The aim of the work was to investigate the longitude (orbital) dependence of the polarization of Jupiter's moon Io and compare results of our study with what is reported in the literature. We used our published observations and supplemented them with new measurements carried out with the polarimeters mounted on the 2.6 m Shajn telescope of the Crimean Astrophysical Observatory and the 2 m telescope of the Peak Terskol Observatory in the UBVRI bands at phase angles between 10° and 12° in August 2023 – February 2024. We have determined that amplitude of the orbital polarization in the V band does not exceed ≈0.1 %. It is the deepest −0.17 ± 0.03 % at L ≈ 270° and the shallowest −0.07 ± 0.03 % near L ≈ 130°. These parameters differ markedly from that obtained by Zellner and Gradie (1975), which found that the orbital polarization variations from 0.4 to 0.5 % for α > 10°, and the negative branch is the deepest near L = 160° and the shallowest near L = 300°. These differences may be a consequence of changes in the reflective properties of the local areas of Io's surface due to long-term changes in Io's local or global volcanic activity.
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