In this work, water-based magnetic Multi-walled Carbon Nanotube Phase Change Material and Copper Metal Foam (MWCNT PCM-CMF) were combined to improve the performance in ice thermal energy storage. The effect of concentration of magnetic MWCNT, porosity and pore density of CMF and magnetic field intensity on the thermal cycle characteristics including supercooling degree, solidification/melting time, cold storage/release capacity and cold storage/release rate were studied. The results indicated that the optimal magnetic field intensity corresponding to the optimal thermal cycle characteristics decreases with the increased concentration of magnetic MWCNT. Moreover, the addition of magnetic MWCNT-CMF significantly accelerates the solidification process, which is dominated by heat conduction. Although the cold storage capacity of composites was ∼ 94% of pure water, the time required for cold storage was ∼ 52% of pure water as well as the cold storage rate was improved by ∼ 80%. The melting behavior is further improved by arranging gradient CMF. As a result, the combination of 0.04 wt% magnetic MWCNT under 75 mT magnetic field and CMF with 10/5 pore per inch (PPI) gradient pore density at 95% porosity has 86.8% reduction in supercooling degree, 39.8% advance in complete cycle time and the mean rate of energy storage/release is 1.52 times than pure water.
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