 8750 GWh in 2023, biomass-derived electricity could contribute approximately 1.0 % to the archipelago's energy needs. These findings highlight the significant role of local biomass resources in advancing renewable energy goals and reduce dependence on non-renewable sources, promoting a greener energy landscape for the Canary Islands.