Abstract The recently demonstrated methods for cooling and trapping diatomic molecules offer new possibilities for precision searches in fundamental physical theories. Here, we propose to study the variations of the fine-structure constant (α=e 2/ħc) and the proton-to-electron mass ratio (μ = mp/me) with time - by taking advantage of the nearly degenerate rovibrational levels in the electronic states of the magnesium fluoride (MgF) molecule. Specifically, due to the cancellation between the fine structure splitting and the rovibrational intervals in the different MgF natural isotopes, a degeneracy occurs for the A 2Π(3/2) (v'=0,J'=18.5,-) and the A2Π(1/2) (v''=0,J''=20.5,-). We find that using the nearly degenerate energy level of such states can be 104 times more sensitive than using a pure rotational transition to measure the variations of α and μ. To quantify the small gap between the A2Π(3/2) (v'=0,J'=18.5,-) and the A2Π(1/2) (v''=0,J''=20.5,-), the special transitions of choice are feasible: the X 2Σ(1/2) + (v=0,J=19.5,+) to the A2Π(3/2) (v'=0,J'=18.5,-) and the X 2Σ(1/2) + (v=0,J=19.5,+) to the A 2Π(1/2) (v''=0,J''=20.5,-). In addition, we estimate the frequency uncertainties caused by the narrow linewidth, Zeeman shift, the Stark shift, Doppler boarding and the Blackbody radiation.
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