Relative Thermal Conductivity Research Articles

Assessment of thermochromic phantoms for characterizing microwave ablation devices.

Thermochromic gel phantoms provide a controlled medium for visual assessment of thermal ablation device performance. However, there are limited studies reporting on the comparative assessment of ablation profiles assessed in thermochromic gel phantoms against those in ex vivo tissue. The objective of this study was to compare microwave ablation zones in a thermochromic tissue-mimicking gel phantom and ex vivo bovine liver and to report on measurements of the temperature-dependent dielectric and thermal properties of the phantom. Thermochromic polyacrylamide phantoms were fabricated following a previously reported protocol. Phantom samples were heated to temperatures in the range of 20°C-90°C in a temperature-controlled water bath, and colorimetric analysis of images of the phantom taken after heating was used to develop a calibration between color changes and the temperature to which the phantom was heated. Using a custom, 2.45GHz water-cooled microwave ablation antenna, ablations were performed in fresh ex vivo liver and phantoms using 65W applied for 5min or 10min (n=3 samples in each medium for each power/time combination). Broadband (500MHz-6GHz) temperature-dependent dielectric and thermal properties of the phantom were measured over the temperature range of 22°C-100°C. Colorimetric analysis showed that the sharp change in gel phantom color commences at a temperature of 57°C. Short and long axes of the ablation zone in the phantom (as assessed by the 57°C isotherm) for 65W, 5min ablations were aligned with the extents of the ablation zone observed in ex vivo bovine liver. However, for the 65W, 10min setting, ablations in the phantom were on average 23.7% smaller in the short axis and 7.4 % smaller in the long axis than those observed in ex vivo liver. Measurements of the temperature-dependent relative permittivity, thermal conductivity, and volumetric heat capacity of the phantom largely followed similar trends to published values for ex vivo liver tissue. Thermochromic tissue-mimicking phantoms provides a controlled, and reproducible medium for comparative assessment of microwave ablation devices and energy delivery settings. However, ablation zone size and shapes in the thermochromic phantom do not accurately represent ablation sizes and shapes observed in ex vivoliver tissue for high energy delivery treatments (65W, 10min). One cause for this limitation is the difference in temperature-dependent thermal and dielectric properties of the thermochromic phantom compared to ex vivobovine liver tissue, as reported in the present study.

Assessment of thermochromic phantoms for characterizing microwave ablation devices.

Thermochromic gel phantoms provide a controlled medium for visual assessment of thermal ablation device performance. However, there are limited studies reporting on the comparative assessment of ablation profiles assessed in thermochromic gel phantoms against those in ex vivo tissue. The objective of this study was to compare microwave ablation zones in a thermochromic tissue mimicking gel phantom and ex vivo bovine liver, and to report on measurements of the temperature dependent dielectric and thermal properties of the phantom. Thermochromic polyacrylamide phantoms were fabricated following a previously reported protocol. Phantom samples were heated to temperatures in the range of 20 - 90 °C in a temperature-controlled water bath, and colorimetric analysis of images of the phantom taken after heating were used to develop a calibration between color changes and temperature to which the phantom was heated. Using a custom, 2.45 GHz water-cooled microwave ablation antenna, ablations were performed in fresh ex vivo liver and phantoms using 65 W applied for 5 min or 10 min ( n = 3 samples in each medium for each power/time combination). Broadband (500 MHz - 6 GHz) temperature-dependent dielectric and thermal properties of the phantom were measured over the temperature range 22 - 100 °C. Colorimetric analysis showed that the sharp change in gel phantom color commences at a temperature of 57 °C. Short and long axes of the ablation zone in the phantom (as assessed by the 57 °C isotherm) for 65 W, 5 min ablations were aligned with extents of the ablation zone observed in ex vivo bovine liver. However, for the 65 W, 10 min setting, ablations in the phantom were on average 23.7% smaller in short axis and 7.4 % smaller in long axis than those observed in ex vivo liver. Measurements of the temperature dependent relative permittivity, thermal conductivity, and volumetric heat capacity of the phantom largely followed similar trends to published values for ex vivo liver tissue. Thermochromic tissue mimicking phantoms provide a controlled, and reproducible medium for comparative assessment of microwave ablation devices and energy delivery settings, though ablation zone size and shapes may not accurately represent ablation sizes and shapes observed in ex vivo liver tissue under similar conditions.

Influence of curing agent modified BN with different molecular structures on the heat conduction and electrical insulation property of epoxy composites

AbstractBoron nitride (hBN) serves as an outstanding high‐performance polymer organic filler. However, its hexagonal crystal structure renders it chemically inert, thus limiting its applications. This study proposes the modification of hBN using economical amine and anhydride curing agents to reduce aggregation and enhance the heat conduction of epoxy resin. Specifically, the DETA curing agent and methyl tetrahydrophthalic anhydride (MTHPA) curing agent were grafted onto the hBN surface via ball milling and eco‐friendly water scrubbing processes. Subsequently, the modified functionalized BNNS were uniformly dispersed in epoxy resin via a wet process to form composite materials. Results indicate that both modified fillers maintain good dispersion at the epoxy interface. Compared to epoxy resin, the heat conduction of the EP/MTHPA‐BNNS composite material with 10 vol% loading increased by 212%. The EP/DETA‐BNNS composite exhibited a relative thermal conductivity enhancement of 191%. Moreover, both of materials demonstrated significantly improved thermal stability, with slightly reduced breakdown strength. Mechanical property testing revealed a maximum increase of 187.5% in fracture elongation.Highlights Comprehensive study on curing agent modified hBN High dispersion of BNNS after wet ball milling Modified BNNS improves composite interface properties The thermal conductivity increases twice under 10 wt% BNNS loading Composite materials with outstanding electrical insulation and high fracture elongation

Microstructure and properties of tungsten‐40 wt.–% copper composites fabricated by binder jet 3D printing

AbstractIn this work, the tungsten‐copper composites were fabricated by binder jet 3D printing technology. The effects of different printing layer thicknesses (50 μm to 100 μm) on the green density and green strength were investigated. Then, under the optimal layer thickness, the effects of different sintering temperatures (1300 °C to 1600 °C) on the microstructure and densification of tungsten‐40 wt.–% copper composites were studied. The experimental results showed that when the printing layer thickness was set as a lower value (50 μm), the tungsten‐40 wt.–% copper green part had the best strength and its density reached a maximum value of 60.73 %. After sintering for green parts printed with 50 μm layer thickness, the relative density, thermal conductivity and electrical conductivity of sintered parts first increased and then decreased with increasing sintering temperature. In our experiments, the tungsten‐40 wt.–% copper sample fabricated by binder jet 3D printing with a printing layer thickness of 50 μm under a sintering temperature of 1500 °C displayed the best properties, in which the relative density, thermal conductivity and electrical conductivity were 97.04 %, 228 W⋅m−1⋅K−1 and 46.5 % IACS, respectively.

A unified hybrid micromechanical model for predicting the thermal and electrical conductivity of graphene reinforced porous and saturated cement composites

Graphene fillers have gained widespread attention as functional reinforcements for cement composites due to their excellent physical properties. The prediction of the thermal and electrical properties of graphene reinforced cement composites (GRCCs) is of great importance for developing intelligent and multifunctional civil engineering materials and structures. In this current work, a unified hybrid micromechanical model combining effective medium theory (EMT) and Mori-Tanaka-Benveniste (MTB) is developed to simultaneously predict the thermal and electrical conductivity of the GRCCs with considering pores and saturation, in which mechanisms including phonon transport, electron tunnelling and Maxwell-Wagner-Sillars (MWS) polarization are incorporated. Graphene nanoplatelets (GNPs) reinforced cement composites (GNPRCCs) samples are prepared and tested to validate the developed unified model. The results show that the electrical conductivity of the GNPRCCs is more sensitive to saturation than the thermal conductivity. When the porosity n = 0.2 and the GNP concentration is 1 wt%, the relative thermal and electrical conductivity increases by 5 % and 193 %, respectively, when the saturation index increases from 0.6 to 1. Elongated pores are more favorable for the formation of ionic networks for electrical conductivity in the saturated GNPRCCs, while spherical pores are more beneficial for heat transport. Elongated graphene fillers are preferred for enhancing both the thermal and electrical conductivity of dry and saturated GNPRCCs. The work is envisaged to provide guidelines for developing multifunctional cement composites.

A Comment on the Utility of Nanofluids: Interactive Influence of Nanoparticle Size and Amount at Varying Temperatures

Interactive influence of nanoparticle diameter, dp and volumetric fraction, φ on major thermophysical characteristics of relative thermal conductivity, kr and dynamic viscosity, μr of nanofluids as a primary function of temperature, T is determined to assess the utility of nanofluids. In the case study common base fluids of water (W) and ethylene glycol (EG) are used. Spherical shape Ag and Al2O3 with a selected dp range of (20–100 nm) are used in the covered φ range of (0.25–5%). Influence of T is set by considering T = 293 K and T = 323 K. The referred data ranges are applied for the calculation of kr and μr of nanofluids Ag–W, EG and Al2O3–W, EG in reference to a calculation procedure provided previously by the authors. The calculated magnitudes of kr and μr are expressed as a function of dp, φ and T. The results reveal that kr and μr rise dramatically as dp decrease from 40 nm to 20 nm and φ increase from 2% to 5% at T = 293 K and T = 323 K. The calculations confirm the relevant literature that the required pumping power increase is associated with low dp and high φ. Therefore, here exists limiting magnitudes of dp, φ as a function of T for the effective utilization of nanoparticles in base fluids. In order to generalize the fact non-dimensional parameters of Prandtl Number, Pr and Reynolds Number, Re should be referred due to the definitions of each depend on thermophysical characteristics and the cited dp, φ and T. The calculations herein have the validity range of Re and Pr of base fluids as 0.0002–0.032 and 3.58–210.30, respectively.

Thermo-capillarity of immiscible binary fluids within serpentine micro-confinements

The thermocapillary flow of multiple liquid layers over contoured substrates finds applications in many industrial phenomena via micro-electromechanical systems/nano-electromechanical systems devices. This study theoretically explores the thermocapillary transport of binary-liquid layers in a wavy microchannel with serpentine wall profiles. Sinusoidal profiles are considered for the microchannel walls' temperature and surface topology. Patterned slip conditions at the walls are also accounted for in the analysis to make the problem more realistic. We semi-analytically solve the energy and momentum equations to understand the system's thermal and hydrodynamic characteristics for the limiting conditions of Ma, Re, and Ca. The leading- and higher-order solutions of the temperature and flow field are separately shown to demonstrate the advection terms' contribution to the transport equations. The circulatory flow obtained due to periodic thermal stimuli can be used to enhance the mixing efficiency of the system. We also present how the parameters like phase difference between the thermal stimulus, relative thermal conductivity, and relative film thickness ratio of the liquid layers can be altered to control the flow characteristics to obtain the most potent thermocapillary effect.

Multiscale modelling for the thermal transport behaviour of ceramic matrix composites with hierarchical structures

Ceramic matrix composites contain many initial defects due to their “ceramic” properties and process characteristics, which presents challenges for the accurate prediction of their material equivalent properties. In this paper, multiscale and high-fidelity modelling of fibre-reinforced C/SiC composites are carried out on a “macro-meso-micro” cross-scale, and the thermal conductivity and relative thermal conductivity of multilevel structure composites based on a hierarchical multiscale model are proposed. The influence laws of SiC porous matrix, carbon fibre volume fraction and temperature on the thermal conductivity of composite materials are given. These findings provide useful insights into equivalent computational methods for material properties under the defect growth of thermomechanical loading.

Novel B4C[sbnd]TiB2 composites with high electrical and low thermal conductivity by selective grain growth in reactive sintering

High electrical conductivity and low thermal conductivity are beneficial for the electrical discharge machining performance of ceramics. In this work, B4C–TiB2 composites were prepared by spark plasma sintering of B4C–TiC–B powder mixture. The chemical reaction between TiC and B, together with subsequent selective matrix grain growth, expelled small in-situ generated TiB2 grains to form conductive interlayers around large B4C grains. The unique microstructure significantly enhances the electrical conductivity of B4C–TiB2 composites, especially at low TiB2 content, while the ultrafine in-situ formed TiB2 grains endow the composites with low thermal conductivity. The effects of TiB2 content on the microstructure, mechanical properties, thermal & electrical conductivity of the composites were investigated. B4C–20 vol% TiB2 composite exhibits excellent comprehensive performance, including a relative density, Vickers hardness, flexural strength, fracture toughness, room electrical and thermal conductivity of 98.6%, 28.15 GPa, 656 MPa, 5.46 MPa⋅m1/2, 1.08 × 105 S/m and 19.37 W/m⋅K, respectively.

Field-assisted sintering of low-temperature thermoelectric material BiTeSe - sintering process and part characterisation

Field-Assisted Sintering Technology (FAST), an advanced consolidation technique, was employed to synthesise low-temperature thermoelectric n-type Bi2Te2.7Se0.3 for energy harvesting applications. A systematic investigation of sintering parameters, including pressure, temperature, holding time, and heating rates, was conducted to optimise the material’s properties. Post-sintering characterisation encompassed measurements of relative density, thermal conductivity, electrical resistivity, and Seebeck coefficient. Factor analysis revealed the hierarchical influence of sintering variables, with temperature emerging as the most critical parameter, followed by pressure and holding time. The study successfully identified optimal FAST sintering conditions for Bi2Te2.7Se0.3, resulting in enhanced thermoelectric properties. This research demonstrates the efficacy of FAST in producing high-quality, low-temperature thermoelectric materials and provides valuable insights into the relationship between processing parameters and material performance.

Hybrid knitted fabric for electromagnetic radiation shielding: thermo-physical properties

Textile materials for protection against electromagnetic radiation are used now not only for special purposes but in everyday clothing too. In this regard, the thermo-physical properties of such materials are very important. In this study, the hybrid knitted fabrics with electromagnetic shielding properties manufactured on 8E flat-bed machine from 0.12 mm stainless steel wire and 30 × 2 tex cotton yarn have been tested. Fabric samples differ by variant of stainless steel wire incorporation (separately or along with cotton yarn) and their positioning in the structures (loop and/or tuck). Hybrid fabric formed by the alternation of two courses of rib 1 × 1 from cotton yarn and two courses from steel wire has higher porosity and therefore higher relative water vapor permeability and lower thermal conductivity compared with fabric formed from cotton yarn and a steel wire simultaneously. The research results showed that the introduction of stainless steel wire along with cotton yarn into the knitted structure leads to changes in stitch density and therefore in the area of porosity compared with cotton fabric. The thermal conductivity coefficient and evaporative resistance of these fabrics are similar to cotton 1 + 1 rib fabric. Thus, the studied hybrid knitted fabrics with shielding properties against electromagnetic radiation can be recommended for clothing manufacturing. The half-Milano rib fabric knitted from cotton yarn and a steel wire with the greatest electromagnetic interference shielding effectiveness has a good level of comfort similar to cotton fabric.

Enhancing cryogenic thermal conductivity of epoxy composites through the incorporation of boron nitride nanosheets/nanodiamond aerogels prepared by directional‐freezing method

AbstractIn the realm of electronic circuits, materials with high thermal conductivity are sought after as ideal packaging components. It is crucial that such materials not only possess excellent thermal conductivity, but also maintain desirable dielectric properties. To this end, boron nitride nanosheets (BNNS) and BNNS/nanodiamond (ND) aerogels with a three‐dimensional (3D) structure using the ice‐template method were prepared. Subsequently, these aerogels were utilized as a framework to produce 3D‐BNNS/epoxy and 3D‐BNNS/ND/epoxy composites via the vacuum‐assisted impregnation method, which exhibit enhanced anisotropic thermal conductivity. Furthermore, the thermal conductivity exhibited by the 3D‐BNNS/epoxy composites outperforms those containing randomly distributed BNNS. The experiment also reveals sintering the aerogel at elevated temperatures to remove the PVA can significantly improve the thermal conductivity exhibited by the 3D‐BNNS/epoxy and 3D‐BNNS/ND/epoxy composites. Importantly, the 3D‐BNNS/ND/epoxy composites illustrate exceptional thermal conductivity values of 1.326 W/(m·K), indicating a remarkable synergistic effect of BNNS and ND in improving thermal conductivity. It is noteworthy to state that the relative thermal conductivity ratio of the 3D‐BNNS/epoxy and 3D‐BNNS/ND/epoxy composites to pure epoxy resin was markedly higher at lower temperatures than the values measured at room temperature, signifying their superior heat transfer performance at lower temperatures. In addition, the composites depict excellent dielectric properties and lower coefficients of thermal expansion values. Finally, the 3D‐BNNS/ND/epoxy composites also have significantly improved Tg (132.5 and 152.6°C). The high‐performance polymer composites described in this study are envisaged for implementation within the realm of electronic packaging materials.

Wavy Marangoni effect and strategic slip-pattern-driven species transport in micro-confined sandwiched liquid films

In microfluidic systems, analyte/reagent mixing is essential to achieve rapid chemical/biochemical reactions. The low Reynolds number (Re) flow, however, makes passive mixing difficult and necessitates the use of some external stimulus to cause disturbance in the system. Here, we report how a periodic thermocapillary effect may interact with strategically patterned wall wettability and boost the mixing dynamics in a micro-confined ternary-liquid film system. Approximate, yet without compromise on the physics involved, analytical solutions to the energy and Navier–Stokes equations under creeping flow conditions are obtained to comprehend the thermal and hydrodynamic characteristics of the thermo-capillarity. In the binary fluid limit, our model is validated with the findings of Pendse & Esmaeeli (Intl J. Therm. Sci., vol. 49, 2010, pp. 1147–1155), and good agreement is found. The flow characteristics in the ternary-liquid system due to discrete wall temperatures is also demonstrated via finite-element-based numerical simulations, and agreement with the semi-analytical solution is noted. The qualitative study of the flow pattern reveals that enhanced mixing is obtained as a result of vortical motion created by the interplay of the periodic thermo-capillarity-driven interfacial flow and wall slip. The observation is further consolidated from the numerical simulation of the species transport equation. The species distribution so obtained is compared with fully developed laminar flow for the same inlet concentration. Our study further investigates the effects of the fluids’ relative thermal conductivity, wall slip length, relative film thickness and thermal (or slip) phase differences on the mixing efficiency of the proposed arrangement. While wall slip, relative film thickness and relative thermal conductivity regulate mixing in the top and bottom layers, phase difference determines how well the middle fluid layer mixes. Slip at the walls creates vortex distortions to get a strong churning effect. The lower thermal conductivity of the top and bottom fluids weakens the thermocapillary flow; however, the dominance of the patterned slip improves mixing in such cases.

Predicting the temperature field of thermal cloaks in homogeneous isotropic multilayer materials based on deep learning

Thermal cloaks can realize thermal manipulation and have been widely applied in the engineering field. Traditional methods, like the finite element method (FEM) and finite difference method, obtain the temperature of the thermal cloak with time-consuming. A deep learning model is proposed to predict the temperature field in homogeneous isotropic multilayer materials. The FEM is applied to solve the thermal cloak and the training data are obtained. The layer's properties, including different layers, thickness, relative thermal conductivities and distribution modes, of the thermal control or manipulative ability for temperature and heat diffusion are also investigated. The deep learning mode is developed by mapping the parameters layout to the temperature field as an image-to-image regression task and the relationship between the layer's properties and the cloaking performances is intelligently established. The temperature field of the arbitrary layout composite can be acquired almost with no time cost. The temperature field with the largest node numbers of medium temperature by the FEM and the deep learning model, is exhibited and compared. Furthermore, we extend the surrogate model to different cases with different boundary conditions, which can still achieve good prediction results. Owing to the high efficiency and complete independence from the mesh densities, the proposed method offers a novel and robust technique for predicting the temperature field and suggestion for the design of the thermal cloak.

Marangoni Flows in a Bilayer Liquid Microfilm Interface on Wave-Contoured Hot Substrates.

This study explores the thermal Marangoni hydrodynamics in an immiscible, binary-liquid thin-film system, which is open to the gas phase at the top and rests on a heated substrate with wavy topology. The sinusoidal contour of the heated (constant-temperature) substrate results in temperature gradients along the liquid-liquid and liquid-gas interfaces, causing fluctuations in the interfacial tension, ultimately leading to Marangoni hydrodynamics in the liquid-liquid films. This type of flow is notable in liquid film coatings on patterned surfaces, which are widely used in MEMS/NEMS applications (Weinstein, S. J.; Palmer, H. J. Liquid Film Coating: Scientific Principles and Their Technological Implications; 1997, pp 19-62; Palacio, M.; Bhushan, B. Adv. Mater. 2008, 20, 1194-1198) and biological cell sorting operations (Witek, M. A.; Freed, I. M.; Soper, S. A. Anal. Chem. 2019, 92, 105-131). We solve the coupled Navier-Stokes and energy equations by the perturbation technique to obtain approximate analytical solutions and an understanding of the thermal and hydrodynamic transport in the system domain. Our study explores the parametric influence of the relative thermal conductivity of the liquid layers (k), film thickness ratio (r), and the system's Biot number (Bi) on these transport phenomena. While the strength of the thermal Marangoni effect that is generated reduces with an increase in the relative thermal conductivity (k), the impact of r depends on the k value. We observe that for k > 1 the intensity of Marangoni flow increases with r; however, the opposite holds for k < 1. Furthermore, larger values of Bi induce higher resistance to the vertical conduction from the wavy substrate compared to the convection resistance offered at the top surface, destructively interfering with the ability of the patterned substrate to generate interfacial temperature fluctuations and hence weakening the Marangoni flow.

Artificial intelligence optimization and experimental procedure for the effect of silicon dioxide particle size in silicon dioxide/deionized water nanofluid: Preparation, stability measurement and estimate the thermal conductivity of produced mixture

Recent studies for nanofluids, did not pay enough attention to the effect of the nanoparticle size and nanofluid stability on the heat transfer rate. In this study, the thermal conductivity (TC) coefficient of silica/deionized water (DW) nanofluid with various sizes of nanoparticles and various rates of nanofluid stability was investigated. Validation experiments, including X-Ray diffraction analysis (XRD), FE-Scanning Electron Microscopy (FE-SEM), Dynamic Light Scattering (DLS), and Zeta Potential (Zp), were carried out to examine the particle sizes and the nanofluid stability. The results illustrated that increasing the temperature leads to the augmentation of the TC coefficient of the SiO2/deionized water in all nanoparticle sizes and all volume concentrations. Also, increasing the volume concentration of the nanofluid leads to the augmentation of the TC coefficient of the nanofluid in all nanoparticle sizes and all temperatures. Eventually, increasing the nanoparticle sizes causes the TC coefficient of the nanofluid to be decreased in all volume concentrations. For the 11 nm nanoparticle size, the amount of the Relative TC (RTC) coefficient enhancement by increasing the temperature was 1.2%, 2.5%, 4.7%, and 6.8% for concentrations of 0.0.1%, 0.1%, 0.5%, and 1%, respectively. For the 50 nm nanoparticle size, this enhancement was from 0.7% to 6.5%, and for the 70 nm nanoparticle size, it was from 0.5% to 5.7%. Finally, Artificial Intelligence (AI) optimization was done to find the optimized size and stability.

Shape retention of W-30Cu composites prepared by 20 wt% Cu melt infiltration into W-10Cu green parts made via BJ3DP

In this work, W-30Cu, W-10Cu, and W green parts were fabricated using BJ3DP, and then 0 wt% Cu, 20 wt% Cu, and 30 wt% Cu were infiltrated to prepare W-30Cu composites, respectively. The effects of Cu infiltration content (0–30 wt%) on the shape retention and properties of W-30Cu composites were studied. The experimental results showed that when the Cu infiltration content was 20 wt%, the W-30Cu composite prepared by 20 wt% Cu melt infiltration into W-10Cu green part had the best shape retention, its shrinkage was within 0.5%, and the relative density and thermal conductivity were 97.75% and 218 W·m−1·K−1, respectively. In this work, a high-shape-retention W-30Cu composite was obtained by treating W-10Cu green part prepared by BJ3DP using a combination of sintering technology and infiltration technology, while also providing a high-shape-retention method for other composites.

Tailoring porosity and pore structure of cellular geopolymers for strength and thermal conductivity

Cellular geopolymer is produced by entraining air in alkali-activated low calcium fly ash (AAF) paste. Rheology control with the use of Bentonite clay and surfactant creates stable aeration on adding Aluminum powder to AAF paste. The clay provides yield stress control in the AAF paste that is required for retaining the bubbles in the suspension. The surfactant is used to prevent the coalescence of the air bubbles in the AAF paste that produces a homogenous void network in the cellular geopolymer. The viscosity of the AAF paste is determined by the silica content and modulus (molar ratio of SiO2/Na2O) of the activating solution. Process variables such as Aluminum powder content and size, clay and surfactant dosages and composition of activating solution are considered to tailor the porosity and pore size in the cellular geopolymer. The total porosity of the cellular geopolymer depends on the viscosity of the AAF paste, which is controlled by the silica content and modulus of the activating solution. The mean pore size and its distribution depend on the Aluminum powder size. The mean pore size decreases with an increase in yield stress of the AAF paste and a decrease in the surface tension. Cellular geopolymer with density lower than 1000 Kg/m3 with thermal conductivity in the range of 0.25–0.20 W/m.K and compressive strengths of 11.5 to 8.5 MPa are produced by controlling the process variables. The strength of the cellular geopolymer depends on the mean pore size in addition to the total porosity. The thermal conductivity is dependent only on the total solidity and hence on the total porosity and is not affected by the pore size distribution. The existing models used for predicting the strength and thermal conductivity in relation to porosity and pore characteristics are explored and modifications are proposed for cellular geopolymers.

Enhanced thermal conductivity of Si3N4 ceramics through pyrolytic carbon prepared by gel casting using DMAA

To reduce the lattice oxygen content of Si3N4 green bodies, samples were prepared using an N,N-dimethylacrylamide (DMAA) system. The endothermic and exothermic peaks are related to the decomposition of organic matter and the reaction between pyrolytic carbon and impurity oxides in the sintering process. Multi-step heat preservation during the thermal degreasing process reduced the carbon content and defects. The α→β phase transformation and aspect ratio of grains changed from 89.2% to 4.84:1 at 1640 °C to 96.3% and 7.80:1 at 1700 °C, respectively. The relative density, hardness, fracture toughness, and thermal conductivity of the Si3N4 samples reached 98.5%, 1353 HV, 8.51 MPa·m1/2, and 97.1 W·m−1·K−1, respectively. Pyrolytic carbon can react with SiO2, which reduces the content of the glass phase in the green body and affects the dissolution and precipitation process and lattice oxygen content. In the structure of the Si3N4 sample, carbon particles with sizes of 100–500 nm and near-spherical shapes were observed. Intergranular-phase YMgSi2O5N was formed during the sintering process, which was conducive to improving the thermal conductivity. This article uses lower temperature and no pressure conditions to prepare Si3N4 ceramics, which can provide reference for batch and low-cost production.

Thermal conductivity of MWCNT-TiO2/Water-EG hybrid nanofluids: Calculating the price performance factor (PPF) using statistical and experimental methods (RSM)

Scientists in chemical and mechanical engineering fields have long been interested in the thermophysical characteristics of nanofluids (NFs), and the thermal conductivity (TC) of many NFs has recently been studied. Purpose of research is to evaluate and compare two new and unique NFs using experimental methods and statistical methods (response surface methodology or RSM) to introduce one of them to the industry. In this research, hybrid nanofluid (HNF) “A” with MWCNT and TiO2(25:75) with Water-EG (80:20) formula and HNF “B” with MWCNT-TiO2(15:85)/Water-EG(50:50) formula were synthesized. Their relative thermal conductivity (RTC) was compared. Based on the findings, HNF “A” in solid volume fraction SVF = 1.12% and T = 50°C has a thermal conductivity enhancement of TCE = 36.30%, which is superior to HNF “B” with TCE = 17.90%. The price performance factor (PPF) of the analyzed HNFs has been studied and compared for the first time in this research under the same settings. In addition, the examination of economic and performance indicators shows that HNF “A” has a significantly higher PPF. As a result, it can be said that using this HNF is economical.