In order to meet the mechanical property of the die steel, this study used laser cladding to prepare a high-entropy alloy coating on Cr12MoV. A finite element method using a double ellipsoidal heat source model is proposed to simulate the evolution of the temperature field in laser cladding. The simulation results showed that with the increase in the power, the peak temperature of the molten pool increased from 2005.5 °C to 2357.4 °C, and the depth of the molten pool increased from 1.60 mm to 2.04 mm. The coating with the laser power of 1600 W had a good macroscopic quality and high lattice distortion (2.43 × 10−2). Due to the increase in laser energy density, the size of equiaxed crystals gradually increased from 1400 W to 1700 W. Under the comprehensive effect of the solution and fine grain strengthening, the coating with the power of 1600 W had a higher average microhardness (600 HV), which is 150% higher than that of the substrate. The experiment results further confirmed the accuracy of the simulation.
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