Temperature-dependent Properties Research Articles

Golden ratio of the r+/r- for the structure-selectivity in the thermoelectric BaZn2-xCdxSb2 system

A total of five Zintl phase compounds in the solid-solution BaZn2-xCdxSb2 (0.10(2) ≤ x ≤ 2) system have been successfully synthesized by the molten Pb-flux method. Both powder X-ray and single-crystal X-ray diffraction analyses proved that the title compounds displayed the phase transition between the BaCu2S2-type phase (space group Pnma, Z = 4) and the CaAl2Si2-type phase (space group P3¯m1, Z = 1) depending on the Zn/Cd mixed ratio. Furthermore, this kind of structure selectivity was dictated by the radius ratio criterion between the cationic and the anionic elements (r+/r–): three Zn-rich compounds with the r+/r– > 1 (BaZn1.90(1)Cd0.10Sb2, BaZn1.75(2)Cd0.25Sb2, and BaZn1.62(2)Cd0.38Sb2) preferred to adopt the BaCu2S2-type phase, while two Cd-rich compounds with the r+/r– ≤ 1 (BaZn0.16(2)Cd1.84Sb2 and BaCd2Sb2) preferred to crystallize in the trigonal CaAl2Si2-type phase. A series of TB-LMTO calculations using the two hypothetical models: BaZn1.5Cd0.5Sb2 and BaZn0.5Cd1.5Sb2, proved that a resonance peak in the density of states of BaZn1.5Cd0.5Sb2 implied the enhanced Seebeck coefficient of the three Zn-rich compounds, and the reduction of band gap observed in a band structure of BaZn0.5Cd1.5Sb2 influenced the electrical conductivity of the Cd-rich BaZn0.16(2)Cd1.84Sb2. Temperature-dependent thermoelectric property measurements showed the maximum ZT of 0.54 for the quaternary BaZn1.62(2)Cd0.38Sb2, which should mainly be attributed to the reduced κtot due to the Zn and Cd disordering in the anionic frameworks.

Characterization and Application of Cyrene as a Biomass-Based Solvent for Homogeneous Heck-Coupling Reaction.

Cyrene, a renewable, non-toxic substance having negligible vapor pressure, even at high temperatures, was proposed as a reaction medium for homogeneous Pd-catalyzed Heck-coupling reactions. It was first characterized by its temperature-dependent physicochemical properties, i.e., vapor pressure, density, surface tension, heat capacity, and viscosity, the key parameters of its reaction and process chemistry. Its refractive indices in the function of temperature were also determined. Hereafter, the effect of reaction parameters (Pd source, nature of the base, the water content of the reaction mixture, leaving group (-I, -Br, -Cl, and -OTf of aromatic substrates) on Pd-catalyzed Heck-coupling reaction was investigated using iodobenzene and styrene as model substrates. Subsequently, 4-substituted iodobenzene and styrene derivatives were applied to investigate the effect of electronic parameters on the reaction efficiency and functional group tolerance. To demonstrate the applicability of the system, thirteen stilbene derivatives were isolated with good to high yields and purity (> 95%) using 0.2 mol% of Pd, 1.5 eq. of Et3N as a base, in 1 mL of Cyrene for 2 h at 100 °C.

Golden ratio of the r+/r- for the structure-selectivity in the thermoelectric BaZn2-xCdxSb2 system

A total of five Zintl phase compounds in the solid-solution BaZn2-xCdxSb2 (0.10(2) ≤ x ≤ 2) system have been successfully synthesized by the molten Pb-flux method. Both powder X-ray and single-crystal X-ray diffraction analyses proved that the title compounds displayed the phase transition between the BaCu2S2-type phase (space group Pnma, Z = 4) and the CaAl2Si2-type phase (space group P3¯m1, Z = 1) depending on the Zn/Cd mixed ratio. Furthermore, this kind of structure selectivity was dictated by the radius ratio criterion between the cationic and the anionic elements (r+/r–): three Zn-rich compounds with the r+/r– > 1 (BaZn1.90(1)Cd0.10Sb2, BaZn1.75(2)Cd0.25Sb2, and BaZn1.62(2)Cd0.38Sb2) preferred to adopt the BaCu2S2-type phase, while two Cd-rich compounds with the r+/r– ≤ 1 (BaZn0.16(2)Cd1.84Sb2 and BaCd2Sb2) preferred to crystallize in the trigonal CaAl2Si2-type phase. A series of TB-LMTO calculations using the two hypothetical models: BaZn1.5Cd0.5Sb2 and BaZn0.5Cd1.5Sb2, proved that a resonance peak in the density of states of BaZn1.5Cd0.5Sb2 implied the enhanced Seebeck coefficient of the three Zn-rich compounds, and the reduction of band gap observed in a band structure of BaZn0.5Cd1.5Sb2 influenced the electrical conductivity of the Cd-rich BaZn0.16(2)Cd1.84Sb2. Temperature-dependent thermoelectric property measurements showed the maximum ZT of 0.54 for the quaternary BaZn1.62(2)Cd0.38Sb2, which should mainly be attributed to the reduced κtot due to the Zn and Cd disordering in the anionic frameworks.

Unveiling highly sensitive Dy3+ doped BaMgAl10O17 phosphor’s thermoluminescence trap features and temperature dependent luminescence for solid state lighting applications

This article explores the structural, morphological, thermoluminescence, and temperature-dependent emission properties of novel Dy3+ doped BaMgAl10O17(BAM-Dy) phosphors. Structural studies reveal that the phosphor has a similar structure to β-alumina. Rod-shaped interlinked surface morphology is a notable characteristic of the BAM-Dy samples. Incorporation of Dy3+ ions lead to the formation of distinct emission peaks (485 nm, 577 nm, and 635 nm) in the PL emission spectra. The effect of dopant concentration on the light output is crucial, and the highest PL intensity is observed for 1.5 mol% of Dy3+ concentration. The potential use of BAM-Dy phosphors for Gamma radiation detection and measurement is tested through thermoluminescence studies, which reveal high sensitivity, low threshold dose values, and exceptional response to low gamma doses, making them suitable for dosimetry applications. The investigation of trap parameters provides useful information about the number of traps, trapping mechanism, and trap energies, which is essential for in-depth study of synthesized phosphors for γ dosimetry application. The study of the effect of temperature on the luminescence behaviour is crucial for the application of phosphors in the light-emitting field. The BAM-Dy samples exhibit excellent thermal stability even at 210 °C, making them suitable for use in the field of White LEDs.

Quantification of Charge Transport and Mass Deprivation in Solid Electrolyte Interphase for Kinetically-Stable Low-Temperature Lithium-Ion Batteries.

Graphite (Gr)-based lithium-ion batteries with admirable electrochemical performance below -20 °C are desired but are hindered by sluggish interfacial charge transport and desolvation process. Li salt dissociation via Li+-solvent interaction enables mobile Li+ liberation and contributes to bulk ion transport, while is contradictory to fast interfacial desolvation. Designing kinetically-stable solid electrolyte interphase (SEI) without compromising strong Li+-solvent interaction is expected to compatibly improve interfacial charge transport and desolvation kinetics. However, the relationship between physicochemical features and temperature-dependent kinetics properties of SEI remains vague. Herein, we propose four key thermodynamics parameters of SEI potentially influencing low-temperature electrochemistry, including electron work function, Li+ transfer barrier, surface energy, and desolvation energy. Based on the above parameters, we further define a novel descriptor, separation factor of SEI (SSEI), to quantitatively depict charge (Li+/e-) transport and solvent deprivation processes at Gr/electrolyte interface. A Li3PO4-based, inorganics-enriched SEI derived by Li difluorophosphate (LiDFP) additive exhibits the highest SSEI (4.89×103) to enable efficient Li+ conduction, e- blocking and rapid desolvation, and as a result, much suppressed Li-metal precipitation, electrolyte decomposition and Gr sheets exfoliation, thus improving low-temperature battery performances. Overall, our work originally provides visualized guides to improve low-temperature reaction kinetics/thermodynamics by constructing desirable SEI chemistry.

Development and Experimental Validation of a Two-stage Thermoelectric Heat Pump Computational Model for Heating Applications

The utilisation of thermoelectric technology as a heat pump in heating applications necessitates comprehensive investigation. The scalable nature of thermoelectric technology enables its operation at elevated temperatures without the requirement of refrigerants. In this work, an accurate computational model that can simulate one- and two-stage thermoelectric heat pumps is developed. This model uses the electric-thermal analogy and the finite difference method, including the thermoelectric effects, temperature dependent properties, thermal contact resistances and all heat exchangers, even the intermediate heat exchanger in the case of a two-stage configuration. Moreover, the model has been experimentally validated by built and tested prototypes, being the first time that a two-stage thermoelectric heat pump model is experimentally validated.The discrepancy between the simulated and experimental results is below the ± 10 % for COP, ± 8 % for generated heat and temperature lift in the airflow, and less than the ± 6 % for consumed power. Additonally, the model simulates real tendencies under different operating conditions, proving the reliability of the developed thermoelectric heat pump model.Finally, the model is used to optimise a thermoelectric system combining one- and two-stage thermoelectric heat pumps, and hybridising them with electric resistances. An airflow of 16.5 m3/h is heated from 25 °C to 160 °C, achieving a maximum COPtot of 1.21. Lastly, the importance of considering the thermal resistances of the heat exchangers is computationally modelled and demonstrated. Not taking them into account would overestimate the performance of the TEHP system by more than the 7 %.

Computational Investigation of the Influencing Parameters on the Solidification of Thermoplastic Beryllium Oxide Slurry in a Cylindrical Shell

This article presents a computational study of the influencing parameters on the solidification of the thermoplastic beryllium oxide slurry in an annular forming cavity. The main purpose of this paper is to study the effect of cooling and casting conditions on the solidification of the BeO suspension by considering the temperature-dependent rheological and physical properties. The results of calculations of the Bingham–Papanastasiou rheological model with experimental data in the intervals of phase transitions with different casting rates of beryllium ceramics have been validated. The use of the regularization parameter made it possible to approximate the flow of the slurry at all levels of its shear rates as highly viscous, followed by a continuous transition to a solid state. The speed of heat removal from the molding during the solidification period is determined by the speed of movement of the slurry and the temperature field on which the width of the transition region depends. The process of solidification of the slurry mass has been evaluated by changing its heat flow distribution and density along the length of the concentric channel. The obtained model calculation results make it possible to control the casting process and eventually realize a uniform structure of castings.

Fusarium oxysporum mediated synthesis of nitrogen-doped carbon supported platinum nanoparticles for supercapacitor device and dielectric applications

A scalable method has been developed for synthesizing nitrogen-doped carbon-supported platinum nanoparticles. Fusarium oxysporum was utilized as reducing and stabilizing agent, and calcination was employed to produce the carbon support. The unique properties of Fusarium oxysporum facilitate the reduction of metal ions while preventing agglomeration and maintaining nanoparticle stability. An extensive investigation of the electrochemical supercapacitor and temperature-dependent dielectric properties of the nanoparticles demonstrates their suitability for supercapacitor applications. Electrochemical analysis showed N-doped C/Pt NPs with high specific capacitance, 482.77F/g at 2.0 A/g, retaining 94 % capacitance even under 20 A/g after 10,000 cycles. The symmetric supercapacitor device displayed 275F/g at 2 A/g, maintaining 61.10 Wh/kg energy density at 1000 W/kg power density, with ∼ 92 % capacitance retention after 10,000 cycles. Dielectric properties of N-doped C/Pt NPs were analyzed at both ambient (300 K) and elevated (450 K) temperatures, revealing temperature-dependent characteristics and alternating current conductivity. At 0.75 MHz, the dielectric permittivity (ɛ’) was measured at 31, with tangent loss at 2.01 and a.c. conductivity at 2.597 × 10-3 O−1 m−1. Increasing the frequency to 6.0 MHz resulted in a 2.38-fold rise in dielectric permittivity and a decrease in tangent loss to 0.77, demonstrating the temperature-sensitive nature of dielectric relaxation.

Phase-field ductile fracture simulations of thermal cracking in additive manufacturing

We present a multiphysics phase-field fracture model for thermo-elasto-plastic solids in the context of finite deformation and apply it to simulate the hot cracking phenomenon during metal additive manufacturing. The model is derived in a thermodynamically consistent manner, with the intercoupling mechanisms among elastoplasticity, phase-field crack and heat transfer comprehensively considered. It involves particularly coupled parameters among these materials physics, e.g. plasticity-dependent degradation function and fracture toughness, damage-dependent yield surface and thermal properties, and temperature-dependent elastoplastic properties and fracture strength. The finite element implementation of the coupled phase-field model is benchmarked with simulations results of a tensile test of an I-shape specimen, encompassing elastoplasticity, hardening, necking, crack initiation and propagation, in contrast to the related experimental results. The validated model is further employed to simulate the multiphysics hot cracking phenomenon in additive manufacturing in the context of both the effective powder-bed model and the powder-resolved model thanks to prior non-isothermal phase-field powder-bed-fusion simulations. Simulation results reveal certain key features of the hot crack and its dependency on process parameters like beam power and scan speed, which are helpful for the fundamental understanding of crack formation mechanisms and process optimization.

Ultra-large strain response in BNT-BT-KNN thin films boosted by electric field-induced inversion of long-range ordered polarization

Bismuth sodium titanate (BNT)-based piezoelectric materials are the most promising candidates for lead-free actuator applications. With the request for integration and size miniaturization of devices, it is urgent to develop thin films for microdevices to be compatible with semiconductor processes. Through composition engineering, BNT-based thin films were fabricated on silicon substrates, with ultra-high strain response and negligible hysteresis in strain curves. The DC-dependent and temperature-dependent dielectric properties were collected to investigate the relaxor state of thin films. The structure and polarization transition and evolution as a function of electric field and time were analyzed based on the electric characterization, in-situ Raman measurements, and dynamics PFM. The reversible phase transition and polarization order-disorder transformation are the most significant features for reaching a large strain of >1.6% in BNT-based thin films.

Supramolecular self-assembling hydrogel based on imidazole/d-sorbitol deep eutectic solvent for tissue clearance

Embedding and tissue clearing with high refractive index reagents are essential for 3D tissue imaging. However, the current liquid-based clearing condition and dye environment suffer from solvent evaporation and photo-bleaching, causing difficulties in maintain the tissue optical and fluorescent features. In traditional embedding technique, paraffin is highly astigmatic and paraffin-tissue complex is opaque; CLARITY series of gel-type tissue transparency methods usually achieve cross-linking of tissue and gel network first, and then active or passive degreasing by using SDS, TritonX-100 and so on, and finally, the tissue achieves a transparent state by refractive index matching. Based on high permeability of deep eutectic solvents (DES) and the optical transparency potential of polyols, this study developed a DES self-assembled hydrogel-based copolymer to embed mouse tissue for clearing and imaging prepared with imidazole and d-sorbitol. In addition to preserving the high optic transparency of the tissue, the DES hydrogel system is compatible with multiple fluorescence labeling, particularly lipophilic dyes. This DES hydrogel system provides a unique opportunity for simultaneous tissue embedding and clearing. The self-assembled hydrogel achieves 3D imaging at a solid state, and 2D images can be obtained through slicing after 3D imaging of complete organs. Due to its temperature dependent hydrogel properties, the hydrogel-tissue complex achieves gel-sol transition and allows tissue reuse. This transparent and hydrogel condition provides a friendly tissue and cellular environment to facilitate high resolution 3D imaging, preservation, transfer, and sharing among laboratories to investigate the morphologies of interest in experimental and clinical conditions.

An analytical study of thermal environment’s effect on the free vibration of FGM double curved FG shells

The main objectif of this work is to examine the thermal environment’s effect of on the free vibration of double curvature shells made of functionally graded materials. A new mathematical model based on higher order shear deformation theory, is developed to incorporate the influence of dependent and independent thermal stresses, which can be uniform, linear, nonlinear, or sinusoidal on the mechanical properties of the double curvature shell. Two material couples, ( S i 3 N 4 / SUS 304 , ZrO 2 /Ti‐6Al‐4V ) , are considered as progressive materials, accounting for temperature-dependent and temperature-independent heat conduction and material properties in the thickness direction. The temperature field is assumed to be uniform across the shell surface but varies only in the thickness direction. The accuracy of the analytical results is validated by comparing them with existing literature results for functionally graded material (FGM) shells with infinite radii under dependent and independent temperature conditions. The study aims to demonstrate the thermal effects on material composition, as well as various specific geometric shapes such as plates, cylinders, spheres and ellipses and how different temperature laws influence the frequencies of vibrating double curvature FGM shells. Both existing theories accurately predict temperature-independent and temperature-dependent vibration responses of the shells. By verifying and comparing the results with the literature, a better agreement is achieved, thereby paving the way for further research in this field.

An analytical study of thermal environment’s effect on the free vibration of FGM double curved FG shells

The main objectif of this work is to examine the thermal environment’s effect of on the free vibration of double curvature shells made of functionally graded materials. A new mathematical model based on higher order shear deformation theory, is developed to incorporate the influence of dependent and independent thermal stresses, which can be uniform, linear, nonlinear, or sinusoidal on the mechanical properties of the double curvature shell. Two material couples, ( S i 3 N 4 / SUS 304 , ZrO 2 /Ti‐6Al‐4V ) , are considered as progressive materials, accounting for temperature-dependent and temperature-independent heat conduction and material properties in the thickness direction. The temperature field is assumed to be uniform across the shell surface but varies only in the thickness direction. The accuracy of the analytical results is validated by comparing them with existing literature results for functionally graded material (FGM) shells with infinite radii under dependent and independent temperature conditions. The study aims to demonstrate the thermal effects on material composition, as well as various specific geometric shapes such as plates, cylinders, spheres and ellipses and how different temperature laws influence the frequencies of vibrating double curvature FGM shells. Both existing theories accurately predict temperature-independent and temperature-dependent vibration responses of the shells. By verifying and comparing the results with the literature, a better agreement is achieved, thereby paving the way for further research in this field.

A critical methodological revisit on group-contribution based property prediction of ionic liquids with machine learning

As group-contribution (GC) concept is convenient and pragmatic for predictive property modeling, exploring the limits of GC-based models by pairing different machine learning (ML) algorithms in a critical modeling procedure is of great interest. In this work, based on four temperature-dependent and two temperature-independent ionic liquid (IL) properties (viscosity, surface tension, refractive index, thermal conductivity, IPC-81 cytotoxicity, and thermal decomposition temperature), GC modeling is critically performed and analyzed by including six ML algorithms (multivariate linear regression, ridge regression, artificial neural network, support vector regression, random forest, and extreme gradient boosting). Following rigorous cross-validation, the significant effect of the point-based and IL-based dataset split schemes on modeling the four temperature-dependent properties is clearly demonstrated. The optimal algorithm for modeling each of the six IL properties is determined, wherein the effect of random dataset splits is also evaluated. Finally, the effect of molecular occurrences of group in GC modeling is proposed and exemplified.

A Four-Mode Optical Thermometer Designed in Double Perovskite Ca2GdNbO6:Bi3+,Eu3+

High-sensitive multi-mode optical thermometry has become a superstar in the temperature sensing field and attracted great attention. Herein, a novel four-mode optical thermometer is designed in Eu3+ and Bi3+ co-doped double perovskite Ca2GdNbO6. The crystal structures of the host and the doped samples were characterized with X-ray diffraction patterns and Rietveld refinements. Under the excitation of 340nm, the phosphors exhibit multiple emissions coming from Bi3+ and Eu3+. The energy transfer from Bi3+ to Eu3+ is proved in the perovskite and the transfer efficiency reaches as high as 92%. Benefiting from the different temperature-dependent photoluminescent properties of Bi3+ and Eu3+, a four-mode optical thermometer based on fluorescence intensity ratio, CIE coordinate, fluorescence lifetime, and excitation intensity ratio is realized in the Ca2GdNbO6:0.03Bi3+,0.01Eu3+ phosphor. The maximal relative sensitivities of the four modes are 1.90% K−1 at 460K, 0.514% K−1 at 500K, 2.69% K−1 at 437K, and 1.43% K−1 at 310K, respectively, most of which are higher than those of recently reported phosphors. These good thermometric performances suggest that Ca2GdNbO6:Bi3+,Eu3+ has a great potential application in temperature detection field.

Dynamic topology optimization of two-phase viscoelastic composite structures considering frequency- and temperature-dependent properties under random excitation

This article proposes an efficient optimum design method of constrained layer damping (CLD) plates characterized by non-proportional damping subjected to random excitation. Considering frequency and temperature dependence, a two-phase viscoelastic composite material composed of stiffness-phase and damping-phase materials is used as the damping layer. The pseudo excitation and hybrid expansion methods are adopted to compute the random responses at the specified frequency intervals as the objective functions. The sensitivity analysis is performed through the adjoint vector method. The similarity index is defined to distinguish the various optimal layouts quantitatively. Several numerical examples clearly demonstrate the robustness and effectiveness of the proposed method, highlighting a remarkable improvement of over 60% in computational efficiency. Furthermore, it is proved that, when subjected to broadband random excitation, the damping materials' temperature- and frequency-dependent properties are critical factors in obtaining accurate vibration responses and desirable optimal layouts. The effects of the layer thicknesses and volume fractions of composite structures on topology optimization are also discussed. The results indicate that both layer thickness and volume fraction can change the mechanical properties of the composite structure and further affect the distribution characteristics of the damping material.

Pyridyl-substituted nitronyl nitroxides: comprehensive magnetochemical and quantum chemical study.

A series of pyridyl-substituted nitronyl nitroxides was synthesized and structurally characterized. A comprehensive magnetochemical and quantum chemical study of extended raw of the nitroxides with different substituents R in the pyridine fragment was performed. It was shown, that temperature-dependent magnetic properties are determined by the short contacts between nitroxide groups of adjacent molecules as well as between nitroxide group and methyl substituents in the pseudo axial positions of imidazoline fragments. Quantum chemistry allows to select the appropriate model of exchange cluster for analysis of experimental magnetic data and evaluation of the exchange interaction parameters. For NN-PyCl the "order-disorder" transition was detected by means of low temperature XRD. The difference in the experimental and calculated exchange interaction energies may serve as an indicator of temperature-induced structural rearrangements. For instance, for methyl substituted nitronyl nitroxide NN-PyMe structural transformations and significant changes in exchange interaction energies were observed.

A double-layer light shutter consisting of polymer dispersed liquid crystal and azo dye/quantum dot

We have developed a double-layer liquid crystal light shutter and investigated its temperature dependent morphological, electro-optical, and dielectric properties. The optical layers of the shutter are in direct contact, reducing optical losses. The shutter comprises a polymer dispersed liquid crystal film adjacent to an azo dye methyl red and CdSeS/ZnS quantum dot doped cholesteric liquid crystal layer. This novel double-layer light shutter device is switchable between opaque and transparent states at room temperature, and it exhibits low threshold and saturation voltages. Both the threshold (Vth) and saturation (Vsat) voltages are found to decrease with increasing temperature. The electrical characteristics of the shutter, namely the real part of dielectric constant (ε′) and the ac conductivity (σac) also increase with temperature in the low frequency region. Our results show that this double-layer light shutter has interesting potential for simple electro-optical devices and smart window applications.

Dynamic simulation of unsteady Casson–Carreau fluid flow considering temperature-dependent variable-properties and thermo-solutal mixed convection over flat and slendering sheets

The present investigation delves into the intricate interplay between surface effects and fluid dynamics, focusing on the flow characteristics of Casson and Carreau fluids endowed with temperature-dependent thermophysical properties. Specifically, the study explores the ramifications of radiative, mixed convection, and magnetized processes on heat and mass transfer phenomena. A comprehensive mathematical model is developed to analyze the behavior of Casson–Carreau fluids in conjunction with microscopic particles and gyrotactic microorganisms over both flat and slender surfaces. Leveraging similarity transformations, the governing equations are transformed into dimensionless form, facilitating numerical solutions using the bvp5c solver in MATLAB. The ensuing numerical and graphical analyses elucidate key physical quantities, including local skin friction coefficients, gyrotactic microorganism density, Nusselt number, and Sherwood number, across a spectrum of physical parameters. Notably, the investigation underscores the profound influence of flat surfaces on flow patterns and highlights the heightened consumption of fluid particles with increasing variable diffusivity and thermal conductivity. Moreover, enhanced values of parameters such as variable motile microorganism diffusion coefficient, Brownian motion parameter, and temperature-dependent thermal conductivity parameter are found to augment the Nusselt number, indicative of intensified heat transfer rates. This research underscores the imperative of comprehending the intricate dynamics of fluid flow and heat transfer, offering actionable insights for enhancing engineering designs and addressing multifaceted challenges across domains encompassing chemical engineering, environmental science, and biomedical applications.

Influence of ice properties on wave propagation characteristics in partially frozen soils and rocks: a temperature-dependent rock-physics model

A better understanding of the temperature effects on the propagation characteristics of elastic waves in frozen soils and rocks is imperative for accurately quantifying their freezing degrees. While existing rock-physics models based on the three-phase Biot (TPB) theory adeptly interpret observed velocity versus temperature (VVT) curves, they often lack a comprehensive understanding of the mechanisms underlying attenuation versus temperature (AVT) curves. In this study, we first extend the TPB theory to incorporate the temperature-dependent properties of ice, including changes in volumetric fraction, morphology, and viscoelasticity, by integrating relevant thermodynamic laws. Model parameters related to ice properties and interactions, such as rigidity, shear moduli, density, and friction, are redefined. Then, using a numerical rock-physics modeling approach, we examine influential factors and modes of wave VVT and AVT responses. Our results show that both P- and S-wave velocities increase with source frequency, consolidation degree, and frame-supporting ice content, while decreasing with temperature and pore-floating ice content. Both P- and S-wave attenuation factors increase with frame-supporting ice content and decrease with consolidation degree. Rising temperatures tend to amplify the peak magnitude of P-wave attenuation factors and shift the central frequency of S-wave attenuation factors. Finally, within a temperature-controlled laboratory environment, we conduct ultrasonic wave transmission testing on brine-saturated sediment and rock specimens. Results demonstrate that as the temperature increases from –15 to –3 °C, both the P- and S-wave velocities decrease, while the P-wave attenuation factors decrease and the S-wave attenuation factors initially rise before declining. Our viscoelastic TPB theory outperforms existing ones in interpreting S-wave AVT observations. This temperature-dependent rock-physics model holds promise for interpreting sonic logging data in time-lapse monitoring of permafrost, glaciers, and Antarctica.